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1
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ANSWERS, HINTS & SOLUTIONS

CRT – IV
(Paper-2)
ALL INDIA TEST SERIES
Q. No. PHYSICS CHEMISTRY MATHEMATICS
1. B B B
2. D A C
3. B B A
4. D C B
5. B C C
6. B D C
7. A C C
8. D A B
9. B A B
10. C A C
11. B C B
12. C D B
13. D D B
14. A A A
15. D B B
16. C C D
17. D C A
18. B D B
19. B C D
20. C D B
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website: www.fiitjee.com
2
Physics PART – I
SECTION – A
 1 1
1. hv = 13.6 (3)2  2  2  = 2.75 eV
4 5 
for n= 4 to n = 3
1 1
hv = (13.6) × (3)2  2  2  = 5.95 eV
3 4 
for shorter wavelength
3.95 = 5.95 –    = 2eV
for longer wavelength eVs = 2.75 – 2 = 0.75 eV.
2. If F = 0
300
Then assuming no relative motion acceleration of A + B = = 20 m/s2
15
20 m/s2 > g
where  = 0.5 and g = 10 m/s2
 relative motion shall exist. Hence F = 0 N.
3. The electrostatic force on proton is along positive x-axis and the magnetic force is along negative
x-axis. Initially net force on charge q is zero. Since the velocity of proton is increased in repeat
experiment, the magnetic force on proton shall increase and the proton would then be deflected
in negative x-direction.
4. The reference potential at point A and B be o and x respectively.

Applying Kirchoff laws
20  x 10  x 0  x
  0
R1 R2 R3
or x = 10 V thus i = 0.
6. The electric field of the negatively charged sphere is not entirely canceled inside the dielectric.
This field points toward the sphere and so a positive particle placed inside the dielectric would
tend to move toward the sphere. This means that the potential on the negative side of the
dielectric is higher than that on the positive side.
7. The KE of given section AP and PB will x

be equal if MI of each section AP and A P B
section PB about A is same. L
x2 L2 x2
IAP= (x) IPB= IAB – IAP = (L) – (x)
3 3 3
x3 L3 x 3
 IAP= IPB  = 
3 3 3
3
L L
or x3= or x = 1/3
2 2
3
 y 1  x  2
8. For first & second position = , =
x O y O
y2 
 2
= 1 =4
x  2
y
 = 2 and y + x = 96
x
 y = 64, x = 32
O y Position 2
= = 2  A is True
2 x y x
Distance between two position of lens = y – O
x = 32 cm  B is True Principle axis I2
xy 64  32 x y
Focal length of lens f =  I2
x  y 64  32
Position 1
64
=  C is True
3
Distance of lens from shorter image = x = 32
cm  D is True
9. NA = N0e–t
dNB
= NA – NB
dt
 dN  –t t
et  B  NB  = N0e · e
 dt 
e t · NB = N0 · t
NB = N0te–t
dNB
= N0 e t  et t 
dt
dNB  1
If = 0 then (NB)maximum i.e. at t =  
dt 
dNA
– = N0e–t
dt
d2NB dNB
2
= N0  et  et   2 e t  t  = 0 for to be maximum
dt dt
2
That is t = activity of A and B will be same

12. t cos   µs N for no relative motion

3
t cos   (10 –t sin )
4
3
t (cos  + sin ) 0
4
10
t1 = to start motion
4cos   3 sin 
10
tmin = as (4 cos  + 3 sin )max = 5 for  = 37°
5
4
a = t cos  – µk (10 – t sin ) = t (cos  + µs sin ) – µk 10

t2
t 2
v = (cos   k sin )   k 10t
2 t1
 (t 2  t 2 ) 
v =  2 1 (cos   k sin )  k 10(t 2  t1 )
 2 
(t 2  t1 )
= [ (t1 + t2) (cos  + µk sin ) – 2µk10]
2
 50 
  2
= 
9  3   50  2  4  1  3   20 
    
2   9  5 3 5  3 
16  68 20 
=   1
9 3 3 
16 48 928
= × =
9 3 27
256
V= m/s
9
t2 sin  = 10
10  50 
t2 = =  
 sin   9 
t1= 2
14. Irms (XL2  R2 )1/ 2 = 300 = Irms (X2C  R2 )1/ 2

give XC = XL
 200
so Irms = rms 10 =  R = 10 
2R 2R
XC2 + 102 = 302
XC = 20 2 
so VCmax = Imax · XC
= 10 2 × 20 2
= 400 volt
N sin 
16. N sin  = mg
2 N
mv
 N cos  = 
F.B.D. of particle
R N cos 
gR
tan  = = v = gR cot  
v2 mg
v = gh as h increases v increases.
2R 2h tan  h
T = = = 2 tan  as  increases T
v gh g
increases.
17. 3y defination
5
18. By NLM
N sin = 4 ma4 ...(1)
3mg – Ncos – T1 = 3 ma2 ...(2)
T1 – T2 cos 60 = 2 ma2 ...(3)
T2 – mg = ma1 ...(4)
a3 = a4 = a2
a2cos60 = a1
5mg 42mg
b  mg  
37 37
mg 21ma
3mg  Ncos   
2 4
5mg 37ma

