12 Chemistry23 24 sp01

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Class 12 - Chemistry
Sample Paper - 01 (2023-24)
Maximum Marks: 70
Time Allowed: : 3 hours
General Instructions:
Read the following instructions carefully.
a. There are 33 questions in this question paper with internal choice.

b. SECTION A consists of 16 multiple-choice questions carrying 1 mark each.
c. SECTION B consists of 5 very short answer questions carrying 2 marks each.
d. SECTION C consists of 7 short answer questions carrying 3 marks each.
e. SECTION D consists of 2 case-based questions carrying 4 marks each.
f. SECTION E consists of 3 long answer questions carrying 5 marks each.
g. All questions are compulsory.
h. Use of log tables and calculators is not allowed.
Section A
1. Which one of the following is employed as antityphoid drug?
a) Diphenyl hydramine
b) Chloramphenicol
c) Omeprazole
d) Chloroquine
2. ____ are joined together by phosphodiester linkage between 5′ and 3′ carbon atoms of the pentose sugar.
a) Nucleosides
b) Nucleic acids
c) Proteins
d) Nucleotides
3. In the following compounds:
The order of acidity is

a) (ii) > (i) > (iii) > (iv)
b) (i) > (iv) > (iii) > (ii)
c) (iv) > (iii) > (i) > (ii)
d) (iii) > (iv) > (i) > (ii)
4. Prop – 2 – enal is called
a) Veleraldehyde
b) Acrolein
c) Phthaldehyde
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d) None of these
5. At 227°C, the presence of catalyst causes the activation energy of a reaction to decrease by 4.606 KCal, the rate of the
reaction will be increased by:
a) 1000 times
b) 2 times
c) 100 times
d) 10 times
6. Match the items of column I with appropriate entries of column II.
Column I Column II
(a) For electrolyte CaSO4 (i) i = 5
(b) For ideal Solution (ii) i = 2
(c) For electrolyte Al2(SO4)3 (iii) i = 4
(d) For electrolyte Na3PO4 (iv) i = 1

a) (a) - (iv), (b) - (i), (c) - (ii), (d) - (iii).
b) (a) - (i), (b) - (ii), (c) - (iii), (d) - (iv).
c) (a) - (iii), (b) - (ii), (c) - (iv), (d) - (i).
d) (a) - (ii), (b) - (iv), (c) - (i), (d) - (iii).
7. Which one of the following is a synthetic halogen compound?
a) Chloramphenicol
b) Diphenyl hydramine
c) Chloroquine
d) Omeprazole
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8. Gadolinium belongs to 4f series. Its atomic number is 64. Which of the following is the correct electronic configuration
of gadolinium?
a) [Xe] 4f 65d26s2
b) [Xe] 4f75d1 6s2
c) [Xe] 4f86d2
d) [Xe] 4f95s1
9. The reaction A+2B → C+D obeys the rate equation, Rate = k[A] [B] what would be the order of this reaction?
x y
a) x
b) x + y
c) x – y
d) Cannot be predicted with the equation
10. Which one of the following is used for the separation and purification of aldehydes
a) hydrogen cyanide
b) None of these
c) Grignard reagent
d) Sodium hydrogensulphite
11. Alcoholic compounds react:
a) only as nucleophiles.

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b) both as nucleophiles and electrophiles.
c) only as electrophiles.
d) None of these
12. p – toluenesulphonyl chloride is used to:
a) as a replacement of benzenesulphonyl chloride
b) All of these
c) for the distinction of primary, secondary and tertiary amines
d) for the separation of a mixture of amines
13. Assertion (A): Vitamin D can be stored in our bodies.
Reason (R): Vitamin D is a fat-soluble vitamin.
a) Both A and R are true and R is the correct explanation of A.
b) Both A and R are true but R is not the correct explanation of A.
c) A is true but R is false.
d) A is false but R is true.
14. Assertion (A): The boiling points of aldehydes and ketones are higher than hydrocarbons and ethers of comparable
molecular masses.
Reason (R): There is a weak molecular association in aldehydes and ketones arising out of the dipole-dipole
interactions.
15. Assertion (A): SN1 reactions are unimolecular.
Reason (R): SN1 reaction proceed through the formation of the carbocation, which is slow step of the reaction.
16. Assertion (A): The acidity of alcohols follows the order 1 > 2 > 3 .
∘ ∘ ∘
Reason (R): The +I effect of alkyl groups (3 > 2 > 1 ) favours the dissociation of -OH group.
∘ ∘ ∘

