CHEMISTRY BY ASHWANI OHRI

THERMODYNAMICS (Assignment)
Basic concept d) A quantity which is used to express
1. Dead body is an example of pressure volume work
a) Close system 6. For an adiabatic process:
b) Open system a) Q = + W b) Q = 0
c) Isolated system c) E= q d) P V=0
d) Adiabatic system 7. An ideal gas is allowed to expand under
2. In which one of the following sets, all the adiabatic conditions. What is zero for
properties belong to same category (all such a process?
extensive or all intensive)? a) G b) T
a) mass, volume, pressure c) S d) None of these
b) temperature, pressure, volume 8. In thermodynamics, a process is called
c) heat capacity, density, mass reversible when
d) enthalpy, internal energy, volume a) surroundings and system change into
3. A well stoppered thermos flask contains each other
some ice cubes. This is an example of b) there is no boundary between system
[AIIMS] and surroundings
a) Closed system c) the surroundings are always in
b) Open system equilibrium with the system
c) Isolated system d) the system changes into the
d) Non-thermodynamic system surroundings spontaneously
4. Which among the following is not a state Internal Energy, First Law of
function? [CBSE PM7] thermodynamics, Enthalpy and their
a) Internal energy (E) b) Free energy (c) relationship.
c) Enthalpy (H) d) Work (W). 9. When 10 ml of 0.1 M soln. of HCI is mixed
5. A thermodynamic state function is with 10 ml of 0.1 M of KOH solution the
a) One which obeys all the laws of rise in temperature was observed to be
thermodynamics 4°C. If 100 ml of 0.1 M HCI and 100 ml of
b) A quantity which is used to measure 0.1 M KOH is mixed in the same vessel,
thermal changes the rise in temperature would be
c) A quantity whose value is independent a) 40°C b) 4°C
of the path c) 20°C d) Unpredictable
10. Which of the following statement does not kcal/mol. What will be the change in
represent first law of thermodynamics? internal energy (ΔE) of 3 mole of liquid at
a) Energy of universe is conserved same temperature:
b) It is not possible to construct a a)13.0 kcal b) -13.0 kcal
perpetual motion machine c) 27.0 kcal d) -27.0 kcal
c) Energy of system and surrounding 19. When 50 cm 3 of 0.2 N H2SO4 is mixed
during any chemical or physical change with 50 cm 3 of 1 N KOH, the heat librated
remains constant. is
d) It is not possible to convert heat into a) 11.46kJ b) 57.3k J
work completely. c) 573 kJ d) 573 J
11. A gas occupies 2L at STP. It is provided 20. The enthalpy of combustion of methane at
with 300 J of heat so that its volume 25°C is 890 kJ. The heat librated when
become 2.5 L at a pressure of 1 atm. The 3.2 g of methane is burnt in air is
value of ΔU of the process is a) 445 kJ b) 278 kJ
a) 249.35 J b) 350.65 J c) -890 kJ d) 178 kJ
c) 150.35 J d) 400.0 J 21. The ΔHf o for CO2(g), CO(g) and H2O(g) are
12. The heat of combustion of benzene 393.5, -110.5 and -241.8 kJ mol-1
determined in a bomb calorimeter is -870 respectively. The standard enthalpy
kcal mole-1 at 298 K. The value of ΔE for change (in kJ mol-1) for the reaction
the reaction is CO2 g H2 g CO g H2O g is
a) -174 kcal mole-1
b) -870 kcal mole-1 a) 534.1 b)- 41.2
c) + 870 kcal mole-1 c) -262.5 d) -41.2
d) + 1740 kcal mote-1 22. In the dia[gram given below, the work
13. The heat evolved during the combustion done in complete cycle ABCD in Joule is
of 46 g ethanol in a bomb calorimeter was
determined to the 670.48 kcal mol-1 at
25°C. The value of ΔE of the reaction at
the same temperature is
a) - 335.24 kcal
b) -669.28 kcal
c) - 670.48 kcal
d) cannot be predicted
14. The heat of formation of NH3 at constant
pressure at 350°C is -50.2 KJ mole-1. a) 36 x 10-3J b) -36 x 10-3 J
-3
What will be the heat of formation of NH3 c) 60x10 J d) -60 x 10-3J
at constant volume at this temperature 23. Work done in vaporisation of one mol of
