DPP No.

* Marked Questions are having more than one correct option.

1. Write resonating structure for each of the following :

(a) (b) (c)

(d) (e) (f ) – CH = CH2

2. Write resonating structure for each of the following :

O
|| ..
(a) CH3  CH  CH  C  CH3 (b) H 2 N CH  CH  C  N

(c) (d) CH3 – O – CH = CH –

 ..
(e) (f) CH3  C  O :

(g) (h)

(i) (j)

(k) (l) CH2 = C = O (m)

2
1 3
3.
4

Which of the following statements is true about this molecule.

(A) C1–C2 and C3–C4 bonds are of same length.
(B) C1–C2 bond is shorter than C3–C4 bonds.
(C) C1–C2 bond is longer than C3–C4 bond.
(D) C1–C2 and C2–C3 bonds are of same length.

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4. Which of the following compounds do not have all C—O bonds of same length :
(A) CO2 (B) HCOOH (C) CO32– (D) HCOO–

5. Which of the following compounds do not have all C—C bonds of same length :

(A) (B) (C)  (D) 

6. Resonance effect is not observed in :

O

OH Cl N NH3
(A) (B) (C) (D)
O

7. Pairs of structure which are resonance structure.

OH O
||
(A) CH = C - H + CH  C  H
2 2
• •
(B) CH2=CH–CH=CH2 C H 2  CH  CH  C H 2
(C) CH2=CH–OH CH 3  C  O
|
H
NH 2 NH 2
| | 
(D) CH 3  CH 2  C  NH 2 CH 3  CH 2  C  N H 2


8. Identify the major contribution in following resonance structures :

NH 2 NH 2
| | 
(A) NH 2  C — N H 2 NH 2  C  N H 2


O O O O
||  || || |
(B) CH 3  C  C H  C  CH 3 CH 3  C  CH  C  CH 3
O
–
O
(C)

O O
| •• |
(D) CH 3  C  O H CH 3  C  O  H
 •• 

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 ANSWER KEY
DPP No. 3

1. (a) (b)

(c)  

(d) 

(e)  (f )  – CH = CH2

O
||
2. (a) CH3  CH  CH  C  CH3 (a)
..
(b) H 2 N CH  CH  C  N (b)

(c) (c)

(d) CH3 – O – CH = CH – (d)

(e) (e)

 ..
(f) CH3  C  O : (f)

(g) (g) (h)

(h)

(i) (i)

(j) (j)

+ +
(k) (k) (l) CH2 = C = O
+

..   –2 
..

(l) CH 2 = C = O C H2 – C  O (m) (m) N– N  N

3. (B) 4. (B) 5. (B) 6. (D) 7. (D)

8. (A) II (B) II (C) I (D) II

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