Weekly Test

Section – Chemistry
Topic – P Block and Basic Chemical Equilibrium
Q1. In diborane :
(a) four 2𝑐 − 2𝑒 − bonds and four 3𝑐 − 2𝑒 − bonds are present.
(b) four 2𝑐 − 2𝑒 − bonds and two 3𝑐 − 2𝑒 − bonds are present.
(c) two 2𝑐 − 2𝑒 − bonds and four 3𝑐 − 2𝑒 − bonds are present.
(d) two 2𝑐 − 2𝑒 − bonds and two 3𝑐 − 2𝑒 − bonds are present.

Q2. Which of the following statement is correct:

(a) Boron and Aluminium halides behave as Lewis acids
(b) Al forms [AlF6 ]3− ion but B does not form [BF6 ]3− ion
(c) The p𝜋 − p𝜋 back bonding occurs in the halides of boron and not in those of
aluminium
(d) All of these

Q3. Which of the following is least likely to behave as Lewis base?

(a) OH −
(b) H2 O
(c) NH3
(d) BF3

Q4. In borax bead test which compound is formed?

(a) Orthoborate
(b) Metaborate
(c) Double oxide
(d) Tetraborate

Q5. Dimer 𝐀𝐥2 𝐂𝐥6 is formed because

(a) Al is electron rich
(b) Aluminium is having lone pair of electron
(c) Aluminium forms coordinate bonds with chlorine to complete its octet
(d) Aluminium donates lone pair to form bridge

Q6. When we heat borax strongly then it will yield the following compound
(a) NaBO2
(b) B2 O3
(c) Na2 B4 O7
(d) Both (a) & (b)

Q7. In diborane each boron forms

(a) Two bonds
(b) Three bonds
(c) Four bonds
(d) Five bonds

Q8. Group 14 elements have general electronic configuration

(a) ns2
(b) 𝑛𝑠 2 𝑛𝑝4
(c) ns2 np6
(d) 𝑛𝑠 2 𝑛𝑝2

Q9. Tendency of carbon for catenation is because carbon-carbon atom bond energy is
(a) Low
(b) High
(c) Zero
(d) Negative

Q10. In graphite, the bond is

(a) Ionic
(b) Covalent
(c) Co-ordinate
(d) Metallic

Q11. The mixture of CO &H2 is known as

(a) Water gas or producer gas
(b) Water gas or synthesis gas
(c) Synthesis gas or producer gas
(d) Producer gas

Q12. The geometry of SiCl4 is

(a) Tetrahedral
(b) Square planar
(c) Octahedral
(d) Planar triangular

Q13. The silicates which contain discrete tetrahedral units are

(a) Sheet silicates
(b) Ortho silicates
(c) Three dimensional silicates
(d) Pyrosilicate
CuPowder 2H2 O
Q14. CH3 Cl + Si ⟶ (X) ⟶ (Y)
570 K

(Y) & (X) respectively are

(a) (CH3 )2 SiCl2 , (CH3 )2 Si(OH)2
(b) (CH3 )2 Si(OH)2 , (CH3 )2 SiCl2
(c) SiCl4 , Si(OH)4
(d) Si(OH)4 , SiCl4
Q15. Hydrolysis of dimethyl dichloro silane; (CH3 )2 SiCl2 followed by condensation
polymerisation yields straight chain polymer of

Q16. Suitable conditions for melting of ice are:

(A) High temperature and high pressure
(B) High temperature and low pressure
(C) Low temperature and low pressure
(D) Low temperature and high pressure

Q17. For the following three reactions I, II and III, equilibrium constants are given

1 CO(g) + H2 O(g) ⇌ CO2 ( g) + H2 ( g); K1

2 CH4 ( g) + H2 O(g) ⇌ CO(g) + 3H2 ( g); K 2
3 CH4 ( g) + 2H2 O(g) ⇌ CO2 ( g) + 4H2 ( g); K 3

Which of the following relations is correct?

(A) K1 √K 2 = K 3
(B) K 2 K 3 = K1
(C) K 3 = K1 K 2
(D) K 3 K 32 = K12

Q18. Equilibrium constant K p for the reaction CaCO3 ⇌ CaO + CO2 is 0.82 atm at
727∘ C.
If 1 mole of CaCO3 is placed in a closed container of 20 L and heated to this temperature,
what amount of CaCO3 would dissociate at equilibrium?
(A) 0.2 g
(B) 80 g
(C) 20 g
(D) 50 g
Q19. For A + B ⇌ C + D, if initially the concentration of A and B are equal but at
equilibrium concentration of D will be twice of that of A then what will be the
equilibrium constant of C + D ⇌ A + B reaction ?
9
(A) 4
9
(B) 7
1
(C) 4
(D) 4

Q20. The dissociation equilibrium of a gas AB2 can be represented as,

2AB2 ( g) ⇌ 2AB(g) + B2 ( g)

The degree of dissociation is 𝑥 and is small as compared to 1. The expression relating the
degree of dissociation ( x ) with equilibrium constant K P and total pressure 𝑃 is:
1
(A) (2 K p /P)2
(B) K p /P
(C) 2 K p /P
1
(D) (2 K p /P)3

Q21. 10 moles of 𝐴2 , 15 moles of 𝐵2 and 5 moles of 𝐴𝐵 are placed in a 2 litre vessel and
allowed the come to equilibrium. The final concentration of AB is 10.5M,

A2 ( g) + B2 ( g) ⇌ 2AB(g)

Determine the value of equilibrium constant (K C ) for the reaction.

(A) 25.3
(B) 31.5
(C) 36.3
(D) 40.5

Q22.
NH4 HS(s) ⇌ NH3 ( g) + H2 S( g)

The equilibrium pressure at 25∘ C is 0.660 atm. What is K p for the reaction?
(A) 0.109( atm)2
(B) 0.218( atm)2
(C) 1.89( atm)2
(D) 2.18( atm)2

Q23. Consider reaction,

CaCO3 ( s) ⇌ CaO(s) + CO2 ( g)

In a closed container at equilibrium. What would be the effect of addition of CaCO3 on
the equilibrium concentration of CO2 ?
(A) Increases
(B) Decreases
(C) Data is not sufficient to predict it
(D) Remains unaffected

Q24. What is the equilibrium expression for the reaction P4 ( s) + 5O2 (g) ⇌ P4 O10 ( s)?
[P O ]
(A) K c = [P 4][O10]5
4 5
[P O ]
(B) K c = 5[P4 ][O
10
4 2]
(C) K c = [O2 ]5
1
(D) K c = [O ]5
2

Q25. Consider the following gaseous equilibria with equilibrium constants K1 and K 2
respectively.

1
SO2 ( g) + O2 ( g) ⇌ SO3 ( g)
2
2SO3 ( g) ⇌ 2SO2 ( g) + O2 ( g)

The equilibrium constants are related as

(A) 2 K1 = K 22
1
(B) K12 =
K2
1
(C) K 22 = K1
2
(D) K 2 = K21