CRT 4 Sol

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AITS-CRT-IV-PCM(Sol)-JEE(Main)/15
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ANSWERS, HINTS & SOLUTIONS
CRT –IV
(Main)
S. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. A B A
2. B D D
3. D A A
4. B D A
5. C B C
6. C C C
7. B C C
8. D D D
9. D B B
10. A C A
11. D D B
12. B C C
13. A B A
14. C B A
15. C A A
16. C C A
17. B C C
18. D A B
19. A B B
20. C B B
21. B A B
22. B C B
23. D C B
24. D B A
25. C D C
26. C C B
27. A D C
28. A A D
29. D C C
30. A D C
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2
Physics PART – I
SECTION – A
1. Angular frequency of SHM is equal to angular velocity of particle  = V/R.
T
2. V = n = n(2x)  T  x
M
If tension is twice then x will increase to 2 x.
1 T
3. f0  [M = mass/length]
2l M
for elastic wire T = Kx
x  elongation from natural length
Hence frequency depends on K and original tension.
5. Temperature is maximum for which product of P and V is maximum as no. of moles is same for
each containers
PV = nRT
T  PV
Hence option (c) is true.
6. S = [ – 2] + [ – 2 (60 – )]

= 2 – 2 – 120 + 2 = constant
Angle of incidence and final reflected ray does not depend on .
60º – 
 60º
8. It only depends on temperature. In a mixture all gases has same temperature.
9. U  nCV T From graph

Maximum change in internal [T3 > T2 > T1] energy is in process 4.
 300  11
10. n = 1  
 850  17
Work done in each cycle is
W 1200
n= Qin =  17
Qin 11
1200  17
Qrej = Qin – W =  1200
11
1200  6
= = 654.54
11
11. Quantities in option a, b, c has dimensions of [M L–1T2] but angular momentum per unit mass has
2 –1
dimension [Mº L T ].
3
R V I
12.  100 =  100   100
R V I
5 0.2
=  100   100
100 10
Total percentage error = 7%
 
13. S = 2 –   C 
C 2 

= C
2
14. Series of resonant frequency must be integral multiple of fundamental frequency. This series is
integral multiple of 75 H2. Hence missing frequency is 75 H2.
T
15. V V T

String with maximum tension will have maximum velocity.
V1 = 3 m/sec, V2 = 2m/s, V3 = 4m/s
1
V4 = m/s. Hence third string will have maximum tension.
2
dQ 
16.  KA
dt x
Rate of heat transfer, cross section area and thickness is same for all slab therefore
1
K

Slab which has minimum difference of temperature across interface will have maximum thermal
conductivity.
Hence (c) option is true.
19. The number of mother nuclei decaying in a short time interval dt is = Nmmdt. But death of a
mother nucleus implies the birth of a daughter nucleus.
The number of daughter nuclei decaying in the same time interval is = Ndddt.
The number of daughter nuclei will remain constant when Nmmdt = Ndddt
or Nmm = Ndd
21. Let fission rate be n per second; then

n × 200 × 106 × 1.6 × 10–19 = 5 × 1
5
 n  1.56  1011 / sec
3.2  10 11
2
22. I =  25 mA
80
24. The acceleration of particle at t  0 is 0.
25. After the upper spring is cut, the block 1 and 2 will move with same acceleration.
 a  2g
4
dV
26.  (Q  av)
dt
Adh
 (Q  av)
dt
h2 t
Adh
 Q K   dt
h1 h 0
2A   Q  K h2  
t K
K 2 
 h1  h2   Qln  Q  K 
h1  

2
1 1 V 1
27. KA 2  2m 0  KA '2 (by energy and momentum considerations)
2 2 4 2
2 1 2 2
KA  mV0  KA '  A '  2A
2
5
A '  2A   
4
x  A ' sin   ' t   
K
' 
2m
 K 
x   2A sin  t 
 2m 4 
 
28. 1  1085Å &  2  304Å

hc hc
E1   11.5eV E 2   40.8eV
1 2
KE of electron after collision
= 100 – 52.3 = 47.7 eV
29. Net force on the system is zero hence momentum is conserved so

mv 0  2mv
Both wires will have same velocity when steady state will be achieved.
1
K  mv 02
4
I 1 mgl
30. T = 2 f=
mgl 2 I
I is moment of inertia about axis passing from suspension point.
1
f , I about axis side to side in plane of loop is more hence f is greater in first case.
I
5
Chemistry PART – II
SECTION – A
1. O
O
Si
O O Si
O O O
O O
Si
O
8
Structure of silicate anion Si3 O10  
in mineral kinoite.
2. NO2 is a brown coloured gas:

