You are on page 1of 12

Study AITS with www.puucho.

com

From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students
from Classroom /Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
FIITJEE JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS
FULL TEST –I
(Paper-2)

Q.
PHYSICS CHEMISTRY MATHEMATICS
ALL INDIA TEST SERIES

No.
1. C D B
2. C A B
3. D C A
4. B B C
5. B B D
6. D C D
7. B D C
8. C B A
9. A C C
10. D B C
11. B A D
12. D C A
13. B A C
14. A D A
15. A C A
16. B B C
17. B A B
18. A B A
19. B C A
(A)  (s), (B)  (q), (A  p, q, r), (B  q), (A)  (q), (B)  (r),
1.
(C)  (p), (D)  (r) (C  p, r, S), (D  p) (C)  (s), (D)  (p)
(A)  (q); (B)  (r); (A  p, q, s), (B  r, s), (A)  (s), (B)  (p),
2.
(C)  (s); (D)  (p) (C  q), (D  r, s) (C)  (q), (D)  (r)
(A)  (p), (B)  (r), (A  p, r), (B  q, p), (A)  (s), (B)  (r),
3.
(C)  (s), (D)  (q) (C  q), (D  q, s) (C)  (p), (D)  (q)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14
2

Physics PART – I

2. T sin  = mg/2 T sin 


T
T = T cos 
mg mg
= cot   T cos 
T
2 2 tan 

1
3. mv 2  pt (P = const)
2
2Pt
 v=
m
dv 2P 1
a= 
dt m 2 t
mP 1
F = ma = 
2t v
      m m
5. F  F1  F2  F3  F4  F5
   
F2  F5 and F2  F4 F2 F3
m m
 
F1  F3  2F2 cos 30  2F1 cos 60
F1 F4
Gm2 Gm2 Gm2 m F5 m
F3 = ; F 2 = ; F 1 =
4a2 3a2 a2
Gm2  5 1  2
F= 2    = m a
a 4 3
Gm  5 1 
=   
a3  4 3
4 3a3
T = 2

Gm 5 3  4 
6.
P S

R
P

v  g  a   m  g  a 
7. a= = 20 m/s2
m
2h
t= = 1 sec
a

R
10. Time period becomes 2 . We can’t neglect the roundness of earth for the pendulum of
g
infinite length.

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

3 AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

d
12. The ve sign is  signifies the direction of induced emf.
dt

14. process AB U = constant


P RT
 and U  t
 M
 P = const
Process BC isochoric
Process CA  isothermal

15. Q = QAB + QBC + QCA


10U0
Q = 5U0 + 3U0 + ln2.5
3
16. W AB = QAB  UAB = 5U0  (3U0) = 2U0

1  w 1   
17. For lens L1, ray must move parallel to the axis after refraction    x = 10 cm
 x R1

18. For lens L2, image must form at centre of curvature of the curved surface after refraction through
plane part.
2 
  0
R2 x 
 x = 8 cm

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14
4

Chemistry PART – II

1.
CH2MgBr
Br OH
H H
Mg 
H

Ether
  
Re arrangment
O O

H3C H3C
2. O O O O

H3CO 3 CH O  H3CO


O O

 O
H
O
  O
O
COOCH3 OH O
H3COOC COOCH3
3. P PAo X A  PBo  PAo 1  XB   PBo XB
P PAo   PAo  PBo B
Thus PAo  120 Torr
PAo  PBo  75  PBo  45 Torr
Hence C is correct answer.
o 1000
4. BaSO  
4
Conc  normality 
  1000 1000  8  10 5
Normality  o
 = 2 × 10-4.
BaSO 400
4

Normality
Molarity   10 4 M  Solubility 
2
Ksp = S2 = 10–8 M2.
1
5. Tav 
K
10  0.693 6.93
T99.9  10  ty 2  
K K
 6.693   1 
Number of natural life times =  / 
 K  K 
= 6.93

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

5 AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

6. OH
O B O

HO B O B OH

O B O
OH

7. Ca  OCl Cl.H2 O  Cl2


145 71
71
Percentage   100  49
145
Hence D is correct answer.
 d  c   0.0033
17.     1.32  104 m min1
 dt  25
I
 d c   4 1
 dt   2.6  10 m min
 II
 dc   3 1
   1.02  10 m min
 dt III
18. On comparing rates order w.r.t A = 2, and w.r.t. B = 1. Thus rate law = K[A]2[B]
dx 2
19.  K  A  B 
dt
 dx / dt 
K  0.26
 A 2 B

