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CHEMISTRY
Instructions (Q 1 to 4) : Single Option Correct type MCQs
1. Equal volumes of 0.015 M CH3COOH & 0.015 M NaOH are mixed together. What would be molar conductivity of mixture
if conductivity of CH3COONa is 6.3 × 10–4 S cm–1 :
(A) 8.4 S cm2 mol–1 (B) 84 S cm2 mol–1 (C) 4.2 S cm2 mol–1 (D) 42 S cm2 mol–1

O3 Ca(OH)2 (i) NaOI

2.  (A)   (B)  (C)
Zn/H 2O Δ  (ii) H

Identify product :
COOH COOH COCH3
(A) (B) (C) (D)
COOH

3. During group analysis reddish brown ppt. is only obtained in group-III test. Which of following inference is incorrect :
(A) Fe2+ may be present in the original sample (B) Fe3+ may be present in the original sample
(C) (Fe & Fe ) may be present in the original sample(D) Fe3+ has to be present in the original sample.
2+ 3+

4. Select the incorrect statement :

(A) Cyclopropane is more acidic than propane
Br
(B) F is a meso compound with (2S, 3S) configuration
F
Br
(C) N-methylaniline is a non-resolvable compound

COOH COOH

(D) is more acidic than

NO2 NO2

Instructions (Q 5 to 6) : Multiple Option Correct type MCQs.

5. Select the incorrect statement(s) from the following :
(A) Rate of sulphonation of C6H6 & C6D6 will be equal
(B) On treatment of salicylic acid with Br2/water (in excess) it results in a dibromo product
 (C) When HCOOEt is treated with MeMgBr in excess followed by hydrolysis it will results in the formation of tertiary
alcohol
Me Cl
| | aq.KOH
(D) MeCH 2  CH  CH  Me   Product. Product is enantiomer of the reactant
Optically pure SN 2

6. The colour of KMnO4 is discharged by which of the following gases :

(A) NO (B) NO2 (C) N2O (D) N2O5

Instructions (Q 7 to 10) : Numerical Value Answer type question. Answer to be calculated upto two decimal places.
7. Consider the following equilibria at 300K.
2A(g) + H2O(g)  C(g) + 3D(g); KP = 3 × 1022 atm
The equilibrium was attained in a container by taking A, C and D at partial pressures of 2 atm each along with large
amount of liquid water. If vapour pressure of water at 300 K is 38 mm of Hg then calculate partial pressure of A when
equilibrium gets established.
[Express your answer in terms of 10–10 atm.]

8. Calculate the volume (in litre) occupied by 4 moles of a Vander-Waal gas present at a temperature of 400 K & exerting
a pressure of 2 atm if Vander-Waal constant a & b are respectively 33.256 Pa-m6/mol2 & 10–2 m3 / mole. ( round off your
answer to nearest integer) :
Given : R = 0.0821 atm-lit/mol K or 8.314 Pa - m3 / mol K

9. 1 litre solution containing 0.1 M Na2S2O3 & 0.2 M IO4¯ is titrated with I2 according to following reaction.
Na2S2O3 + I2  Na2S4O6 + I¯
IO4¯ + I2  IO3¯
Calculate millimoles of I2 consumed ?

10. The structure of diamond and silicon is same and can be described as atoms taking corners and faces of a cube and also

 density (diamond) 
taking positions of alternate tetrahedral voids. What is the value of   × 100.
 density (silicon) 

At.mass (g/mol) Covalent Bond Length (Å)

Carbon :12 C – C =1.50
Silicon:28 Si – Si = 2.25
MATHEMATICS
Instructions (Q 1 to 6) : Single Option Correct type MCQs
 1 1 1 1 a
1. If tan  tan 1  tan 1  tan 1  tan 1  is expressed as a rational in lowest form then (a + b) has the value equal
 2 3 4 5 b
to :
(A) 19 (B) 27 (C) 38 (D) 45

x2  3x  5
2. If Lim exists then :
x  4x  1  xk
(A) k = 2 (B) k < 2 (C) k > 2 (D) k  2

x y z
3. If p, q, r and x, y, z are distinct real numbers such that = = = k > 0,
q  2r  p r  2 p  q p  2q  r
then (q – r)x + (r – p)y + (p – q)z is :
(A) positive for all p, q, r
(B) negative for all p, q, r
(C) zero for all p, q, r
(D) positive for some values of p, q, r and negative for other values

