PINNAACLE CLASSES

Mass of Br
= ×100
46. (b)% of Br Mass of organic compound
80
= ×100=73. 39 %
109 or approx. 75%

47. (a)

CH 3 COOAg+Br 2 ⃗
CS 2 CH 3 Br+ AgBr+CO 2
48. (a)

49. (d)C 2 H 5 OH +SOCl 2⃗

Pyridine C 2 H 5 Cl+SO 2 +HCl

50. (c)

51. (c) CH 3 COCH 3 +3 I 2 + 4 NaOH →CHI 3 +3 Na+ CH 3 COONa +3 H 2 O

52. (d)

CH 3 −CH=CH 2 +HBr ¿⃗
Marko wnikoff's ¿ rule ¿→CH 3 −CH −CH 3 ¿
|
53. (a) Br

54. (d)(None): Due to chirality

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only compound (iv) will undergo racemisation. Hence, all the given options are
incorrect.

55. (a): Maleic acid shows geometrical isomerism and not optical isomerism.

56. (c): If reaction is , there will be the formation ofcarbocation and the
rearrangement takes place. In these reactions there is no rearrangement hence both
are mechanism.

57. (c): reactions proceed via the formation of a carbocation intermediate.

More stable is the carbocation more reactive is the alkyl/aryl halide towards
In carbocation, the two phenyl rings by their effect and by
its effect diminish the positive charge and make it stable.

58. (c):

59. (d)

60. (c) : The given compound may be written as

Both geometrical isomerism (cis‐trans form) and optical isomerism is possible in the
given compound.
No. of optical isomer
(where no of asymmetric carbon)
Hence total no. of stereoisomers
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61. (a) : Meso compound does not rotate plane polarised light. Compound which
contains tetrahedral atoms with four different groups but the whole molecule is
achiral, is known as meso compound. It possesses a plane of symmetry and is
optically inactive. One of the asymmetric carbon atoms turns the plane of polarised
light to the right and other to the left and to the same extent so that the rotation due
to upper half is compensated by the lower half, i.e., internally compensated, and
finally there is no rotation of plane polarised light.

62. (b) :

63. (d):
Due to absence of asymmetric carbon atom.

64. (d): reaction is favoured by heavy (bulky) groups on the carbon atom attached to
halogens and nature of carbonium ion in substrate is
Benzyl Allyl Tertiary Secondary Primary Methyl halides.

65. (b): atomic radii belongs to the same group orderly Atomic
radii go on increasing as the nuclear charge increases in preceeding downwards in a
group. The decreasing order of bond length
. The order ofbond dissociation energy
During dehydrohalogenation C‐I bond breaks more easily
than C‐F bond. So reactivity order of halides is,

66. (a):

67. (b): Chlorination of ‐butane takes place via free radical formation. i.e.

‐hybrid planar shape intermediate and may attack from either side to give
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(Mixture of 50% ‐form and 50% ‐form)

68. (c) :

The above compound has no chiral ‘C’‐atom. All the ‘C’ atoms are attached to two
identical ‘H’ atoms, so they are not asymmetrical.

69. (b) :

Withdrawal of electrons groups from ortholpara positions cause easier removal

of ‐Cl atom due to the development of positive charge on ‐and ‐positions.

70. (d):

71. (d): Isobutylene is obtained.

Br

Thus, the reaction produces isobutylene.

72. (d): Grignard reagent is prepared by heating an alkyl halide with dry magnesium
powder in dry ether.

73. (b):

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 PINNAACLE CLASSES

74. (b):
At temperature, substitution occurs instead of addition.

75. (a): Cl in 2, 4, 6‐trinitrochlorobenzene is activated by three groups at ‐and ‐

positions and hence undergoes hydrolysis most readily

76. (c):
2‐Chlorobutane contains a chiral carbon atom and hence it is optically active
compound.

77. (b) JEE Main 2021

78. (d) JEE Main 2021

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79. (c) JEE Main 2021

80. (d) JEE Main 2021

Temperature ¿ 623 K
Pressure ¿ 300 atm

81. (a)

82. (b)

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83. (d)
We have been given a bulky base, hence elimination will take place & not
substitution.

84. (c)

85. (c)
is formed in the above reaction

86. (c)

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87. (c) Reaction (c) is Sandmeyer’s reaction

88. (a)The reaction between CH3Cl and hydroxide ion to yield methanol and chloride
ion follows a second order kinetics, i.e. the rate depends upon the concentration of
both reactants.

89. (b) The product of ozonolysis can give an idea about probable alkene. These are
represented as follows

Complete reaction is as follows

90. (a)Arylchloride can be easily prepared by electrophilic substitution of arenes with

chlorine in the presence of Lewis acid catalyst like iron or iron (III) chloride

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