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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

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ANSWERS, HINTS & SOLUTIONS

CONCEPT RECAPITULATION TEST – II


(Paper-1)

Q. No. PHYSICS CHEMISTRY MATHEMATICS


ALL INDIA TEST SERIES
Program & 4423 Students from All Programs have qualified in JEE Advanced, 2016

1. AC ABC ACD
2. ACD ABC ABC
3. BD B AB
4. ABC ABC ACD
5. AC ABCD A
6. ABCD AB AB
7. ACD AC ABCD
8. ABCD AB ABC
9. AC AC AD
10. AC AB AB
(A)  r,s (A)  p,q (A)  s
(B)  r,s (B)  q,r (B)  r
1.
(C)  r,s (C)  r,s (C)  q
(D)  r,t (D)  p,s (D)  p
(A)  p (A)  p,q,r (A)  p
(B)  q (B)  r (B)  p,q
2.
(C)  s (C)  q,s (C)  p
(D)  r (D)  q,r (D)  r,s
1. 1 6 5
2. 3 4 3
3. 1 6 2
4. 6 4 6
5. 1 3 2
6. 2 5 3
7. 5 7 4
8. 5 1 6

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

Physics PART – I

SECTION – A
1. AC
Sol. Mass per unit length of the wire = 0.1 kg/m.
At any instant, tension in the string is (2 + 2.25 t) g N
10 t
(2  2.25 t)g
v ; 0 dx  10 0 2  2.25 t dt
0.1
t = 0.612 s
T   2  2.25  0.612   10  33.77 N

2. ACD
  dB ×
Sol.  E  d l  A dt × R ×
× × ×
E2 x 2  d2  R 2k O ×
× × ×
R 2 k
E d
2 x 2  d2
 

qR2 P
Wext   qE  dx  k
0 4 E

3. BD
Sol. Length  Gx cy hz
x y Z
L  M1L3 T 2  LT 1  ML2 T 1 
By comparing the power of M, L and T in both sides we get
 x  z  0,3x  y  2z  1 and  2x  y  z  0
By solving above three equations we get
1 3 1
x  , y   ,z 
2 2 2
4. ABC
Sol. Assume x-axis along OA and y-axis perpendicular to it in the plane of ring.
After 1st collision
v
Velocity of particle = along x-axis
2
v
And velocity of ring = along y-axis
2
v ˆ v ˆ
After second collision velocity of ring = i j
2 2
Velocity of particle = 0
R 2
Time to return at point A = 4 
v

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

5. AC
 (10,5)
Sol. v AB   3  a  ˆi   3  b  ˆj
  vAB B
a AB  o
 3  a   2  10 and  3  b   2  5 A
1 (0,0)
a = –2 and b =
2

6. ABCD
Sol. Equilibrium of piston gives
kx0
PS  kx0 or P PS kx0
S
Since, the chamber is thermally insulated Q = 0
 Elastic potential energy of spring = work done by gas
1 2
or, work done by gas = kx0
2
This work is done in the expense of internal energy of the gas.
1 2
Therefore, internal energy of the gas is decreased by kx0 .
2
Internal energy of an ideal gas depends on its temperature only. Internal energy of the
gas is decreasing. Therefore, temperature of the gas will decrease.

7. ACD
  
Sol.  
Fm  q v  B and apply Newton’s second law of motion.

8. ABCD
mv 2
Sol. T  mgcos 600  … (i) 600
l u
2
1  5  l 1 l
m gl   mg  mv 2 … (ii)
2  2  2 2
3 5
v gl and T  2mg gl
2 2
Net force is in horizontal direction when  = 600

9. AC
11R
Sol. Equivalent resistance across capacitor (after shorting the battery) = .
4
3E
Voltage across capacitor in steady state = .
4
4t
CE  
q  1  e 11RC 
4  

10. AC

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

L 2 1
Sol.   
Re q 8 4
at steady state inductor short circuited
Hence i = 0.75

SECTION – B

1. A  rs B  rs C  rs D  rt
Sol. For cases (a), (b) and (c), magnetic field due to I1 and I2 are mutually perpendicular.
Therefore, they do not exert any force on each other.
For case (d), magnetic fields at point P due to I1 and I2 are in the same direction.