a) + 60.5KJ b) -45KJ water at 373 K against the pressure of 1
c) -50.2KJ d) -60.5KJ atmosphere is approximately
15. ΔUºcomb of solid naphthalene (C 10H8) is a) -3100.0 J b) 31.20 J
-1228.2 kcal mol-1. The value of ΔHºcomb of c) -20.2 J d) + 20.2 J
C10He(s) in kcal mol-1 would be 24. In a closed insulated container a liquid is
a) -1229.39 b) -1225.3 stirred with a paddle to increase the
c) +1225.39 d) +1029.39 temperature. Which of the following is
16. For the gaseous reaction involving the true?
complete combustion of isobutane a) ΔE = W 0, q = 0
a) ΔH – ΔE b) ΔH > ΔE b) ΔE= W = q 0
c) ΔH = ΔE 0 d) ΔH < ΔE c) ΔE = 0, W = q 0
17. The heat of combustion of solid benzoic d) W = 0, ΔE = q 0
acid at constant volume is -321.30 kJ 25. A gas is allowed to expand at constant
mole-1 at 300 K. The heat of combustion external temperature from a volume of 1.0
at constant pressure is L to 10.0 L. It expands against an external
a) - 321300 - 300 R pressure of 0.50 atm. If the gas absorbs
b) - 321300 + 300 R 250 J of heat from the surroundings, what
c) - 321300 - 150 R are the value of q, w and ΔE? (Given 1 L
d) - 321300 + 900 R atm = 101 J)
18. Latent heat of vaporisation of a liquid at q W ΔE
500 K and 1 atm pressure is 10.0 a) 250 J -455 J -205 J
 b) -250 J - 455 J -710 J 34. Carbon forms two oxides on combustion.
c) 250 J 455 J 710 J Carbon (IV) oxide and carbon (II) oxide
d) -250 J 455 J 205 J having values of their standard enthalpy
26. 1 mole of gas occupying 3 litre volume is of formation as —393.5 and -281.50 kJ
expanded against a constant external mol-1 respectively. The value of
pressure of 1 atm to a volume of 15 litre. ΔHcombustion of C will be
The work done by the system is a) -393.5 kJ mol-1 b) 112.0 kJ mol
a) 1.215 x 103J b) 12.15 x 103J c) -678.6 kJ mol -1
d) -112.0 kJ mol
c) 121.5 x 103J d) None 35. The values of ΔH°f of C2H2(g) and C6H6(g)
27. One mole of an ideal gas at 300 K is are respectively 230 and 85 kJ mol-1 The
expanded isothermally from an initial standard enthalpy change for trimerisation
volume of 1 litre to 10 litre. The ΔE for this of acetylene to benzene is
process is (R = 2 cal K-1 mol-1) a) 205 kJ mol-1 for benzene
a) 163.7 cal b) 1381.1 cal b) 605 kJ mol-1 for benzene
c) 9 litre atm d) Zero c) -605 kJ mol-1 for benzene
28. When 1.5 g of benzoic acid is burnt in a d) -205 kJ mol-1 for benzene
bomb calorimeter at 25°C increases the 36. At 298 K, the enthalpy changes of
temperature of 18.94 kg of water by cleavage of successive O — H bonds of
0.632°C. If specific heat of water at 25°C water molecules are
is 0.998 J, the value of the heat of H2O g H g OH(g); H = 498 kJ
combustion of benzoic acid is mol -1
a) 972 kJ b) 872 kJ
c) 766 kJ d) 582 kJ OH g H(g) + O(g); ΔH = 428 kJ mol
29. One mol of a gas is heated at constant From the above data, the value of HO—H
pressure to raise its temperature by 1°C. bond is
The work done in Joules is a) 498 kJ mol-1 b) 428 kJ mol-1
a) -4.3 b) -8.314 c) 463 kJ mol -1
d) 70 kJ mol-1
c) -16.62 37. The bond energies of C — C, C = C, H —
d) Unpredictable from data given H & C — H linkages are 350, 600,400 and
30. For which change ΔH ΔE: 410 kJ per mole respectively. The heat of
a) H2 g l2 g ˆˆ ˆˆ ˆˆˆ 2Hl g hydrogenation of ethylene is
a) — 170 kJ mol-1 b) — 260 kJ mol-1
b) HCl aq NaOH aq NaCl aq H 2O l
c) — 400 kJ mol -1
d) — 450 kJ mol-1
c) C s O2 g CO2 g 38. lf HJº , of IC/(g), C/(g), and l(g) is 17.57
d) N2 g 3H2 g ˆˆ ˆˆ ˆˆˆ 2NH3 g 121.34 and 106.69 J mol-1 respectively.
