· ALLE '"

- ...... C ARCE:n IN S TITUT

CJ•h 115' Si·Eii=t THERMODYNAMICS & CHEMICAL EQUILIBRIUM
9. The internal energy change when a system goes
THERMODYNAMICS & from state A to Bis 40 kJ/mole . If the system goes
CHEM ICAL EQUILIBRIUM from A to B by a reversible path and returns to
1. state A by an irreversible path what would be the
Wiic ,1 two ideal liquid,s are mixed, the enthalpy of
th L· \: 'stem net change in internal energy
( I I I )ccreases (1) < 40kJ (2)Zero (3) 40kJ (4) > 40kJ
(2) Increase 3 3
10. An ideal gas expands in volume from I x 10- 111 to
(J l Remains unaffec ted
J x J 0- 2 m 3 at 300 K against a constant pressure of
( 4) May increase or decrease
2. /1. 111111onium nitrate can decompose with explosion Ix 105 Nm- 2 • The work done is _ __
b: the following reaction (I) -900 J (2) -900 kJ (3) 2710 kJ (4) 900 kJ
NH 4 NO 3 (s) ➔ N 2 O(g)+2H 2 O; 11. Identify the state functions among the following
(I) +q (2) w (3) q+w (4) q/w
L'l H =-37.0KJ / mot
12. AS 0 and tlH 0 for combustion of methane are
Ca lculate the h eat produced when 2.50g of
J86JK _, and -74.8kJmor' respectively. The
NH,NO 3 decomposes _ _
value of tlU 0 for the process would be -
(I) 1.06 KJ (2) 0.96 KJ
(3) l.16KJ (4) 1.26KJ (I) Unpredictable (2) (74.8- R )JK- '
3. The heats of neutralisation of four acids A,B,C and
(3) 74 .78 kJ (4) (596R-74.8)kJ
D when neutralised against a common strong base
are 13.7, 9.4, 11.2 and 12.4 kcal respectively. The 0
13. The standard free energy change AG is related
weakest among these acids is
(I) A (2) B to equilibrium constant, KP as _ _ __
(3) C (4) D
[ e rG•
4. Which one of the following is correct- (1) KP= -RT f ntlG
0
(2) K = -
P RT
()) -L'.lG=L'.lH-TtlS (2) flH=flG-TtlS
(3) K =- LlG (4) K p = e(-6G•tRT)
(3) L'.lS = ~ -[ ilG-ilH] (4) tlS = ~[ tlH -llG] p RT
14. Two moles of an ideal monoatomic gases are
5. One mole of an ideal gas at 300 K is expanded allowed to expand adiabatically and reversibly from
isothermally from an initial volume of I litre to 10 300 K to 200 K. The work done in the system is
litres. The dE for this process is
(Cv = 12.51 /KI mol) _ __
1 1
(R = 2calmol- K- ) (1) -12.5 kJ (2) -2.5 kJ (3) -6.25 kJ (4) 500 kJ
(1) 163.7 cal (2) Zero 15. Which of the following process/es proceed towards
more disordered state ?
(3) 138.1 cal (4) 9 litatm.
(I) Stretching the rubber band
6. For the process _ _ CO 2 (s) ➔ CO 2 (g) (II) Sublimation of dry ice
(1) Both L'.lH and L'.lS are positive (III) Crystallisation of salt from solution
(2) AH is negative and AS is positive (IV) dissolution of sugar in water
(1) I, IV (2) I, III (3) III, IV (4) II, IV
(3) AH is positive and AS is negative
16. The equilibrium N 2 + 0 2 ~2NO is established
(4) Both AH and AS is negative
in a reaction vessel of 2.5L capacity. The amounts
7. The difference between AH and AE at constant of N 2 and 0 2 taken at the start were respectively
volume is equal to - 2 moles and 4 moles. Half a mole of nitrogen has
been used up at equilibrium. The molar
(1) R (2) PAV (3) VAP (4) IR
2
concentration of nitric oxide is
(1) 0.2 (2) 0.4 (3) 0.6(4)0.1
8. For a reversible reaction at equilibrium AG is -
(I) Positive (2) Negative
(3) Zero
( 4) May be positive or negative
 ~ .ALLEM . THERMODYNAMICS & CHEMICAL EQUILIBRIUM
~• CARIEER IN S TITUT E
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17. An equili brium mixtu re for t he rc;ic ti on 23 . fn which of th e_fo ll ow in g rea~ti on ?oubling the
vo lum e ofco nta 1ner ca use a shift to ri ght ?
2 H:S ( g) s==== 21l l (g ) + Si (g )
( I) 2CO (g ) l· 0 2(g ) ~ 2 C0 2(g)
had I mole of 1-1 2S. 0 .2 mole of II 2 nnd 0.8 mol e
I
of S ~ in a 2 litre ll nsk. ll1c vn luc of K, in 111 0 1 L i~ (2) N 2 (g) + J I r i (g ) ~ 2 NH 1 (g)
( I) 0.004 (2) 0.080 (J) PC l5 (g ) ~ PC I-' (g) + C l2( g)
(3) 0.0 16 (4) 0. 160
I 8 . In which of the fo ll owi ng.equilibrium , change in the (4) H 2 (g) +C l2 (g ) ~ 2 HC l(g)
vol ume of the svstcm does not alt er the number of 24. For th e gas phase reacti on,
n1oles ·
2NO~N 2 +O 2 ,L1H =-43.Skcalmor'
t I) N~(g) + 0 2 (g)~2NO(g)
Which one of the statement below is true for
(2) PC l5 (g)~ PC l3 (g) + C l2 (g)
N 2 (g) + 0 2 (g)~2NO(g)
(3) N 1 (g) + 3H 2 (g ) ~ 2NH 3 (g ) (!) K is independent of T
(2) K increases as T decreases
(4) so 2 c1 2 ~so 2(g) + c1 2(g) (3) K decreases as T decreases
19. What are the most favourable conditions for the (4) K varies with the addition ofNO.
fo llowing reaction to occur ?
25. In what manner will increase of pressure affects
I the following equilibrium?
so2+-02 r=:=SO3, L1H =-Ve
2
C( s) + Hp(g);==CO(g) + H 2 (g)
(I ) Low T, High P (2) Low T, Low P
(3) High T, Low P (4) High T, High P (I) Shift in the forward direction
(2) Shift in the backward direction
20. Which of the following equilibria will shift to right
side on increasing the temperature ? (3) Increase in the yield of hydrogen
(4) No effect
(I) CO (g) + H 2 O (g) r=:=CO 2 (g) + H 2 (g) 26. At a certain temperature, the following reactions:
(2) 2SO 2 (g) + 0 2 (g)~2SO3(g) NO(g)+½0 2 (g)~NO 2 (g)

