HS BISHT

DR

R.K AMO/
ASPIRING THOUGHT INSPIRED RESULIS
DR. R.K. CHEMISTRY CLASSES
Conrec Y THERMODYNAMICS
Time: 1.5 Hour
Tn corfecF Negative: -1

de ft Total Marks: 180

Qbiective Questions 4 Marks Each Select the correct answer:
1. One mole of an ideal gas is allowed to expand reversibly and adiabatically from a temperature of 27 °C
work during the process is 3 kJ, then the final temperature ofthe gas is:
fthe
L 100 K b 150 K c) 195 K d) 255 K
In a closed insulated container, a liquid is stirred with a paddle to increase the temperature. In this
process, which of the following is true?
a) AF W-Q-0 b)AE +0, O= W=0

AT W+0, 0= 0 d)AE O#0, W=0 =

The molar heat capacity of water at constant pressure is 75 JK mol. When 1.0,KJ hat is supplied to
100 g of water which is free to expand, the increase in temperature of water is:
a) 6.6 KK b) 1.2 K LC24K d)4.8 K
h e bond energies of 1H-HI, Br-Br and HBr are 433, 192 and 364 kJ mol respectively. The AH° tor
the reaction,
l1, (g) + Br, (g) 2 HBr (g) is:
T O 3 kJc)-261 kJ d) + 103 kJ
a) 261 kJ
The heat change taking place during the reaction H0 () HO(g) is
(Given AlH H,O (g) -57 kcal, A,H H,O ()=- 68.3 kcal)

a) 11.53 kcal b)-115.3kcal A 1 . 3 kcal d)-113 kcal

6. The absolute enthalpy of neutralisation (standard value=- 57,33 kJ mol") of the reaction, Mg0 (5)

ICI MgCl, +
H,O will be (in terms ofnumèricalvalue)
less than 57.33 kJ mol bb57.33 kI mol
geater than 57.33 kJ mol d) 57.33 kJ mol
ATeaction occurs spontancously if:
TASAll and both All and AS are tve
a)
b) TASAll and AS is -ve
LCPS AlH and both All and TAS are +ve
l) TASAH and AH and TAS both are +ve
()+ Clh (g) 2 BrCl (g) are 30 kJ mol and
The enthalpy and entropy change för the reaction, Br
The temperature at which the reaction will be in equilibrium is:
105 JK'mol respectively.
b) 300 K 285.7K d) 273 K
a) 450 K
O C/1 bar
or a phase H,O() H,O(S):
b) AS 0 c)
AH =0 A U -0
(aAG-0 PCl (g)+ Clh (g). Which ofthe following conditions
, 19tor the gas phase reaction, PCls (g)
are correct?
a) AH0 and AS <0 b)AH>0 and AS<0
daH> 0 and AS >0
AH-0 and AS<0
will be the heat of formation of methane
if heat of combustion of carbon is xk.J, heat of
What
formation of water is k), and heat of combustion of methane is z kJ?
a) ( r - - ) kJ b)(-2-x +2y) kJ
d r - 2 y + 2) kJ
c)r 2-)kJ
AE
OC12. ldentify the reaction in which AH #
(Rhombic) O, (g) + SO, (g)
S
b) N: (g)+ O, (g)- 2NO (g)
(Co(g)O. (g) CO ()
d) H:(g)+Ch (g) 2HCl (g)
7340941477
S.C.O. 220 Ist Floor, Seetor 37-C, Chandigarh (M) 9855111219,
Email: kakar.rajesh88@gmail.com
 DR

RK C H E M I S T R Y
CLASSES

DR. R.K.
APTRING THOUGHT INSPIRED RESULD

and AS for the reaction,.

. T h e value ol AH
(g) CO, (g)
Ceraphite) O ,
at
spontaneous
reaction will be
K'respectively. The d) 710 K
are 1 70kJ and 170 J c) 510 K standard c rec

HTIOK (). The

a) 910K
6 CO, (g) +6 H,O respectively.
glucose, Colli2O, +
60, (2) a n d - 2 3 7 . 2 kJ
mol
Torcombustion of 394.5
-

and H,O () a r e - 9 1 0 . 5 ,
TOrmati0n of glucose, CO, (g)
O1
standard free energy change will be d)-57.582 kJ The
Le2879.7 kJ respectively.
b)-28.797 kJ mol
a) 287.97 kJ
-692, 1676 and-911 kJ
of MgO, AlLO; and SiO,
are

13. The heat of formation

oxide is: cannot be predicted
moststable c) SiO d)
L MgO ideal gas under adiabaticcondition?
for free expansion of an
.Which of the following is córrect option W=0
0 , AT<0. W#0
b) q-0, AT #0,
W=0
d) q0, AT 0,
=