31. 2.5 moles of an ideal gas at 2 atm and Then bond dissociation energy of I-C/
300 K expands isothermally to 2.5 times bond is
its original volume against the external a) 35.15 J mol-1 b) 106.69 J mol-1
-1
pressure of 1 atm. The calculated value of c) 210.47 J mol d) 420.9 J mol-1
q, w and ΔE are 39. What is the ΔH in the reaction 2H2 (g) +
a) -4.7 kJ, 0 and + 4.7 kJ O2 (g) 2H2O (I). Bond energies of
b) + 4.7 kJ, -4.7 kJ and O (H - H), (O = O) and (O -H) are 105,120
c) -4.7 kJ, O and O d) 0, 0 & + 4.7 kJ and 110 kcals per mole respectively
Hess's Law & Bond energy a) -100 kcal mole-1 b)-120 kcal mole-1
-1
32. If the enthalpy of reaction c) -11 kcal mole d)-110 kcal mole-1
40. The bond energy of an O - H bond is 109
H2 g Cl2 g 2HCl g is -186.8 KJ
kcal mol-1. When a mole of water is
then the enthalpy of decomposition of HCI formed
per mote at the same temperature is a) 218 kcal is released
a) -186.8 KJ b) + 93.4 KJ b) 109 kcal is released
c) + 186.8 KJ d) -93.4 KJ c) 218 kcal is absorbed
33. One mole of an anhydrous salt AB d) 109 kcal is absorbed
dissolves in water with evolution of 21.0 J 41. ΔHf of graphite is 0.23 kJ/mole and ΔHf of
mol-1 of heat. If the heat of hydration of diamond is 1.896 kJ/mole. ΔHtransitjon from
AB is - 29.4 J mol-1, then the heat of graphite to diamond is
solution of the hydrated salt AB is a) +1.66 kJ/mole b) 2.1 kJ/mole
a) 50.4 J mol-1 b) 8.4 J mol-1 c) 2.33 kJ/mole d) 1.5 kJ/mole
-1
c) - 50.4 J mol d) -8.4 J mol-1
42. The heat change for thermite reaction The value of ΔHcombustion of carbon
involving the reaction between ferric oxide disulphide in kJ mol-1 is
and metallic aluminium producing molten a) -1104 b) +1104
iron is c) + 807 d) -807
2AI + 3/2 O 2 AI2O3; ΔH = - 400 Entropy, 2nd Law of thermodynamics
Kcal/mole 51. If the enthalpy of vaporization for water is
2Fe + 3/2 O2 Fe2O3; ΔH = - 200 186.5 kJ mol-1. the entropy of its
Kcal/mole vaporization will be
a) -100 kcal b) -200 kcal a) 0.5 kJ K-1 mole-1
c) +100 kcal d) +200 kcal b) 1.0 kJ K-1 mole-1
43. In the reaction: S + 3/2 O 2 SO3 + 2x c) 1.5 kJ K-1 mole-1
joules and SO 2 + 1/2 O2 SO3 + y d) 2.0 kJ K-1 mole-1
joules, the heat of formation of SO2 is 52. ΔSº and ΔH° for combustion of methane
a) (x+y) b) (x-y) are 186 JK-1 and -74.8 kJ mol-1
c) (2x+y) d)-(2x-y) respectively. The value of ΔUº for the
44. The enthalpies of atomisation of CH4 (g) process would be
and C2H6 (g) are respectively 400 kJ mol-1 a) Unpredictable
and 670 kJ mol-1. The value of ΔHC-C b) (74.8 – R)JK-1
would be c) 74.78 kJ
a) 270 kJ mol-1 b) 70 kJ mol-1 d) (596R - 74.8) kJ
c) 200 kJ mol -1
d) 240 kJ mol-1 53. What is the entropy change (in JK-1 mol-1)
45. Which of them has ΔHf ° = 0 when one mole of ice is converted into
a) Charcoal b) Sugar water at 0°C? (The enthalpy change for
c) Common salt d) White P the conversion of ice to liquid water is 6.0
46. Equal volumes of 1 molar hydrochloric kJ mol-1 at 0°C)
acid and sulphuric acid are neutralised by a) 20.13 b) 2.013
dil. NaOH solution and x kcal and y kcal c) 2.198 d) 21.98
of heat are liberated respectively. Which 54. The entropy change for the conversion of
of the following is true? 1 mol of α-tin (at 13°C, 1 atm) to 1 mol of
a) x = y b) x = 1/2 y β-tin (13°C, 1 atm), if enthalpy of
c) x = 2y d) None transition is 2.095 kJ mol-1 is:
47. The enthalpy of neutralisation of acetic a) 7.32 J mol-1 K-1
acid and sodium hydroxide is - 55.4 kJ. b) 14.62 J K-1 mol-1
What is the enthalpy of ionisation of acetic c) 56.3 J mol-1K-1
acid? d) 0
a) -1.7 kJ b) + 1.7 kJ 55. Which one of the following has ΔSº
c) + 5.54 kJ d) -5.54 kJ greater than zero?
