PINNAACLE CLASSES

26. (b)

27. (a) The rate of backward reaction favoured by increase of pressure in the reaction
as Δn is positive
PCl 5
⇌ PCl 3 +Cl 2

H 2( g )+ I 2( g ) 2 HI
28. (a) 2 ⇌ 2

Δn=0 ; ∵ K c =K p

29. (c)Solid + liquid ⇌ Solution ΔH =+ve

Increase in temperature favours forward reaction.

30. (a) Addition of an inert gas of constant volume condition to an equilibrium has no
effect.

31. (b)Le chatelier principle is not applicable to solid-solid equilibrium.

32. (a) In that type of reaction the state of equilibrium is not effected by change in
volume (hence pressure) of the reaction mixture.

33. (c) N 2 + O2 ⇌ 2 NO ; Δn=0

34. (a)
Δn
35. (b)K has the units of (conc. ) , where Δn=10−9 =+1

36. (c)Unit of K c = (unit of concentration)n

= (mole litre–1)n
n = 10 – 9 = 1
Kc=
∴ mol Litre–1.

nr> np K p<Kc
37. (c)When then
where n r = no. of moles of reactant
np
= no. of moles of product.

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38. (b)2 N 2 O5 → HNO 2 +O 2

N 2 O5
Rate of decomposition of
1 K [ N 2 O5 ]
=− .
2 dt
1 d [ NO 2 ]
NO 2 = .
Rate of formation of 4 dt

∴ Ratio = 2 : 1

39. (d)If Q> K c reaction will proceed right to left to decrease concentration of product.

PCl 5 PCl 3 + Cl 2
40. (d) ⇌
Initial conc. 1 0 0
At equilibrium 0.5 0.5 0.5
Px 2 1×0 . 5×0 . 5 0. 5×0. 5 1
K p= = = = =0 . 3
(1−x2 ) [1−(0 .5 )2 ] 0 . 75 3

41. (c)2HI ⇌ H 2 + I 2
Initial conc. 2 moles 0 0
22
×2
at equilibrium 100 0.22 0.22
=2−0 . 44=1. 56

[ H2] [ I2] 0. 22×0. 22

K= = =0 . 0199
[ HI ]2 [1 .56 ]2 .

42. (b)When adding HCl in CH 3 COOH solution the concentration of H is increased. So

+

−
reaction is proceed in reverse direction and the concentration of CH 3 COO is
decreased.

43. (b)The reaction is exothermic so high temperature will favour backward reaction.

moles
=
44. (c)Active mass litre
wt . in gm /molecular wt . 120/ 60 2
= = = =.4
V in litre 5 5

[ C ]3
K=
45. (d) [ A ]2 [ B ] .

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46. (6)
(Given : R = 8.3 J K-1 mol-1 and ln 10=2.3)

and Keq =

Mole-1(nearest integer)
Ans = 6

47. (3)
The yield of SO3 at equilibrium will be due to
B. Increasing pressure
C. Adding more SO2
D. Adding more O2

48. Ans. 2
Sol. 2NO + O2  2NO2
(moles 2 0.5 0
before reaction)
after reaction  2–1 0 1
=1
n = |2.5 – 2| = 0.5
Change in pressure
ΔnRT 1 300
P = V = 0.5 × 12 × 6 .25 atm
= 2 atm

49. Ans. 5
Sol. AB2(g) AB(g) + B(g)
Initial 100 0 0
At equ. 100 – x x x
At eq. P = 120
120 = 100 – x + x + x
= 100 + x = 120
x = 20
x×x 20×20
=
Kp = 100 – x 100 – 20 = 5

50. 354 JEE Main 2021

N 2 O4 ( g ) ⇌2 NO 2 ( g ) ; ∆ ng =2−1=1

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Now, K p=K c ∙ ( RT )∆ ≫¿¿

Or, 600.1=20.4 × ( 0.0831 ×T )1
∴ T =353.99 K =354 K

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