(3) Hp(g)~H 2 (g)+½0 2 (g) NO 2 (g) + NO(g)~ Np 3(g)

have equilibrium constants K 1 and K 2
(4) 4HCI (g) + 0 2 (g)~2H 2 O(g) + 2Cl 2 (g)
respectively. The equilibrium constant for the
21. Which ofthe following is not affected by pressure
change?
reaction 2NO(g)+½0 2 (g)~N 2 O 3 (g)
(I) 2NO2 (g)~NP◄ (g) at the same temperature would be
(2) CO 2 (g)+Hp(t )~CO 2 (solution) (]) K 1 +K 2 (2) K 1 /K 2
(3) K 2 /K 1 (4) K 1K 2
(3) H 2 (g) + l 2 (g)~2HI(g)
2 7. A quantity of PCl 5 was heated in a 10 litre vessel
(4) 203 (g)~3O2 (g) at 250°C. It dissociates as
22. In which of the following, the forward reaction is
favoured by use of high pressure ? PCl 5 (g)~PCl 3 (g) + Cl 2 (g)
(1) H 2 + l 2 ~2HI At equilibrium the vessel contains 0.1 mole of
PCl 5 , 0.20 mole of PCl 3 and 0.20 mole of
(2) N 2 +0 2 ~2N0
Cl 2 • The equilibrium constant ofthe reaction is
(3) 2NH 3 ~ N 2 +3H 2 ( 1) 0.02 (2) 0.05
(3) 0.04 (4) 0.025
(4) 2SO 2 +O 2 ~2SO 3
 THERMODYNAMICS & CHEMICAL EQUILIBRIUM
2s. The c q 11 i/,/,,
·
co ns ,~1111 111
11 1111
·
· . .
a r cvcrs 1LJ cc 11c 111 ic al Eq uilib rium consta nt fo r th e fo ll owing reactio n is
r eac 11 or 1 .1 1 .1 g ive n l c mpcrn iu rc · )
( I ) Dc p..- 11.!, ,,11 Ili c i n i ria l co n " . . aA -t h l3 ~ c C + dD
rcal· t.1 111, c.:c.: ntr .-i t, 0 11 of tln:
. 11
(2) Dcp L·11d, l'll Ili c co nL·c rll r;ll 10
rnld 11, 1, .1 1 eq uil ibr ium of o n e of th e
(3) Dtll> 1h 1 1 dqw nd t' n lh L· initi 1 , . .
of r l'.1t·1,1111s " co n ce ntrnt1 0 11 s