48. When Zn dust is added to sufficiently a) CaO s CO2 g ˆˆ ˆˆ ˆˆˆ CaCO3 s
large volume of aqueous solution of
copper sulphate, 3.175 g of copper metal b) NaCl aq ˆˆ ˆˆ ˆˆˆ NaCl s
and 20 J of heat is evolved. The ΔH for c) NaNO3 s ˆˆ ˆˆ ˆˆˆ Na aq NO3 aq
the reaction
Zn (s) + CuSO 4 (aq) ZnSO4 (aq) + Cu d) N2 g 3H2 g ˆˆ ˆˆ ˆˆˆ 2NH3 g
(s) is (at wt of Zn = 65.3, at wt of 56. Which of the following statements
Cu = 63.5) regarding the entropy is not true?
a) -20 J b) -200 J a) S (monoclinic) > S (rhombic)
c) -400J d) -65.3 J b) C (diamond) > C (graphite)
49. N2(g) + 2O2(g) 2NO2(g) + 2x kJ c) H2O(g) > H2O(l)
d) O3(g) >O2 (g)
2NO(g) + O2(g) 2NO2(g) + y kJ
57. 1 mole of an ideal gas at 25°C is
The value of ΔH, of NO(g) is:
subjected to expand reversibly ten times
a) 1/2(y - 2x) b) y - 2x
of its initial volume. The change in entropy
c) x-y d) 2(x-y)
of expansion is
50. Given:
a) 19.15 JK-1 mol-1
C 2S CS2 ; Hº 117kJ b) 16.15 JK-1mol-1
C O2 CO2 ; Hº 393kJ c) 22.15 JK-1 mol-1
S O2 SO2 ; Hº 297kJ d) None of these
58. Entropy decreases during 66. Which of the following pairs of a chemical
a) Crystallisation of sucrose from solution reaction is certain to result in a
b) Boiling of egg spontaneous reaction?
c) Melting of ice [CBSE PMT 2005
d) Vaporisation of camphor a) Exothermic and decreasing disorder
Free Energy Change, Criterion of b) Endothermic and decreasing order
Spontaneity c) Exothermic and increasing disorder
59. In a certain chemical reaction AH = 150 d) Endothermic and increasing disorder
kJ and AS = 100 JK–1 at 300 K. The value 67. The condition for the spontaneity of a
of AG would be reaction is .
a) Zero b) 300 kJ a) G = 0 b) G < 0
c) 330 kJ d) 120 kJ c) G > 0 d) G 0
60. The standard free energy change for a 68. For the equilibrium PCI5 (g) ˆ PCI3 (g) +
gaseous reaction at 27°C is X kcal. If CI2 (g) at 298 K, Kp = 1.8 x 10-7, the value
equilibrium constant for a reaction is 100 of G° would be
and R is 2 cal K-1 mol–1. Then X is a) 44.80 kJ mol-1 b) 45.80 kJ mol-1
-1
a) -2.7636 b) -2.6736 c) 38.80 kJ mol d) 80.80 kJ mol-1
c) +2.6746 d) 2.7636 69. Calculate the temperature at which
61 Given that AGº , for AI2O3(s) and G = 5.2 kJ mol-1, H = 145.6 kJ mol-1
Na2O(s)-1582 kJ and -377 kJ mol-1 and S = 216 JK-1 mol-1 for a
respectively. Mark the correct statement spontaneous chemical reaction
a) Na is not able to reduce AI203 to Al a) 698°C b) 425°C
b) Al and Na2O do not react c) 650 K d) 650°C
c) Al cannot reduce Na2O to Na In each of the following questions, a
d) None statement of assertion (A) is given and a
62. What is the free energy change, G when corresponding statement of reason (R) is
1.0 mote of water at 100°Cand 1 atm given just below it of the statements, mark
pressure is converted into steam at 100°C the correct answer as:
and 1 atm pressure? A) If both A and R are true and R is the
a) 540 cal b) -9800 cal correct explanation of A
c) 9800 cal d) 0 cal B) If both A and R are true but R is not the
63. Enthalpy of a reaction at 27°C is 15kJ correct explanation of A
mol-1. The reaction will be feasible if C) If A is true but R is false
entropy is D) If both A and R are false
a) 15 J mol-1 K-1 70. Assertion: Heat of neutralisation of
b) -50 J mol-1 K -1 bothHNO3 and HCI with NaOH is 57.3 kJ
c) Greater than 50 J mol-1 K -1 mol-1.
d) Less than 50 J mol K-1 Reason: NaOH is a weak
64. A reaction occurs spontaneously if electrolyte/base.
[CBSE PMT 2005] (AIIMS1997)
a) T S = H and both H and S are a) A b) B
+ ve c) C d) D
b) T S > H and both H and S are 71. Assertion: A reaction which is
+ ve spontaneous and accompanied by
c) T S < H and both H and S are decrease of randomness must be
+ ve exothermic.