 2 tan x  (cos 2 x  1)(sec 2 x  2 tan x)

4. If f   = , then the domain and range of y = f (x) are :
 1  tan 2 x  2
(A) [– 1, 1], (0, 2) (B) (– 1, 0), [0, 1)

(C) (0, 2) (– 1, 1) (D) (– , ) – (2n + 1) , n I, [0, 2]
2

x
1
x 3
5. If f (x) = (5t 3 – 3 f '(t )) dt , then f '(3) is equal to :

15 35 45 2
(A) (B) (C) (D)
2 2 2 45

6. From any point on the line 2x + y = 1, tangents are drawn to the circle x2 + y2 = 9, then the chords of contact pass through
the fixed point :
(A) (18, 9) (B) (9, 18) (C) (9, 9) (D) (18, 18)

Instructions (Q 7) : Multiple Option Correct type MCQs.

7. Which of the following functions f has/have a removable discontinuity at the indicated point ?

x2  2 x  8 x7
(A) f(x) = at x = – 2 (B) f(x) = at x = 7
x2 | x7|

x3  64 3 x
(C) f(x) = at x = – 4 (D) f(x) = at x = 9
x4 9 x
Instructions (Q 8 to 10) : Single Option Correct type MCQs based on below comprehension passage
Consider a variable line L which passes through the point of intersection ‘P’ of the lines 3x + 4y – 12 = 0 and x + 2y – 5 = 0,
meeting the coordinate axes at the points A and B.

8. Locus of the middle point of the segment AB has the equation :

(A) 3x + 4y = 4xy (B) 3x + 4y = 3xy (C) 4x + 3y = 4xy (D) 4x + 3y = 3xy

9. Locus of the feet of the perpendicular from the origin on the variable line ‘L’ has the equation :
(A) 2(x2 + y2) – 3x – 4y = 0 (B) 2(x2 + y2) – 4x – 3y = 0 (C) x2 + y2 – 2x – y = 0 (D) x2 + y2 – x – 2y = 0

10. Locus of the centroid of the variable triangle OAB has the equation (where ‘O’ is the origin) :
(A) 3x + 4y + 6xy = 0 (B) 4x + 3y – 6xy = 0 (C) 3x + 4y – 6xy = 0 (D) 4x + 3y + 6xy = 0

Instructions (Q 11 to 13) : Single Option Correct type MCQs based on below comprehension passage
Z1, Z2, Z3 are the vertices of an equilateral triangle of side 2 units.

11. (Z1 – Z2)2 + (Z2 – Z3)2 + (Z3 – Z1)2 =

(A) 0 (B) 1 (C) 3 (D) 4

12. Z12  Z 22  Z 32  Z1Z 2  Z1Z 3  Z 2 Z 3 

(A) Z1Z2 + Z1Z3 + Z2Z3 (B) 0 (C) 2( Z12  Z 22  Z32 ) (D) Z1 + Z2 + Z3

1 1
13.  =
Z1  Z 2 Z3  Z1

1 1 1
(A) Z  Z (B) Z  Z (C) 1 (D)
3 2 2 3 2

Instructions (Q 14 to 15) : Assertion - Reason type MCQs.

This section contains 2 questions numbered 14 and 15. Each question contains STATEMENT-1 (Assertion) and
STATEMENT-2 (Reason). Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
(A) Statement 1 is True, Statement 2 is True; Statement 2 is a correct explanation for Statement 1
(B) Statement 1 is True, Statement 2 is True; Statement 2 is not a correct explanation for Statement 1
(C) Statement 1 is True, Statement 2 is False
(D) Statement 1 is False, Statement 2 is True

14. Statement 1: If in a triangle ABC, cot  = cot A + cot B + cot C, then sin3  > sin (A – ) · sin (B – ) · sin (C – )
and

sin( A  ) sin A
Statement 2: If in a triangle cot  = cot A + cot B + cot C, then =
sin  sin A sin B sin C

4 AB
15. Statement 1: The equation sec2  = is possible only if A = B (where A and B are real) and
( A  B)2
Statement 2: For any real number , sec  lies between – 1 and + 1.
PHYSICS
Instructions (Q 1 to 5) : Numerical Value Answer type question. Answer to be calculated upto two decimal places.
1. A cylindrical vessel, whose diameter and height both are equal to 30 cm, is placed on a horizontal surface and a small
particle P is placed in it at a distance of 5.0 c from the centre. An eye is placed at a position such that the edge of the
bottom is just visible (see figure). The particle P is in the plane of drawing. Up to a minimum height h water should be
poured in the vessel to make the particle P visible. If h = x/10 cm, find x ?

