Concept Adv (1) 3 Soln

1
AITS-CRT-III-(Paper-1)-PCM (Sol)-JEE(Advanced)/16
FIITJEE Students From Classroom / Integrated School Programs have secured to 2 Zonal, 6 State & 18 City Topper Ranks. 33 in Top 100, 78 in Top 200 and 205 in
FIITJEE JEE(Advanced)-2016
ANSWERS, HINTS & SOLUTIONS
CONCEPT RECAPITULATION TEST – III

Top 500 All India Ranks bagged by FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.
PAPER-1
ALL INDIA TEST SERIES
Q. No. PHYSICS CHEMISTRY MATHEMATICS
1. B B C
2. C B B
3. D C C
4. D A C
5. B D A
6. C C D
7. A B D
8. B B B
9. A C C
10. D C B
11. B, D A, B, D A, C, D
12. A, C, D A, B, C B, C, D
13. A, B, C B, C A, B, C
14. A, B, D B, C, D A, C
15. A, C A, D A, C
1. 1 5 5
2. 1 7 1
3. 2 4 3
4. 2 6 5
5. 2 5 1
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics PART – I
SECTION – A
1. We must take into account here that the heat transferred per unit time is proportional to the
temperature difference. Let us introduce the following notation: Tout1,Tout2 and Tr1 , Tr2 are the
temperatures outdoors and in the room in the first and second cases respectively. The thermal
power dissipated by the radiator in the room is k1(T  Tr ), where k1 is a certain coefficient. The
thermal power dissipated from the room is k 2 (Tr  Tout ), where k2 is another coefficient. In
thermal equilibrium, the power dissipated by the radiator is equal to the power dissipated from the
room. Therefore, we can write
k1(T  Tr1 )  k 2 (Tr1  Tout1 )
Similarly, in the second case,
k1(T  Tr 2 )  k 2 (Tr2  Tout2 )
Dividing the first equation by the second, we obtain
T  Tr1 Tr1  Tout1

T  Tr 2 Tr 2  Tout2
Hence we can determine T:
Tr2 Tout1  Tr1Tout2
T  60º C
Tr2  Tout1  Tout2  Tr1
k
2. The maximum velocity of the insect is A .
M
k
Its component perpendicular to the mirror is A sin 600.
M
k
Thus maximum relative speed  3A .
M
CC CC
3. E  C1C2 cos 0 t  1 3 cos(0  )t  1 3 cos(0  )t
2 2
Of the three components, the highest frequency component will liberate the electrons with
maximum kinetic energy
h
(K.E)max    (0  )   = 2.39 eV.
2
4. Path difference of the two rays (one coming

directly to antenna and other after reflection
from water surface B 

x  AB  AC 
2 h
h h 
 x =  cos 2   C
cos  cos  2
A
h 
= 1  cos 2  
cos  2

or x  2hcos  
2
For constructive interference x  n
3
 1
n  
2
 or h  
2cos 
5. Impact takes place along the normal to the vsin

inclined plane usin u
 u sin   v cos  ucos
v
v  u tan  vcos

v sin  u tan   sin 
e 
ucos  ucos 
e  tan 2 
7
6. 4kR2 2  MR2 2  constant
10
d 7 d
4kR2 2  MR2 2 0
dt 10 dt
7M
 T
10k
 
7. Assuming ring as dipole, then dipole moment P and E are in same direction, so potential energy
U = –PE

 i  r 2B0 2
8.  
I 1 2
mr
2
2 2B0i

m
1
the moment of inertia of ring about axis of rotation (diameter of the ring)= mR2
2
9. Induced emf in the rod   Blv

 Blv  t/RC
Current in the circuit I  e t/RC  e
R R
Since the net force on the rod should be zero, the external force will be equal in magnitude but
opposite to the magnetic force.
B2l2 v  t/RC
 FIlB e
R
10. Let mass of the earth is Me and mass of object is m.

