PINNAACLE CLASSES

1. SN1 reaction is feasible in : The correct, order of SN1 reactivity is

(a) B > C > A (b) B > A > C
(c) C > B > A (d) A > B > C

(a) + KOH (aq.) 6. The increasing order of reactivity of the following

isomeric halides with AgNO3 (H2O + alcohol) is
(b) + KOH (aq.)
(a) C6H5 – CH = CH – CH2 – CH2 – Cl
C 6H5  CH  CH  CH  CH3
(c) + KOH (aq.) |
Cl
(b)
C 6H5  C  CH  CH2  CH3
(d) + KOH (aq.) |
Cl
(c)
2. Bottles containing C6H5I and C6H5CH2I lost their
original labels. They were labelled A and B for C 6H5
testing. A and B were separately taken in a test |
C 6H5  C  CH  CH2
tube and boiled with NaOH solution. The end |
solution in each tube was made acidic with dilute Cl
HNO3 and then some AgNO3 solution was added. (d)
Substance B gave a yellow precipitate. Which one
of the following statements is true for this 7. What will be the major product of the following
experiment? reaction ?
(a) A was C6H5I H CH3
(b) A was C6H5CH2I | |
CH3 — C — C — CH — CH3
(c) B was C6H5I | | | CH3OH, 30C
(d) Addition of HNO3 was unnecessary H CH3 Br    
H CH3 C H3
3. The decreasing order of nucleophilicity among the | | |
nucleophiles : CH 3 — C — C — C — CH3
| | |
OCH3 H H
(a)
(A) (B) H CH3 OCH3
| | |
CH3 — C — C — C — CH3
| | |
(C) (D) H CH3 H
(b)
(a) (C), (B), (A), (A) (b) (B), (C), (A), (A)
(c) (D), (C), (B), (A) (d) (A), (B), (C), (D) H CH3 CH3
| | |
CH3 — C — C — C — CH3
4. Which of the following is the correct order of | | |
decreasing SN2 reactivity? H OCH3 H
(c)
(a) RCH2X > R3CX > R2CHX
H CH3 H
(b) RCH2X > R2CHX > R3CX | | |
(c) R3CX > R2CHX > RCH2X CH3 — C — C — C — CH2
| | | |
(d) R2CHX > R3CX > RCH2X H CH3 H OCH3
(d)
5. Consider the following bromides :
8.

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 PINNAACLE CLASSES
CH 3

—
CH 3 — CH 2 — N— C H 2— CH 2— CH 3

—

OH / 
CH 3  
H2O / Acetone
    (a) ; Product (a) is (a) CH3–CH=CH2 (b) CH2= CH2

OH
|
(c) (d) CH3OH

13. Which one is the strongest nucleophilic site in the

(a) (b) OH following species ?

(c) (d)

9. When the concentration of alkyl halide is tripled

and the concentration of ion is reduced to half, the (a) 1 (b) 2 (c) 3 (d) 4
rate of SN2reaction increases by:
(a) 3 times (b) 2 times (c) 1.5 times (d) 6 14.
times

10. HBr
 HBr

CH 3  (a)  (b)
The product (a) and (b) are respectively :
H OH

C 2H 5
PCl5
(D -2 -B u ta n o l)    X ; (X) is
(a) &
(a) S-2-Chlorobutane
(b) R - 2-Chlorobutane
(c) Mixture of R and S 2-Chlorobutane
(d) 1-Chlorobutane (b) &

11. Which one of the following hexachlorocyclohexane

is least reactive and which one is most reactive for (c) &
E2 reactions with a strong base for
dehydrohalogenation.

(d) &

15. Which of the following reaction is not feasible

(a)I least &II most (b)II least &I most CH OH

(c)III least &I most (d)III least &II most  
3

(a)  +
CH3
12. Identify the major product in the following
reaction ? CH3
OCH3

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 PINNAACLE CLASSES

(d) pqrs

(b) + 17. Assertion: Boiling point of alkyl halide increases

with increase in molecular weight. Reason:
Boiling point of alkyl halides is in the order
.
(a) Both A and R are correct and R is correct
C H OH explanation of A.
25
(c)  + (b) Both A and R are correct but R is not correct
explanation of A.
(c) A is correct but R is incorrect.
+ (d) Both A and R are false.
CH3
| 18. Identify the set of reagents/reaction condition ‘X’
CH3  C  Cl and ‘Y’ in the following set of transformations
|
CH3
(d) + HCl + (a) X = dil. aqueous NaOH, 20°C Y = HBr/acetic acid
 O 20°C
(b) X = conc. alcoholic NaOH, 80°C Y = HBr/acetic
16. Match the following. acid 20°C
Column I (Reactant) Column II (c) X = dil. aqueous NaOH, 20°C Y = Br2/CHCl3, 0°C
(Product) (d) X = conc. alcoholic NaOH, 80°C Y= Br2/CHCl3,
0°C

(A) (p) 19. How much chloroform can cause dizziness for a
short time?
(a) 100 parts per million
(b) 200 parts per million
(c) 900 parts per million
(d) only 1 part per million

20. The reaction of with

(B) (q) produces

(a)
(C) (r)
(b)

(c)
(D) (s)

ABCD (d)
(a) rsqp
(b) qrsp
(c) qprs 21. How many groups are ortho/para director in the
electrophilic aromatic substitution?
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 PINNAACLE CLASSES

(i) -NH2 (ii) -COH (iii) -N = O (iv) -COOH

(v) -Et (vi) -N = NH2 (vii) -SO3H 24. How many of the following groups if substituted at
o- and/or p-positions of chlorobenzene, increase its
(viii) (xi) reactivity towards nucleophilic substitution?
-CN, -CH3 - NH(CH3), -COOH, -NO2, -OCH3

25. How many stereoisomers can be drawn for the

following molecule?
H3CCH2CH = CHCH2CH(C1)CH3
22. Identify number of reactions that can give benzene
as major product

(1)

(2)

(3)

(4)

(5)

(6)

23.

The electrophile involved in above reaction

has______lone pair of electrons on central
carbon atom.
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