Sol 30 PDF

1
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ANSWERS, HINTS & SOLUTIONS

CRT –II
(Main)
ALL INDIA TEST SERIES
S. No. PHYSICS CHEMISTRY MATHEMATICS

1. C A D
2. B B B
3. B D C
4. D B A
5. C C C
6. B A D
7. A C B
8. B B A
9. D B A
10. D A B
11. B A C
12. C C B
13. C A A
14. B D B
15. B B C
16. C C B
17. A A A
18. C B C
19. B C B
20. B B C
21. D D D
22. C A D
23. A D B
24. D A D
25. D D C
26. B B B
27. A B B
28. D C A
29. D D B
30. B D D
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2
Physics PART – I
SECTION – A
1. Since the compartment (including passengers) is stationary, so the combined centre of mass of
compartment and passengers is fixed i.e. C2 is fixed. When the passengers move here and
there in the compartment then in an attempt to keep C2 fixed C1 has to move.
2. Since the balance has equal arms and it is a false

balance, so the pans must be having different weights.
Let w1 and w2 be the weights of left pan and right pan
respectively. Let w be the true weight of object. When
placed in left pan it weights x i.e. a total weight of w + w1
on left balances a total weight of w2 + x on the right pan.
 w + w1 = w + x ..............(1)
Similarly it weighs y when placed in right pan i.e.
y + w1 = w + w2 ..............(2)
From (1)
w1 – w2 = x – w ............................(3)
From (2)
w1 – w2 = w – y .............................(4)
x–w=w–y
xy
 w
2
h1 h
3. The center gravity of liquid in the first column is and that in the second column is 2 .
2 2
Let litial Potential Energy be Ui
h  h 
 Ui  (Ah1)g  1   (Ah2 )g  2 
2
   2 
1
 Ui = Ag(h12  h22 )
2
h1  h2
When the water column in the two equavalises then equivalent height is and the center of
2
h1  h2
gravity in both the columns is . If Uf be the final potential energy in both the columns then
4
  h  h2   h1  h2  
Uf  2  A  1   g
  2   4  
1
 Uf  Ag(h1  h2 )2
4
Since work done is equal to the decrease in potential energy,
So, w = Ui – Uf
2
h h 
 w  Ag  1 2 
 2 
3
5. From the concepts of projectile motion,

1
2r  gt 2
2
Since x = AB = (2v)t
4r
 t
g
r
 AB  4v
g
6. y = ax2
dy  dx  
  y  (2ax)x  2acx   x  c
dt  dt 
d2 y 
Further a   y  2acx  2ac 2
dt 2
7. (0)A  4v  (A  4)V
4v
 V
A4
Negative sign indicates the recoil speed.
8. Let the extension produced in the spring due to rotation be x.

Then, for the body to be in equilibrium
Fspring  Fcentrifugal
 kx  m(  x)2
m2
 x
k  m2
 
10. E  V
  U ˆ U ˆ U 
 E    ˆi j k 
 x y z 
U
 6  8y 2  8x
x
U
 16xy  8  6z
y
U
 6y
z
At (0, 0, 0)
U U U
6,  8 , 0
x y z

 | E |(0,0,0)  6iˆ  8 ˆj

 | E | 10NC1
 
 | F | q | E |

 | F | 20 N
4
11. Since P1V = n1RT 1

and P2V = n2RT2
After joining the vessels we have
P(2V) = (n1 + n2)RT
PV P V 
 P(2V)   1  2  RT
 RT1 RT2 
1  P1 P2 
 P   T
2  T1 T2 
0.693 1
12. 
X Y
 Y > X
 dN 
Since,      XN
 dt  X
 dN 
And      YN
 dt  Y
 dN   dN 
     
 dt  Y  dt  X
Decay rate of Y > Decay rate of X.
1
15. vd 
neA
16. Soft iron has highest susceptibility.
17. mT = constant