d) T S > H and H is +ve and S is Reason: All exothermic reactions are
- ve accompanied by decrease of
65. The absolute enthalpy of neutralisation of randomness.
the reaction a) A b) B
MgO (s) + 2 HCI (aq) MgCI2 (aq) + c) C d) D
H2O ( l ) will be 72. Assertion: Enthalpy of neutralisation of
[CBSE PMT 2005] weak acid and strong base is numerically
a) Greater than - 57.33 kJ mol-1 less than 57.1 kJ.
b) Less than - 57.33 kJ moM-1 Reason: Strong electrolytes are fully
c) -57.33 kJ mol-1 ionised,
d) 57.33 kJ mol-1 a) A b) B
c) C d) D
73. Assertion: A reversible process is a) 6.6 K b) 1.2 K
associated with maximum work c) 2.4 K d) 4.8 K
Reason: In a reversible expansion the 82. For a process, CO 2(g) → Dry ice
system and contracts against maximum a) H as well as S is less than zero
possible pressure b) H is positive while S is negative
a) A b) B c) Both H as well as S are positive
c) C d) D d) H is < 0 but S > 0.
74. Assertion: G°f (Graphite) = 0 83. The temperature at which the reaction,
Reason: For free elements in their Ag2O(s) 2Ag(s) + 1/202(g) is at
standard state, G°f is taken to be zero. equilibrium is ..........; Given H = 30.5 kJ
a) A b) B mol-1 and S = 0.066 kJ K-1 mol :
c) C d) D a) 462.12 K b) 362.12 K
75. Assertion: 1st law of thermodynamics is c) 262.12 K d) 563.12 K
not adequate in precenting the direction of 84. For the process
process.
Reason: 1st law of thermodynamics NH3 (g) + HCI (g) NH4CI (s) What
is correct?
relates E with work done by the system
a) H and S are > 0
when q = 0
b) H < 0; S>0
a) A b) B
c) H > 0; S < 0
c) C d) D
76. Assertion: Two moles of an ideal gas d) H < 0; S < 0
85. In an oven, using 10 kg coal (assume the
expand spontaneously into vacuum, the
coal is 80% carbon in weight), insufficient
work done is zero.
Reason: Work done in cyclic process is oxygen is supplied such that 60% of
carbon is converted to CO 2 and 40 %
zero
carbon is converted to CO. The heat gen-
a) A b) B
erated, when coal is burnt in this fashion
c) C d) D
77. Assertion: Reversible process and cyclic would be given: C (s) + O2 (g) CO2
process have same meaning (g) + 394 kJ
Reason: Hcy cle and Ecy cleis zero C(s) + (1/2) 02 (g) CO (g) + 111 kJ
a) A b) B a) 183200kJ b) 187200 kJ
c) C d) D c) 185200 kJ d) 181200 kJ
78. Assertion: Molar entropy of vaporisation 86. The average molar heat capacities of ice
of water is different from that of ethanol and water are 37.6 and 75.2 J mol-1 K-1
Reason: Water is more polar than ethanol respectively and its enthalpy of fusion is
a) A b) B 6.02 kJ mol-1. The amount of heat
c) C d) D required to raise the temperature of 10 g
Miscellaneous of water from -10°C to 10°C is equal to
79. One gram sample of ammonium nitrate is a) 2376 J b) 4752 J
decomposed in a bomb calorimeter. The c) 1128 J d) 3970 J
temperature of calorimeter increases by 87. For a reaction R1, G = x kJ mol-1. For a
6.12 K. The heat capacity of the system is reaction R2, G = y k J mol-1. Reaction
1.23 kJ/g/deg. What is molar heat of R1 is non-spontaneous but along with R2 it
decomposition of NH4NO3? is spontaneous. This means that
a) -7.53 kJ mol-1 b) -398.1 kJ mol-1 a) x is -ve, y is +ve but in magnitude x > y
c) -16.1 kJmol-1 d) -602 kJ mol-1 b) x is + ve, y is -ve but in magnitude y > x
80. Consider the following reaction occurring c) both x and y are -ve but not equal
in an automobile d) cannot be predicted
2C8H18(g) + 25 O 2 (g) 16CO2 (g) + 88. The decreasing order of calorific values is
18H20(g) the sign of H, S and G a) C2H2>C4H10>C3H8>C2H4
would be b) C4H10>C3H8>C2H4>C2H2
a) +, —, + b) —, +, — c) C2H4>C3H8>C4H10>C2H2
c) —, +, + d) +, +, — d) C3H8>C4H10>C2H4>C2H2
81. The molar heat capacity of ureater at 89. One mole of an ideal gas is allowed to
constant pressure C is 75 JK-1 mol-1. expand reversibly and adiabatically from a
When 1 kJ of heat is supplied to 100 g of temperature of 27°C. If the work done
ureater which is free to expand, the during the process is 3 kJ, the final
increase in temp, of water is
 temperature will be equal to (C v = 20 JK-1) 96. For the gas phase reaction,
a) 150 K b) 100 K PCl5 (g) ˆ PCI3 (g) +Cl2 (g) Which of the
c) 26.85 K d) 295 K following conditions are correct?