2 4
 10g 
a 
 37 
mg mg 9ma2
So, T2   2mg  
2 2 4
19. f A = 0
2v 0 2  10
f B = f0   3000  200 Hz
c  vs 300
2cv s 2   350  50
f C = f0   3000  875 Hz
c 2  v 2s 400  300
360  2  50
f D =   3000  900Hz
400  300
20.  df   ERd cos 

R  RE   sin 
 2RE
t   ERd .R sin 


 ER2   cos 2 
  
2 
      
 ER 2   cos        cos      
 2   2  
t net  ER2  2 sin  
MR2
  –2E 2 
2
 2E 2 
  – 2 

 MR 
4EA
w
m

w  2ER2  sin d  td
0
2
w  2ER 1  cos  
6
Chemistry PART – II
SECTION – A
1. Hyponitrous acid is hydrate of nitrous oxide.
2. As most liquids follow Trouton’s rule which provides constant value of Sovap  90 J/K.
RMT02 RMT0
So K b  
1000  H0V 1000  S0V
as R and  S 0V are constant so Kb is proportional to MT0 (T0 increases along with M) while,
S 0f may vary with a good deal particularly when M is very high.
3. 2Fe3+ + Fe  3Fe2+, G° = –ve  Eocell   ve
8  105
4. pNO2   10  8 atm,  pN2O4  2 atm
106
2
pNO 82
Kp  2
  32 atm
pN2O4 2
32
Kc   0.974 mol L1
0.0821 400
(ng = 1)
6. Cl F Cl
I Cl C C 
k1
F  : B  
 Cl C CF 3  HB (fast)
k 1
H F carbanion
(S)
k2
II Cl2C CF2   Cl2 C  CF2  : F (slow)
F
Rate = k2 [Carbanion]
Also,
k [Carbonion][HB]
Kc  1 
k 1 [S] [: B  ]
k c [S][B  ]
 [Carbanion] = , so
[HB]
[S][B ] – –1
Rate = k2kc Rate  [S] [B ] [HB]
[HB]
7. Fe2O3(s) + 3CO(1 atm)  2Fe(s) + 3CO2 (1 atm),

G25o C given for reaction is Go25o C as all the species are in their standard states.
So, for the reaction
2Fe(s) + 3CO2 (2 atm)  Fe2O3(s) + 3CO (20 atm),
Go25o C will be equal to + 10 kJ
7
3
PCO (20)3
Q 3
 3
 103
PCO 2
2
G = G° + 2.303 RT log Q
–3 3
= 10 + 2.303  8.314  10  298 log 10
= 10 + 17.11
= 27.11 kJ
8. Substitution of —OH by Br atom takes place by carbocationic intermediate formation in rds. The
stability of carbocation involved is as follows:
CH2 CH2 CH2 CH2
> > >

OCH3 Br O2N
9. Sc 2 Si2 O7 is a pyrosilicate
Silicates containing Si2 O67  ios are pyrosilicate
Zn2 SiO4 orthosilicate
Ca3 Si3 O9 and Be3 Al2Si6 O18 are cyclic silicates

B  OH 3  H 2O B  OH 4  H 
10.
CH2 OH OH OH CH2 O OH
+
B B
CH2 OH 2H2
OH CH2 O OH
OH
CH2 OH
CH2 OH CH2 O O CH2

B
CH2 O O CH2
11. Br Br
Br2 /CCl4
Br
Br2 /light Alc. KOH/

Monobro min ation
    
(B) (C)
(X)
+
2 
NaNH excess H2O Na
   
(D)
Br
NBS Zn/

  
(B) (E) (F)
8
13. As it suffers loss in weight with H2SO4, ionization sphere contains H2O molecule. As complex also
–
gives white ppt. with AgNO3, the ionization sphere should contain Cl ion. So formula of the
complex may be [CoBrCl(en)2]Cl.H2O.
14. Only one Cl– ion is ionisable from the complex. So, 1 mole of complex will generate half mole of
PbCl2 precipitate.
15. Equilibria shown for bulb ─I is a mix of