4
 T  T0
3
Since, P  T 4 (from Stefan’s Law)
256
 Pnew  P
81
tan 
18. tan 1 
cos 
tan  tan 
and tan 2  
cos(90   ) sin 
tan 
 cos   ..................(1)
tan 1
tan 
and sin   ..................(2)
tan 2
Dividing (2) by (1), we have
tan 1
tan   .
tan 2
19. A and C are statements of Lenz’s Law. B is the correct option.
20. Iv sin component of current gives no power consumption and hence is called wattless current.
5
21. v2 = 2(a2 – x2)

 v12  2 (a2  y12 ) ...................(1)
 v 22  2 (a2  y 22 ) ....................(2)
From (1) and (2), we get
y12  y22
T  2
v 22  v12
 v 
22. n  2 
 2 
 v  3n
n'  3   
 4  4
a
23. Resolving power of telescope =
1.22
where a is the diameter of objective lens and  is the wavelength of light used. On increasing a,
more light is collected by objective lens and so, the image formed is more bright. Thus,
resolving power of telescope increases.
D
24. 
d
So, angular with, 2θ is
2 2
2  
D d
6328  10 10

0.2  103
 θ = 3164 × 10–6 radian
180
   3164  106  degree

 θ = 0.18 degree
 2θ = 0.36 degree.
I
25. If I is the intensity of the incident unpolarised light, the intensity transmitted by the first is
. This
2
is the intensity of incident light on the second polaroid. Intensity transmitted by the second
I 2 3
polaroid is   cos θ, where θ is the angle between the axes. Here sinθ = , cos θ is therefore
2
  5
4
.
5
2
I I 4 8
cos2       I
2 2 5 25
8
is the required ratio.
25
26. 50 VSD = 49 MSD

49
1 VSD = MSD
50
 VC = 1 MSD – 1 VSD
49
 VC  1MSD  MSD
50
6
1
 VC  MSD
50
 1 MSD = 50 (VC) = 50 (0.001 cm)
 1 MSD = 0.05 cm = 0.5 mm
 1 MSD = 0.5 mm
27. IC = IE – IB = 4 mA – 40 μA = (4 – 0.04) = 3.96 mA

I 3.96
 C   0.99
IE 4
28. Electric energy density

1 2
u0  0Erms
2
E
Since, Erms  0
2
1
 u0  0E02
4
29. By the Law of conservation of energy

(U + K)surface = (U + K)∞
GMm 1 1
  m(3v1 )2  0  mv 2
R 2 2
GM 9v 2e 1 2
    v
R 2 2
2 2GM
Since, v e 
R
2 2
v 9v 1
  e  e  v2
2 2 2
 v 2  8v 2e
 v  2 2v e
30. Let h be the height of the water level at any instant. Then the rate of decrease of water level is
dh
 . Therefore
dt
dh
A  av  a 2gh
dt
dh a
   2gh
dt A
H2 1
dh  a 
  1/2
 2g   dt
H1 h A 0
H2 a 
 2 h1/ 2    2g  t
H1
A 
 a 
 2  H1  H2    2g  t
A 
A 2
 t H1  H2 
a g 
7
Chemistry PART – II
SECTION – A
1. Salicylic acid contains – OH group and – COOH group. Therefore FeCl3 and NaHCO3 tests are
used.
2. ZnO gives yellow colour on heating and white on cooling.
3. PbCl2  K 2CrO4  PbCrO4  2KCl

yellow ppt.

4. Dissociation of H2O(H2O    
 H  OH) is opposite to neutralization. Hence, enthalpy of
dissociation is equal to enthalpy of neutralization but has opposite sign.
5. For preparation of iodoform reagent which can supply I+ is require i.e. KOI or KOH/I2.
6. I– ion is more easily oxidized than Br– ion and hence violet colour due to I2 appears first.
7. AuCl3 is reduced by SnCl2 to form colloidal sol of gold.