 1
Ca NO3  2   CuO  2NO2   O2 
2

Hg  NO3 2   Hg  2NO2  O2 
 1
NaNO3   NaNO2   O2 
below 500o C 2
 1
AgNO3   Ag  NO2   O2 
2
3. Bond order of O2 is 2.5

Bond order of NO is 2.5
Bond order of N2 is 2.5
Bond order can be calculated using molecular orbital diagrams.
4.
N Net dipole moment
H H
H
Bond angle around central atom decrease down the group. Also electronegativity of N > P > As >
Sb and electronegativity of H > P > As > Sb. Electronegative of P is very close that of H.
P Net dipole moment
H H
H
Ca3P2 + 6H2O  3Ca(OH)2 + 2PH3
2F2 + 2H2O  4HF + O2
3F2 + 3H2O  6HF + O3
6
5. XeF6 may act as fluoride donor when it reacts with non metal fluorides.


XeF6  SbF3   
 SbF6  XeF5
XeF6  excess H2O  XeO3  6HF
XeF6  H2O  XeOF4  2HF
6. Co
 NH3 5 CO3  ClO3
   
x 0 2 1
x + 0  5 + (–2)  1 = + 1
x=+3
Co3
3d 4s 4p
in Co3
complex
d2 sp3
Coordination number = 6
No. of unpaired e– (n) = 0
   n n  2   0
Number of ‘d’ electron = 6
7. Hg + X2  HgX2 (where X = F, Cl, Br or I)

Mac-Aurthor’s process is used in extraction of gold and silver
4M  8NaCN  2H2O  O2  4Na M  CN2   4NaOH Where, M = Ag, Au.
8. H3C C N OH H3C C N O
Ni2  NH3  Ni
H3C C N OH H3C C N OH
Red precipitate
2 2
Hg  Co(SCN)2  aq   Hg  SCN 2  CO
Blue precipitate
3Mn  NO3 2  aq  5NaBiO3  aq   9HNO3  aq  3HMnO4  aq  3H2O     5Bi NO3 3
Purple 
10 0
9. Pd  4d 5s  10  electron
2 2 6 2 4
S  1s 2s 2p 3s 3p  10 p electrons
10. Longest wavelength of Li2+, Balmer series  n1 = 2, n2 = 3

1  1 1  1 1 1 
 RH  32  2  2    RHZ 2  2  2  
x 2 3     n1 n2  
7
1 9  4
 RH  9   ....(1)
x  36 
+
Shortest wavelength of He Paschen series 
n1 = 3, n2 = 
1 1 1 
 RH  22  2  2  .....(2)
  3  
From equation (1) and (2)
5
RH  9 
 36 5  9 45
  
x 1 4  4 16
RH  4 
9
45x

16
11.
3RT 8RT 2RT
Vrms  Vavg  Vm.p 
M M M
For N2 at 27°C For H2 at 27°C For CO at 27°C
3RT 8RT 2RT
Vrms  Vavg  Vmp 
28 2 28
3 4 1
Vrms : Vavg : Vmp  : :
28  14
= 0.33 : 1.128 : 0.267
Atomic wt. 109.75

12. Mass of each atom =  23
 1.82  1022
NA 6.022  10
In FCC number of atom/unit cell = 4
Mass of unit cell = 4  1.82  10–22 = 7.29  10–22 g
mass 7.29  10 22 g
9g / cm3  density  
volume a3
7.29  1022 g
a3   81 10 24 cm3
9g / cm3
a = 900 pm
13. 

A  OH 2  2
 A  2OH

0.0416g / L
104g/ mol
 A 2    4  10 4 g / mol
 
OH   10 pOH  103
 
2
Ksp =  A 2  OH 
2

= 4  104 103  = 4 × 10-10
3
Ksp = 4s for A(OH)2
8
Ksp 3 4  10 10
S3   2.16  10 3
4 4
14. 