(4) Is llt' I ch.ll'::ic tcris· 1ic o f the i·eacti·on

29 Thcrc:Kl l< 'll PCl, (s)~Pc r ( ) +
J g
( . .
Cl2 g) 1s rn
.. . -
1 1 1
cqud1 m11111 f t 1c e quilibrium c .
. oncentratton of
PCI, (&) do ubl
1:-- ed, th .
en conc ent ration of
·
C l: (g) ,, ould become: = KCRT
(4) KP p
( I) 1/2 o(i1s initial va lue
32. Match the following
(2) 1/4 of its initial va lue
Column-I Column - II
(3) Four tim es of its initial value
Isothermal
(4) Two times of its initial value (A) reversible (P) q =fiU
30. Passage: For general reaction process
' w=-PllV
(B) Adiabatic process (Q)
aA+bB~cC+d D w=LlU
(C) Isobaric process (R)
equilibrium constant Kc is given by the following (D) Isochoric process (S) w =-n RTln{V2 /V1)
[er [ot (1) A-P, B-R, C-Q, D-S (2) A-S, B-R, C-P, D-Q
relation. K" (3) A-S, B-R, C-Q, D-P (4) A-R, B-P, C-S, D-Q
[Ar [B)6
33. Match the following
However, when_ ~II _reactants and products are
gases, the eqmlibnum constant is generally If K is equilibrium constant a reach then
expressed in terms of partial pressures. The Column-I Column - II
relationship between the partial pressure (p) ofany (A) Reaction is reversed (P) ✓ K
one gas in the equilibrium mixture and the molar (B)
Reaction is divided (Q) Kl
concentrations can be correlated provided the gas bv 2
behaves as an ideal gas. Reaction is
When 8. I ml of hydrogen and 9 .3 ml of iodine (C) multiplied by 2 and (R) -Kl
reversed
vapour are heated to 444 °, I 3 .5 ml of HI are Reaction takes place
produced. The equilibrium volume for H 2 and 12 in two steps, each l
(D) (S)
respectively should be _ __ with same K2
(2) 2.55 and 2.55 equilibrium constant
(I) 1.35 and 1.35
(1) A-P, 8-Q, C-R, D-S (2) A-P, B-R, C-S, D-Q
(3) 1.35 and 2.55 (4) 2.55 and 1.35
(3) A-R, B-P, C-S, D-Q (4) A-S, B-Q, C-P, O-R
31. Passage: For general reaction,
34. How many of the given quantities are state function
aA + bB~cC + dD (i) ~H (ii) ~U
equilibrium constant Kc is given by the following (iii) Q (iv) W
(v) Qp (vi) Qv
. K - [er [Dt
relation. c - [ AJ3 [B t (1)1(2)2 (3)3
35. How many of the following does not affect Kc·
(4)4

However, when all reactants and products are

(i) Initial concentration (ii) Temp
gases, the equilibrium constant is generally
exp~esse~ in terms of partial pressures. The (iii) Catalyst (iv) Pressure
relat1ons_h1p between the partial pressure (p) of any (v)Volume
one gas m the equilibrium mixture and the molar (1)1(2)2 (3)3 (4)4
concentrations can be correlated provided the gas
behaves as an ideal gas.
 .e-
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ALLEM
CA"(Cl\ fNSMTUTI! THERMODYNAMICS & CHEMICAL EOUIUBR/UM
U,Ul b-C!WiX!l:O