There is no peptisation involved.
8. In accordance with Huckel rule, carbocation (III) is aromatic and hence most stable. Carbocation
(IV) is stabilized by resonance and hence more stable than carbocation (I and II). In carbocation
(II), +ve charge is present on a more electronegative sp-hybridized carbon while in carbocation
(I), it is present on a less electronegative sp2-hybridised carbon and hence carbocation (I) is more
stable than carbocation (II). Thus, the overall stability increases in the order : II < I < IV < III.
O
HIO4 COOH
9. CHO
OH
O
10. SeO2 oxidizes – CH2 – next to carbonyl group to another C group.
O O
SeO2
CH3 C CH3   CH3
 C CHO  Se  H2 O
x
11. 1 Mole of C60H122 = 60  12 g + 122  1 g = 842 g

= 6.022  1023 molecules
Weight of 1 molecule = (842/ 6.022  1023) gram.
12. 2C 6H5 COOH   (C6H5 COOH)2

Before asso. 1 mol
After asso. 1 – x x/2
Total = 1 – x + x/2 = 1 – x/2
x
1
2 x
i  1
1 2
8
Cl
Cl 2 Cl
13. 1 3 , resultant bond moment of C1 – Cl and C3 – Cl bonds adds up to the bond
moment of C2 – Cl. Hence, it has maximum value.
14. NO2+ has no unshared electron. It has only bond pairs in two directions. Hence, shape is linear
O N O with bond angle = 180º.
15. For reaction (i), K p  PCO2  8  10 2 (given)

2
PCO
For reaction (ii), K p   2 (given)
PCO
2
PCO
 2 or PCO  0.4
8  10 2
16. Boron is diagonally related to Si.
17. In , N is linked to two c-atoms and has one lone pair. Hence, electron geometry is
N
triangular planar and hybridization is Sp2.
k
18. E2   2
 328 kJ mol1
2
K = 1312 kJ mol–1
k
E4   2
4
1312
  82 kJ mol1
16
19. Among isoelectronic ions, size increases the –ve charge increases.
i.e. F– < O2– < N–3
20. Greater the boiling point, less is the vapour pressure. Hence, the correct order of vapour pressure
wil be
Water < acetone < ether
21. Conjugate base = conjugate acid – H+

= H 2 – H + = H –.
22. The redox changes are

Mn7   5e   Mn2
Fe2   Fe3   1e
152
Equivalent weight of FeSO4 =
1
Milli equivalent of KMnO4 = Meq. Of FeSO4
9
2
 0.05  5  V   1000
15 2 1
 V  52.63 ml
r r
23. C2  N2  rCN
2 2
X r r x
  N2  y  N2  y 
2 2 2 2
r 2Y  X
 N2 
2 2
 rN2  2y  x
7 2
24. Outer elect. Configuration of Co atom = 3d 4s
3+ 6
Outer elect. Configuration of Co ion = 3d
–
As F is a weak ligand, it cannot cause forcible pairing of electrons within the 3d level. Hence
3 2
sp d hybridization will result outer orbital complex.
25. n(g) = np – nr = 5 – 3 = 2
H = E + ng RT
E = H – ng RT
= 19–(2  2 × 10–3  300)
= 19 – 1.2 = 17.8 K cal.
26. Gº = – RT ln Kp = – (8.314 J k–1 mol–1) (900 K)

(2.303)log(0.05) = 22400 J mol–1.
27.
NaOH 
OH 
  
O
Br O CH3
Br
28. 75% of reaction is completed in two half-lives.
29. In the final solution, [H+] = (10–6 + 10–3)/ 2

 0.5005  10 3  5.005  104
pH   log[H ]   log(5.005  104 )
 4  0.6994  3.3
30. O O O
C H ONa
2 CH3 COC2H5 
2 5
 H3C C CH2 C OC2H5
A
(A) forms oxime due to keto group, shows tautomerism, also shows idoform test due to
O
CH3 C
group.
10
Mathematics PART – III
SECTION – A
1 1 3 1 1 1
1.  x2     x2  
2 2 2 2 2 2
 2 1  2 1
 x  2   0,1  x  2   1,0
   