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14
6

Mathematics PART – III

1. Total number of lines made = 9C2 = 36


Now, these 36 lines are 9 sets each with 4 parallel members. With 5 vertices number of lines
made
5
= C2 = 10
Clearly, atleast 2 members belong to the same set
So, atleast one pair is parallel

OA 2  OB 2  AB2
2. cos  
2OA  OB
2
 OA  OB 
OA 2  OB2   
  3  OA  OB   1
2 2
=  2
2OA  OB 8 OA  OB 4
For maximum cos ,
3  OA 2  OB 2  1 3 2  OA  OB 1 1
     =
8  OA  OB  2 8 OA  OB 4 2

 
3

3. S1 = a1
S2 = a1 + a2
S3 = a1 + a2 + a3

Sn = a1 + a2 + ….. + an
If we divide all S1, S2, ….. Sn by 23 we get remainders 1, 2, 3, 4, ….., 22
So, two of these give same remainders Sp, Sq
 Sp – Sq will be divisible by 23
Sp – Sq = ap + 1 + ap + 2 + ….. + aq

 12 12 22 42   2
4. Using Cauchy we get,  z1  z2  z3  z 4  
z

z

z

z
  1  1  2  4   64
 1 2 3 4 

1 b
5. Point of intersection is   ln  
2 a
For C1,
dr d
 ae , now tan 1  r =  ae  a 1e  1
d dr

 1 
4
For C2,
dr  1
 be  tan 2   be      e  1
d  b
3
 2 
4
3  
 Angle of intersection is 2  1   
4 4 2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

7 AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

6. Let c, d, e be the three points where y = f(x) crosses x–axis. Then, f(c) = f(d) = f(e) = 0
Assuming a < c < d < e < b. The function f satisfies Rolle’s theorem in two intervals (c, d) and
(d, e). Since f and f are continuous and f(c) = f(d) = 0
So, there exists, at least one point in the interval (c, d) and (d, e) such that derivative is zero
Let, C1  (c, d) such that f(C1) = 0 and C2  (d, e) such that f(C2) = 0. Now the function f
satisfies Rolle’s theorem since f, f are continuous and f(C1) = f(C2) = 0
So, by Rolle’s theorem, there exists a number C3 in between C1 and C2 such that f(C3) = 0
 Minimum one root C3 of the equation f(x) = 0 lies in the interval (a, b)

7. Dividing the given differential equation by 3xy(y2 – x2)


y  y2  2x2  x  2y 2  x2 
dx  dy  0
3xy  y 2  x2  3xy  y 2  x 2 
dx xdx ydy dy
    0
x y2  x 2 y2  x 2 y
1 d y  x 
2 2
 d  ln  xy    0
2 y2  x2

 d ln  x 2 y 2  y 2  x 2     0

 ln  x 2 y 2  y 2  x2    c
 x2y2(y2 – x2) = c

2
8. Let the circle be x 2   y     a2 . Let the point of intersection of tangents at P and Q be (h, k).
Then equation of PQ, is hx   k    y     a2  0 . As it passes through  a,0  , so,
ha    k     a2  0 .
  2  k  a  h  a   0. D  0  k 2  4a h  a   0
i.e. y 2  4a  x  a  .

1 1
   x 2 f  x dx 
  f  x   2xf  x   x f  x  dx = 
2
2 2
– 22 + 2 = 0
9. Consider 
0 0
However f(x) assumes only positive values i.e. in (0, 1)
2
 ( – x) (f(x)) > 0  integral can’t be zero

10. Differential equation can be written as, (p – x)(p – 2 sin x)(2p + cos x) = 0 which has solution as
2
(2y – x – c)(y + 2 cos x – c)(2y + sin x – c) = 0
n+1
11. Put x = –1 we get (–1 + 1) p(–1) + 1 = (–1) (n + 1)!
 1n1

 n  1 !
 1n1 x  x  1 .....  x  n  x
So, p  x   
 n  1 ! n  1 x 1
1, where 'n' is odd