46 . Which of the following is not a state fu ncti on

3<,. At 27°( the internal energy change of reaction
( I) Pressure (2) Vol ume
1-1:(g) + C/ 2 (g) ➔ 2HCl(g) is 2 cal. What is the (3) Temperature (4) Heat
cnthalphy change of this reaction? 47. At equili brium, which is correct
( 1) 2 cal (2) 4 cal (3) 6 cal (4) 3 cal ( I) tiG = 0 (2) tiH = 0
3 7. At constant temperature for the reaction (4) t.Go= 0
(3) 1'.S= 0
C3 H8 (g) + 5O 2 (g)-...+ 3CO2 (g) + 4H 2 O(/) , 48. Tea placed is thermo fl asks is an example of
6E-6H is ( l) Open system
( 1) + RT (2) - 3RT (3) + 3RT (4)- RT (2) Close system
38. The favo urable condition for a spontaneou s (3) Isolated system
reaction are (4) It cannot act as system
49. A thennally isolated gaseous system can exchange
( I ) T6 S >6H.6H = +ve,6S = +ve
energy with the surroundings, the mode of ernergy
(2) T6S > 6 H,6H = +ve,6S =-ve
may be
(3) T6 S = tiH,tiH = -ve, tiS = -ve (I) Heat (2) Work
(4) TtiS = tiH, tiH = +ve,tiS = +ve (3) Heat and radiation (4) Internal energy
39. 40% of PCl 5 is not dissociated at 300°C . The so. For the reaction,
reaction is carried out in a flask of I lit capacity. aA(s) + bB(g) ➔ dD(s) + cC(g). Then
The value of Kc would be (I) tiH-tiE=( b-d)RT
( l) 3.2 (2) 1.6 (3) (3.2)-1 (4) 0.9
is dynamic? (2) tiH-tiE=( c-b)RT
40. Which of the following equilibrium
(3) tiH-tiE=(a +b)-(c + d)RT
( I) Solid ~ liquid (2) Liquid ~ vapour
(4) tiH-tiE=( a-d)RT
(3) Solid ~ vapour(4)AII ofthese 51. The specific heat of a gas is found to be 0.075
41. If PCl 5 is 80% dissociated at 2S0°C then its calories at constant volume and its formula weight
vapour density at room temperature will be is 40. The atomicity of gas would be
( I) 56.5 (2) 104.25 (3) 101.2 (4) 52.7 (I) One (2) Two
(3) Three (4) Four
42. In a chemical equilibrium A+B ~ C+D 52. For strecthed rubber, Entropy
when one mole each of the two reactants are (I) Increases
mixed, 0.4 mol each of the products are formed. (2) First increases then decrease
TI1e equilibrium constant is, (3) Decreases
4 (4) First decreases then increases
(I) I (2) 0.36 (3) 2.25 (4) 9 53. In which of the following does the reaction go
almost to completion?
43. Evaluate KP for the reaction: H2 + 12 ~2HI . (I) Kc= 103 (2) Kc = 102
If 2 moles each of H2 and 12 are taken initially. (3) Kc = 10-2 (4) K = J0-3
54. K is how many times equal to k for the given
At equilibrium moles of HI are 2. '
(3) 0.25 (4) 1.0 re~ction?
(I) 2.5 (2) 4
44. On cooling of following system at equilibrium, N 2 (g) + 3H 2 (g)~2N H 3(g)
(02(s) ~ ( Q 2 (H)
I
(I) R iT2 (2) R 2 T2
(I) There is no effect on the equilibrium state
(2) More gas is formed R
(3) More gas is solidified (3) T (4) RT
(4) None of these
45. Which of the following statements is correct for a 55. For reaction, 2A + B;:== 2C, K = x .
reversible process in a state of equilibrium?
Equilibrium constant for C~A + ..!.B will be
(I) tiG = 2.30 RT log k 2 ,
(2) tiG 0 = - 2.30 RT log k X
(I) x (2) -
(3) tiG 0 = 2.30 RT log k 2
(4) tiG = -2.30 RT log k I
(3) - (4) ✓x
✓x