Worksheet 2

//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [78]
1. The derivatives that are not found in nature are .........
(A) Alkanes (B) Carbohydrates (C) Haloalkanes (D) Fats
2. The compounds obtained by the substitution of hydrogen by halogen in alkane series is ......
(A) Aryl halides (B) Alkyl halides (C) Carbon halides (D) All of these
Which of the following drug is used in treatment of typhoid fever ?
RK
3.
(A) Bromopheneramine (B) Chloramphenicol (C) Chloroquine (D) Iodoform
4. Which of the following is present in a hormone thyroxine ?
(A) Fluorine (B) Iodine (C) Bromine (D) Chlorine
5. Which of the following is a primary halide ?
A
(A) Neopentyl bromide (B) Isopropyl bromide
(C) 2-Bromobutane (D) 2-Bromo-2-methyl propane
6.
7.
(A) Covalent RM
The nature of bond of carbon of alkyl group and halogen in alkyl halide is .........
(B) Co-ordinate covalent (C) Metallic
Which of the following is a vicinal dihalides ?
(D) Ionic
Br
|
(A) CH 3 – CH – CH 2 (B) CH 2 – CH2 – CH 2 (C) CH 3 – C – CH 3 (D) All of these
| | |
TE
| |
Br Br Br Br Br
8. Which of the following is a benzylic halide ?
CH2 – Cl CH2 – Br CH3
WA
CH3 CH3 CH3

CH2 – Br | | |
(A) (B) CH2 – C – CH 3 (C) CH2 – C – CH3 (D) CH2 – C – Br
| | |
CH3 CH3 CH3
9. Which of the following is allylic halide ?
(A) H 3C – CH = C – CH2 – CH – CH 3
T
| |
Br CH 3
SE
(B) Br – CH2 – CH = CH – CH 2 – CH – CH 3
|
CH3
CH3
|
(C) CH3 – C CH
| |
CH3 Br
(D) Br CH 2 – CH – CH 3
|
CH 3
10. Which of the following is vinylic halide ?
Br
|
(A) H 3C – CH = CH – C – CH 3 (B) Best Br
Wish You - All The
|
CH3
Which of the following is vinylic halide ?
Br
|
(A) H 3C – CH = CH – C – CH 3 (B) Br
|
CH3
CH 3
|
(C) CH 3CH 2 – CH = C – CH 2 – CH 2 – C – CH 3 (D) Cl CH2 – CH = CH – CH2 – Br
| |
Br CH3
11. Which of the following is an aryl halide ?
(A) 1-Chloromethyl-3-(2,2-dimethylpropyl) benzene
(B) 1-Bromo-2-(1-methylpropyl) benzene
(C) 1-Bromo-3,3-dimethyl-1-phenylbutane
(D) 3-Bromo-3-methyl-1-phenylbutane
RK
12. Which of the following is the correct order of dipole moment ?
(A) CH2Cl2 > CHCl3 > CCl4 (B) CHCl3 > CH2Cl2 > CCl4
(C) CCl4 > CH2Cl2 > CCl4 (D) CHCl3 > CH2Cl2 > CCl4
13. Which of the following is the correct order of dipole moment ?
A
(A) CH3F > CH3Cl > CH3Br > CH3I (B) CH3Cl > CH3F > CH3Br > CH3I
(C) CH3F > CH3Cl > CH3I > CH3Br (D) CH3I > CH3Br > CH3F > CH3Cl
14.
(A)
X
(B)
X
RM
The correct structure of o-dihalobenzne is .......
(C)
X
X
(D)
X
X
X X
sp 3
TE
15. In which of the following compounds the halogen is not bonded to carbon ?
(A) Ethylidene dichloride (B) Chloroethyl benzene
(C) 3-chlorocyclohex-1-ene (D) 1-chlorocyclohex-1-ene
16. The isomerism not shown by alkyl halides is....
(A) Chain isomerism (B) Functional isomersim (C) Position isomerism (D) Optical isomerism
WA
17. The IUPAC name of CH2 – CH2 is .........

