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Arjuna JEE (2024)

Chemical Equilibrium DPP-02

1. For the reaction CaCO3(s) CaO(s) + 6. The equilibrium constant for the reaction
3C2H2 ⇌ C6H6 is 4.0 M–2 at T K. If the equilibrium
CO2(g), the value of Kp is
concentration of C2H2 is 0.5 M, then the
PCO2 concentration of C6H6 at equilibrium is
(1) PCO2 (2)
PCaCO3 (1) 0.5 M (2) 1.5 M
–2
PCaCO3 (3) 5 × 10 M (4) 0.25 M
[CaO][CO2 ]
(3) (4)
[CaCO3 ] PCaO PCO2
7. G° for the reaction X + Y ⇌ C is –4.606 kcal at
1000 K. The equilibrium constant for the reverse
2. The figure shows the change in concentration of mode of the reaction is
species A and B as a function of time. (1) 100 (2) 10
The equilibrium constant KC for the reaction, (3) 0.01 (4) 0.1
A(g) ⇌ 2B(g) is
8. The amounts of 0.8 mol of PCl5 and 0.2 mole of PCl3
are mixed in a 1 L flask. At equilibrium, 0.4 mole of
PCl3 is present, The equilibrium constant for the
reaction,
PCl5(g) PCl3(g) + Cl2(g) will be
(1) 0.05 mol L–1 (2) 0.13 mol L–1
–1
(3) 0.013 mol L (4) 0.60 mol L–1

(1) KC > 1 (2) K < 1 9. Which reaction has ng = 2?

(3) K = 1 (4) data insufficient (1) CaCO3(s) ⇌ CaO(s) + CO2(g)
(2) 3Fe(s) + 4H2O(g) ⇌ Fe3O4(s) + 4H2(g)
3. In the reversible reaction (3) NH4Cl(g) ⇌ NH3(g) + HCl(g)
2HI(g)  H2(g) + I2(g), Kp is (4) CuSO4 . 5H2O(s) ⇌ CuSO4 . 3H2O(s) + 2H2O(g)
(1) Greater than KC (2) Less than KC
(3) Equal to KC (4) Zero 10. If one third of HI decomposes at a particular
temperature, Kc for 2HI(g) ⇌ H2(g) + I2(g) is:
4. NH4COONH2(s)  2NH3(g) + CO2(g). If (1) 1/16 (2) 1/4
equilibrium pressure of gaseous mixture is 3 atm (3) 1/6 (4) 1/2
then Kp will be
(1) 4 (2) 27 11. Equilibrium concentration of HI, I2 and H2 is 0.7,
4 1
(3) (4) 0.1 and 0.1 M respectively. The equilibrium constant
27 27 for the reaction,
I2(g) + H2(g) ⇌ 2HI(g) is:
5. What is the unit of KP for the reaction:
(1) 0.36 (2) 36
CS2(g) + 4H2(g) CH4(g) + 2H2S(g).
(3) 49 (4) 0.49
(1) atm (2) atm–2
(3) atm2 (4) atm–1
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12. The equilibrium concentrations of X, Y and YX2

are 4, 2 and 2 respectively for the equilibrium,
2X + Y ⇌ YX2. The equilibrium constant Kc is:
(1) 0.0625 (2) 0.625
(3) 6.25 (4) None of these
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (1) 7. (4)
2. (1) 8. (2)
3. (3) 9. (4)
4. (1) 10. (1)
5. (2) 11. (3)
6. (1) 12. (1)

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