2. Ap Bq Cs Dr


E E E i1-i3 E
Sol. On solving by KVL we get, i1  , i2   , i3 
R R R
2E i3
 i1  i2  and i1  i3  0 b R1
R
So reading of ammeter A1 is E/R = 4/3 i1 E i1-i2 E i1
a R3
A2 is 2E/R = 8/3, A3 is zero and Vab = 4V i2
R2

SECTION – C

1. 1
Sol. The light escape is confined within a cone of apex angle b
' 2c ' where c is the critical angle. Imagine a sphere with a c
source of light as its centre and the surface area abc is A.
c
c c  c c
here A   2R2 sin  d  2R 2 (1  cos c ) R
0
P
  3 
 R2 1
c  sin    60º 
  2  
A 1
 Power transfer  P  2
 4   1W
4R 4

2. 3
1 1 1
Sol. Applying lens formula,  
v u f
1 dv 1 du
  0
v 2 dt u2 dt
dv
 v0
dt

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

dv
 v1  v 0 (v1 = velocity of object towards lens)
dt
1  1  n2 
 v1  v 0  v0 , v1   2  v 0 , v1  3v 0 = 3 m/s
n2  n 

3. 1
2q1L 2q2 x 2q3 (2L  x) I
Sol.   0 … (i)
2A  0 2A 0 2A 0 +q1 +q2 –q3 +q
+Q 3 +Q
dq dq3 dq2 –q1 –q2
I 1   … (ii)
dt dt dt v
From (i),
q1L  q2 x  2q3L  q3 x  0 L x 2L–x
dq1 dq dx dq dq dx
 L  x 2  q2  2 3 L  x 3  q3 0
dt dt dt dt dt dt
v
 I (q2  q3 ) = 1 mA
3L

4. 6
 Lsin

dL L
Sol.  L cos 
dt 
L cos
m 2
=  sin  cos  
3
m 2 2
=  sin  cos 
3

5. 1
Sol. 1
I 2
Q 7 1
3
II 4 I 2
8 IV
5
III 6 6
7 III
IV 8 P 5 Q
P 9 9
V 10 3
V 10
4 II

0 A
Equivalent capacity, CPQ = C =
d

6. 2
Sol. Let at any time t charge flown through the plate B to plate A is q and instantaneous
current is I.

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

–Q0+q –q

A B
I

R 
 2q  Q0 
From loop theorem    IR    0
 2C 
dq  2q  2C  Q0
 R 
dt 2C
dq dt
 
2C  Q0  2q 2 RC
Now for charge on plate A to be zero q = Q0.
Q0 t
dq dt
Integrating  
0
2C  Q0  2q 0 2 RC
 2C  Q0 
= t  RC ln  
 2C  Q0 
Putting the value of C, Q0,  and R
We get t = 2 seconds.

7. 5
1 1 1 m(2r)2 2 1 2 2
Sol. K.E. = mv 2  mv 2  w  mr w = 5.
2 2 2 12 2

8. 5
Sol. At stable equilibrium, U is minimum.
dU d2U
= 0 and >0
dx dx 2
1  x 3 ax 2 
=    20x  = 0.
dx  3 2 

2
 x – 9x + 20 = 0.  (x – 5) (x – 4) = 0.
x = 5 and x = 4 are points of equilibrium.
d2U
And U minimum when > 0. i.e. at x = 5.
dx 2

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

Chemistry PART – II

SECTION – A

1. ABC
H2O
Sol. KO   O2 gas
H2O
CaC2   C2H2 gas
H2O
Mg3N2   NH3 gas
H2O 2
Ba NO3 2   Ba  2NO3

2. ABC
Sol. Neither the lone pair of oxygen nor the pi – bonds are in conjugation in (D).

3. B
Sol. COCl2  H2O 
 CO2  2HCl

4. ABC
Sol. Silicones are the polymers of the hydrolysis products of alkyl silicon chlorides.

5. ABCD
Sol. The boiling point of water is 100oC.
 Dissolution of any non-volatile solute of any quantity in water will cause elevation in
boiling point. So, the boiling point of aqueous solution of any non-volatile solute is
greater than 100oC.

6. AB
Sol. In C the net charge on cationic as well as anionic parts of the complex is zero. Such
complexes are not formed. D is not an isomer of the complex due to different molecular
formula and molecular mass.
7. AC

Sol. (A) 4LiNO3  2Li2 O  4NO2  O2

2NaNO3  2NaNO2  O2

(B) MgCl2 .6H2O  MgCl2 .H2O  5H2O

Na2SO4 .10H2O  Na2SO4  10H2O

(C) 2FeSO4  Fe 2 O3  SO2  SO3

Fe2  SO 4 3  Fe 2O 3  3 SO3
8. AB
Sol. All aliphatic aldehydes respond to Fehling test. Benzaldehyde does not give Fehling’s
test.
9. AC
Sol. The coordination number in both the structure is 12 and the packing fraction is 74%

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

10. AB
Sol.  The dipole moment of NH3 is greater than NF3 because the bond pair dipole moment is
enhanced by the lone pair dipole moment in NH3. In NF3 the resultant of bond pair dipole
moment is opposed by the lone pair dipole moment.
 CHCl3 is unsymmetrical, hence it contains certain dipole moment whereas CCl4 is
symmetrical with zero dipole moment.