| |
Br Br
(A) Ethane-1,2-dibromide (B) 1,2,-dibromo ethane
(C) Ethylidene bromide (D) Ethylene dibromide
18. Which of the following is 3o-Benzylic halide ?
T
CH 3 CH3 Cl
CH3
| | | CH2 – Cl
SE
(A) C – Cl (B) CH 2 – C – Cl (C) CH2 CH2 – C – Cl (D)

| | |
CH3 CH3 CH3
19. Which of the following has highest bond enthalpy ?
(A) CH 3–F (B) CH3–Cl (C) CH3–Br (D) CH3 – I
20. The common name of vicinal dihalide is ........
(A) 1,2-dihaloalkane (B) Alkylene dihalide
(C) Alkylidene halide (D) Alkane-1,2-dihalide
21. Which of the following carbocation is maximum stable ?
CH3
| CH 2 Å
(A) CH3 – C Å (B) (C) (D) H 2C = CH – CH 2
|
CH 3
Wish You - All The Best

22. Which substances are used in aerosol mixtures of insectiside substance ?
(A) Freon-22 (B) CClF3 (C) CCl2F2 (D) All of these
23. Alkyl halides are insoluble in .........
(A) Water (B) Benzene (C) Hexane (D) Toluene
24. Which of the following alkylhalides show optical isomerism ?
(A) 2-Bromobutane (B) Isobutylbromide
(C) Neopenthylbromide (D) 1,4-dichlorobutane
25. The alkyl halides are best prepared from ........
(A) Alcohols (B) Alkenes (C) Ethers (D) Alkanes
26. Which of the following is optically active ?
H3C CH3 H3C H H 3C CH3

H3C H
RK
(A) H (B) CH3 (C) CH3 (D) Br
H Br H3C Br Br
H H H Br H3C
H
H
27. Sym-Tribromobenzene is ..........
Br Br
Br Br Br
A
Br Br
(A) (B) (C) (D)
Br Br Br Br Br
28.
29.
(A) I2 + HIO3 (B) KI + H3PO4
Consider the following reaction :
RM
To prepare alkyl iodides from alcohols, which of following reagent is used ?
(C) NaI + Acetone (D) KI + H2SO4
HCl
R – OH ¾¾¾
® R – Cl + H2O
The above reaction is not true if R is ..........
TE
CH3
|
(A) (B) CH3 – (C) CH3 – CH2 – (D) CH 3 – C –
|
CH 3
30. In the following reaction :
WA
HCl
R – OH ¾¾¾
® R – Cl + H2O the, ZnCl2 is not required if R is ..........
CH3
|
(A) CH3 – (B) CH 3 – C – (C) CH 3 – CH – (D) CH3 – CH2 –
| |
CH 3 C 2 H5
T
31. The major product in the reaction is ..........

I
(A)
SE
I
(B)
+ HI
(C) I
(D)
32. The correct order of reactivity of alcohols with haloacids is ........
(A) 1º > 2º > 3º (B) 1º > 3º > 2º (C) 3º > 2º > 1º (D) 2º > 3º > 1º
33. In the given reaction the total number of products obtained are .........
(A) One
(B) Two + HI
(C) Three
(D) Four Wish You - All The Best
(A) One
(B) Two + HI
(C) Three
(D) Four
34. High purity and more quantity of haloalkanes are obtained by.....
(A) reaction of alcohol with sodium halide and conc. H 2SO4.
(B) reaction of alcohol with phosphorus halide.
(C) reaction of alcohol with HCl in presence of ZnCl2.
(D) reaction of alcohols with SOCl2.
35. Which of the following is not prepared directly from benzene ?
(A) Chlorobenzene (B) Bromobenzene (C) Methylbenzene (D) Fluorobenzene
36. Which of the following reagent is not used to prepare alkyl halides from alcohols ?
(A) Br2 / CCl4 (B) Red P + Br2 (C) NaBr / H2SO4 (D) KI + H3PO4
RK
37. Which of the following have the maximum boiling point ?
CH3
CH 2 – Cl |
(A) (B) CH3 – CH2CH2CH2Cl (C) CH 3 – CH CH 2Cl (D) CH 3 – C – Cl
| |
CH 3 CH 3
The major product in the reaction is .......
A
38.
CH3
(A) H
H Br
CH3
Br RM
CH3 H3C CH3
H Br C=C + Br2
TE
(B) Br + Enantiomer H H
H
CH3
Br – CH 2 CH 2 – Br
(C)
C C
WA
H H
Br – CH2 H
(D) C C
H CH 2 – Br
39. The metallic fluoride used in a Swartz reaction is.......
(A) NaF (B) Cu2F2 (C) Hg2F2 (D) MgF2
T
40. Which of the following has maximum density ?