 2 1   2 1 
x  2   1  x  2   1
   
1 1
1  x2   2 1  x 2   0
2 2
1 3 1 1
 x2    x2 
2 2 2 2
1 3 1
 | x | |x|
2 2 2
1 3 1

2 2 2
  3  1   3  1 3  1  1 
I  tan1 1dx  1 tan
1
1dx  1 cot
1
( 1)dx      
3
4  2  4 2 4  2 
 
2 2 2
   

4 2  2 3  2  6  
2 2
 32   2 2
 32 
2. m  2n  60  n  2m  60
1
For m = 1; 1  2n  60 and n  2  60   n  2  n  1, 2
2
For m = 2; 2  2n  60 and n  4  60  1  n  4  n = 1, 2, 3, 4
3
For m = 3; 3  2n  60 and n  6  60   n  6  n = 2, 3, 4, 5, 6
2
m=4 n = 2, 3, 4, 5, 6, 7, 8
m=5 n = 3, 4, …….. 10
m=6 n = 3, 4 ………12
Total order pair =
m 1 m 2 m 3 m 4 m 5 m 6 m 6 m 8 m 9 m 13 m 14 m 15 m 16
2
 4 
  57 
  8
 10
11  13
   14  .......  
20  22
 23
  23
 
22
  22
   21

 21  20

   20
   19
  19
   18
  18
   17
  17
   16
  16
 
6  12  18
 .............  42
   46  2(22  21  .......  16)
7 terms
7 7
  (6  42)  46  2   (22  16)
2 2  7  24  46  7  38  480
3. In the figure O is circumcentre and shaded region shows location of P

Distance of P from side BC is maximum if P is at A
11
mn
4. Let first term is a then x = a + (m – 1)d, y = a + (n – 1)d and s = [2a  (m  n  1)d]
2
(x + y) = 2a + (m + n – 2)d and (x – y) = (m – n)d
 xy   xy 
d=    (x + y) = 2a + (m + n – 1)d –  m  n 
 m  n   
m  n xy
S=   (x  y)  m  n 
 2  
1 1 
5. sin 1    x   check f(1–) = sin–11+, f(1) = sin–11, f(1+) = sin–11–
2  x 
Hence function is discontinuous so non differentiable
5.5n  3n  4n
6. lim  0 , divide numerator and denominator by highest power i.e. (9n)
n  5n  2n  27  9n
7. P(x1 + t (x2 – x1), y1 + t(y2 – y1)

t x  (1  t)x1 t y  (1  t)y1
x 2  y 2
t  1 t t  1 t
For internal division
t > 0 and (1 – t) > 0  0 < t < 1
8. x1 x/r y1 y/r
x2 x y2 y
x3 xr y3 yr
Slope of line joining (x1, y1) and (x2, y2)
yy / r y r  y r(y  y / r)
m  Slope of line joining (x2, y2) and (x3, y3)  m  
xx / r x r  x r(x  x / r)
Slope is same hence (x1, y1), (x2, y2) and (x3, y3) are in straight line
9. cos A + 2 cos B + cos C = 2