Section B
17. What is meant by hexadentate ligand? Give one example. How is such ligand useful for measuring hardness of water.
18. Explain the following observations:
i. The transition elements have great tendency for complex formation.
ii. There is a gradual decrease in the atomic sizes of transition elements in a series with increasing atomic numbers.
19. Answer the following:
1. For a reaction R → P, half-life (t1/2) is observed to be independent of the initial concentration of reactants. What is
the order of reaction?
2. There is no bar on the no. of collisions among the reaching species. Why most of the reactions do not take place
under normal conditions?
20. A sample of drinking water was found to be severely contaminated with chloroform (CHCl3) supposed to be a
carcinogen. The level of contamination was 15 ppm (by mass):

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i. express this in percent by mass.
ii. determine the molality of chloroform in the water sample.
OR
Calculate the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to lower its melting point
by 1.5oC. Kf = 3.9 K kg mol-1.

21. a. Arrange the following compounds in the increasing order of their boiling points:
CH3COCH3, CH3CH2OH, CH3COOH
b. Write the IUPAC name of the given compound:
Section C
22. a. The resistance of a conductivity cell containing 0.0001 M KCl solution at 298 K is 1500Ω . What is the cell constant
if the conductivity of 0.001 M KCl solution at 298 K is 0.146 × 10 S cm−3 −1
b. Predict the products of electrolysis in the following:

A solution of H2SO4 with platinum electrode.
23. For the first order thermal decomposition reaction, the following data obtained:
C2H5CI(g) ⟶ C2H4(g) + HCI(g)
Time/s Total pressure/atm

0 0.30
300 0.50
Calculate the rate constant.
(Given: log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021)
24. Write the structures of the major products expected from the following reactions:
a. Mononitration of 3-methylphenoI
b. Dinitration of 3-methylphenol
c. Mononitration of phenyl methanoate
OR
Nitration is an example of aromatic electrophilic substitution and its rate depends upon the group already present in the
benzene ring. Out of benzene and phenol, which one is more easily nitrated and why?
25. How do you convert the following?
i. Benzoic acid to benzaldehyde.
ii. Ethyne to ethanal.
iii. Acetic acid to methane.
26. In the button cell, widely used in watches, the following reaction takes place
(aq) Given that
2+ −
Zn (s) + Ag O (s) + H O (l) → Z n
2 2 (aq) + 2Ag (s) + 20H
Θ Θ
E +
= 0.80V , E 2+
= −0.76 V
(Ag /Ag) (Zn /Zn)
Calculate standard emf and standard free Gibbs energy of the cell.
27. i. What is meant by chirality of a compound? Give an example.
ii. Which one of the following compounds is more easily hydrolysed by KOH and why? CH3CHClCH2CH3 or
CH3CH2CH2CH2Cl

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iii. Which one undergoes SN2 substitution reaction faster and why?
28. Calculate the equilibrium constant for the reaction.

2+ 2
Zn(s) + C u (aq) ⇌ Z n (aq) + C u(s)
Given: E 0
Zn
2+
/Zn
= −0.763V
and E 0
cu
2+
/cu
= +0.34V
Section D
29. Read the text carefully and answer the questions:
The d-block of the periodic table contains the elements of the groups 3 to 12 and are known as transition elements. In
general, the electronic configuration of these elements is (n - 1)d1-10 ns1-2. The d-orbitals of the penultimate energy level
in their atoms receive electrons giving rise to the three rows of the transition metals i.e. 3d, 4d and 5d series. However,
Zn, Cd and Hg are not regarded as transition elements. Transition elements exhibit certain characteristic properties like
variable oxidation stables, complex formation, formation of coloured ions, alloys, catalytic activity etc. Transition metals
are hard (except Zn, Cd and Hg) and have a high melting point.
i. Why are Zn, Cd and Hg non-transition elements?
OR
Why are melting points of transition metals high?