(A) n-C3H7Cl (B) CCl4 (C) CHCl3 (D) n-C3H7Br
SE
41. Which of the following cannot be prepared from benzene diazonium halide ?
(A) Chlorobenzene (B) Fluorobenzene (C) Iodobenzene (D) None of these
Acetone
42. CH3CH2 – Br + NaI ¾¾¾¾¾
® X + NaBr
The (X) in above reaction is ...........
(A) Iodomethane (B) Iodoethane (C) Iodopropane (D) Iodobutane
43. Alkyl Fluorides are prepared by......
(A) Finkelstein reaction (B) Hunsdiecker reaction (C) Wurtz reaction (D) Swartz reaction
44. The reaction :
CCl
CH3COOAg + Br2 ¾¾¾®
4 CH3Br + CO2 +AgBr
is known as.....
(A) Finkelstin reaction (B) Hunsdiecker reaction
(C) Birnbaum-Simonini reaction (D) Balz-Schiemann reaction
is known as.....
(A) Finkelstin reaction (B) Hunsdiecker reaction
(C) Birnbaum-Simonini reaction (D) Balz-Schiemann reaction
45. The reaction :
+ – F
NH2 N2 Cl
NaNO 2 HBF4
0-5ºC D
is known as.....
(A) Sandmeyer’s reaction (B) Balz-schiemann reaction
(C) Birnbaum-Simonini reaction (D) Gatterman reaction
HBr
46. H3C – CH – CH = CH2 ¾¾¾ ®
|
CH3
Br
|
RK
(A) CH 3 – CH – CH – CH 3 (B) CH 3 – C – CH 2 – CH 3
| | |
CH3 Br CH3
Br
|
(C) CH 3 – CH – CH 2CH 2Br (D) CH 3 – C – CH 2CH 2 Br
| |
A
CH3 CH3
47. C2H5Br can be obtained in a laboratory by the action of ethyl alcohol with.....
48.
(A) KBr
Br2
CH3 – CH = CH2 ¾¾¾®
773K
CH 3 – CH – CH 3
(B) KBr + conc.
(A). The (A) is....

RM
(C) NH4Br (D) Br2
CH 3 – CH – CH2
(A) | (B) | |
Cl Cl Cl
(C) Cl – CH2 – CH = CH2 (D) CH3 – CH2 – CH2 – Cl
TE
SO Cl
CH3 – CH = CH2 ¾¾¾¾®
2 2
49. light (A). The (A) is....
(A) Cl – CH2 – CH = CH2 (B) CH 3 – CH – CH 3

WA
|
Cl
(C) CH 3 – CH – CH2 (D) Cl – CH2 – CH2 – CH2 – Cl
| |
Cl Cl
NBS
50. In the reaction : (P) The (P) is ..........
light
Br
T
Br Br
(A) (B) (C) (D)
Br Br
SE
Br Br
51. In the reaction :
I
[X]
+ I2
The [X] is .........