cos A + cos C = 2(1 – cos B)
AC A C B
2cos .cos  2  2sin2
2 2 2
B A C 2B A C B A C A C B
sin cos  2sin , cos     2sin , cos cos  sin sin  2sin
2 2 2  2 2  2 2 2 2 2 2
s(s  a) s(s  c) (s  b)(s  c) (s  a)(s  b) (s  a)(s  c)
 2
bc ab bc ab ac
a + c = 2b i.e. a, b, c, in AP
1 1
x2  t 2  x2 4 
10 f(x) = 
2t
dt =   2  t  t  2  2  t  dt
0 0
1
 t2  1
=  (x2  4) n| 2  t |   2t  = (x2 + 4) n2 – – 2
 2 0 2
5
i.e. y = x2 n2 + 4 n2 – which is a parabola
2
2
11. Since (4, –4) and (9, 6) lie on y = 4a(x – b)
 4 = a(4 – b) and 9 = a(9 – b)
12
 a = 1 and b = 0
 The parabola is y2 = 4x
Let the point R be (t2, 2t)
4 4 1 4 4 1
1 1 1 5 10
 Area of PRQ = 9 6 1 = 5 10 0 = 2
2 2 2 2 2 t  4 2t  4
t 2t 1 t  4 2t  4 0
2
1 1 5  1 125
= (10t + 20 – 10t2 + 40) = – 5t2 + 5t + 30 = –5(t2 – t + ) + 30 + = –5  t   +
2 4 4  2 4
1
Area in largest when t =
2
1
 Coordinates of the point R are ( , 1)
4
 3 x 0
 2
12. f(x) =  a  x 0  x 1
mx  b 1  x  2

For Lagrange’s mean value theorem f(x) must be continuous in [0, 2] and differentiable in (0, 2)
Hence, a = 3, m + b = 2
 2x 0  x  1
f(x) = 
 m 1 x  2
 m = – 2 and hence b = 4
13. It is rectangular hyperbola  e  2
14. Normal to ellipse is ax sec   by cos ec  a2  b2
 x 2  2x  1   (x  1)2 
15. f(x) = cos   = cos  
 5   5 
1 (x  1)2 9
Since 0  x  2,  
5 5 5
2
(x  1) (x  1)2 
cos = 0 only when =
5 5 2
5
f(x) > 0 if 0 < x < 1
2
5
f(x) < 0 if  1< x < 2
2
5
 x=  1 is a point of local maximum
2
13
x5 dx
16. I
1  x3
1 + x = t2
3
3x2 dx = 2t dt
2 (t 2  1)t dt 2 2 2 1 
I    (t  1)dt   t 3   t   c
3 t 3 3 3 
2 2 2 2 2
  t 3  3t   c  t 3  t  c  (1  x 3 )3/2  (1  x 3 )1/2  c
9 9 3 9 3
n n
1
17.  (r  1)(r  ) (r  2 )   (r 3  1)  4 n2 (n  1)2  n
r 1 r 1
18. zz   z  z    0
zz  2z  2z  5  0
z0  2 r  45
r=3
| z  2 | 3
19. 7 {7(x2  13)  6}  {14  2(x2  13}  (x 2  13) {6  (x 2  13)2 }  0

   2  0
20. f(f(x)) = k(x5 + x) (k  0)

f(f(x)) . f(x) = k(5x4 + 1)  Can be + or –
But it may not be –ve. Because if f(x)  ing then f(f(x)).f(x) > 0
and If f(x)  ing then f(f(x)).f(x) > 0 i.e. f(x) is either  ing or  ing (also k > 0)

21. Let c makes an angle  from â  bˆ then cos2  + cos2  + cos2  = 1
2 cos2  = 1– cos2  b̂
0  1  cos2  1
1 1 1
0  2cos2   1  0  cos2     cos  â
2 2 2
  3  â × b̂
  , 
4 4 
22. A = (2, –1, 1), B = (1, 2, 3), C = (3, 1, 2)


OA  2iˆ  ˆj  kˆ

OC  3iˆ  ˆj  2kˆ
ˆi ˆj kˆ
 
OA  OC  2 1 1  3iˆ  ˆj  5kˆ
3 1 2
 Equation of plane OAC: 3x + y – 5z = d
Put (0, 0, 0), d = 0
 Plane is 3x + y –5z = 0
| 3  1 2  5  3 | 10 5
Shortest distance =  2
9  1  25 35 7
14
23. Initially there is one plane