3A 
 2B  2C  D
Initial Po 0 0 0
o
Equilibrium P  2x 2x 2x x
o
Equilibrium pressure = P – 2x + 2x + 2x + x
50 = Po + 3x ………..(1)
From question 5 = Po – 2x ………..(2)
From equation (1) and (2)
55 = 5x
x = 11
Kp 
PB2 .PC2 .PD

 22 2  22 2 11
PA3 53
= 20614.5
K p  K c  RT  n
Kp 20614.5
Kc  n
 2
RT   0.082  400 
= 19.16
15. Adiabatic reversible expansion

T1P11  T2P21
1
P 
T2  T1  1 
 P2 
For mono atomic gas  = 1.66
T2 = 172.88
T2 = –100.27°C
1
16. C6H10     8 O2  g  6CO2  g   5H2 O   
2
H = E + ng RT
H = E + (6 – 8.5) RT
H = E – 2.5 RT
2.303 a
17. t log o
k at
0.693 0.693
k 
t1/ 2 20
2.303 10
t  log 7
0.693 10
20
= 34.75 min
18. Adsorption of gas on solid is always exothermic.
9
Tb 0.104K
19. m   0.2 mol Kg1
Kb 0.52K Kg Mol

  MRT  M 
RT
7.38 atm


0.082 L atm mol1 K 1  300 K 
–1
= 0.3 mol L
Assuming volume of water does not change significantly on addition of glucose
In 1 L solution  0.3 mol glucose and 1 kg water
mass of solution
density 
volume of solution
=
 
0.3 mol  180g mol1  1000g
1000 mL
= 1.054 g mL
20. 8e–. satisfying (4n + 2)e– rule 

only 6e– are in one plane and in
cyclic conjugate. Therefore, aromatic.
6e– satisfying (4n+2)e– rule 

aromatic
N
Due to repulsion between internal
H hydrogen atom  non aromatic
H
10e– satisfies (4n + 2)e– rule 

aromatic
S S
O
Non aromatic because cyclic
delocalisation of e– is abscent.
21. Br
Br
Br2 /h

 Br
Br
Br
Five products
22. Br MgBr COOH
NBS Mg (i) CO
20   
THF
 
2

10 Allylic bromination
(ii) H3O
10
23. CH3 Aliphatic tertiary amine, nitrogen electron pair is not in conjugation.
N
2
Nitrogen is sp hybridised. Nitrogen electron pair is not in
N
conjugation.
Nitrogen electron lone pair is in conjugation with phenyl ring.

NH2
H Nitrogen e– lone pair is in conjugate with two C=O groups leading to

two equivalent resonative structures.
O N O
24. OH OH
Al O
2 3 (i) O
3 (i)  Na 
    
 (ii) Me S 2 O (ii) NH4Cl, H2O
25. NH2 NHCOCH3 NHCOCH3 NHCOCH3

NO 2
CH3 COCl Conc. H2 SO4 Conc. HNO3

Base
 
 

NH2 SO 3H SO 3H
NO 2
(i) H3 O
 
(ii) OH
26. LiAlH4 can reduce both aldehyde as well as ester group into. But use OH OH protects aldehyde
group and hence only ester group is reduced.
O O O O
O O
H OCH3 OH OH H OCH3 (i) LiAlH
H OH

  4
 
H  ii H3O
11
27. Hunsdieker reaction

R  COOAg  Br2  R  Br  CO2   AgBr 
Free radical mechanism is followed.
O
28. At pH = 3, condition is highly acidic so all NH2 group will get protonated. Protonation of C NH2
group is very difficult. So at pH = 3 structure will be
O NH3
H2N C CH CH COOH
NH 3
29. Cl Cl
H3C CH 2 CH2 CHCl 2 H 2C CH2 CH2 CH2
Cl Cl Cl
H3C CH CH2 CH H3C CH2 C CH3
(R & S)
Cl
CH3
CH3 Cl
H3C CH CHCl 2
H3C CH2 CH CH2
(R & S)
Cl CH3 Cl
CH3 CH3
H 2C CH CH 2
H3C C CH2 Cl
Cl
Indicate chiral carbon
30. Balanced chemical equation is



 2MnO  s   10CO2  g   6H2O     2KCl(aq)
2KMnO4  aq  5H2C2 O4 aq  2HCl  aq  
Kp depends only on partial pressure of gaseous species
10

