QAD series 2023 /Chemistry NAME

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Physical Chemistry
1. In a closed insulated vessel, a liquid is stirred with 13. The value of H for the combustion of ethane and
paddle to increases the temp. Which of the following acetylene are -341.1 and -310.9 kcal, respectively. The
is true? better fuel is:
a) E = W ≠ 0, q=0 b) E = W = q ≠ 0 a) ethane b) acetylene c) both a & b d) none
c) E = 0, W = q ≠ 0 d) W = 0, E = q ≠ 0 14. The heat of formation of methane at 25c at a constant
pressure is-17.890 kcal. Its heat of formation at
2. A → B, H = 4 Kcal mol S = 10 cal mol–1 k–1. The
–1
constant volume is: (R = 1.987 cal degree -1 mol-1)
reaction is spontaneous when the temp. is a) -17.297 kcal b) +17.297 kcal
a) 400K b) 300 K c) 500 K d) none c) -172.97 kcal d) +172.97 kcal
3. An ideal gas is allowed to expand under adiabatic 15. Two moles of an ideal gas expand spontaneously into
condition What is zero for given change? a vacuum. The work done is:
a. T b. G c. S d. none a) 2 Joule b) 4 Joule c) zero Joule d) infinite
4. Which of the following is correct for the reaction? 16. The enthalpy of combustion of benzene is-3264.6kjper
mole. The total heat released by combustion of 150g in
C2H4(g) + 3O2 → 2CO2(g) + 2H2O(l)
kJ of benzene in open container is,
a) H = E + RT b) H =  + 2RT a) 816.15 b) 1632.3 c) 6528.2 d) 2848.5
c) H = E – RT d) H =  – 2RT 17. The following is not endothermic reaction:
5. The temperature of the system decreases in an: a) Combustion of methane
a) Adiabatic compression b) Isothermal compression b) Decomposition of water
c) Dehydrogenation of ethane to ethylene
c) Adiabatic expansion d) Isothermal expansion d) Conversion of graphite to diamond
6. Based on 1 law of thermodynamics, which one of the
st
18. Which one of the following process is not
following is correct, spontaneous?
a) for isochoric process: E = -q a) Dissolution of CuSO4 in water
b) for an adiabatic process: E = -w b) Reaction between H2 and O2 to form water
c) water flowing down hill
c) for isothermal process : q = w
d) flow of electric current from low potential to high
d) for cyclic process: q=-w 19. The heat of transition (H1) of graphite into diamond
7. Given that C + O2 → CO2 H = -xKJ would be, where
2CO + O2 → 2CO2 H = -yKJ the enthalpy of C (graphite) + O2(g) → CO2(g) ; H = – xkj
formation of carbonmonoixde will be: C (diamond) + O2(g) → CO2(g) ; H = – ykj
2x - y y - 2x a) ( x + y) kj mol-1 b) (x – y)kjmol-1
a) 2 b) 2 c) 2x – y d) y – 2x
c) (y – x)kjmol -1 d) none of these
8. A piece of ice kept at room temperature melts of its 20. The lowest value of heat of neutralization is obtained
own. This reaction is governed by for:
a) first law of thermodynamics a) HCl + NaOH b) CH3COOH + NH4OH
b) Second law of thermodynamics c) NH4OH + HCl d) NaOH + CH3COOH
c) Third law of thermodynamics 21. The reaction A → B, H = +24kJ, B → C, H = –18kJ.
d) Zero law of thermodynamics The decreasing order of enthalpy of A, B, C follow the
9. In thermodynamics, a process is said to be reversible order
when:
a) A, B, C b) B, C, A c) C, B, A d) C, A, B
a) surrounding and system change into each other
b) there is no boundary between system and 22. Standard molar enthalpy of formation of CO 2 is equal
surrounding to:
c) The surrounding are always in equilibrium with a) zero
system b) The standard molar enthalpy of combustion of
d) the system changes into surroundings spontaneously gaseous carbon
10. Heat liberated when 100ml of 1N NaOH is neutralized c) The sum of standard molar enthalpies of formation of
by 300ml of 1N H2SO4 is CO & O2
a) 22.92 kJ b) 17.19 kJ c) 11.46 kJ d) 5.73 kJ d)The standard molar enthalpy of combustion of carbon
11. For the process, Dry ice → CO2(g) (graphite)
a) H = +ve, s = -ve b) both H, s = -ve 23. Hºf (CH3OH) is given by chemical equation:
c) both H, s = +ve d) H = -ve, s = +ve 1
a) CH4(g) + 2 O2(g) → CH3OH(g)
12. If enthalpies of formation for C2H4(g),CO2(g) and
H2O(l) at 25c and 1 atm pressure are 52kj/mol, - b) CO(g) + 2H2(g) → CH3OH(l)
394kj/mol and -286kj/mol respectively, then enthalpy 1
c) C (graphite) + 2 O2(g) + 2H2(g) →CH2OH(l)
of combustion of C2H4(g) will be
a) -141.2 kj/mol b) -1412 kj/mol 1
d) C (diamond) + 2 O2(g) + 2H2(g) →CH3OH(l)
c) -14.2 kj/mol d) +1412 kj/mol
