GARG Radiation GARG Radiation

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Chemistry (b) High heat of vaporisation
(c) High basicity
By - Tribhuwan Sir
(d) All of these
5. A cylinder of gas supplied by Bharat Petroleum is assumed to
Unit Test : Thermodynamics contain 14 kg of butane. It a normal family requires 20,000 kJ of
energy per day for cooking, butane gas in the cylinder last for ….
−1 −1
1. What is the entropy change (in JK mol ) when one mole of ice Days [Kerala PMT 2004]
o ΔH c C 4 H 10 =−2658 KJ per mole
is converted into water at 0 C (The enthalpy change for the ( of )
−1 o
conversion of ice to liquid water is 6.0 kJ mol at 0 C ) (a) 15 days (b) 20 days
[CBSE PMT 2003] (c) 50 days (d) 40 days
(a) 21.98 (b) 20.13 (e) 32 days
(c) 2.013 (d) 2.198 6. The heat of neutralization of HCl by NaOH under certain
2. One mole of NaCl (s) on melting absorbed 30.5 kJ of heat and its condition is – 55.9 kJ and that of HCN by NaOH is –12.1 kJ. the
−1
entropy is increased by 28.8 JK . The melting point of NaCl is heat of ionization of HCN is [MP PET 2001]
−1 −1
(a) −68.0 kJ mol (b) −43.8 kJ mol
[DPMT 2004]

(a) 1059 K (b) 30.5 K

−1 −1
(c) 28.8 K (d) 28800 K (c) 68.0 kJ mol (d) 43.8 kJ mol
N H ( g)→2 N ( g)+4 H ( g)
3. The enthalpy change ( ΔH ) for the process 2 4 7. Equilibrium constant of a reaction is related to
−1 [AIIMS 1991]
in 1724 KJ mol . If the bond energy of N−H bond in ammonia is o
(a) Standard free energy change ΔG
391 KJ mol−1 . What is the bond energy of N−N bond is N 2 H 4
[MP PMT 2004]
(b) Free energy change ΔG
−1 −1 (c) Temperature T
(a) 160 KJ mol (b) 391 KJ mol
−1 −1
(d) None
(c) 1173 KJ mol (d) 320 KJ mol o
8. The standard Gibbs free energy change ΔG is related to
4. Liquid ammonia is used in refrigeration because of its K
[DCE 2003] equilibrium constant p as [MP PET/PMT 1998]

(a) High dipole moment

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 GARG Radiation GARG Radiation
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o
knowledge... Run and managed by IITians & NIFFTiansLight of knowledge...

(a)
K p =−RT ln ΔG
o
(b)
K p=
e ΔG
RT ( )
ΔG o −
ΔGo
K p =− K p =e RT
(c) RT (d)
N 2 O5 NO 2
9. The standard enthalpy or the decomposition of to is
58.04 kJ and standard entropy of this reaction is 176.7 J /K . The
o
standard free energy change for this reaction at 25 C is
[DCE 2004]

(a) –5.38 kJ (b) 5.38 kJ

(c) 5.38 kJ (d) –538 kJ
H 2 O(l) H 2 O( g)
10. For the equilibrium ⇌ at 1 atm and 298 K
[AIIMS 2004]
o
(a) Standard free energy change is equal to zero
(GΔ =0 )

(b) Free energy change is less than zero ( ΔG<0)

o
(c) Standard free energy change is less than zero ( ΔG <0 )
o
(d) Standard free energy change is greater than zero
( ΔG >0 )

Ag 2 O( s ) → 2 Ag( s )+(1/2)O2 ( g )
11. For reaction the value of
−1 −1 −1
Δ H = 30 .56 kJ mol and ΔS=0.066 k JK mol . Temperature at
which free energy change for reaction will be zero, is [MH CET
1999]

(a) 373 K (b) 413 K

(c) 463 K (d) 493 K

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