 GMem  A
Force on object at A   r  towards centre.
r 
3 Re
 R 
2
R2
r2 
 GMem  4
Force on object along the tunnel   3
r
 R  r
 GM  R2
Acceleration of object along the tunnel   3 e  r 2 
 R  4
4
11. Charge stored on capacitor 3F = 36 C 36

charge stored on capacitor 6 F = 72 C – +
– +
After connected the plates
– +
36  Q 72  Q – +
 +
3 6 –
i.e., – 72 + 2Q = 72 – Q
+ –
3Q = 2 × 72 + –
Q = 48 + –
48  36 + –
 V3f = =4V + –
3 72
B3l 3l 9
12. V0  VC   Bl 2
2 2
VA  VC  4Bl2
13. For isothermal process Q = W.

Curve 3 corresponds to isothermal process, and Curves 1 and 2 correspond to isobaric
processes.
For isobaricprocess
W = pV = RT (n = 1)
i  2 W 2
Q = CpT =   RT (i = degrees of freedom)  
 2  Q i2
2 W 2
For curve 1,    i= 5 (diatomic gas) (given tan 1 = 2/7)
i2 Q 7
2 W 2
For curve 2,   I = 3 (monatomic gas) (given tan 2 = 2/5)
i2 Q 5
CE
14. Initially, QA  QB  , when dielectric is inserted.
2
2CE 2CE CE CE
Q 'A  Q 'B  , Q =  
3 3 2 6
CE CE2
Work done by battery = E 
6 6
Q '2A Q2A 7CE2
UA  Uf  Ui   
2C 2C 72
SECTION – C
1. Q value of the reaction, Q = (2  4  7.06 – 7  5.6) MeV 

Q = 17.28 Mev Li
p
Applying C.O.E for collision 
kp + Q = 2 k  . . . (i) 
2mpk p = 2 2m k  cos
2 
 kp = 16 k cos 
kp = k ( cos  = ¼)
Putting in (i) we get
kp = Q = 17.28 MeV
kp/17.28 = 1
5
2. The light escape is confined within a cone of apex

b
angle ' 2c ' where c is the critical angle. Imagine a c
a
sphere with source of light as its centre and the
surface area abc is A.
here c c  c c
c R
2
A  2R sin  d  2R2 (1  cos c ) P
0
 1  3 

 R2  c  sin    60º 
  2  
A
 Power transfer  P 
4R2
1
 4   1W
4
3. The wavelength of the sound wave in air is

320
  2  102 m . The positions of maxima on
16  103
the circumference of the circular track will be given by
d sin   n  S1
When d is the separation between the sources and  is

the angular position of nth maximum as shown in the d
figure
 2 sin  = n (2  102) S2
n
sin  =
100
Since sin  lies between 0 and 1 there are 400 maxima
on the entire circle.
These 400 maximas will be heard by the person in the time
400
t  200s
2beats / s
Speed of the train = 36 km/h
5
 36   10m / s
18
From the obtained values so far we get length of track
L= (10 m/s) (200s)= 2000 m
So, L/1000 =2m
3 v/2
4.  Ndt  2mv
2 2
 (Ndt)R  5 mR  V1
3 2
mvR  mR 2  N
2 5
Let V and V1 are the speeds of the plank and the sphere in
the horizontal direction respectively.
N
 Ndt  MV  mV 1
6
3
 mv  MV
2
3 mv 3 4 mR 2 m
V   R
2 M 2 15 M 5M
2
and V1  R  2 m/s
5
q1 q2
5.  ; q1  q2  2Q0
C1 C2
0 A  A
C1  ; C2  0
d0  vt d0  vt
q1 d0  vt

q2 d0  vt
 d  vt 
q2  0   q2  2Q0
 d0  vt 
 2d0 
q2    2Q0
 d0  vt 
2Q0
q2   d0  vt 
2d0
dq2 Q0 v
I  =2A
dt d0
7
Chemistry PART – II
SECTION – A
O O
1. In (A): becomes aromatic when so it has higher dipole moment.
In (B): though has more number of  - H than but in former compound angle strain is
more.
2. H3C H3C
C CH2 PPh3
O  C CH2  O  PPh3
witting reaction

H3C H3C
3. CH3 CH3
Br H H Br
Br  H
H Br
Both are enantiomers.
4. O O
CHO 
COOH 
CH2
 i OH  
CHO 
 ii H
 CH2OH H2C
O O
 