SECTION – B

1. A  pq, B  qr, C  rs, D  ps


4KCN
Sol. (A) Fe2  2KCN 
 Fe  CN2  Fe  CN 6 

excess
K4

Fe(OH)2 is not soluble in excess NaOH and excess NH4OH


(B) HgO is not soluble in excess NaOH and excess NH4OH
2KI
Hg2   2KI  HgI2  HgI4 
 K 2
2KI
 PbI2   K 2 PbI4 
(C) Pb2   2KI 
Pb2  H2S 
 PbS  2H
3PbS  8HNO3  3Pb NO3 2  2NO  3S  4H2O
KCN
(D) Ag  KCN 
 AgCN    K  Ag  CN 
 2

Ag  H2S 
 Ag2S  2H
3 Ag2S  8 HNO3  6 AgNO3  2NO  3 S  4H2O

2. A  pqr, B  r, C  qs, D  qr
HCOONa 0.1
Sol. (A) pH  pKa  log  3.74  log  3.74
HCOOH 0.2
 pH < 7
(B) pH = -log [H+] = -log10-1 = 1,  pH < 7
CH3COOH cannot dissociated in presence of HCl due to common ion effect.
(C) CH3COOH  NH4OH  CH3COONH4  H2O
Hydrolysis of CH3COONH4 will take place
1 1
 
pH  pK w  pKa  pKb  14  4.74  14  9.26  
2 2
= ½ [14 + 4.74 – 4.74] = 7.  pH = 7 and the solution is a buffer
(D) HCOONa  HCl  HCOOH  NaCl
Initial meq 30 10 0 0
Meq. After reacn 20 0 10 10
HCOONa 20
It is a buffer, pH  pKa  log  3.74  log  4.04,  7
HCOOH 10

SECTION – C
1. 6
Sol. H = nCvT
4.48
or, 12   CV  15
22.4

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

or, Cv = 4
CP – CV = R = 2  CP = CV + 2 = 4 + 2 = 6 cal

2. 4
Sol. The products are CH3CH2CH2NO2, CH3CHCH3, CH3CH2NO2 and CH3NO2 because C–C

NO2
and C – H bond cleavage takes place in this reaction.

3. 6
Sol. For zero order reaction the half-life is directly proportional to the concentration of
reactant.
t 1/ 2  4sec X t 1/ 2  2sec X
X  
2 4
 Total time needed for 75% reaction = 4 + 2 = 6 sec

4. 4
Sol. CHO
CH = NNHC6H5
CH = NNHC6H5
CHOH
CHOH
C6H5NHNH2 C6H5NHNH2
C =O
   
(CHOH)3 H2O  C6H5NH2 , NH3
(CHOH)3
(CHOH)3
CH2OH
CH2OH
CH2OH

CH = NNHC6H5

C = NNHC6H5 C6H5NHNH2
 

(CHOH)3

CH2OH

5. 3
Sol. 
2X  g  
 2Y  g   Z  g 
Initial 1 0 0
At equi 1-  /2
 Partial pressure [If total pressure P]
 1   
px    P  P py  P  P
 1  /2  1  /2
  /2  P
pz   P 
 1  /2  2
2  P 
p y  p z   P   2 
2

 Kp  2

px  P2

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

3 P
Kp 
2
1
 2K p  3
  
 P 

6. 5
Sol. Work done in anticlockwise cycle is positive and in clockwise cycle is negative.
moles of A are present. Total number of moles of A,B and C at the end of 75% reaction
are X. What will be the value of 2X

7. 7
Sol. One mole of A will form 2 moles of B and C after completion of reaction when 75% of A
converted into B and C then total No of moles X = 0.5 + (2  0.5 + 12 ) = 3.5
Hence 2X = 3.52 = 7

8. 1
Sol. Sb2S3  s  3H2  g  2Sb  s  3H2S  g 
 0.01 x   0.013x  2x 3x

1.19
No.of moles of PbS formed =  0.005
239
 0.005 
At eqn. H    
 250 
3
 0.005 
KC    1
 0.005 

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

Mathematics PART – III

SECTION – A

1. ACD
      
Sol. 
On expanding we get a. c a  a. a    c    b
    

 c  a. c a  b
 (a) is correct and (b) is ruled out.
   2 2

 c  a. c a  b
 
If  is the angle between a and c then
2 2
4   2cos    2  2cos    1
3
 cos       30o ; 150o
2
 (C) and (D) is correct.