H-1
y 0 .A7 0.
W-0
reaction 4H (g) - 2 H2 (g) is 869.6-kJ. Thedissociationepergy of
for the
, nthalpy change
bond is: L434.8 k
b)-434.8 kJ c)-869.6kJ
a)217.4 kJ 500 °C is as follows
decomposition of Al,0;
at

18. heGibb's energy for 960 kJ mol

Al+O : A,G
=

AlO oxide Al,0; at 500 °C is at

for the electrolytic

reduction of alumipiúm
needed
The potential difference
least:
a) 5.0 V
b) 4.5 V c)3.0 V reaction
.sv has:
energies of activatiop for forward
and reverse
Areaction having cqual d) AG 0
=

ba AG AS 0 c) AS 0
a ) All0 by the cyclic process
shown by the following diagram?
represented
L
2911ow much ofheat change is
VL)

15P(KPa) d) 10 xJ
c) nJ
3)10 J from 40 L to 5L, reversibly
and adiabatically. The
final temperature
300-K
KArgon gas is compressed at
is: d) 450 K
b ) 900 KK c) 600 K
Ley 1200 K constant volume. The related
heated from 300 K to 600 K at
gas are
29 5moles of an ideal monoatomic
entropy change is d) 15.0
a) 6.3
0.4 certain temperature is 0.2 cal/g/°C.
Its specific heat at
volume at a
constant
23 Specilic heat of ozone at
c o n s t a n t pressure is:
c)0.332 cal/g/C d) 0.665 cal/g/°C
cal g °C
y0.28 cal/g/"C Calculate the
0.266 benzene is 30.8 kJ mol at its boiling point (80.I °C).
The enthalpy of vaporization of
the condensation process.
entropy changein c) 240 JK mol d)-240 JK mol

873 JK mol (b)87.3JK mol pressure-volume work is

a) at constant 7 and P
and in which only
In an irreversible processtaking place (dS) satisfy the criteria:
change in entropy
free energy (dC) and
being done. the change in Gibbs bXds)> 0, (dG)Tp <0
a) (dS) 0. (dG)Tp0 0. (dG)Tp >0
d) (dS)
=

JK
c)(S) 0. (dG)Tp 0
monoxide (CO) from
its elements at 298 K is: (R =8.314
of carbon
(AH AU) for the formation
mol ) b2477.57 J mol
1238.78J mol
7340941477
9855111219,
Chandigarh (M)
S.C.O. 220 Ist Floor, Sector 37-C,
Email: kakar.rajesh88@gmail.com
 DR
RK-

RESULIS
NRINGTIHOUGHTINSPIREUD DR. R.K. CHEMISTRY CLASSES
2477.57 J mol d)- 1238.78 J mol
27 n a fuel cell, methanol is used as a fucl and oxygen gas is used oxidiser. The reaction
as an
ls
CH,OH (/) 0 , (g) CO, (9)+211,0 ()
At 298 K. standard Gibbs' energies of formation
of CH,OH (), H,O () and CO; (g) are100.
237.2 and 94kmol respectively. If standard enthalpy of combustion of methanol is 26 KJ
mol, etficieney of the fuel cell will be:
a) 87 b) 90% e97% d) 80%
T h e standard cnthalpy of formation of NH, is -46.0 kJ mol.If the enthalpy of formation of l; Iro
its atoms Is 436 kJ mol and that of N, is- 712 kJ mol, the average bond enthalpy of N H bond in
NH is:
) I102 kJ mol b)-964 kJ mol Le352 kJ mol d) +1056 kJ mol
9 e T a particular reversible reaction at temperature T, AH and AS were found tobe+ve. If 7e 1s the
temperature at equilibrium, the reaction would be spontaneous when:
a)
7 T b) TT LcPT. d) T, is 5times
A
30. AEand AlH both are zero in:
)othermal process b) reversible process c) isochoric process yclicprocess
I n an isothermal process
a) 0 and AF = 0 (b) 0 and AF = 0 c ) 0 and AF 0 d)q 0 and AE 0
32Which of the following is correct for thermodynamic equilibrium?
(1) AV 0 (1) AP=0 (111)AT=0 V)An =0
) Only b) IIl and IV
c)1, l and IV A l l of these
Maximum work can be extractcd from a system in:
Isothermal reversible process
b) isothermal irreversible process
c) isothermal reversible as well as irreversible process
neither reversible nor irreversible
The correct inereasing order of energy content is
a) erg c a l o r i e j o u l e < litre-atm b f g < joule < ealorie < litro-atm
oule-erg calorie < litre-atm d )joule < calorie< litre-atm < erg
leat of neutralisation is highest for:
a) INO, NH,OH b) HSOt NH,OH
Ler 1ICINaOll d) cannot be decided

S.C.o. 220 Ist Floor, Sector 37-C, Chandigarh (M) 98551 11219, 7340941477
Email: kakar.rajesh88@gmail.com