PINNAACLE CLASSES

o
46. The enthalpy of combustion of methane at 25 C is 890 kJ . (c) 170 (d) 270

The heat liberated when 3.2 g of methane is burnt in air is

54. The H−H bond energy is 430 kJ mol and Cl−Cl bond
(a) 445 kJ (b) 278 kJ −1
energy is 240 kJ mol . ΔH for HCl is −90 kJ . The H−Cl
(c) −890 kJ (d) 178 kJ bond energy is about
−1 −1
(a) 180 kJ mol (b) 360 kJ mol
C+ O2 →CO 2 C+ 1/2O2 →CO −1 −1
47. If (i) , (ii) , (iii)
(c) 213 kJ mol (d) 425 kJ mol
CO+ 1/2O2 →CO 2
, the heats of reaction are Q , −12, −10
respectively. Then Q= 55. If enthalpies of methane and ethane are respectively 320 and
(a) – 2 (b) 2 360 calories then the bond energy of C−C bond is
(c) – 22 (d) – 16 (a) 80 calories (b) 40 calories
(c) 60 calories (d) 120 calories
48. How much energy is released when 6 mole of octane is burnt
ΔH o
f for 2 CO ( g), H O( g)
2 C 8 H 18 (l) 56. If the bond energies of H−H , Br−Br and HBr are 433, 192
in air ? Given and
respectively are – 490,– 240 and + 160 kJ/mol
and 364 kJ mol−1 respectively, the ΔH o for the reaction,
(a) – 6.2 kJ (b) – 37.4 kJ H 2 (g )+Br 2 (g )→2 HBr( g) is
(c) – 35.5 kJ (d) – 20.0 kJ
(a) + 261 kJ (b) – 103 kJ
(c) – 261 kJ (d) + 103 kJ
49. The enthalpy change ( ΔH ) for the neutralisation of 1 M HCl
by caustic potash in dilute solution at 298 K is H 2 O(l)→ H 2 O( g ); P=1 atm T=373 K ,
57. For the change , the
(a) 68 kJ (b) 65 kJ
free energy change ΔG=0 . This indicates that
(c) 57.3 kJ (d) 50 kJ
H 2 O(l) H 2 O( g )
(a) is in equilibrium with
50. Energy required to dissociate 4 gm of gaseous hydrogen into (b) Water boils spontaneously at 373 K
o
free gaseous atoms is 208 kcal at 25 C . The bond energy of
H−H bond will be (c) Water does not boil spontaneously at 373 K
(a) 104 kcal (b) 10.4 kcal (d) Condensation of water vapour occurs
(c) 1040 kcal (d) 104 cal spontaneously at 373 K

51. Which one of the following bonds has the highest average o
bond energy (kcal/mol) 58. ΔG for the reaction X +Y ⇌ Z is – 4.606 kcal . The value
o
(a) S=O (b) C≡C of equilibrium constant of the reaction at 227 C is
(c) C≡N (d) N≡N ( R=2.0 cal . mol−1 K −1 )
(a) 100 (b) 10
H , Cl 2 (c) 2 (d) 0.01
52. The bond dissociation energies of gaseous 2 and HCl
are 104, 58 and 103 kcal respectively. The enthalpy of
formation of HCl gas would be N2O4
59. The standard enthalpy of the decomposition of to
(a) – 44 kcal (b) 44 kcal NO 2
is 58.04 kJ and standard entropy of this reaction is
(c) – 22 kcal (d) 22 kcal 176.7 J/K. The standard free energy change for this reaction
o
at 25 C is
53. The first ionization energy for Li is 5.4 eV and electron (a) 539 kJ (b) – 539 kJ
affinity of Cl is 3.61eV. The ΔH (in kJ/mol) for the reaction (c) – 5.39 kJ (d) 5.39 kJ
Li(g )+Cl (g )→ Li + +Cl− is (if resulting ions do not combine
−19
with each other) (1 eV =1.6×10 J ) 60. Spontaneity of a chemical reaction is decided by the negative
(a) 70 (b) 100 change in
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 PINNAACLE CLASSES

(a) Internal energy (b) Enthalpy −1

(b) – 523.2 kJ mol
−1
(a) – 439.3 kJ mol
(c) Entropy (d) Free energy −1 −1
(c) – 221.1 kJ mol (d) – 339.3 kJ mol
61. The essential condition for the feasibility of a reaction is that
(a) The reaction should be exothermic 66. For spontaneity of a cell, which is correct
(b) The entropy of products must be larger than that of (a) ΔG=0, ΔE=0
reactants
(b) ΔG=−ve, ΔE=0
(c) The reaction is to be accompanied with free
energy decrease (c) ΔG =+ ve, ΔE =+ve
(d) The reaction has to possess high activation energy
(d) ΔG=−ve, ΔE =+ve