(A) FeI3 (B) HNO3 (C) HI (D) H3PO4
52. In the reaction :
CH3 SO Cl
2 2
(P)
hv
The product (P) is .........
CH3
CH3 CH3 Wish You - All The Best
(A) + (B)
(P)
hv
The product (P) is .........
CH3
CH3 CH3
(A) + (B)
Cl Cl Cl
CH2 – Cl CH2 – Cl
(C) (D)
Cl
53. The product (C) obtained in the following sequence of reaction is :
Br Br
(A)
NO2
NH2
RK
Cl
Br Br (i) HONO
Sn/HCl
(B) (A) (B)
(ii) Cu 2Cl2
Br Br
NO2 (i) HONO
Cl (C)
(ii) H3 PO2
A
(C) Br Br
(D)
Br
Cl
Br RM
Br
54. Which of the following will undergo SN2 most readily ?
TE
(A) CH 3 – C – CH 2 – I (B) CH3CH2I
||
O
(C) CH3 – O – CH2 – I (D) H2C = CH – CH2 – I
55. Arrange the following in decreasing order of their SN2 reactivity :
WA
(i) CH2Cl (ii) CH = CH – CH2 – Cl
(iii) H2C = CH – CH2 – Cl (iv) CH3CH2CH2Cl

(A) (iv) > (iii) > (i) > (ii) (B) (ii) > (i) > (iii) > (iv)
(C) (i) > (ii) > (iv) > (iii) (D) (iii) > (ii) > (i) > (iv)
56. Which of the following is correct order of hydrolysis ?
T
CH2 – Cl
(i)
Cl Cl
CH2 – Cl
SE
(ii) (iii) (iv)

H3CO
(A) (iii) > (iv) > (ii) > (i) (B) (ii) > (i) > (iii) > (iv)
(C) (iii) > (ii) > (i) > (iv) (D) (iv) > (i) > (ii) > (iii)
57. Identify the correct reactivity order of SN1 reaction :
O NH
(i) (ii) (iii)
Cl Cl Cl
(A) (iii) > (ii) > (i) (B) (i) > (ii) > (iii) (C) (i) > (iii) > (ii) (D) (i) > (ii) > (iii)
58. HO CH2 – Br
+
Ag(aq)
(P)
The product (P) in the reaction is ........

OH O NO2 OH
(A) (B) (C) (D) CH
HO CH2 – Br
+
Ag(aq)
(P)
The product (P) in the reaction is ........

OH O NO2 OH
(A) (B) (C) (D) CH3
59. The major product of the reaction is .......
CH3
H OC2H5
(A) H Br
CH3
CH3 CH3
C2H5O H H Br C2 H5 ONa +
RK
(B) H Br H Br D
CH3 CH3
CH 3 Br
(C) C=C
H CH 3
A
CH 3 CH3
(D) C=C
H Br
60.
ether. This reaction is called.....
(A) Wurtz Fittig reaction
RM
Toluene is obtained by reaction of mixture of chlorobenzene and methyl chloride with Na metal in dry
(B) Fittig reaction

(C) Grignard reaction (D) Friedel crafts reaction
61. The correct order of nucleophilic strength is.....
TE
(A) OH > CH3COO > CH3O > C6H5O (B) OH > CH3O > C6H5O > CH3COO
(C) OH > CH3O > CH3COO > C6H5O (D) CH3O > OH > C6H5O > CH3COO
62. Which one is the Swartz reaction from the following ?
acetone
(A) CH3Cl + NaI ¾¾¾¾¾ ® CH3I + NaCl
WA
acetone
(B) CH3Br + Nal ¾¾¾¾¾ ® CH3I + NaBr
(C) CH3Br + AgF ¾¾® CH3F + AgBr
Dry ether CH · CH + 2 NaCl
(D) 2CH3Cl + 2Na ¾¾¾¾¾ ¾® 3 3
63. Which one is not a Sandmeyer reagent ?
T
(A) Cu2Cl2 + HCl (B) Cu2Br2 + HBr (C) Cu2(CN)2 + KCN (D) Cu2I2 + KI
64. How many numbers of possible stereoisomers are there of 2, 3, 4-trichloro pentanoic acid ?
SE
(A) 8 (B) 12 (C) 16 (D) 4

