JEE Mains Part Test

Section 2 – Chemistry
Syllabus – Haloalkanes and Isomersim

Q1. Which is the best solvent to use for the solvolysis reaction of t- butyl chloride?
(a) Water
(b) Carbon tetrachloride
(c) Formic acid
(d) Heptane

Q2. The compound most reactive towards SN1 reaction is

(a) Me3 C − CH2 Cl
(b) MeOCH2 Cl
(c) PhCH2 CH2 Cl

(d)

Q3. Which of the following compounds will undergo an SN 2 reaction most readily?
(a) (CH3 )3 CCH2 I
(b) (CH3 )3 CCl
(c) (CH3 )2 CHI
(d) (CH3 )2 CHCH2 CH2 CH2 I

ssQ4. CH3 CD2 CHBrCH2 CD3 on reaction with alc. KOH gives:
(a) CH3 CD2 CH = CHCD3
(b) CH3 CD = C = CHCD
(c) CD3 CD2 CH = CHCH3
(d) CH3 CD = CHCH2 CD3

Q5.

Q6. Nucleophilicity order is correctly represented by

(a) NH2− > F − > HO− > CH3−
(b) CH3− > NH2− > HO− > F −
(c) CH3− < NH2− < HO− < F −
(d) CH3− ≈ NH2− > OH − ≈ F −

Q7. Most reactive alkyl halide towards E2 mechanism is

Q8. The major product formed in the following reaction is

Q9. Which of the following reacts under SN 2 conditions with sodium cyanide, NaCN, to
produce the following product?

(a) trans-1-iodo-2-methylcyclopentane
(b) cis-1-iodo-2-methylcyclopentane
(c) cis-2- methylcyclopentanole
(d) trans -2- methylcyclopentanole

Q10. The major product formed in the following reaction is

aq. KOH
CH3 CH(Cl)CH2 − CH2 OH ⟶

Q11. Which of the following reactions will go faster if the concentration of the
nucleophile is increased?

Q12. The reaction of with 𝑅Mg𝑋, leads to the formation of :

(a) RCHOHR
(b) RCHOHCH3
(c) R 2 CHCH2 OH
(d) 𝑅CH2 CH2 OH
Q13. Arrange the following in decreasing order of S𝑁2 reaction

(a) 𝑆 > 𝑃 > 𝑄 > 𝑅

(b) 𝑄 > 𝑆 > 𝑅 > 𝑃
(c) 𝑄 > 𝑅 > 𝑃 > 𝑆
(d) 𝑅 > 𝑄 > 𝑃 > 𝑆

Q14. Arrange the following in decreasing order of S𝑁2 reaction

(a) 𝑆 > 𝑅 > 𝑃 > 𝑄

(b) 𝑆 > 𝑅 > 𝑄 > 𝑃
(c) 𝑅 > 𝑆 > 𝑄 > 𝑃
(d) 𝑆 > 𝑃 > 𝑅 > 𝑄

Q15. Arrange the following in decreasing order of S𝑁1 reaction

(a) 𝑃 > 𝑄 > 𝑅 > 𝑆

(b) 𝑄 > 𝑅 > 𝑆 > 𝑃
(c) 𝑄 > 𝑃 > 𝑅 > 𝑆.
(d) 𝑄 > 𝑅 > 𝑃 > 𝑆

Q16. Arrange the following in decreasing order of S𝑁1 reaction

(a) 𝑃 > 𝑄 > 𝑅 > 𝑆

(b) 𝑆 > 𝑅 > 𝑃 > 𝑄
(c) 𝑄 > 𝑆 > 𝑃 > 𝑅
(d) 𝑄 > 𝑆 > 𝑅 > 𝑃

Q17.

Q18.

Q19.

Q20. Consider the following reaction

Which of the following products is not expected to form?

Q21. Which of the following reactions will go faster if concentration of nucleophile is
increased?

Q22. Find the product of the following reaction :

Q23. Find the major product of the following reaction :

Q24. In the following reaction the most probable product will be :

Q25. Find the major product of the following reaction :