2. ABC
3 1
Sol. 8 sin x  
cos x sin x
 8 sin2 x cos x  3 sin x  cos x
4 1  cos 2x  cos x  3 sin x  cos x
3 cos x  2  cos 3x  cos x   3 sin x
cos x  2 cos 3x  3 sin x
1 3
cos x  sin x  cos 3x
2 2
 
cos  x    cos3x
 3
 
3x  2nx   x  
 3
(+) (–)
 
3x  2x  x  3x  2n  x 
3 3
 
2x  2n  4x  2n 
3 3
 n 
x  nx  x 
6 2 12
0,2
   6   5 
  
6 2 12 12 12

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

5  11
 
6 12 12
3  18   17
  
2 12 12 12
 23
2  
12 12

3. AB
Sol. det  A  B    det  A  det B  det  A  B 
   
  det A T det B T det  A  B 
  det  A  A  B  B 
T T

  det  A  A  B  B 
T T

  det  A AB  A BB 
T T T T

  det B  A  T T

T
  det  A  B 
  det  A  B   det  A  B   0

4. ACD
g 0  h  g 0 
Sol. g'  0   Lim 0
h h
 g  x  is differentiable  x  R
        
2x sin     sin    2  x  1 sin     sin  ; x  1
g'  x    x x  x  1  x  1
 0 ; x  0,1

But Lim g'  x   does not exist  g '  0   g'  x  is discontinuous at x = 0
x 0

Similarly Lim g'  x   does not exist.


x 1

5. A
t
 sin t 2 dt 2 sin t 2 2 2 2
0
Sol. Lim  Lim  Lim  
t 0 1
t sin t 2
t 0 sin t 2  2t 2 cos t 2 t0 t 2
1 2 3
1 2
2 tan t 2
6. AB
Sol. The point of intersection of diagonal is (0, 0) and
one vertex A (2, 1) 2 (2, 1) m  1
 Vertex is (–2, –1) verties B and D are i  2  i  2

 1  2i, 1  2i 3

 B  1,2  and D 1,  2 


 Equation of the sides are 1
x  3y  5, 3x  y  5 .

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7. ABCD
Sol. The three planes intersect in a line.

8. ABC
10
Sol.  2x  3y  z 
  
10!  2x   3y   z 
General term  
 ! !  !
10
………..(1)

12! 12  11
 Number of terms    66
10!2! 2
Put x  y  z  1 in (1), we get
Sum of all the coefficients 0.
Put   2,   3,   5 in (1),
10! 2 3 10! 9
We get coefficient of x 2 y 3 z5   2   3  
2!.3!.5! 5!

9. AD
100
100 k 100 100
Sol. Clearly,  100
Ck  x  2  3k    x  2   3   1  x 
k 0

Hence, coefficient of x 50 is 100


C50 . Now verify
100
Option (A), (D) equal to C50
(B) 99!  100
C50 
100
(C) C101

10. AB
Sol. log3 2z  1  log3 2z  1 (as cot 1 x is a decreasing function)
 2z  1  2z  1

 
Or  2z  1 2z  1   2z  1 2z  1  
 
2 z  z  2 z  z  
zz0
2Re  z   0
 Re  z   0

SECTION – B

1. A s B r C q D p
Sol. (A) cos  2A     cos  2B   
 2 cos  A  B  cos  A  B   
Maximum value is 2cos  A  B  when cos  A  B     1
(B) cos 2A  cos 2B  2 cos  A  B  cos  A  B 

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

Maximum value is 2 cos  A  B  when cos  A  B   1


 
(C) For y  sec x, x   0,  , tangent drawn to it any point lies completely below the
 2
sec 2A  sec 2B
graph of y  sec x, thus  sec  A  B 
2
 sec 2A  sec 2B  2 sec  A  B 
Hence, minimum value is A  B
(D) tan   cot   2 cos 2  A  B 
2
  tan   cot    2  2 cos 2  A  B 
2
  tan   cot    4 sin2  A  B 