Decomosition
A (s)  
 P(g)  H2 S(g)
 K p  4 2  16

Sub lim ation
A (s)  
 A (g) Kp  2

Decomosition
A (s)  
 P(g)  H2S(g) K p  16
16.
x x

Decomosition
B(s)  Q(g)  H2S(g) K p  25
y y
16  x(x  y), 25  y(x  y)
Totalpressure  2x  2y  V.P.of A (g)  14.8mm
19. 2, 4DNP test is given by aldehydes and simple ketones, Baeyer’s test is used to identify CC
unsaturation and iodoform test is given by methyl ketones or alcohols containing CH3CH(OH)
group. No condition for tautomerism in (D) and (D) but (A) can not give idoform test due to active
methylene group.
9
Mathematics PART – III
SECTION – A
1. If f  a   f a  h  and f  a   f a  h  for h  0 and h  0 , then x  a is a point of maxima
x x x sin x
2. cos cos 2 ......... cos n 
2 2 2 x
2n sin
2n
3.  h'  x   f '  x   g' 1  x   0

 f '  x   f ''  x   0
d x

dx

e f 'x  0 
 e x f '  x  is decreasing function
 e x f '  x   e0 f '  0  for x  0
 f '  x   0 x  0
 g' 1  x   0 x  0
4. f 1  x   x  1
 h1  x   x 3  x
d 1

dx
 
h  x   3x 2  1
5.  f  x   tan2x  tan x
 
 f 2n  tan 2n 1  tan2n
 g  n   tan2n1  tan1
g  2013   tan22014   tan1
6. Since distance from origin is unchanged

1 1 1 1
So, p   2  2  2
1 1 p a b

a2 b2
2
1 2  1 1
    
p2 ab  a b 
x
7. y 2
 y2  x2 y  x  0
x y
 x 
  2x  2  1

dy   2xy  1
   x y  
 2x 2  x2  y  
dx x 2  2y 
x2  y  y x

x2  y   y 


 y 
10
1 dy

 x2  y

d  ln y  
 y  x2
y dx 
x 2  y x  y2 dx  
x2  y x  y 2   
 ln y  c  
 y  x  dx 2
 x  y  x  y 
2 2
1 1  5
 f 'y  and for x  1 , y 2  y  1  0  y 
y 2
d
f "(x) g"(x)  f '(x) / g'(x) g' d  f '  2f '  x 
dx
8.  =
f '  x  .g'(x)
= .  
f x
 f(x).g(x)  1
f '  x  g'  x  f ' dx  g' 
2
 g'  x  
 1  1
9. y = log1/3  x    log3 9x 2  6x  1 = log1/3  x    log3 | 3x  1| = 1
 3   3 
1
Since, x  , maximum {AB} = 3
3
3n
2a   3n  1 d
10. an = 2   3;
2n n
2a   2n  1 d   2a   n  1 d
2 2
2n
1
 Lt  .3  6
n 
r 1 n
6 3 6 3 6
11.  
x2  [x] d | 3  x |      
x 2  [x] d(3  x)   x 2  [x] d(x  3)    x 2  [x] dx   x 2  [x]  
0 0 3 0 3
6 3 6 3 6
 x 
2
  [x] d | 3  x |   x 2 dx   x 2 dx   [x]dx   [x]dx
0 0 3 0 3
3 3 3 6 3 3 1
x3  x3 
=      [x]dx  3  [x  3]dx  9  (72  9)   [x]dx   [x]dx  3  3dx
3  0 3 0 0 0 0 0 0
= 72 – 18 + 9 = 72 – 9 = 63.
3 0 3
12.  | x | d | x |  [ x]d(  x)   [x]dx
2 2 0
0 3 0 3 3
=   [ x]dx   [x]dx   [x]dx   [x]dx   [x]dx  2(3  2)  2
2 0 2 0 2
n 1
1 1 1 1 1  1 
13.-14. f(1,n)  f(1,2)    ...   1    
3n  2 3n  2 3n  3 3 2   3  
11
15. Let r and R be radius of required & given circle respectively &
let centre is (h, k) A
By given condition 2
(h  1)  (k  2) 2
=Rr r
C
r 30°
Now, = sin 30°
AB B (1, 2)
r = AB/2 = (R  r)/2 (AB = R  r)
R
 r
3
R 2R
 (h  1)2  (k  2)2 = R  =
3 3
3 3
Now, R =
2
2 3 3
 (h  1)2  (k  2)2 =   3
3 2
 Locus is (x  1)2 + (y  2)2 = 3 which is C
16. When major axis of ellipse (E) is parallel to x- (1, 2+3)

axis then equation of E will be
 x  12  y  2 2
 1 …..(1)
a2 b2
F (1+3, 2)
Such that a2 + b2 = 3 A B (1, 2) C D
(1–3, 2) (1+(3/2), 2)
In this case one focus will lie in between F (1–(3/2), 2)
and D and other in between A and F.
i.e., 0 | x  1| 3 and y = 2 (1, 2–3)
sin x
17. (P)  xf  x    f  x  dx    xdx
x
(Q)  y  z  4  x
  y  z 2 
2 2
and y  z   
 2 
 