65. Which of the following statement is incorrect for bimolecular nucleophylic substitution reaction
(SN2) ?
(A) It is a second order reaction.
(B) In SN2 reaction the substrate does not undergo heterolytic fission.
(C) The rate of SN2 reaction does not depends on concentrations of both substrate and nucleophilic
reagent.
(D) SN2 reaction occurs in single step without forming intermediate.
66. Which of the following is allylic halide ?
(A) Benzyl chloride (B) (1 - bromo ethyl) benzene
(C) 1 - bromo benzene (D) 3 - chloro cyclo hex - 1 - ene

acetone
67. Name the following reaction CH3CH2Cl + NaI ¾¾¾¾¾
® CH3CH2I + NaCl
(A) Swartz reaction (B) Finkelstein reaction
(C) Wurtz reaction (D) Hell-Volhard Zelinsky reaction
68. Which of following structure shows R configuration ?
H H CH3 OH
(A) H3C OCH3 (B) HO OCH3 (C) H OH (D) H NH2

CH2CH3 CH3 CH3
CHO
69. The reaction of (CH3)3CONa with ........ reagent is the most easy ?
(A) (CH3)2 CHBr (B) CH2CH2Br (C) (CH3)3CBr (D) C6H5Br
70. Which statement is improper for tetrachloro methane ?
RK
(A) When it comes in direct contact of skin, red rashes are formed.
(B) At high temperature on reaction with water forms phosgene.
(C) It is used for extinguishing the fire in substances like oil and petrol
(D) It is insoluble in water and gives fragrance
A
71. Which of the following compound is the most basic ?
NH2 NH2 NH2 NH2
(A)
Cl
(B)
OCH3
RM (C) (D)
NO2
72. Which of the following group of compounds are extinguisher, antiseptic, insecticide and anesthetic
respectively ?
(A) CHCl3, CHI3, DDT, CCl4 (B) DDT, CHCl3, CCl4, CHl3
TE
(C) CCl4, CHI3, DDT, CHCl3 (D) CCl4, CHI3, CHCl3, DDT
73. Polarimeter is used to determine of compounds.
(A) D and L configuration (B) d and l configuration
(C) R and S configuration (D) Both D and L as well as d & l configuration
WA
74. 1,2-dichloro ethane is which type of halide ?

(A) Geminal halide (B) Vicinal halide (C) Alkylidene halide (D) Allylic halide
75. In which of the following, halogenated carbon possesses sp3 hybridization ?
Cl
Cl CH2 – Cl
(A) (B) (C) CH2 = CH–Cl (D)
T
76. How many s and p bonds are present in Vinyl Chloride ?

(A) 5 s and 1 p (B) 4 s and 2 p (C) 5 s and 2 p (D) 4 s and 1 p
SE
77. The rate of the second order reaction depends on .........

(A) only concentration of substrate (B) concentration of two reactants
(C) concentration of product (D) concentration of neucleophile
78. Give the product of following reaction
NH2
NaNO2 + 2HCl
¾¾¾¾¾¾¾¾ ®
273K – 278K
(A) Nitrobenzene (B) Chlorobenzene

(C) Benzene diazonium chloride (D) Benzene

Section [ A ] : 1 Mark MCQ
No Ans Chap Sec Que Universal_QueId

1. C Chap 10 (Part2) E-A 1 QP21P11B1212_P2C10S9Q1
2. B Chap 10 (Part2) E-A 2 QP21P11B1212_P2C10S9Q2
5. A Chap 10 (Part2) E-A 7 QP21P11B1212_P2C10S9Q7
15. D Chap 10 (Part2) E-A 18 QP21P11B1212_P2C10S9Q18
Welcome To Future - Quantum Paper

62. C Chap 10 (Part2) E-D 3 QP21P11B1212_P2C10S12Q3
63. D Chap 10 (Part2) E-D 2 QP21P11B1212_P2C10S12Q2
64. A Chap 10 (Part2) E-D 1 QP21P11B1212_P2C10S12Q1
67. B Chap 10 (Part2) E-D 7 QP21P11B1212_P2C10S12Q7


Student Name : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
Roll Number : 0 1 2 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9
A B C D A B C D A B C D A B C D
1. 21. 41. 61.
2. 22. 42. 62.
3. 23. 43. 63.
4. 24. 44. 64.
5. 25. 45. 65.
6. 26. 46. 66.
7. 27. 47. 67.
8. 28. 48. 68.
9. 29. 49. 69.
10. 30. 50. 70.
11. 31. 51. 71.
12. 32. 52. 72.
13. 33. 53. 73.
14. 34. 54. 74.
15. 35. 55. 75.
16. 36. 56. 76.
17. 37. 57. 77.
18. 38. 58. 78.
19. 39. 59.
20. 40. 60.