90. For vaporization of water at 1 atmospheric [CBSE PMT 2008]
pressure, the values of H and S are a) H > 0 and S > 0
40.63 kJ mol-1 and 108.8 JK-1 mol-1, b) H < 0 and S<0
respectively. The temperature when c) H > 0 and S<0
Gibbs energy change ( G) for this d) H =0and S<0
transformation will be zero is 97. Given that, bond energies of H - H and
[CBSE PMT (mains) 2010] Cl–O 430 kJ/mol and 240 kJ/mol
a) 273.4 K b) 393.4 K respectively. H HCI is - 90 kJ/mol.
c) 373.4 K d) 293.4 K Bond enthalpy of HCI is
91. Standard entropies of X2, Y2 and XY3 are [CBSE PMT 2007]
60, 40 and 50 JK-1 mol-1 respectively. For a) 380 kJ mol-1 b) 425 kJ mol-1
the reaction c) 245 kJ mol -1
d) 290 kJ mol-1
1
/2 X2 + (3/2) Y2 XY3, H = - 30 kJ 98. In a closed container, a liquid is stirred
to be at equilibrium, the temperature with a increase the temperature, which of
should be the following is true? [PMT Pb 2007]
[CBSE PMT (Prelims) 2010] a) U = W 0, q = 0
a) 500 K b) 750 K b) U = W = 0, q 0
c) 1000K d) 1250K c) U = 0, W = q 0
92. When a beaker containing water is d) W = 0, U = q 0
heated, the thermodynamic system is 99. 6 moles of an ideal gas expand
[HP PMT 2010] isothermally reversibly from a volume of 1
a) Only water in beaker litre to a volume of litres at 27°C. What is
b) Only beaker the maximum work done?
c) Beaker with water [Vellore 2006]
d) Shape and size of the beaker a) 47kJ b) 100kJ
93. From the following bond energies: c) 0 d) 34.465 kJ
H - H bond energy: 431.37 kJ mol–1 100. The reaction,
C = C bond energy. 606.10 kJ mol–1 Zn (S) + CuSO 4, (aq) ZnSO4, (aq)
C - C bond energy: 336.49 kJ mol-1 + Cu (s) is example for a
C - H bond energy: 410,50 kJ mol-1 [Vellore 2006]
Enthalpy of the reaction, a) spontaneous process
H H H H b) non - spontaneous process
| | | | c) isobaric process
C C H H H C C H d) reversible process
| | | | 101. The enthalpy of hydrogenation of
H H H H cyclohexene is 119.5 kJ mol-1. If
will be resonance energy of benzene is-150.4 kJ
[CBSE PMT 2009] mol-1, its enthalpy of hydrogenation would
a) 553.0 kJ mol-1 b) 1523 kJ mol-1 be
-1
c) -243.6 kJ mol d) -120.0 kJ mol-1 [CBSE PMT 2006]
94. Standard free energies of formation (in a) - 208.1 kJ mol -1
b) -269.9 kJ mol-1
kJ/mol) at 298 K are - 237.2, - 394.4 and c) - 358.5 kJ mol-1 d) -5.08.9 kJ mol-1
- 8.2 for H2O (I), CO2 (g) and pentane (g), 102. Identify the correct statement for change
respectively. The value of Eºcell for the of Gibbs energy for a system ( Gsy stem ) at
pentane oxygen fuel cell is constant temperature and pressure
[CBSE PMT 2006]
[CBSE PMT 2008]
a) If Gsy stem = 0, the system has attained
a) 2.0968V b) 1.0968 equilibrium
c) 0.0968V d) 1,968V b) If GSy stem = 0, the system is still
95. Bond dissociation enthalpy of H2, Cl2 and moving in a particular direction
HCI are 434,242 and 431 kJ mol-1 c) If GSy stem < 0, the process is not
respectively, Enthalpy of formation of HCI spontaneous
is [CBSE PMT 2008] d) If Gsy stem > 0, the process is
a) - 245 kJ mol-1 b) - 93 kJ mol-1 spontaneous
-1
c) 245 kJ moi d) 93 kJ mol-1
103. Assume each reaction is carried out in an 298 K and 1atm pressure. Then entropy
open container. For which reaction will change for the reaction
H = E? [CBSE PMT 2006] H2(9) + CI2[g) 2HCI(g) is
a) C (s) + 2H2O (g) 2H2 (g)+CO2 (g) [BHU 2005]
b) PCI5(g) PCI3(g) + CI2(g) a) +540.3 b) +727.3