QAD series 2023 /Chemistry NAME
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24. Energy required to dissociated 4g of gaseous hydrogen a) 10 atm b) 30 atm c) 45 atm d) 5 atm
into free gaseous atoms is 208 kcal at 25c. the bond 40. The molar mass of an ideal gas can be calculated from
energy of H – H bond will be: the expression:
a) 104 kcal b) 10.4 kcal c) 1040 kcal d) 10 kcal dRT RT Pd dRT
25. The occurrence of a reaction is impossible if: a) M = PV b) M = Pd c) M = RT d) M = P
a) H is + ve; S is also + ve but H < TS 41. Equal masses of methane & O1 are mixed in an empty
b) H is - ve; S is also + ve but H > TS container at 25ºC. The fraction of total pressure
c) H is - ve; S is + ve exerted by oxygen is
d) H is + ve; S is – ve 1 2 1 273 1
a) 2 b) 3 c) 2 × 298 d) 3
26. A reaction is spontaneous at low temp but non
spontaneous at high temp. Which of the following is 42. At a constant pressure, what should be the percentage
true? increase in the temperature in Kelvin for a 10%
a) H > 0, S > 0 b) H < 0, S > 0 increase in the volume
c) H > 0, S = 0 d) H < 0, S < 0 a) 10% b) 20% c) 5% d) 50%
27. If a molecule MX3 has zero dipole moment, the sigma 43. A football bladder contains equimolar proportions of
bonding orbitals used by M (at no. < 21) are H2 and O2. The composition by mass of the mixture
a) pure p b) sp c) sp2 d) sp3 effusing out of punctured football is in ratio (H 2 : O2)
28. Highest viscosity is exhibited by is
a) Glycerol b) Ethylene glycol a) 1 : 4 b) 2 2 : 1 c) 1 : 2 2 d) 4 : 1
c) Water d) Ethanol 44. 100 ml of O2 gas diffuses in 10 sec. 100 ml of gas X
29. Which of the following pairs of molecules have diffuses in t sec. Gas X and t can't be
permanent dipole moments for both members? a) H2, 2.5 sec b) SO2, 16 sec
a) SiF4, NO2 b) NO2, CO2 c) NO2, O3 d) SiF4, CO2 c) CO, 10 sec d) He, 4 sec
30. Which of the following molecule has shortest C-H 45. Gas deviates from ideal gas nature because molecules
bond? a) are colourless
a. ethane b. methane c. ethene d. ethyne b) attract each other
31. During hydrogen bond formation maximum energy is c) contain covalent bond
for: d) show Brownian movement
a) F …. H …. S b) O …. H …. N 46. A gaseous mixture of 2 moles of A, 3 moles of B, 5
c) O …. H .... O d) N .... H .... N moles of C and 10 moles of D is contained in a vessel.
32. Which of the following has nonplanar geometry? Assuming that the gases are ideal and the partial
a) XeF2 b) PCl3 c) XeF4 d) CS2 pressure of C is 1.5 atm. The total pressure is
33. Lattice energy of an ionic compound depends upon a) 3 atm b) 6 atm c) 9 atm d) 15 atm
a) Charge on the ion only 47. The density of gas is 1.964 gm lit –1 at 273 K and
b) Size of the ion only pressure of 76 cm hg. The gas is
c) Packing of ions only a) CH4 b) C2H6 c) CO2 d) Xe
d) Charge on the ion and size of the ion 48. If open flask containing air is heated from 300 K to 500
34. Which of the given pairs have similar geometry? K. The percentage of air escaped to atm. is nearly:
a) NH3,BH3 b) HgCl2, SnCl4 a) 16.6 b) 40 c) 60 d) 20
c) CH3- ,CH3+ d) SO4--,ClO4- 49. The rate of diffusion of CH4 at given temp. is twice
that of gas X. The mol. wt. of X is
35. The molecule having one unpaired electron is
a) 64 b) 32 c) 4 d) 8.0
a) NO b) CO c) CN¯ d) O2
50. Any gas shows maximum deviation from ideal gas at
36. AlCl3 is covalent while AlF3 is ionic. This fact can be
a) 0ºC & 1 atm pressure b) 100ºC & 2 atm
justified on the basis of
a) valcence bond theory b) crystal structure c) – 100ºC & 5 atm d) 500ºC & 1 atm
51. Dalton’s law of partial pressure is applicable to which
c) lattice energy d) Fajan's rule
of the following systems?
37. As compared to pure atomic orbitals, hybrid orbitals
a) NO + O2 b) NH3 + HCl
have
a) Low energy b) Same energy c) CO + H2 d) H2 + Cl2
52. Reducing the pressure from 1.0 to 0.5 atm would
c) High energy d) None of these
change the number of molecules in one mole of
38. The angles between covalent bonds is maximum in
ammonia to
a) CH4 b) BF3 c) PF3 d) NH3
a) 75% of initial value b) 50% of initial value
39. A gas at pressure 5 atm is heated from 0ºC to 546 and
c) 25% of initial value d) none of these
simultaneously compressed to 1/3 of its origin volume.
Hence final pressure is

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