 K p  PCO2 
12
Mathematics PART – III

SECTION – A
sin  x  sin x  x  sin x 1

1. lim  lim 
x 0 sin  x  tan x  x 0 x  tan x 2
2. f  
3  x exists for 3x  0
i.e. Domain of ‘f’ is 0,  
But, for x  0  0  3  x  3
3. Suppose |  | 1 , we have
| 3 | |  5   3   ||  |5  |  |3  |  |  1  1  1
 3  3 A contradietion
Thus |  | 1   lies either on or outside the unit circle
4. Here a  0, b  0, c  0, d  0
 a2  b2  c 2  ab  bc  ca
 3(a2  b2  c 2 )  (a  b  c)2  d2
a2  b2  c 2 1
 
d2 3
5. Clearly from Descarte’s rule of sign equation has 4 positive real roots lets say , , , and 
    a1;    a2 ;    a3 and   5
         ... 4
using AM  GM  .   .4 33  3 3    5
4 4
a1 a3
– .  5  a1a3  80
4 4
8. Curve is (y – 2)2 = 2x3 – 4 ..... (1)

dy 3x 2

dx y  2
 Equation of tangent at (x1, y1)
3x12
y  y1   x  x1 
y1  2
As it passes through (1, 2)
3x12
 2  y1  1  x1 
y1  2
2
or  y1  2   3x12  x1  1
or 2x13  4  3x13  3x12 [As (x1, y1) lies on the curve]
13
or x13  3x12  4  0
or (x1 + 1) (x1 – 2)2 = 0
 x1 = –1 or 2
But x1  = –1 (it is clear from equation (1))
 x1 = 2
 y1 = 2  2 3
Points of contact are (2, 2 + 2 3 ) and (2, 2 – 2 3 )
 Sum of x–coordinates of points of contact is 4
 Sum of y–coordinates of points of contact is 4
b b
9. If  f  x dx   f  x  dx
a a
 f(x) is either positive in (a, b)

or f(x) is negative in (a, b) and also b > a
Also g(x) = f(x)
When f(x) > 0  g (x) > 0  g(x) is increasing function
When f(x) < 0  g (x) < 0  g(x) is decreasing function
Also g(0) = 0
b b
 f  x  g  x  dx   g  x  g'  x  dx
a a
2 2
=
 g b     g  a   which will be positive for 0 < a < b
2
A
s1 x12 s1 x1
10.  or 
 a2  a
s2 x 2 s3 x 3
Similarly  and  s1 s3
 a  a P
s2
B C
x1 x2 x3
-1
11. Let f (x) = t  f(t) = x
f (b) b b
  
2x b  f 1(x) dx   2f(t).(b  t).f '(t)dt = b [(f(t)) ]a –
2 b
 t .2f(t) .f '(t) dt
f(a) a a
b 2 2
= a  f  x     f  a    dx

2n
1  z 0  1  z 0 2
1  z0 2
n 1
 
1  z0 2  1 
12.
1
1  z  . 1  z 
0
2 2
0
2n
=
1  z0

1  z0
 1  i   1  n  , if n > 1;
 22 
5
If n = 1, 1  z0  1  z02    4
1  i 
17. If one number is drawn from the set {1, 2, 3…….n} the probability  that it is divisible by 2 is given
n
2
by    
n
14
 P (the number is not divisible by 2) = 1 – 

2 2
Now, x – y = (x – y) (x + y)
2
 P2 = . + (1 – )(1 – ) = 1 – 2 + 2 
g
18. To exhaust all single digit numbers he must have written  i2  285 digits, to exhaust 10 he
i 1
must write 2  102 more digits i.e. 485 digits. So 500th digit will occur when he is writing 11
sin x 1
19. Taking 2 =t t2
2
1  t2  1 t2  3
a  a  min    a
t  t  2
20. If p1 and p2 are length of perpendiculars from foci to any tangent then p1p2  b2  16 and
p1  p2  8  p1  p2  4
Hence only two tangents are possible
21. Option (B) is correct because in this case a  0, b  0 (Let b  c )

