CHEMISTRY 1

BATCH: XI – IIT/NEET DPT Date 25.12.2023

THERMODYNAMICS (FULL)

1. For the complete combustion of ethanol, 6. Given

C2H5OH(l) + 3O2(g)  2CO2(g) + 3H2O(l) (I) C(diamond)+O2(g) 
the amount of heat produced as measured in
CO2 ( g ); H o  92.0 kcal mol–1
bomb calorimeter is 1364.47 kJ mol–1 at
(II) C(graphite)+O2(g)  CO2(g);
25oC. Assuming ideality,, the enthalpy of
combustion, ΔH C , for the reaction will be H o  96.0 kcal mol–1
[R = 8.314 JK–1 mol–1] At 298 K, 2.6 kg of carbon (diamond)
(diamon is
(a) –1366.95 kJ mol–1 converted into graphite. Thus, entropy change
(b) –1361.95 kJ mol–1 is:
(c) –1460.50 kJ mol–1 (a) 2.907 kcal K–1 (b) 2.013 kcal K–1
(d) –1350.50 kJ mol–1 (c) 305.4 cal K–1 (d) –2.013 kcal K–1

7. For a certain reaction X  Y the value of

2. When 20 mL of a strong acid is added to 20
kali, the temperature rises by 5oC.
mL of an alkali, H and S are 50.50 kJ mol–1 and 100.03
If 200 mL of each liquid, is mixed, the JK–1 respectively. the temperature at which
temperature rise will be: G  0 is:
(a) 5oC (b) 50oC (a) 505oC (b) 232oC
(c) 20oC (d) 0.5oC (c) 252oC (d) 450oC

3. The amount of heat required to raise the 8. Standard entropy of X2, Y2 and XY3 are 60,
temperature of 1 mole of diatomic gas by 1oC 40 and 50 J K–1 mol–1, respectively, for the
at constant pressure is 600 cal. The amount of reaction,
heat which goes as internal energy of the gas 1 3
X 2  Y2  XY3, H  30 kJ, to be at
is nearly. 2 2
(a) 60 Cal (b) 30 Cal equilibrium,
ibrium, the temperature will be:
(c) 42.6 Cal (d) 49.8 Cal (a) 1250 K (b) 500 K
(c) 750 K (d) 1000 K
4. Molar heat capacity of water in equilibrium
with ice at constant pressure is: 9. Which reaction, with the following values of
(a) zero H and S at 350 K is spontaneous and
(b) Infinity (  ) endothermic?
(c) 40.45 kJ K–1 mol–1 H kJ mol 1 S kJ mol 1
(d) 75.48 kJ K–1 mol–1
(a) –48 + 135  10 3
5. For the reaction (b) –48 135  10 3
X 2 O 4 ()  2XO 2 .(g) E  2.1 kcal,
(c) +48  135  10 3
S  20 cal/K at 300 K. Hence G is:
(d) +48  135  10 3
(a) 2.7 kcal (b) –2.7
2.7 kcal
(c) 9.3 kcal (d) –9.3
9.3 kcal

Sarwar Classes, Venus Tower, Medical Road, Civil Lines, Aligarh. Ph: 9219418880
 CHEMISTRY 2

10. Which of the following reactions is At 298 K standard Gibbs energies of

associated with the most negative change in formation for CH3OH(l),
OH( H2O(l) and CO2(g)
entropy? are –166.2, –237.237.2 and –394.4 kJ mol–1,
(a) 2SO2 ( g )  O2 ( g )  2SO3 ((g ) respectively. if standard enthalpy of combust
(b) C 2 H 4 ( g )  H 2 ( g )  C 2 H 6 ( g ) ion of methanol is –726 kJ mol–1, efficiency
of the fuel cell will be
(c) C (s graphite)  O2  CO2 (g )
(a) 80% (b) 87%
(d) 3C 2 H 2 ( g )  C 6 H 6 ( g ) (c) 90% (d) 97%

11. The entropy change involved in the 15. Calculate the entropy change when 3.6 g of
isothermal reversible expansion of 2 moles of liquid water is completely converted into
an ideal gas from a volume a 10 dm3 to a vapour at 100oC. C the molar heat of
volume of 100 dm3 at 27oC is: vaporization is 40.85 kJ mol–1.
(a) 38.3 J mol 1K 1 (b) 35.8 J mol 1K 1 (a) 6.08 J K–1 (b) 109.5 J K–1
(c) 21.89 J K–1 (d) –21.89 J K–1
(c) 32.3 J mol–1 K–1 (d) 42.3 J mol–1 K–1

16. Predict which of the following reaction (s)

(
12. Two moles of an ideal gas is expanded
has a positive entropy change?
irreversibly and isothermally at 37oC until its
volume is doubled and 3.41 kJ heat is I. Ag  (aq)  Cl  (aq)  AgCl ( s )
absorbed from surrounding, S total (system + II. NH4Cl(s)  NH3(g) + HCl(g)
surrounding) is: III. 2 NH 3 ( g )  N 2 ( g )  3H 2 ( g )
(a) –0.52 J/K (b) 0.52 J/K (a) I and II (b) III
(c) 22.52 J/K (d) 0 (c) II and III (d) II

13. C2 H 6 ( g )  3.5 O2 ( g )  2CO2 ( g )  3H 2O( g ) 17. A particular state of system is arrived at

starting
ting from a given state in two different
S vap ( H 2 O, )  x1 cal K 1 (boiling point =
ways (l) following reversible path and (2)
T1) irreversible path. Which of the following
H f ( H 2 O)  x2 relations would be correct if the processes are
H f (CO2 )  x3 isothermal?
(a) S rev  S irrev
H f (C 2 H 6 )  x4
(b) q rev  qirrev
Hence,  H for the reaction is:
q rev
(a) 2 x3  3x 2  x 4 (c) S rev  S irrev 
T
(b) 2 x3  3x 2  x 4  3x1T1 qirrev
(d) S irrev   S rev
(c) 2 x  3x 2  x 4  3x1T1 T
(c) x1T1  x 2  x3  x4

14. In a fuel cell, methanol is used as fuel and

oxygen gas is used as an oxi oxidiser. The
reaction is

CH 3OH (l )  O2 ( g )  CO2 ( g )  2 H 2 O(l )
2

Sarwar Classes, Venus Tower, Medical Road, Civil Lines, Aligarh. Ph: 9219418880
 CHEMISTRY 3

ANSWER KEY
DPT XI
XI-IIT/NEET DATE 25.12.2023
THERMODYNAMICS (FULL)

Que. 1 2 3 4 5 6 7 8 9 10
Ans. A A C B B A B C C D
Que. 11 12 13 14 15 16 17
Ans. A B B D C C C

Sarwar Classes, Venus Tower, Medical Road, Civil Lines, Aligarh. Ph: 9219418880