OMR ANSWER SHEET
Marks Identifier :
A B C D A B C D A B C D A B C D
1. 21. 41. 61.
2. 22. 42. 62.
3. 23. 43. 63.
4. 24. 44. 64.
5. 25. 45. 65.
6. 26. 46. 66.
7. 27. 47. 67.
8. 28. 48. 68.
9. 29. 49. 69.
10. 30. 50. 70.
11. 31. 51. 71.
12. 32. 52. 72.
13. 33. 53. 73.
14. 34. 54. 74.
15. 35. 55. 75.
16. 36. 56. 76.
17. 37. 57. 77.
18. 38. 58. 78.
19. 39. 59.
20. 40. 60.

//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [78]
1.
2.
3.
4.
5.
6.
7.
8.
9.

10.
11.
12.
13.

14.
15.
16.
17.
18.
19.
20.
21.
22.
23.

24.
25.
26.
27.
28.
29.
30.

31.
32.
33.
34.
35.
36.

37.
38.
39.
40.
41.
42.
43.
44.

45.
46.
47.
48.
49.
50.
51.

52.
53.
54.
55.

56.
57.
58.
59.

60.
61.
62.
63.
64.
65.
66.
67.

68.
69.
70.
71.
72.
73.
74.
75.

76.
77.
78.

Worksheet 2

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Worksheet 2

Uploaded by

Copyright:

Available Formats

//X Section A

CH3 CH3 CH3

17. The IUPAC name of CH2 – CH2 is .........

(A) C – Cl (B) CH 2 – C – Cl (C) CH2 CH2 – C – Cl (D)

Wish You - All The Best

H3C CH3 H3C H H 3C CH3

31. The major product in the reaction is ..........

40. Which of the following has maximum density ?

(A). The (A) is....

(A) Cl – CH2 – CH = CH2 (B) CH 3 – CH – CH 3

The [X] is .........

(i) CH2Cl (ii) CH = CH – CH2 – Cl

(iii) H2C = CH – CH2 – Cl (iv) CH3CH2CH2Cl

(ii) (iii) (iv)

The product (P) in the reaction is ........

The product (P) in the reaction is ........

59. The major product of the reaction is .......

(B) Fittig reaction

(A) 8 (B) 12 (C) 16 (D) 4

Wish You - All The Best

(A) H3C OCH3 (B) HO OCH3 (C) H OH (D) H NH2

74. 1,2-dichloro ethane is which type of halide ?

76. How many s and p bonds are present in Vinyl Chloride ?

77. The rate of the second order reaction depends on .........

(A) Nitrobenzene (B) Chlorobenzene

Wish You - All The Best

No Ans Chap Sec Que Universal_QueId

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper

1. 21. 41. 61.

2. 22. 42. 62.

3. 23. 43. 63.

4. 24. 44. 64.

5. 25. 45. 65.

6. 26. 46. 66.

7. 27. 47. 67.

8. 28. 48. 68.

9. 29. 49. 69.

10. 30. 50. 70.

11. 31. 51. 71.

12. 32. 52. 72.

13. 33. 53. 73.

14. 34. 54. 74.

15. 35. 55. 75.

16. 36. 56. 76.

17. 37. 57. 77.

18. 38. 58. 78.

19. 39. 59.

20. 40. 60.

1. 21. 41. 61.

2. 22. 42. 62.

3. 23. 43. 63.

4. 24. 44. 64.

5. 25. 45. 65.

6. 26. 46. 66.

7. 27. 47. 67.

8. 28. 48. 68.

9. 29. 49. 69.

10. 30. 50. 70.

11. 31. 51. 71.

12. 32. 52. 72.

13. 33. 53. 73.

14. 34. 54. 74.