41. In the reaction NaHCO3+HCl→NaCl+H2CO3, sodium bicarbonate 49.

Calculate the heat evolved when 266 g of white phosphorus (P 4)

acts as burn in air according to the equation
a. Acid c. Ampoteric substance P4(s) + 5O2(g)→ P4O10(s) ΔH=-3013 kJ/mol
b. Base d. spectator ion a. 3013 kJ c. -6463 kJ
42. Gases A and B have MWs of 15 and 30 g/mol, respectively. At b. 6463 J d. -3013 kJ
30oC, their speed will differ by how many percent? 266
a. A higher than B by 50% ∆ H= (−3013 kJ )=−6463.371 kJ
124
b. B higher than A by 50%
50. The reaction A → B has ΔH= − 153 kJ/mol, is reacted in a
c. A higher than B by 41%
d. B higher than A by 41% constant-volume calorimetry. Assuming that the heat capacity of

√
the bomb is negligible, calculate the change in temperature of
rA MB 3.00-L water (initially at 25oC) when 3 moles of A has reacted.
= =√ 2
rB M2 a. 52 c. 72
b. 62 d.82
r A =r A √ 2=1.414 r A , ∴ A is higher ny 41 %
153000 ( 3 )=3000( 4.184)(x−25)
43. Calculate the density of a mixture of 50%methane, 30%oxygen
and 20% carbon dioxide at 100oC and 1 atm. x=61.57 ℃
a. 0.8622 g/L c. 0.8622 g/m3 51. The reaction in the previous problem is carried out at the same
b. 0.8622 g/mL d. None manner, only that the water was elevated to a temperature of
50oC, how many grams of A is reacted? The molecular weight of
component %mole MW weighted MW A is 29 g/mol.
a. 20.5 c. 94.7
CH4 50 16 8 b. 59.5 d. 84.3

O2 30 32 9.6
153000 ( 29x )=3000 ( 4.184) ( 50−25) ; x=59.48 g
o
CO2 20 44 8.8
52. Given KClO3 is heated, calculate ∆ H rxn . [Given
o
∆ H f : KCl O 3=−391.20 kJ / mol , KCl=−435.87 kJ / mol
Total 100 26.4
]
a. -89.34 kJ c. -44.67
PM 1 ( 26.4 ) b. b. 346.53 d. -827.07
ρ= = =0.8622 g/ L 2 KClO3 →2 KCl+3 O2
RT 0.08206 (373.15) o
44. A vessel contains two gases A and B at 100oC and 1 atm, the ∆ H =2 (−435.87 )−2 (−391.20 ) =−89.34 kJ
rxn
density is 1 g/L. If the partial pressure of A is 0.25 atm, average 53. A gas expands from 264 mL to 971 mL at constant temperature.
molecular weight of the two gases? Calculate the work done (in joules) by the gas if it expands
a. 31 c. 51 against a constant pressure of 4.00 atm?
b. 41 d. 61 i. 707 c. 2828
ρRT (1)(0.08206)(373.15) ii. 0.283 d. -286.55
M= = =30.6207 g /mol W =−P ∆ V =−4 ( 101325 ) ( 0.971−0.264 ) /1000=−286.54
P 1
45. If the molecular weight if B is 20 g/mol in the previous problem,
what is the molecular weight of A? 54. Consider the following apparatus. Calculate the partial pressure
a. 62.48 c. 48.62 of helium after the stopcock is open. The temperature remains
b. b. 24.86 d. 86.24 constant at 16°C.
0.25 ( x )+ 0.75 ( 20 )=30.6207 ; x=62.48 g/mol a. 0.4331
b. 2.0695
46. Carbon dioxide is being collected over water at 30 oC and 1 atm c. 2.2339
from the decomposition of 100 g of Na2CO3 as it being heated. d. 0.1643
The total volume collected is 1000 mL. How much carbon dioxide
is collected? (VP of water at 30oC is 31.82 mmHg)
a. 0.039 g c. 1.947 g V T =1.2+3.4=4.6 L
b. 1.695 g d. 16.95 g 0.63 ( 1.2 )
N a2 C O3 → N a2 O+C O2 n He = =0.03186
0.08206 ( 16+ 273.15 )
760−31.82
( 1) 2.8 ( 3.4 )
PV 760 n Ne= =0.40122
mC O = M= (44)=1.695 g 0.08206 ( 16+273.15 )
2
RT 0.08206 ( 30+273.15 )
47. What is the degree of completion of the reaction? x He =0.073566
a. <10% c. From 50% to 90% ( 0.03186+0.40122 )( 0.08206 )( 16+ 273.15 )
b. From 10% to 50% d. >90 % PT =
4.6
100 1 44
mC O theo=
106 1 1
2 ( )( )
=41.5094 g ¿ 2.2339
P He=0.073566 (2.2339 )=0.1643 atm
1.695
%completion= ∗100=4.08 % 55. From the previous problem, what is the total pressure after the
41.5095
o
48. 100 g of water is heated from 25 to 80 C, what is the amount of stopcock is opened?
heat acquired by the water? specific heat of water is 4.184 J/g∙ oC a. 0.4331 c. 2.2339
a. 23 kJ c. -23 kJ b. b. 2.0695 d. 0.1643
b. 23 J d. -23 J 56. A mixture of Na2CO3 and MgCO3 of mass 7.63 g is reacted with
q=ms ∆ T =100 ( 4.184 ) ( 80−25 )=23 kJ an excess of hydrochloric acid. The CO2 gas generated
occupies a volume of 1.67 L at 1.24 atm and 26°C. From these
data, calculate the percent composition by mass of Na 2CO3 in
the mixture. [Mg]=24
 a. 26.3% c. 75.5%
b. 50.1% d. 34.4%
N a2 C O3 +2 HCl → 2 NaCl+ H 2 O+ C O2
MgC O 3 +2 HCl → MgC l 2+ H 2 O+C O2
PV 1.24 ( 1.67 )
mC O = M= 44=3.711678
2
RT 0.08206 ( 26+273.15 )

106 1 ( )
x 44 7.63−x 44
+
84 ( )
1
=3.711678 ; x=2.6214 g

2.6214
%N a 2 C O3= ∗100=34.36
7.63