ii. Which transition metal of 3d series does not show variable oxidation state?
iii. Why do transition metals and their compounds show catalytic activity?
30. Read the text carefully and answer the questions:
In order to overcome the scarcity of drinking water in a remote village in Gujarat, Arnav and Aariv two young
entrepreneurs still in their high school, have developed a unique water purifier that is capable of converting sea water
into drinking water. It works on the principle of concentration difference between two solutions.
i. Name the phenomenon/process based on which this product is made?
ii. How difference in concentration of solutions help in converting sea water into drinking water?
iii. What arrangement they must have created in their product to covert sea water into drinking water?
OR
Equimolar solutions of NaCl and glucose are not isotonic. Why?

Section E
31. Attempt any five of the following:
1. Name the enzyme which converts sucrose into glucose and fructose.
2. What type of bonding occurs between two nucleotides?
3. What is the information given by primary structure of proteins?
4. What are any two good sources of vitamin A?
5. What type of linkage holds together the monomers of DNA?
6. What are biocatalysts? Give an example.
7. Name the forces responsible for secondary and tertiary structure.
32. i. Illustrate the geometrical isomerism with the help of an example : [Pt(NH3)4Cl2]2+.
ii. Answer the following:

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a. Differentiate between a bidentate ligand and a monodentate ligand.
b. Write the IUPAC name of [Pt(NH3)4Cl2]Cl2.
c. Draw the structures of geometrical isomers of [Co(NH3)4Cl2]+.
OR
CoSO4Cl.5NH3 exists in two isomeric forms ‘A’ and ‘B’. Isomer ‘A’ reacts with AgNO3 to give white precipitate but
does not react with BaCl2. Isomer ‘B’ gives a white precipitate with BaCl2 but does not react with AgNO3. Answer the
following questions.
i. Identify ‘A’ and ‘B’ and write their structural formulas.
ii. Name the type of isomerism involved.
iii. Give the IUPAC name of ‘A’ and ‘B’.
33. i. Write the structure of main products when aniline reacts with the following reagents :
a. Br2 water
b. HCl
c. (CH3CO)2O/pyridine
ii. Arrange the following in the increasing order of their boiling point: C2H5NH2, C2H5OH, (CH3)3N
iii. Give a simple chemical test to distinguish between the following pair of compounds : (CH3)2NH and (CH3)3N.
OR
i. Give reasons:
a. Although – NH2 group is o/p directing in electrophilic substitution reactions, yet aniline, on nitration gives good
yield of m-nitroaniline.
b. (CH3)2 NH is more basic than (CH3)3 N in an aqueous solution.
c. Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
ii. Distinguish between the following:
a. CH3CH2NH2 and (CH3CH2)2 NH
b. Aniline and CH3NH2

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Class 12 - Chemistry
Sample Paper - 01 (2023-24)
Solution
Section A
1. (b) Chloramphenicol
Explanation: Chlorine containing antibiotics, chloramphenicol, produced by soil microorganisms is very effective for
the treatment of typhoid fever. Chloramphenicol is an antityphoid drug.
2. (d) Nucleotides
Explanation: When nucleoside is linked to phosphoric acid at 5′-position of sugar moiety, we get a nucleotide and
nucleotides are joined by a phosphodiester bond between 5′ and 3′ carbon atoms of the pentose sugar.
3. (c) (iv) > (iii) > (i) > (ii)
Explanation: (iv) > (iii) > (i) > (ii)
4. (b) Acrolein
Explanation:
Acrolein is the common name of prop-2-enal.