Clearly, p  n  1   n
 n  2 , where 'n' is even

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14
8

 2  2
13. If e is the eccentricity then, e2 
2
1 1 1
Now, we know, 2
 2
 ab  2 2
 ab  h2
   
ab 1
  2  2  ,  2 2 
ab  h2 ab  h2

2 2  a  b 2  4  ab  h2 
   
 ab  h 2
1 1
   a  b   4  ab  h2 
2

2 2
2 2
For an ellipse 2
 a  b   a  b   4 ab  h2 

 a  b 2  4h2  2 2
So, e2   a  b    a  b   4h 

2 ab  h 2

14. Put y = z = t = 0
f(0)[f(x) + f(0)] = f(0)
Put x = 0
2f 2(0) = f(0)
1
 f(0) = 0,
2
1 1
If f(0) =  f(x) + =1
2 2
1
 f(x) =
2
If f(0) = 0, z = t = 0
 f(x) f(y) = f(xy)
Let, x = y = 1  f 2(1) = f(1)
 f(1) = 0 or f(1) = 1
We have f(0) = 0, f(1) = 0, y = 1
f(x) = 0
Also, f(0) = 0, f(1) = 1, x = 0, y = t = 1
(f(0) + f(z)) (f(1) + f(1)) = f(–z) + f(z)
 2f(z) = f(–z) + f(z)
 f(z) = f(–z)

15. If y = x in f(x) f(y) = f(xy)


 f(x2) = f 2(x)  0
Put x = t, y = z
[f(x) + f(y)]2 = f(x2 + y2)
2 2 2 2 2
 f(x + y ) = f (x) + f (y) + 2f(x)f(y)  f (x)
2 2 2
 f(x + y )  f(x )
 f is non decreasing for positive x

16. Put y = z = t = 1
 2(f(x) + 1) = f(x – 1) + f(x + 1)
f(2) = 4, f(z) = 9, f(1) = 1, f(0) = 0
f(n) = n2 (Possible function), if f(n – 1) = (n – 1)2
2[f(n – 1) + 1] = f(n – 2) + f(n)

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

9 AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

 f(n) = n2
p
Now, for x  (rational number)
q
p p
f   f  q2   f  pq  f   q2  p2 q2
q
  q
2
p p
 f      (True for rational number)
 q  q
Now, if x  R, lets prove for positive x since if it is proved the function is even and will follow for
negative x
2
Assume for x > 0, f(x) < x
So, now a rational number ‘r’ between f  x  and x  f  x  < r < x
 f(x) < r2 < x2
[f(r) = r2, f is non decreasing]
 f(r) = r2  f(x) [contradiction]
 f(x) < x2 (impossible)
Similarly we can prove contradiction f(x) > x2
So, only possibility f(x) = x2 substituting f(x) = x2 we get
(f(x) + f(z)) (f(y) + f(t)) = f(xy – zt) + f(xt + yz)
(x2 + z2)(y2 + t2) = (xy – zt)2 + (xt + yz)2 [Lagrange identity]
1
So, f(x) = , f(x) = 0, f(x) = x2 are the required solutions
2

17. am3 + m(2a – h) + k = 0


 am3 + m(2a – x1) = 0
 am2 = x1 – 2a {m = 0 (one possible value)}
x  2a
 m2  1 , if x  (0, 2a)
a
 m2 = (–) number, so non real roots

18. Let P(h, k) be the point am 3 + m(2a – h) + k = 0


Since, m1, m1, m1 are the possible roots
 3m1 = 0  m1 = 0
If m1 = 0 is the root then k = 0
am3 + m(2a – h) = 0
h  2a
 m2   0  h = 2a
a
(2a, 0) is the only point

8a
4  3/2 2 2  5 / 2 8a
19. A1   x  2a  dx =  x  2a   2a
2a
27a 3 3a 5
2 2  5 / 2 2 2 48 2a2
= 6a    36a2 6a =
3 3a 5 3 3a 5 5
8a
2  3 / 2 8a 4 64
2a2
A1  
0
4axdx  2 a 
3
x 0 =
3
a 8a 8a 
3