c) 2CO(g) + o2(g) 2CO2(g) c) -166.9 d) + 19.8
112. The Hess's law is applicable for the
d) H2(g) + Br2(g) 2HBr(g) determination of heats of
104. Which is correct for an adiabatic process? [Pb. PMET 2005]
[MP PMT 2004]
a) reaction b) summation
a) P V = 0 b) q = + W c) formation d) all of these
c) E = q d) dq = 0
113. Work done during isothermal expansion
105. In the reaction [MP PMT 2004]
of one mole of an ideal gas from 10 N-m -2
A 2 g 4B ˆˆ ˆˆ ˆˆˆ 2AB4 g to 1 N – m -2 at 313 K is (R= 8,314 JK-1
H < 0, the formation of AB4(g) will be mol-1) [Pb. PMET 2005]
favoured at a) 3.6 kJ b) 0.8kJ
a) Low temperature, high pressure c) -6kJ d) -8kJ
b) High temperature, low pressure Subjective
c) Low temperature, low pressure 1. Answer the following
d) High temperature, high pressure (a) Change in internal energy is a state
106. For which of the reaction H = E? function while work is not, why?
[MP PMT 2004] (b) Why E = 0, for the isothermal
a) N2(g) + 3H2(g) 2NH3(g) expansion of ideal gas?
b) N2(g) + O2(g) 2NO(g) (c) When an ideal gas expands in
vacuum, there is neither absorption nor
c) 2 Na (s) + CI2(g) 2NaCl (s) evolution of heat? Explain,
d) PCl5(g) - PCI3(g) + Cl2(g) (d) Why is standard heat of formation of
107. How much energy is released when 6 diamond is not zero although it is an
mole of octane is burnt in air? Given Hf ° element
for CO2 (g), H2O (g) and C8H18 (I) 2. In expressing enthalpy of neutralisation,
respectively are - 490, - 240 and + 160 we take into account one gram equivalent
J/mol [AIIMS 2004] of the acid and base and not one mole.
a) -6.2 kJ b) -37.4 kJ What is the reason?
c) -35.5 kJ d) -20.0 kJ 3. Hess's law is a corrolary of first law of
108. H,° (298 K) of methanol is given by the thermodynamics. Comment.
chemical equation [AIIMS2005]
4. The molar heat of formation of NH4NO3 is
a) CH4(g)+1/2 O2(g) CH3OH(g) - 367.54 kJ and those of N2O (g) and H2O
b) C (graphite) +1/2 O2(g) + 2H2(g)) (/) are 81.46 kJ and - 285.78 kJ
CH3OH(I) respectively at 25°C and 1 atm pressure.
c) C (diamond) + 1/2 O 2(g) + 2H2(g) Calculate H for the reaction.
CH3OH(l) NH4NO3(s) N2O(g) + 2H2O(l)
d) CO(g) +2H2(g) CH3OH(l) (-122.56 kJmol-1)
109. For the reaction of one mole of zinc dust 5. The enthalpy change involved in the
with one mole of sulphuric acid in a bomb oxidation of glucose is - 2880 kJ mol-1.
calorimeter, U and w corresponds Twenty five percent of this energy is
[AIIMS 2005] available for muscular work. If 100 kJ of
a) U < 0, w = 0 b) U< 0, w < 0 muscular work is needed to walk one
c) U > 0, w = 0 d) U > 0, w > 0 kilometer, what is the maximum distance
110. The enthalpy of combustion at 25°C of H2, that a person will be able to walk after
cyclohexane (C6H12) and cyclohexene eating 120 g of glucose? (4.8 Km)
(C6H10) are -241,-3920 and-3800 kJ/mole 6. Calculate the heat of combustion of
respectively. The heat of hydrogenation of methane at 25°C. The mean bond
cyclohexene is [BHU 2005] energies for the C - H, O = O, C = O and
a) -121kJ/mole b) + 121 kJ/mole O - H are respectively 415,498, 803 and
c)- 242 kJ/mole d) + 242 kJ/mole 463 kJ mol-1 (-802 kJ)
111. The entropy values (in JK-1 mol-1) of H2(g) 7. How will you prove that G must be
= 130.6, Cl2(g) =223.0and HCI(g)= 186.7 at negative if a process is to be of
spontaneous nature?