5. (c) 100 times
K2 ΔEa
Explanation: log. K1
=
2.303RT
4.606×1000
= = 2
2.303×2×500
K2 2
= 10
K1
K2=100 times K1
6. (d) (a) - (ii), (b) - (iv), (c) - (i), (d) - (iii).
Explanation: (a) - (ii), (b) - (iv), (c) - (i), (d) - (iii).
7. (c) Chloroquine
Explanation: Chloroquine is a synthetic halogen compound. It is used for the treatment of malaria.
8. (b) [Xe] 4f75d1 6s2
Explanation: Atomic no. 64 Gd: [Xe] 4f75d1 6s2
9. (b) x + y
Explanation: Order of reaction with respect to A is x and w.r.t to B is y so total order of reaction is x+y.
10. (d) Sodium hydrogensulphite
Explanation:
Aldehydes and ketones form bisulphite addition product with NaHSO3 while impurites does not on hydrolysis we get
pure aldehydes and ketones.

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11. (b) both as nucleophiles and electrophiles.
Explanation: Alcohols as nucleophile: The bond between O−H is broken when alcohol react as nucleophiles.
Alcohols as electrophile : The bond between C−O is broken when alcohol reacts as electrophiles
12. (b) All of these
Explanation: p – toluenesulphonyl chloride can also be used instead of benzene-sulphonyl chloride to distinguish
between 10, 20, 30amines. Also, the product with a primary amine is soluble in alkali, the product with secondary amine
is insoluble in alkali and tertiary amine does not give any reaction, therefore we can isolate and distinguish
between primary, secondary, and tertiary amines.
13. (a) Both A and R are true and R is the correct explanation of A.
Explanation: Vitamin D can be stored in our body because it is a fat-soluble vitamin.
Explanation: Both A and R are true and R is the correct explanation of A.
Explanation: Both A and R are true and R is the correct explanation of A.
16. (c) A is true but R is false.
Explanation: A is true but R is false.
Section B
17. Hexadentate ligand is a ligand which has 6 donor atoms, e.g. EDTA.
EDTA forms complex with Ca2+and Mg2+therefore it is used for estimating hardness of water.
18. i. Due to the comparatively smaller size of the metal ions, high ionic charges and the availability of vacant d-orbitals
for bond formation, transition metals form a large number of complex compounds.
ii. In general, atoms in a given series of transition metals show a progressive decrease in radius with increasing atomic
number. This is because as new electron enters in a d-orbital, the nuclear charge increases progressively by unity.
Due to the poor shielding effect of a d-electrons, the effective nuclear charge increases and radius decreases. Both
these effects counter each other, therefore change in atomic size is negligible.
19. Answer the following:
1. For a reaction R → P, half-life (t1/2) is observed to be independent of the initial concentration of reactants. Thus, it
follows first order reaction.
2. The product formation in a reaction occurs only when reactants have required energy and are properly oriented. In
absence of either one of these parameters, the collisions between reactants doesn't result in product formation.
20. i. 15 ppm (by mass) means 15 parts per million (106) of the solution.
Therefore, percent by mass =
15
× 100%
6
10
= 1.5 × 10 −3
%
ii. Molar mass of chloroform (C HC l 3) = 1 × 12 + 1 × 1 + 3 × 35.5
= 119.5gmol −1
Now, according to the question,

15 g of chloroform is present in 106 g of the solution.
i.e., 15 g of chloroform is present in (106 − 15) 106 g of water.
0
15
mol
Therefore, Molality of the solution =

119.5
6 −3
10 ×10 Kg
= 1.26 × 10 −4
m
OR

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Mass of acetic acid, w1 = 75
Molar mass of ascorbic acid (C6H8O5), M2 = (6 × 12) +( 8 × 1 ) + (6 × 16)
= 176 g mol-1
Lowering of melting point, ΔT f = 1.5 K
We know that:
Kf ×w2 ×1000
ΔTf =
M2 ×w1
Δ Tf ×M2 ×w1
w2 =
Kf ×1000
1.5×176×75
=
3.9×1000
= 5.076 g
Hence, 5.076 g of ascorbic acid is needed to be dissolved.
21. a. Increasing order of boiling point :- CH3CHO < C2H5OH < CH3COOH
b. IUPAC name - hydroxybenzaldehyde
Section C
22. a. At Anode:
2+ −
M g(s) → M g (aq) + 2e
At Cathode:
2+ −
Cu (aq) + 2e → C u(s)
Overall reaction is:

2+ 2+
M g(s) + C u (aq) → M g (aq) + C u(s)
Using nernst equation for n=2,

2+
[M g ]
0 0 0.0591
Ecell = [E 2+ − E 2+ ]− log
Cu /C u Mg /Mg 2 2+
[C u ]
0.0591 0.001
= +0.34V − (−2.37V ) − log
2 0.0001
0.0591
= 2.71V − log 10
2
= 2.71V - 0.0295V
= 2.6805 V
For free gibbs energy
ΔG = −nEF
= −2 × 2.6805 × 96500
= -517336.5 J mol-1
= -517.34 KJ mol-1
b. At cathode: 2H (aq) + 2e + −
→ H2 (g)
At anode: 2OH (aq) → O (g) + 2H (aq) + 4e

−
2
+ −
H2(g) is evolved at cathode and O2(g) is evolved at anode.

23. C2H5Cl(g) ⟶C2H4(g) + HCI(g)
Initial pressure at t = 0, 0.30 atm
After 300s, ptotal = (0.30 - p + p + p) atm
= (0.30 + p) atm
ptotal (given) = 0.50 = 0.30 + p
⇒ p = 0.50 - 0.30 atm = 0.20 atm
Pressure of C2H5Cl(g) at 300 sec
( pC
2
H5 Cl ) = 0.30- 0.20 atm = 0.10 atrn
(pC H Cl
)
2 5
2.303 0
k = log
t
(pC H Cl
)
2 5
300

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2.303 0.30atm
= log
300 0.10atm
2.303 2.303
= log 3 = × 0.4771
300 300
= 3.66 × 10-3s-1
24. The combined influence of -OH and -CH3 groups determine the position of the incoming group. Keeping in view that
both -OH and -CH3 are o- and p-directing groups, the following products are obtained:
a.
b.
c.
OR
Phenol is more easily nitrated than benzene because the oxygen of the -OH group in phenol contains lone pairs and then
showed + M effect, which increases the electron density at 0 and p-positions in the benzene ring as a result electrophiles
attacks at more faster than benzene Nitration which is an electrophilic substitution reaction takes place more readily
where the electron density is more.
25. i. Benzoic acid to Benzaldehyde
ii. Ethyne to ethanal

OH O
H2 O | T automensation ||
CH ≡ CH −−−−−−−−−→ C H = C H2 −−−−−−−−−→ H − C − C H3
Elhyn e (unstable) Ethanal
H2 SO4 /H gSO4
iii. Acetic acid to methane

NaOH − + NaOH /C aO
C H3 C OOH −−−−→ C H3 C O O N a −−−−−−−→ C H4 + N a2 C O3

Acetic acid −H2 O (unstable) Δ Methane
26. For the button cell, chemical reactions are:

At anode:
2+ −
Zn(s) → Z n (aq) + 2e
At Cathode:
− −
Ag2 O(s) + H2 O(l) + 2e → 2Ag(s) + 2OH (aq)
Complete reaction is:

Zn (s) + Ag2 O (s) + H2 O (l) → Zn
2+
(aq) + 2Ag (s) + 20H
−
(aq) , for this reaction, n=2 moles of electrons.
Now,
Θ Θ Θ
E = E +
− E 2+
cell Ag /Ag Zn /Zn