62. In an irreversible process taking place at constant T and P and

in which only pressure-volume work is being done, the 67. The free energy for a reaction having ΔH=31400 ca; .
change in Gibbs free energy (dG ) and change in entropy (dS ) ΔS=32 cal K −1 mol−1 at 1000o C is
, satisfy the criteria
(a) – 9336 cal (b) – 7386 cal
(a)
(dS )V , E <0 , ( dG)T , P <0
(c) –1936 cal (d) + 9336 cal
(b)
(dS )V , E >0 , ( dG)T , P <0

(dS )V , E=0 , (dG)T , P=0 68. The highest catenation ability is shown by
(c) (a) Oxygen (b) Sulphur
(d)
(dS )V , E=0 , (dG)T , P >0 (c) Selenium (d) Tellurium

63. The free energy change for the following reactions are given 69. The number of unpaired electrons in the p-subshell of
below, oxygen atom is
5 (a) 1 (b) 2
C 2 H 2 ( g )+ O 2 ( g) → 2CO (g)+H O(l); ΔG o =−1234 kJ
2 2 2 (c) 3 (d) 4
C (s )+O2 (g ) →CO 2 ( g) ΔG o=−394 kJ
1 70. Most abundant element on earth is
H 2 (g )+ O2 ( g ) → H 2 O(l) ΔG o =−237 kJ (a) O (b) S
2
What is the standard free energy change for the (c) Se (d) Te
H (g )+2 C (s)→C 2 H 2 ( g )
reaction 2
71. Which of the following is most electronegative
(a) O (b) S
(a) – 209 kJ (b) – 2259 kJ
(c) Te (d) Se
(c) + 2259 kJ (d) 209 kJ

72. Oleum is
64. The equilibrium concentration of the species in the reaction (a) Castor oil (b) Oil of vitriol
A+ B≡C+ D are 3, 5, 10 and 15 mole L−1 respectively at H 2 SO 4
(c) Fuming (d) None of them
300 K the ΔG for the reaction is
(a) 13.81 (b) – 1381.8 73. There is no S−S bond in
(c) – 138.18 (d) 1391.6 2− 2−
(a) S2 O 4 (b) S2 O5
2− 2−
65. Standard enthalpy and standard entropy changes for the (c) S2 O3 (d) S2 O7

oxidation of ammonia at 298 K are −382.64 kJ mol−1 and

74. Which of the following hydrides has the lowest boiling
−145.6 JK −1 mol−1 , respectively. Standard Gibbs energy
point
change for the same reaction at 298 K is (a) H 2 O (b) H 2 S

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 PINNAACLE CLASSES

(c) H 2 Se (d) H 2 Te
H 2 SO4
85. acts as dehydrating agent in its reaction with
H 2 C 2 O4
75. The catalyst used in the manufacture of H 2 SO4 by (a) (b) Ba(OH )2
contact process is (c) KOH (d) Zn
Al 2 O 3 Cr 2 O3
(a) (b)
(c) V 2 O5 (d) MnO 2 86. Which of the following group shows the highest boiling
point
H2O H2 S
76. The molecular formula of sulphur is (a) (b)
(a) S (b) S2 (c)
H 2 Se
(d)
H 2 Te

(c) S 4 (d) S8
87. Oxygen is not evolved on reaction of ozone with
77. Which of the following is not suitable for use in a (a) H 2 O 2 (b) SO 2
descicator to dry substances (c) Hg (d) KI
H 2 SO 4 Na2 SO 4
(a) Conc. (b)
CaCl 2 P4 O10 88. Sulphur in +3 oxidation state is present in
(c) (d)
(a) Sulphurous acid (b) Pyrosulphuric acid
(c) Dithionous acid (d) Thiosulphuric acid
78. All the elements of oxygen family are
(a) Non-metals (b) Metalloids
SO 2 + H 2 S →
(c) Radioactive (d) Polymorphic 89. product. the final product is
H 2 O+ S
(a) (b) H 2 SO4
79. The triatomic species of elemental oxygen is known as (c) H 2 SO3 (d) H 2 S2 O3
(a) Azone (b) Polyzone
(c) Triozone (d) Ozone KO 2 +CO 2 → ?
90. (gas)
H2 N2
O2 F 2 (a) (b)
80. Shape of is similar to that of
O2
(a)
C 2 F2
(b)
H 2 O2 (c) (d) CO
H2 F2 C2 H2
(c) (d)

81. Which of the following bonds has the highest energy

(a) Se−Se (b) Te−Te
(c) S−S (d) O−O

82. Which of the following is not a chalcogen

(a) O (b) S
(c) Se (d) Na

83. Which of the following is a suboxide

Ba2 O CaCO 3
(a) (b)
C 3 O2
(c) (d) ZnO

84. Permono sulphuric acid is known as

(a) Marshell's acid (b) Caro's acid
(c) Sulphuric acid (d) None of these

Opp. Om Shakti Temple, Beside Naturals, Ramakrishna Road, Salem : 83009 81676 / 98403 37371