Minimum value occurs when tan   cot  and minimum value is


4 sin2  A  B   2 sin  A  B 

2. Ap B pq C p D rs


Sol. (A) Equation of the plane  is A  x  1  B  y  1  C  z  1  0 where
A  0. B  1.C  0 and  A  B  0.C  0  A  B  C and the equation of  is
x  y  z  3 . which meets the co – ordinates axes at A (3, 0, 0), B (0, 3, 0) and C
0 0 0 1
13 0 0 1 1 9
(0, 0, 3). So volume of the tetrhadron. OABC    27 
60 3 0 1 6 2
0 0 3 1
(B) AB  BC  CA  3 2 , so the area of the face ABC which is an equilateral triangle
3 2 9 3

4

 3 2 
2
. Each of the face OAB, OBC, OCA is an isosceles triangle

with sides 3,3,3 2


1 9 9
So, area of each of these faces is 3 2 9  
2 2 2
3 3
3 3 33
9
(C) Required distance is 2 
1 1 1 2

0003
(D) Distance of O from the face ABC   3 distance of A, B, C from
1 1 1
opposite faces OBC, OAC, OAB are equal and is 3.

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

SECTION – C
1. 5
Sol. Note that z  0 is one root of the given equation u (1+i)
lm (z)
z4  az3  12  9i  z2  bz  0
canceling z, we get z3  az2  12  9i  z  b  0 iu
…………(1)
The 3 vertices of the square other than  0  0i  are u,
iu, u (1 + i)
Now u ui    iu   1  i u  1  i  u  u  12  9i (using O
Re (x)
theory of equation)
4  3i
u2   3  4i  u  3  4i    2  i 
i
 u  2  i or 2  i
2
 u 5

2. 3
1
2x  3x 2  4x 3
Sol.  dx
2 x4  x3  x2
0

 
Put x 2  x 3  x 4  t   2x  3x 2

 4x3 dx  dt
3
dt

0 2 t
3
   t   3  2  3
0

3. 2
1 A
Sol. Area  ab
2
AD : y  x  3
BE  y  2x  4 m1= 1
F
solve G  1, 2  (–1, 2) 3
G 
acute angle  between the medians is m2= 2 
m  m2  
tan   1 o
1  m1m2 90

2 1 1 B C
tan    tan   a/2 D a/2
1 2 3
now, 180     90o      360o
       90o
cot    tan     
2b 2a

tan   tan 
3  or 3  a b
1  tan  tan  2b 2a
1 .
a b

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

 9

2 a 2  b2 
ab
9ab  2  3600
1
 ab  400
2
 Area = 400 sq. units

4. 6
dy
Sol.  k y
dt
dy
 k dt
y
2 y  kt  c
t  0; y  4
4c
2 y  kt  4
y0
kt  4
4
t  60 minutes
1
15

5. 2
 n1 n 1 
n   n   
2n  2  2n  2 2 2  (divide by 2)
Sol. Sum   tan1     tan1 
n 1  2  n2  1  n1  n 1 n 1
1  2
,
2 

n 
n 1 n 1  n 1 n 1 1
   tan1  tan1 1
  tan    tan
1
 tan1

n 1  2 2  2  2 2

 1   1  1  
Lim sum    tan1 
n     cot 
 2 2  2 2
   tan
1
2 
 k  2  k2  2 .

6. 3
x x y y y z z z z
       
2 2 3 3 3 4 4 4 4  9
Sol.
9 2 2 3 3 3 4 4 4 4
       
x x y y y z z z z

7. 4
1 1 3
Sol.  ab sin C  3  2 b sin C   sin C
2 2 b

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AITS-CRT-II-(Paper-1)-PCM (Sol)-JEE(Advanced)/17

2 cos C  3 sin C  b  c ………(1)


a2  b2  c 2 4  b 2  c 2
cos C  
2ab 4b
2 2  3
4b c 
 2   2 3    b  c
 4b   b 
4  b2  c 2 6
   b  c  4  b 2  c 2  12  2b2  2bc
2b b
2 2
 b  c  2bc  16   b  c   4

8. 6
A
Sol. Given, x 2  4x  1  0  x
y=x
4  16  4 4  2 3
  2 3 m1  2  3
2 2
 From the figure, I (a, b) lies on line y  x, 45o 1 (a, b)

So b = a r=1
o o
m2  2  3
Also, from 75 30 D
(0, 0)
r 15o 45o
IBD,  sin30o  BI  2  As, r  1 given   B
BI
BI  2  a2  a 2  4  2a2  a  2
So, I   
2, 2   a, b  (Given)
2 4

Hence, a2  b 4    2   2 246

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