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= 0.80 - (-0.76) = 1.56V
We know that
Θ Θ
Δr G = −nF E
cell
Here, n = 2
F = 96500 C mol-1
Θ −1
ΔG = −2 × 1.56 V × 96000 C mol
= -301080 J mol-1
= -301.08 kJ mol-1
Θ −1
∴ ΔG = −308.08 kJ mol
27. i. An object or molecule which is non-superimposable on its mirror image is called chiral and the property of being
chiral is known as chirality, e.g. lactic acid, CH3CH(OH)COOH
ii. C H 3 − C H − C H2 C H3 is more easily hydrolysed by KOH because this hydrolysis occurs through
|
Cl
SN1 mechanism and this alkyl halide forms a more stable 2° carbocation than CH3-CH2-CH2-CH2Cl which forms a
less stable 1o carbocation as SN1 depends on stability of carbocation.
iii. as iodide ion is a better leaving group because of its larger size therefore, it undergoes SN2
reaction faster.
28. Zn(s) → Zn
2+
(aq) + 2e
−
2+ −
Cu (aq) + 2e → C u(s)
2+ 2+
Zn(s) + C u (aq) → Z n (aq) + C u(s)
Ecell = E0Cu+2/Cu - E0Zn+2/Zn

= + 0.34V - (-0.763V)
= 1.103 V
0
nE
log K =
0.0591
2×1.103
=
0.0591
= 37.326
2.206
log K =
0.0591
k = Antilog 37.326
37
= 2.118 × 10
Section D
29. i. It is because neither they nor their ions have incompletely filled d-orbitals.
OR
It is due to strong interatomic forces of attraction due to presence of unpaired electrons.

ii. Scandium (Sc) and Zinc (Zn).
iii. It is because they show variable oxidation state, can form intermediate complexes and have large surface area
for adsorption of gases.
30. i. The product is based on the phenomenon of Reverse Osmosis between solutions of two different concentration.

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ii. When solutions of two different concentration are separated by a semipermeable membrane and excess pressure
is applied on the solution of higher concentration, solvent flow from higher concentration to lower
concentration. This is called Reverse Osmosis and same can be used to treat seawater and convert into drinking
water.
iii. Following arrangement must have been made:
i. Use of a semipermeable membrane.
ii. Separate Compartment having seawater and Drinking Water separated by semipermeable membrane.
iii. Excess pressure applied in compartment having sea water.
OR
NaCl is an electrolyte and gets dissociated to two ions (Na+ and Cl-) and exerts almost double osmotic pressure
than glucose which is a non-electrolyte and does not dissociate.
Section E
31. Attempt any five of the following:
1. Invertase
2. The two nucleotides are joined by phosphodiester linkage.
3. Primary structure of proteins tells about the sequence in which various amino acids are linked with each other.
4. Milk, carrot
5. The 2 strands of DNA are attached to each other by hydrogen bonds that connect the nitrogenous bases of one strand
to the bases of the other strand (this is called complementary base pairing) where Adenine pairs with Thymine by 2
hydrogen bonds and Guanine pairs with Cytosine using 3 hydrogen bonds.
While nucleotides of DNA are held together by Phosphodiester linkages. The structure of DNA holds the nucleotides
in place using phosphodiester bonds. A phosphodiester bond occurs when exactly two of the hydroxyl group in
phosphoric acid react with hydroxyl groups on other molecules to form two ester bonds. The phosphodiester bond is
the linkage between the 3' carbon atom of one sugar molecule and the 5 ' carbon atom of another, deoxyribose in
DNA.
6. The catalysts present in the living organisms which speed down or fastens down the process are known as
biocatalysts. Eg:- Hormones in our body.
7. The forces which are responsible for tertiary structure of proteins are hydrogen bonds, disulphide linkage,
vanderwalls and electrostatic forces of attraction.
32. i. When the identical groups are on the same side of the metal ion, it is cis-isomer. When they are on opposite sides of
the metal ion, it is trans-isomer.
ii.
a. Bidentate ligand has two donor atoms and can form two bonds whereas monodentate ligand has only one donor
atom and can form only one bond with the metal ion.
b. Diamminedichloridoplatinum(IV) chloride.