2
 4  x 
 6  x2   
 2 
 
2
 x2
3
(R) Sum of digits in N = 705 is divisible by 31 but not 32
(S) Locus of z is an ellipse where a = 4 and b  2 3
i.e. z  1 min  2 3
1
 z 1  2
3
12
18. (P) LHS = sin2  + 1 – [cos2 (120° + ) – sin2 (120° – )]

1 1 3
= sin2  + 1 – [(cos 240°)(cos 2)] = sin2  + 1 + cos2  sin2   1  1  2 sin2  =
2 2

2

(Q) 2e2x – 5ex + 4 = 0
Let roots be x1 and x2, product of the roots be
e x1  e x2  2 , e x1  x2  2
x1 + x2 = ln = 2
(R) a, b  R p1  p2  4 3 tan p1  p2  8 = tan p1p2  b2  16 – tan 3 p2
tan3
p1 2 tan 16x 2  25y 2  400, + tan 3  = 0  = –2
tan 
cot  1 1 1 2
Now    
cot   cot 3 1  tan   cot 3 tan  1 3
1 1
tan3 2
tan  cot 
Alternatively: Prove that  = 1 now proceed
tan   tan3 cot   cot 3
2 sin(   300 ) cos(   120 o ) 1
(S) . 
2 sin(   120o ) cos(   30o ) 3
1 1
cos2  cos2 
2 sin(2  900 )  sin150o 1 2 1 2 1
o o
 or  or 
sin(2  90 )  150 3 1 3 1 3
cos 2  cos2 
2 2
3 1
 3 cos 2  – = cos 2  +
2 2
2 cos 2   cos 2  = 1
19. (P) 2x + y = 0, 4y + 3z = 24 and 12x – 7z = 24. Solving we get the point intersection as
(–12, 24, –24) whose distance from origin is 36
1 2 1
(Q) For no unique solution  = 0  3 3  0
2 1 2
 1(9)   (3)  2 (9)  0    9    81

(R) Let the centre be at origin and the vertex at ( 2, 0) . The remaining vertices will be
 2 2 
corresponding to the complex numbers 2, 2 2 , 23 , ...., 28    cos  i sin  .
 9 9 
The product of distances
= | 2  2 || 2  2 2 | ...  ( 2)8 | 1   | | 1   2 | ... | |  8 |  16  9  144
(S) a  b 3i  (72  56 3i) . ei /3  (36  28 3i) ( 1  3i)
 a = 36 – 84 = –48, b = 36 + 28 = 64. (a + b)2 = 256
13
 
20. (P) 3 tan2  3 tan  ( 3   )  0
2 2
A B
tan  tan
c 2 2  
cot   3
2 A B   
1  tan tan 1  1  
2 2  3

 C
3

sin
sin A 2 if  A    
(Q) Clearly from figure, tan   tan ,  
A   2  
2
(R) sin A cosB  cos A sinB sin C  sin A cosB  cos A sinB

 1  sin(A  B)  sin(A  B)  1 or C 
2
2
 1 
(S) 16  cos2 x    (k  1)2  0 , x  n 
 4 3

Fiitjee: Answers, Hints & Solutions

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ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

4. The reference potential at point A and B be o and x respectively.

7. The KE of given section AP and PB will x

12. t cos   µs N for no relative motion

a = t cos  – µk (10 – t sin ) = t (cos  + µs sin ) – µk 10

14. Irms (XL2  R2 )1/ 2 = 300 = Irms (X2C  R2 )1/ 2

20.  df   ERd cos 

3. 2Fe3+ + Fe  3Fe2+, G° = –ve  Eocell   ve

7. Fe2O3(s) + 3CO(1 atm)  2Fe(s) + 3CO2 (1 atm),

CH2 CH2 CH2 CH2

> > >

CH2 OH CH2 O O CH2

(B) (E) (F)

15. Equilibria shown for bulb ─I is a mix of

Mathematics PART – III

1. If f  a   f a  h  and f  a   f a  h  for h  0 and h  0 , then x  a is a point of maxima

3.  h'  x   f '  x   g' 1  x   0

6. Since distance from origin is unchanged

16. When major axis of ellipse (E) is parallel to x- (1, 2+3)

18. (P) LHS = sin2  + 1 – [cos2 (120° + ) – sin2 (120° – )]

 1(9)   (3)  2 (9)  0    9    81

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