5. HNO3  2H2SO 4  NO2  H3 O  2HSO 4
each mole of HNO3 produces four moles of solute species ( i  4 )
 Tf = 4  6.12  1 = 24.48 K
6. KHCO3 is soluble in water.
7. MeO HO
 i Ac 2 O H / Pd
MeO CHO   HO CH CH COOH 
2


 ii H3 O ,
(X) (Y)
HO HO
(i) Re d P Br
2
HO CH2 CH2 COOH 
 ii NH
 HO CH2 CH COO
3
NH3
'L  Dopa '
8. Next nearest atoms are present at a distance = a (where ‘a’ is edge length of unit cell)
8
9. Back bonding is more effective in BF3 than in BCl3. So lewis acid character BF3 < BCl3.
10. In option (C)

HCl  PO 43  HPO 42  Cl
3mmol 1 mmol
2 mmol L.R 1 mmol
It is not a buffer solution as resulting solution has HCl + Na2HPO4. Remaining solutions are buffer
solutions.
11. O  V at body centre
3a 3a
4 2
x
T.V OV TV TV TV
3a
4
3a
Body diagonal a
x = shortest distance b/w two
tetrahedral void
a
2
12. 
m  CaF2  

1000  K soln  KH2 O 
s
s

1000  4.2  10 5
 0.2  10 5 
200
4
s  2  10 M
3

K sp  4s3  4  2  10 4 
= 3.2  10–11 M3
on increasing dilution conductivity of solution decreases.
13. N2O3  NO  NO2 Brown colour paramagnetic 

N2 O4  2NO2
4
14. Fe 2  Fe  CN 6   K 2Fe Fe  CN6  
white ppt.
3
Fe2  Fe  CN6   Fe4 Fe  CN6  
3
Pr ussian blue
4
Fe3  Fe  CN 6   Fe 4 Fe  CN 6  
Pr ussian blue
3 SnCl2 so ln
Fe3  Fe  CN6   Fe Fe  CN6    Fe4 Fe  CN6 
3
Pr ussian blue ppt.
9
15. O
C I
2

NaOH
 CHI3   Ph  COONa
Ph CH3  X Y
CH3 Ph CH3 CH3

Ph Ph
O
MgBr C OH Cl
i
C H / 

Ph CH3 ii  H 2 :CCl
Cl

R 
CHCl3  KOH  : CCl2  electrophile 
SECTION–C
1. Process A  B
1 1 1
3 2 3 2 1 
WAB   Pdv    T dv   T  RT 2 dT
 
2 2 3
 W AB = – 480 J
Process B  C
1 1
1 3 1
U  V 2 , RT  V 2
2 2 2
1
 3PV 2  1
1
 P
3 V
1600
1 2
WBC   Pdv    dv    40  10 
3 V 3
100
= – 20 J
Total work done by the gas = 480 + 20 = 500 J.
2. Initial KE of e– = 11 ev
It can excite this atom to n = 2
energy absorbed by the atom for n = 1  2
= 10.3 eV
–
 min KE of e after interaction
= 11 – 10.3 = 0.7 eV
1
3. (i) Cl2  2NaOH NaCl  NaOCl H2O
cold/dil
5
(ii) 3Cl2  6 NaOH  5NaCl  Na ClO3  3H2 O
hot / conc.
4. Compound (A) can have only cis isomer which is optically active, while compound (B) can have
both cis and trans isomers and both are optically active.
5. O2 ,O2 , C2 , C22 and N2 have  - bond.
10
Mathematics PART – III
SECTION – A
2r 2 n
1. Coefficient of x in (1 + x + x )
= coefficient of x 2r in (1 + x(1 + x))n
n
 2
1 3
2r
= coefficient of x in   x    
 2 4
Coefficient of x2r in (1 +x(1+ x))n
r
n
=  Cr k r k Cr k
k 0
r
n! r  k!
=  r  k ! n  r  k !  2k ! r  k !
k 0
n
n
=  C2k n2k Cr k
k 0
n
 2
1 3
2r
Coefficient of x in   x    
 2 4
n 2k n k
 1 3
= x2r in  n
Ck  x    
k 0
 2 4
n 2k r  nk
n  1 3
=  Ck 2k C2r    
k r
 2  4
 Ratio of both expansions = 1
2. 2 + 3 + 4 = 2 + (2 + 1) + (3 + ) [since 3 = 2 + 1, 3 = 2 + 1]