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c. Structures of geometrical isomers are given below:
OR
CoSO4Cl.5NH3:
i. Isomer A reacts with AgNO3 but not with BaCl2, it shows that it has Cl ion outside the coordination sphere. Hence,
A = [CO(NH3)5SO4]CI
Isomer B reacts with BaCl2 but not with AgNO3, it shows that it has SO4- outside the coordination sphere
Hence, B = [CO(NH3)5Cl]SO4
ii. Type of isomerism - Ionization isomerism.
iii. IUPAC name of, A = Pentaamminesulphatocobalt (III) chloride and B = Pentaamminesulphatocobalt (III) sulphate.
33. i. a.
b.
c.
ii. Increasing order of boiling point (CH3)3N < C2H5NH2 < C2H5OH Alcohols have a higher boiling point as compared
to that of amines because oxygen being more electronegative forms stronger hydrogen bond as compared to that of
nitrogen. In tertiary amine, there is no hydrogen bond formation due to the absence of H-atoms and hence, has the
lowest boiling point.
iii. (CH3)2NH and (CH3)3N are secondary and tertiary amines respectively. These are distinguished by Hinsberg's
reagent which gives sulphonamide with secondary amines and no reaction with tertiary amines. (CH3)2NH reacts
with benzene sulphonyl chloride to give N, N-dimethyl benzene sulphonamide, which is insoluble in alkali. The

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reaction is as follows:
OR
i. a. Nitration is carried out in acidic medium. In an acidic medium, aniline is protonated to form the anilinium ion
which is meta directing. That is why besides the ortho and para derivatives, a substantial amount of meta
derivative (m-nitroaniline) is also formed.
b. (CH3)2NH is a secondary amine and (CH3)3N is a tertiary amine. Tertiary amine due to the presence of three
alkyl groups is more hindered than secondary amine which has only two alkyl groups attached to it. Therefore
formation of ammonium ion is easier in secondary amine than the tertiary amine. Therefore, it makes secondary
amine less basic than the tertiary amine.
c. The ammonolysis of alkyl halide leads to the formation of the mixture of primary, secondary and tertiary amine
along with the formation of quaternary salt. It is very difficult to separate pure primary amine from this mixture.
Test CH3CH2NH2 (CH3CH2)2NH
ii. a.
Forms a foul-smelling
Carbylamine test (add chloroform and alcoholic KOH No reaction take place
compound (gives positive
to both the compounds separately in a test tube) (gives negative test)
test)
Azo dye Test Aniline Methyl Amine (CH3NH2)

b.
Add a small amount of nitrous acid Forms a yellow coloured dye (gives No dye is formed(gives
with aq. HCl positive test) negative test)

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Read the following instructions carefully.

a. There are 33 questions in this question paper with internal choice.

The order of acidity is

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(b) For ideal Solution (ii) i = 2

(c) For electrolyte Al2(SO4)3 (iii) i = 4

(d) For electrolyte Na3PO4 (iv) i = 1

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a) Both A and R are true and R is the correct explanation of A.

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by 1.5oC. Kf = 3.9 K kg mol-1.

b. Predict the products of electrolysis in the following:

Time/s Total pressure/atm

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28. Calculate the equilibrium constant for the reaction.

Why are melting points of transition metals high?

Equimolar solutions of NaCl and glucose are not isotonic. Why?

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c. Draw the structures of geometrical isomers of [Co(NH3)4Cl2]+.

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Acrolein is the common name of prop-2-enal.

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ii. Molar mass of chloroform (C HC l 3) = 1 × 12 + 1 × 1 + 3 × 35.5

Now, according to the question,

Therefore, Molality of the solution =

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Overall reaction is:

Using nernst equation for n=2,

At anode: 2OH (aq) → O (g) + 2H (aq) + 4e

H2(g) is evolved at cathode and O2(g) is evolved at anode.

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ii. Ethyne to ethanal

iii. Acetic acid to methane

C H3 C OOH −−−−→ C H3 C O O N a −−−−−−−→ C H4 + N a2 C O3

26. For the button cell, chemical reactions are:

Complete reaction is:

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less stable 1o carbocation as SN1 depends on stability of carbocation.

Ecell = E0Cu+2/Cu - E0Zn+2/Zn

It is due to strong interatomic forces of attraction due to presence of unpaired electrons.

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Azo dye Test Aniline Methyl Amine (CH3NH2)

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