x2 y 2
 cx 2  ay 2  ac   1
a c
dy x
22. (cos y  sin y)  (cos y  sin y)e  x  e e
dx
cos y  sin y  u
du x x
  e x u  ee  ue e  x
dx
t
 e e  t (Putting (t, 0))
t
 t.e e  1
23. Fro more than one triplet satisfying all three equations we have
1 1 1
a b c
1 1 1
0
b c a
1 1 1
c a b
 abc
 (x  y  z)  a satisfying the triplets
We get a  10, p  7   2  2  8  0
  2 and 4
 1 1
24.
k 

k 

If f(x) is continuous then lim f(t k )  f lim (tk )  f    1 (Where lim tk  )
 4 k  4
 1
Also as graph is smooth f     0
4
15
x 1
25. f x  x  2  f(x) can not take the value 1 and f(2).
x3
W2 W C z3
26.  1 e  i
W2 W1
W2 W
  2 e i  1  itan 
W1 W1
W1 90°
W1 W 2 
W2
W2
2

 W1 W2 ei  W1  i W1
2
W2 sin   
A z1 B z2
27. (13x  1)2  36

13x  1  6
7
x
13
5
x
13
5
 cos   
13
12
 sin   
13
120
 sin 2  
169
28. (1  x  x 2 )n  a0  a1x  a2 x2    a2n x2n ….. (1)

n
3 1
 a0  a2  a 4  
2
3n  1
a1  a3  a5  
2
Put x  i in equation (1) where i  1
If n  4m  1
 a1  a3  a5   1
a0  a2  a 4   0
3n  1
So, a1  a5  a9    S2
4
3n  3
a3  a7  a11    S4
4
Similarly if n  4m  3
3n  3 3n  1
Then, S 2  and S 4 
4 4
29. If n is even
 n  2  n n2
f(n)  2  1  2    
 2  2 4
n  1 (n  1)2 n  1 n2  1
If n is odd then f(n)  f(n  1)    
2 4 2 4
16
(n  m)2  (n  m)2
f(n  m)  f(n  m)  if both even
4
(n  m)2  1  (n  m)2  1
 it both odd = nm
4
   
30. Obviously A  C and B  D will be non-zero collinear vectors
       
 (A  C).(B  D)  0 and similarly (A  B), (C  D) will be non-zero collinear vectors
   
Hence (A  B)  (C  D)  0

CRT 4 Sol

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S. No. PHYSICS CHEMISTRY MATHEMATICS

1. Angular frequency of SHM is equal to angular velocity of particle  = V/R.

6. S = [ – 2] + [ – 2 (60 – )]

8. It only depends on temperature. In a mixture all gases has same temperature.

9. U  nCV T From graph

21. Let fission rate be n per second; then

24. The acceleration of particle at t  0 is 0.

28. 1  1085Å &  2  304Å

29. Net force on the system is zero hence momentum is conserved so

2. NO2 is a brown coloured gas:

3. Bond order of O2 is 2.5

N Net dipole moment

P Net dipole moment

3F2 + 3H2O  6HF + O3

XeF6  excess H2O  XeO3  6HF

XeF6  H2O  XeOF4  2HF

7. Hg + X2  HgX2 (where X = F, Cl, Br or I)

10. Longest wavelength of Li2+, Balmer series  n1 = 2, n2 = 3

Atomic wt. 109.75

15. Adiabatic reversible expansion

18. Adsorption of gas on solid is always exothermic.

20. 8e–. satisfying (4n + 2)e– rule 

6e– satisfying (4n+2)e– rule 

10e– satisfies (4n + 2)e– rule 

22. Br MgBr COOH

Nitrogen electron lone pair is in conjugation with phenyl ring.

H Nitrogen e– lone pair is in conjugate with two C=O groups leading to

25. NH2 NHCOCH3 NHCOCH3 NHCOCH3

27. Hunsdieker reaction

30. Balanced chemical equation is

Mathematics PART – III

sin  x  sin x  x  sin x 1

8. Curve is (y – 2)2 = 2x3 – 4 ..... (1)

 Equation of tangent at (x1, y1)

As it passes through (1, 2)

or 2x13  4  3x13  3x12 [As (x1, y1) lies on the curve]

 f(x) is either positive in (a, b)

 P (the number is not divisible by 2) = 1 – 

21. Option (B) is correct because in this case a  0, b  0 (Let b  c )

27. (13x  1)2  36

28. (1  x  x 2 )n  a0  a1x  a2 x2    a2n x2n ….. (1)

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