= 2 + (2 + 1) + (2 + 1 + )
= (2 + 2 + 2) + 2 +  = 3 + 
 New root y = 3 + x
 (y – 3)3 = (y – 3)2 + 1
y3 – 10y2 + 33y – 37 = 0
 x   x 
3. f(2x) = f(x) = f(x/2) = f(x/4) = … = f  n 1  = f  n 
2  2 
 x 
consider f(x) = f  n 
2 
 x 
lim f(x)  lim f  n 
n n  2 
 f(x) = f(0)  x  R
(since f(x) is given to be a continuous function)

 f(x) = f(2010) =
2
 3 
cos  cos
 lim 2 2 =0
x 0 sin2 x
11
4.  f  x  3   x 3   13  3  1  x   f  x    0
  f  x   x   1   f 2  x   x 2   1  xf  x   x  f  x    0
2
Using a3 + b3 + c3 –3abc =  a  b  c   a2  b2  c 2  ab  bc  ca 
f 2(x) + x2 + (– a)2 – xf(x) + x + f(x)
1  
=  f x  x 2   x  12   f  x   12  0 
2
Equality occurs at f(x) = x = – 1  f(1) = – 1
But it is given that f(1)  – 1
Only solution is f(x) = 1 – x
Domain of 1  f  x  = x is x  R+  {0}
5. cot + cot( + /3) + cot( – /3) + 3 cot (3) = 0

Put  = /2 – 
tan + tan – /3 + tan ( + /3) – 3 tan3 = 0
 
tan   tan tan   tan
tan + 3  3  3 tan3 = 0
 
1  tan  tan 1  tan  tan
3 3
3
 3 tan   tan  
3   3 tan3 = 0
 1  3 tan3  
0 = 0 so infinite solutions
  
6. px + qy = a
 
Let p x – q y = R n̂
 
R = px  qy
2
 2  2    a
px  qy  px  qy  4pqx.y  0 but x . y 
4pq
2   
 a  4pqx.y  px  qy  0
 
   a  a
 px  qy  x  ,y
2p 2q

x q
 
y p
7. Normal y = mx – 2am – am3 is tangent to the hyperbola if c2 = a2 m2 – b2 (for a line of the form
y = mx + c)
 (– 2am – am3)2 = a2(m2 – 1)
4m2+ m6 + 4m4 = m2 – 1
6 2 4
m + 3m + 4m + 1 = 0
but m + 4m + 3m2 + 1  1 for real ‘m’ so no normal can be drawn.
6 4
8. Let the centres of the first two circles be C1 and C2

and that of the third circle be at C. C
Let M be the foot of the perpendicular from C to C1C2.

C2 M
Let radius of S = 0 be x and that of S1 = 0 and S2 = 0 C1
be r.
12
CM = x, CC2 = r – x  C2M =  r  x 2  x 2
2
C1C2 = r, CC1 = r + x, MC1 = r +  r  x   x 2
le 2 2 2
 In  CMC1, CC1 = CM + MC1
2
 2
(r + x)2 = x2 + r +  r-x   x 
2
r2 + 2rx = r2 + (r – x)2 – x2 + 2r  r  x   x 2
2 2
4rx – r = 2r  r  x   x 2
 Squaring on both sides
 16x2 = 3r2
3r
x=
4
9. f(x) = k ln (sin x) and k = 2
10. The given equation is 0 = t2  2t + 2 = (t  1)2 + 1  t = 1  i = , 

ein
 x +  = cot   1 + 1 + i = ei cosec   (x + )n =
sinn 
ein
and similarly (x + )n = .
sinn 
(x   )n  (x   )n ein  e in sin n
Hence =  .
 2i sinn  sinn 
11. f(x + y) = g(x) + h(y) …(1)