4 3 11 352 2a2
Area = 2(A2 – A1) = 2  16 2a2    = 32 2a2  
3 5 15 15

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14
10

SECTION – B

1. (A) |A – xI| = 0
There exists a non zero matrix X such that AX = xX
 [(Adj A)A]X = x(adj A)X
 |A|IX = x(adj A)X
 |A|X = x(adj A)X
AX
   adj A  X
x
AX
  adj A  X 
2
(B) A ' I   A  I '  A  I
 A ' I  0 if and only if A   I = 0
 A ' I  0 if and only if A   I = 0
or  is the root of A ' xI  0 if and only if  is the root of |A – yI| = 0
 e–i is the required solution
 A11   A12 .......... A1n 
 
0 A 22  ..... A 2n 
0 | | 
(C) B  I    =0
| | | 
| | | 
 
 | | A nn   
 (|A11| – )(|A22| – ) ….. (|Ann| – ) – 0
Clearly the elements of principal diagonal become the roots
(D) Let, AX = X [X is a non zero matrix]
 X' AX = X' X = X'  AX'IX
X' AX and X'IX are both real
Also, X' X  0 , X  0
   X' AX / XIX is real so  can have real values

1
2. (A) z = cos  + i sin , z   2cos 
z
1
z  2isin 
z
1
zp  p  2cosp
z
4 2
4 2  1  1  1   1   2 1
Now,  2isin    2cos     z    z   =  z 6  6   2  z 4  4  z  2   4
 z  z  z   z   z 
then, 2 cos 6 – 2.2. cos 4 – 2 cos 2  + 4
4 4 4 2 2
 2 i sin  2 cos  = 2(cos 6 – 2 cos 4 – cos 2 + 2)
=2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

11 AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14

1 C
(B) Volume of tetrahedron =   ArABD   CQ
3
1  AB 
=    DP  CQ
3 2 
Let, CD be the largest side and AB = x  1
B D
Let, T be closer to A than B Q
x T
 BT  P
2
x2 A
 CT 2  BC2  BT 2  1 
4
x2
 CT  1  (same for DP, CQ)
4
1 x  x2  1  1
So, V    1   x 4  x 2   Vmax 
3 2  4  24 8
(C) By AM  GM
cos x
cos3 x   cos2 x (x is an acute angle)
4
Now, setting x = A, B, C we get
x1 + x3  cos2 A + cos2 B + cos2 C + 2 cos A cos B cos C = 2x2
3
 x1 + x2 + x3  3x 2 
2
A B C Sa Sb Sc
(D) Let, u  cot , v  cot , w  cot  u  , v , w
2 2 2 r r r
S S  a   S  b  S  c 
 uvw
r r
Now we can rewrite as 49[u + 4v2 + 9w2] = 36(u + v + w)2
2

 (3u – 12v)2 + (4v – 9w)2 + (18w – 2u)2 = 0


1 1
u:v:w=1: :
4 9
S  a S  b S  c 2S  b  c
Multiplying by r we get   
36 9 4 94
2S  c  a 2S  a  b a b c
=    
4  36 36  9 13 40 45

1 4 2 3
3. (A) Put x  y  and substitute, 8y + 4y + a – =0
2 2
3
Again, z = y2 we get, 8z2  4z  a   0
2
3 3
When a  there are 2 non real roots and two real and a  we have 4 non real roots
2 2
 3
1, a  2
 Sum = 
2, a  3
 2
2
xy
(B) xy     1  0 < xy  1
 2 
x y (x + y ) = 2(xy)3((x + y)2 – 3xy) = 2(xy)3 (4 – 3xy)
3 3 3 3

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com
Study AITS with www.puucho.com

AITS-FT-I-(Paper-2)-PCM(S)-JEE(Advanced)/14
12

Put z = xy
4
 4  3z  3z 
z3  4  3z     1
 4 
3 3 3 3
 x y (x + y )  2
(C) There are 9 possible numbers of the type 7775775, 7757575, 7575575 etc.
(D) We have f(9) = f(4 + 5) = f(4 . 5) = f(20) = f(16 + 4) = f(16 . 4) = f(64)
 f(64) = f(8 . 8) = f(8 + 8) = f(16) = f(4 . 4) = f(4 + 4) = f(8) = 9

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
www.puucho.com

You might also like