When C1 is introduced: 1 part is increased
1(210  1)
 Total number of parts = 1 + 1 + 2 + 4 + 8 + 16 + .....  1  = 1024
2 1
24. for x  2, LHS is always non negative and RHS is always –ve
Hence, for x  2 no solution
If 1  x < 2 (x – 2) = (x – 1) – 1 = x – 2 which is an identity
For 0  x < 1, LHS is '0' and RHS is (–)ve  no solution
x < 0, LHS is (+)ve, RHS is (–)ve no solution
25. 
Consider F(x) = cot cos1(| sin x |  | cos x |)  sin1(  | cos x |  | sin x |) 
But |sin x | + |cos x|  [1, 2 ]
 
 F(x) = cot(cos–1(1) + sin–1 (–1)) = cot  0   = 0 = g(3) (As F(x) = 0,  x  DF)
 2
26. Consider a fixed face diagonal. It is parallel to corresponding one on the opposite face. It
intersects the other diagonal of the same face and one diagonal on each of the four neighbouring
faces. The other five face diagonals form five pairs of skew lines with the fixed one. By symmetry,
each of the twelve faces diagonals. The total count of pair of skew lines is 12  5 = 60 but this
must be halved since each pair is counted twice.
27. Clearly N = 
Now M consists of the curve xy = 1 and xy = –1 in the first and fourth quadrant
Hence, N  M
1 x 1 x
28. y , F y  x 
1 x 1 x
3x
F  2  x       2  F  x 
 1 x 
 1
F(F(x)) = –x, F    F  x 
x
29. p  (p  q) and q  (p  q) both are tautologies, while formulae

~ p  (p  q) and ~ p  ~ q are not
30. x  48 , n = 200 standard deviation = 3

2
Variance =  x 2    x 
n  n 
 
9
 x 2   48 2
200
2
x  46200

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ANSWERS, HINTS & SOLUTIONS

S. No. PHYSICS CHEMISTRY MATHEMATICS

2. Since the balance has equal arms and it is a false

5. From the concepts of projectile motion,

8. Let the extension produced in the spring due to rotation be x.

11. Since P1V = n1RT 1

16. Soft iron has highest susceptibility.

17. mT = constant

21. v2 = 2(a2 – x2)

26. 50 VSD = 49 MSD

27. IC = IE – IB = 4 mA – 40 μA = (4 – 0.04) = 3.96 mA

28. Electric energy density

29. By the Law of conservation of energy

2. ZnO gives yellow colour on heating and white on cooling.

3. PbCl2  K 2CrO4  PbCrO4  2KCl

7. AuCl3 is reduced by SnCl2 to form colloidal sol of gold.

11. 1 Mole of C60H122 = 60  12 g + 122  1 g = 842 g

12. 2C 6H5 COOH   (C6H5 COOH)2

moment of C2 – Cl. Hence, it has maximum value.

15. For reaction (i), K p  PCO2  8  10 2 (given)

16. Boron is diagonally related to Si.

21. Conjugate base = conjugate acid – H+

22. The redox changes are

26. Gº = – RT ln Kp = – (8.314 J k–1 mol–1) (900 K)

28. 75% of reaction is completed in two half-lives.

29. In the final solution, [H+] = (10–6 + 10–3)/ 2

Mathematics PART – III

3. In the figure O is circumcentre and shaded region shows location of P

7. P(x1 + t (x2 – x1), y1 + t(y2 – y1)

9. cos A + 2 cos B + cos C = 2

13. It is rectangular hyperbola  e  2

14. Normal to ellipse is ax sec   by cos ec  a2  b2

19. 7 {7(x2  13)  6}  {14  2(x2  13}  (x 2  13) {6  (x 2  13)2 }  0

20. f(f(x)) = k(x5 + x) (k  0)

22. A = (2, –1, 1), B = (1, 2, 3), C = (3, 1, 2)

23. Initially there is one plane

29. p  (p  q) and q  (p  q) both are tautologies, while formulae

30. x  48 , n = 200 standard deviation = 3

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