put x = 0
f(y) = g(0) + h(y)  h(y) = f(y) – g(0) …(2)
put y = 0
f(x) = g(x) + h(0)  g(x) = f(x) – h(0) …(3)
 put (2) and (3) in (1)
f(x + y) = f(y) + f(x) – h(0) – g(0)
Define C1(x) = f(x) – h(0) –g(0)  x  R.
 C1(x + y) = C1(x) + C1(y)
The solution of this functional. Equation is obtained by differentiation through first principles as
C1(x) = Cx (where ‘c’ is a constant)
 f(x) = C1(x) + h(0) + g(0) = cx + h(0) + g(0)
g(x) = f(x) – h(0) = cx + g(0)
h(x) = f(x) – g(0) = cx + h(0)
f(0) = f(1) = c
12. sin4 x  4cos2 x  cos4 x  4 sin2 x

= sin4 x  4sin2 x  4  cos4 x  4  4 cos2 x
= 2 – sin2x + 2 – cos2x = 3
13
equation reduces to
/2
= 1  cos2x = 2 sin1  sin2x  1
1 
cos x  sin sin2x 
f(/8) = cos  / 8  sin1 sin  / 4
 – –3/2 –/2 –/4 0 3/2
1  cos /4 /2 
= cos/8 = /4 = 4 = /4 > 0

2
  3 
f(/6) = cos  sin1   0 –/2
6 3 2 3
so one root exists between (/8, /6).
 1 0 0  1 0 0  1 0 0
13. A2 =  1 0 1  1 0 1  1 1 0 
0 1 0  0 1 0  1 0 1
1 0 0  1 0 0 1 0 0
A = 1 1 0  1
3
1 0   2 0 1
1 0 1 1 0 1  1 1 0 
0 0 0  0 0 0 
A3 – A2 =  1 1 1  A – I =  1 1 1 
0 1 1 0 1 1
3 2
A –A =A–I
 Det A n  I = Det((A – I)(I + A + A2 + … + An –1))
= Det (A – I) Det(I + A + A2 + … + An – 1)
=0
A3 – A 2 = A – I …(1)
 A4 – A3 = A2 – A …(2)
A5 – A4 = A3 – A2 = A – I (Using (1))
If n is even An – An – 1 = A2 – A …(3)
If n is odd An – An – 1 = A – I …(4)
Consider n is even
An – A n – 1 = A2 – A (Using (3))
An – 1 – An – 2 = A – I (Using (4))
 An – An – 2 = A2 – I
n n–2 2
A =A +A –I
n–4
= (A + A – I) + A2 – I
2
n–6
= (A + A2 – I) + 2(A2 – I)
2 n2 2 
= (A ) + A I
2
n n2
An =   A 2   I
 2  2 
A50 = 25A2 – 24I
1 0 0   1 0 0
= 25 1 1 0   24 0 1 0 
 
1 0 1 0 0 1

 1 0 0
=  25 1 0 
 25 0 1
14
2 3 2 3
14. sin 2 – sin 3 = 2sin cos
2 2
2 3 2 3 
< 0, >
2 2 2
2 3 
 cos < cos
2 2
2 3
cos <0
2
 sin 2 – sin 3 > 0
cos 2 – cos 3 > 0 (since cos 2 > 0, cos 3 < 0)
 the equation is an ellipse.
Consider sin 2 – sin 3 – cos 2 + cos 3
= (sin 2 – cos 2 ) – (sin 3 – cos 3 )
 1  1
= 2  sin 2  cos 2    sin 3  cos 3  
 2 2 
     
= 2  sin  2    sin  3   
  4  4 
   
Both 2   , 3  
4 2 4 2
 
And 3   2 
4 4
 sin 2 – sin 3 – cos 2 + cos 3 < 0
 The major axis is y–axis
15. Let (l, m, n) be the direction cosines of the line perpendicular to the plane.
 Equation of the plane lx + my + nz = p
x y z
  =1
p  p  p
     