8. The following data is known about ZnS04:
H = 7.25 kJ mol-1 and S = 7.0 JK-1
mol-1. Calculate its melting point.
[1035.7 K]
9. Calculate the free energy change on
dissolving one mole (58.5g) of sodium
chloride at 25°C. Lattice energy = 777.8
kJ mol-1, hydration energy = - 774 kJ mol-1
of NaCI, S at 25°C = 0.043 kJ mol-1 K-1.
[-9.014 kJ mol-1]
10. Calculate G° for the following reactions
CO (g) + 1/2 O2 (g) → CO2 (g); H° =
-282.84 kJ Given: Sº CO2 = 213.8 JK-1
mol-1 SºO2 (g) = 197.9JK-1 mol-1; SºCO (g)
= 205. 0 JK-1 mol-1 [-257.033W]
11. (i) An average person needs about 10000
kJ per day. How much carbohydrates (in
mass) will he have to consume assuming
that all his energy needs are met only by
carbohydrates in the form of glucose?
Given that the enthalpy of combustion of
glucose = -2816 kJ. [639.2 g]
(ii) A human eats 0.35 kg of
carbohydrates (glucose) and 200g of fats
every day and it is assumed that
combustion of fats can produce energy
equivalent to 39000 k J kg-1.If the body
consumes all the carbohydrates
preferentially, how much will his weight
increase per year, assuming that only 50
percent of the excess fats are excreted.
[15.33kg]
12. Predict the sign of entropy change in each
of the following process and justify,
(i) Normal egg Hard boiled egg
(ii) Loose rubber band stretched
rubber band
(iii) Protein (helical) Protein
(random coil)
(iv) Sublimation of NH4CI
(v) Spreading of a drop of ink into
beaker filled with water
(vi) Sn(s) + 2CI2(g) → SnCI4( l )
13. While studying the properties of gaseous
freon C2CI2F2, a chemist cooled 1.25 g of
the sample of 1 bar pressure from 323 K
to 293 K. During cooling the volume of the
sample decreased from 274 mL to 248
mL. Calculate H and U of the
process. Cp of C2CI2F2 = 80.7Jmol-1K-1
[ H = 22.75 J, U = 25.35 U kJ]
14. Calculate the energy needed to raise the
temperature of 10.0 g iron from 25°C to
500°C if specific heat capacity of iron is
0.45 J (°C)-1 g-1.
[21.37.5 J]
Also calculate the mass of gold (specific
heat capacity 0.13 (J °C-1) g-1) that can be
heated through the same temperature
difference when supplied with the same
amount of energy. [34.62 g]
15. 2.8 g of N2 gas at 300 K and 20 atm was
allowed to expand isothermally against a
constant external pressure of 1 atm.
Calculate E, q and W for the gas.
[0,-236.95 J, 236.95]
16. The specific heats of iodine vapour and
solid are 0.031 and 0.055 cal/g
respectively. If heats of sublimation of
iodine is 24 cal/g at 200°C, what is its
value at 250°C? [22.8 cal/g]
17. An athelete takes 20 breaths per minute
at room temperature. The air inhaled in
each breath is 200 mL which contains
20% oxygen by volume, while exhaled air
contains 10% oxygen by volume.
Assuming that all the oxygen consumed if
used for converting glucose into CO 2 and
H2O(I), how much glucose will be burnt in
the body in one hour and what is the heat
produced? (Room temperature = 27°C
and enthalpy of combustion of glucose is
-2822.5 kJ mol-1 at 0°C).
[32.14 g, 504 kJ]
 ANSWERS
1. b 2. d 3. C 4. d 5. c 6. b 7. C 8. c 9. b
10. d 11. a 12. B 13. c 14. b 15. a 16. D 17. c 18. c
19. d 20. d 21. B 22. b 23. a 24. a 25. A 26. a 27. d
28. a 29. b 30. D 31. b 32. b 33. b 34. A 35. c 36. c
37. a 38. c 39. D 40. a 41. a 42. b 43. D 44. b 45. d
46. b 47. b 48. C 49. a 50. a 51. a 52. D 53. d 54. a
55. c 56. b 57. A 58. a 59. d 60. a 61. B 62. d 63. c
64. b 65. a 66. C 67. b 68. c 69. c 70. C 71. c 72. b
73. a 74. a 75. B 76. c 77. d 78. a 79. D 80. b 81. c
82. a 83. a 84. D 85. b 86. d 87. b 88. D 89. a 90. c
91. b 92. c 93. D 94. b 95. b 96. a 97. B 98. a 99. d
100. a 101. a 102. A 103. d 104. d 105. a 106. B 107. b 108. b
109. a 110. b 111. D 112. d 113. c