A
2. A particle executes simple harmonic motion between x = –A and x = +A, the time taken for it to move from x = 0 to x =
2

A A
is T1 and to move from to is T2, then T1 = nT2. Find value of n ?
2 2

3. In a stationary wave that forms as a result of reflection of waves from an obstacle, the ratio of the amplitude at an
antinode to the amplitude at node is 6. What percentage of energy is transmitted.

4. An aluminium wire of cross-sectional area 10–6 m2 is joined to a steel wire of the same cross-sectional area. This
compound wire is stretched on a sonometer pulled by a weight of 10 kg. The total length of the compound wire between
the bridges is 1.5 m of which the aluminium wire is 0.6 m and the rest is steel wire. Transverse vibrations are set up in
the wire by using an external source of variable frequency. Find the lowest frequency of excitation for which the
standing waves are formed such that the joint in the wire is a node. What is the total number of nodes at this frequency.
The density of aluminium is 2.6 × 103 kg/m3 and that of steel is 1.04 × 104 kg/m3. (g = 10 m/s2)

5. A container filled with air under pressure P0 contains a soap bubble of radius R. The air pressure is halved isothermally
5R 12 nS
and the radius of soap bubble becomes . If surface tension of soap water solution is S, P0 is found to be . Find
4 R
n.

Instructions (Q 6 to 7) : Multiple Option Correct type MCQs.

6. Three simple harmonic waves, identical in frequency n and amplitude A moving in the same direction are superimposed

in air in such a way, that the first, second and the third wave have the phase angles ,  + and () respectively at
2
a given point P in the superposition.
Then as the waves progress, the superposition will result in
(A) a periodic, non-simple harmonic wave of amplitude 3A
(B) a stationary simple harmonic wave of amplitude 3A
(C) a simple harmonic progressive wave of amplitude A
(D) the velocity of the superposed resultant wave will be the same as the velocity of each wave
7. A glass full of water is placed on a weighing scale, which reads 10 N. A coin with weight
1 N is gently released into the water. At first, the coin accelerates as it falls and about
halfway down the glass, the coin reaches terminal velocity. Eventually, the coin rests on
the bottom of the glass. Acceleration due to gravity is 10 m/s2. The scale reads
(A) 10.5 N when the coin accelerates at 5 m/s2
(B) 11.5 N, when the coin decelerates at 5 m/s2
(C) 11 N, when the coin moves with terminal velocity.
(D) 11 N, when the coin rests on the bottom.
10.00 N

Instructions (Q 8 to 10) : Single Option Correct type MCQs based on below comprehension passage
In the circuit shown, switch K is initially open. Both the cells are ideal and C = 30µF, E1 = 1V, R1 = 2, E2 = 3V,
R2 = 4. At t = 0 second, the switch K is closed. A and B are two points on circuit as shown.

1 2

1 2

8. Just after the switch K is closed, the magnitude of current in amperes through resistance R1 is :
1 4
(A) (B) (C) 1 (D) 2
3 3

9. VA and VB are potentials of points A and B respectively. After the switch K is closed, the potential difference VB – VA.
(A) Remains constant
(B) Decreases
(C) Increases and then becomes constant after long time
(D) Decreases and then becomes constant after long time

10. Long after the switch K is closed, the magnitude of charge on the capacitor in steady state is :
(A) 10 C (B) 30 C (C) 50 C (D) 90 C

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CHEMISTRY
1. (B) 2. (A) 3. (D) 4. (B) 5. (All) 6. (A, B)
7. [5] 8. [0066] 9. [90] 10. [01.45]

MATHEMATICS
1. (A) 2. (D) 3. (B) 4. (D) 5. (C) 6. (A)
7. (A, C, D) 8. (A) 9. (B) 10. (C) 11. (A) 12. (B)
13. (A) 14. (D) 15. (C)

PHYSICS
 
1. [ h =  10 23  cm = 26.7 cm thus x = 267] 2. [2] 3. [49] 4. [163.4]
 23  3 
5. [8] 6. (C, D) 7. (A, C, D) 8. (A) 9. (A) 10. (C)

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