 l  m n
A  p / l,0,0  ,B  0,p / m,0  ,C 0,0,p / n 
Centroid of tetrahedron OABC is
p p p 
(x, y, z) =  , , 
 4l 4m 4n 
Using l2 + m2 + n2 = 1
16
x2 y2 + y2z2 + z2x2 = 2 x2 y 2 z 2
p
1 1 1 16
 2 2 2  2
x y z p
p p p
Put x = sec  sec  , y = sec  cosec , z = cosec
4 4 4
1 4 1 4 1 4
 cos  cos ,  cos  sin ,  sin 
x p y p z p
2 2 2
 1  1  1 16 2 2 2 2 2
         2 cos  cos   cos  sin   sin  
x y z p
15
16  16
= 2
cos2   sin2    2
p p
SECTION – C
5 5
1.  n  1 n   n  
n 2
2  = n
n 2
3
 1 = 220 = 44k  k = 5
2. 1  tan x o  1  tan  x  1o  ... 1  tan  x  44 o   1  tan1o 1  tan 2o  ... 1  tan 45o 
1  tan1o 1  tan 2o 1  tan 3o  ... 1  tan 43o 1  tan 44o 1  tan 45o 
= 1  tan1o 1  tan 44o 1  tan 2o 1  tan 43 o 1  tan 42o ... 1  tan 22o 1  tan 230   2
Using 1  tan x o  1  tan  45  x    2
o
We have
1  tan1o 1  tan 2o 1  tan3o ... 1  tan 44o 1  tan 45o   223
 1  tan x o  1  tan  x  1  1  tan  x  2  ... 1  tan  x  44    223
o o o
Equality occurs at x = 1
f –1 (x)
3. f(x) is symmetric about y = x
2 y Required Area
Required area = 2 
 f  x   x dx f(x)
0
 2 


= 2   sin x dx   sin x dx 
0 



= 2 (2 + 2) = 8
 2k = 8 0  2 x
k=3
A( a )
4. Choose B as the origin  0 
AF 1 EF
Let  , 
FD  CF 2
E( a)
3
c 2a
a  2 c 
 F 5  3
 1  1
Equating coefficient of a,c B( 0 )
D(
2
c)
C( c )
5
2
 2 
  , 5 
  1 3   1   1   1
  1 2 5
  
  1 3 2
4
  
15
16
4
2
  15
5    1 4
1
15
2 4

5    1 15  4
30  8  20  20
 10   12
6

5
1 5 n
 
 6 n1
n=5
5. Let Radius of new circle = r

From symmetry centre of the required circle is (0, 0)
2
 C1O  2  2  1 = 2 – 2 = r – (2 – 1)
r=1
C1O is the distance from origin to centre of any of four circles

Concept Adv (1) 3 Soln

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Concept Adv (1) 3 Soln

Uploaded by

Copyright:

Available Formats

1

ANSWERS, HINTS & SOLUTIONS

CONCEPT RECAPITULATION TEST – III

Q. No. PHYSICS CHEMISTRY MATHEMATICS

4. Path difference of the two rays (one coming

5. Impact takes place along the normal to the vsin

9. Induced emf in the rod   Blv

10. Let mass of the earth is Me and mass of object is m.

11. Charge stored on capacitor 3F = 36 C 36

13. For isothermal process Q = W.

1. Q value of the reaction, Q = (2  4  7.06 – 7  5.6) MeV 

2. The light escape is confined within a cone of apex

3. The wavelength of the sound wave in air is

1. In (A): becomes aromatic when so it has higher dipole moment.

6. KHCO3 is soluble in water.

10. In option (C)

11. O  V at body centre

13. N2O3  NO  NO2 Brown colour paramagnetic 

CH3 Ph CH3 CH3

5. O2 ,O2 , C2 , C22 and N2 have  - bond.

Mathematics PART – III

2. 2 + 3 + 4 = 2 + (2 + 1) + (3 + ) [since 3 = 2 + 1, 3 = 2 + 1]

5. cot + cot( + /3) + cot( – /3) + 3 cot (3) = 0

8. Let the centres of the first two circles be C1 and C2

Let M be the foot of the perpendicular from C to C1C2.

9. f(x) = k ln (sin x) and k = 2

10. The given equation is 0 = t2  2t + 2 = (t  1)2 + 1  t = 1  i = , 

11. f(x + y) = g(x) + h(y) …(1)

12. sin4 x  4cos2 x  cos4 x  4 sin2 x

= cos/8 = /4 = 4 = /4 > 0

1 0 1 0 0 1

5. Let Radius of new circle = r

You might also like