SPM Trial 2010 Che Q&A (Melaka)

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SULIT 4541/1
4541/1
Chemistry
Paper 1
September
1 1/4 jam
PERSIDANGAN KEBANGSAAN PENGETUA-PENGETUA

SEKOLAH MENENGAH MALAYSIA (PKPSM) CAWANGAN MELAKA
DENGAN KERJASAMA
JABATAN PELAJARAN MELAKA
____________________________________________________
PEPERIKSAAN PERCUBAAN
SIJIL PELAJARAN MALAYSIA 2010
CHEMISTRY
Kertas 1
Satu jam lima belas minit
JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Kertas soalan ini mengandungi 50 soalan.
2. Jawab semua soalan.
3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan.
4. Hitamkan satu ruangan sahaja bagi setiap soalan.
5. Rajah tidak dilukis mengikut skala kecuali dinyatakan
6. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan
Kertas soalan ini mengandungi 25 halaman bercetak.
4541/1 SULIT
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SULIT 4541/1
INFORMATION FOR CANDIDATES
1. This question paper consists of 50 questions.
2. Answer all questions.
3. Answer each question by blackening the correct space on the answer sheet.
4. Blacken only one space for each question.
5. If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the space for the new answer.
6. The diagrams in the questions provided are not drawn to scale unless stated.
7. You may use a non-programmable scientific calculator.
MAKLUMAT UNTUK CALON
2. Jawab semua soalan
5. Sekiranya anda hendak menukarkan jawapan, padamkan tanda yang telah dibuat.
Kemudian hitamkan jawapan yang baru.
6. Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan.
Question 1 to Question 50 are followed by four options A, B, C or D.

Choose the best option for each question and blackened the corresponding space on
the objective answer sheet.
Bagi Soalan 1 hingga Soalan 50, tiap-tiap soalan diikuti oleh empat pilihan jawapan A,
B, C dan D. Pilih satu jawapan yang terbaik bagi tiap-tiap soalan dan hitamkan ruangan
yang sepadan pada kertas jawapan objektif anda
2
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1 Which of the following substances undergoes sublimation process when heated?

Manakah antara bahan berikut mengalami proses pemejalwapan bila dipanaskan?
A Sodium chloride
Natrium klorida
B Ammonium chloride
Ammonium klorida
C Sodium nitrate
Natrium nitrat
D Ethanol
Etanol
2 Diagram 1 shows the set-up of the apparatus to study Process I.

Rajah 1 menunjukkan susunan radas bagi mengkaji Proses 1
Air
Process 1
Bromine gas
Lid (brown)
Bromine gas
(brown)
Diagram 1
Rajah 1
What is Process 1 ?
Apakah Proses 1 ?
A Condensation
Kondensasi
B Evaporation
Penyejatan
C Diffusion
Resapan
D Sublimation
Pemejalwapan
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3 Which of the following processes will decrease the kinetic energy of the particles of a
substance?
Proses yang manakah akan mengurangkan tenaga kinetik zarah-zarah bagi suatu bahan?
A Melting
Peleburan
B Freezing
Pembekuan
C Boiling
Pendidihan
D Evaporation
Penyejatan
4 Which of the following substances consists of atoms?

Manakah antara bahan berikut mengandungi atom?
A Copper
Kuprum
B Nitrogen gas
Gas nitrogen
C Lead(II) iodide
Plumbum(II) iodida
D Naphthalene
Naftalena
5 The graph below shows the cooling curve of naphthalene.

Graf di bawah menunjukkan lengkung penyejukan bagi naftalena.
Temperature/°C
Time/s
Why is curve A obtained in the graph?
Kenapakah lengkung A terjadi ?
A Impure naphthalene is cooled.
Naftalena tak tulen disejukkan.
B Naphthalene evaporates during cooling process
Naftalena meruap semasa proses penyejukan
C Naphthalene is not stirred during cooling process
Naftalena tidak dikacau semasa proses penyejukan
D Naphthalene freezes after achieving its freezing point
Naftalena membeku setelah mencapai takat beku
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6
Electron moves around the nucleus in fixed orbital shells
Elektron bergerak mengelilingi nukleus dalam petala yang tetap
Which of the following scientists proposed the atomic theory stated above ?
Ahli sains yang manakah mencadangkan teori atom di atas?
A J.J. Thomson
B Niels Bohr
C Ernest Rutherford
D James Chadwick
7 How many protons, neutrons and electrons does an atom of aluminium contain?
Berapakah bilangan proton, neutron dan elektron bagi atom aluminium ?
27
Al
13
Number of protons Number of neutrons Number of electrons

Bilangan proton Bilangan neutron Bilangan elektron
A 13 14 13
B 13 27 13
C 14 13 14
D 27 14 13
8 The following statements are true about lead-acid accumulator except

Pernyataan-pernyataan berikut adalah benar mengenai akumulator asid- plumbum
kecuali
A lead plate is the negative terminal

kepingan plumbum adalah terminal negatifnya
B carbon plate is the positive terminal
kepingan karbon adalah terminal positifnya
C the accumulator can be recharged
akumulator ini boleh dicas semula
D the electrolyte in this accumulator is sulphuric acid
elektrolitnya ialah asid sulfurik
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9 Table 1 shows the proton number and the nucleon number of atom X.
Jadual 1 menunjukkan nombor proton dan nombor nukleon bagi atom X
Proton number 11
Nombor proton
Nucleon number 23
Nombor nukleon
Table 1
Jadual 1
Which of the following is correct about the position of X in the Periodic Table of elements?
Yang manakah benar mengenai kedudukan X dalam Jadual Berkala Unsur?
Group Period
Kumpulan Kala
A 1 2
B 2 1
C 1 3
D 5 2
10 Table 2 shows the electron arrangement of atoms P , Q , R and T

Jadual 2 menunjukkan susunan elektron atom-atom P, Q, R dan T
Atom P Q R T
Atom
Electron arrangement 2.1 2.4 2.8.2 2.8.7
Susunan elektron
Table 2
Jadual 2
Which of the following pairs of elements can combine to form a covalent compound?
Pasangan unsur yang manakah dapat berpadu membentuk sebatian kovalen ?
A Q and T
B P and R
C R and T
D Q and R
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11 Which statement is true about the reaction of a sodium atom with oxygen atom to form
sodium oxide ?
[Proton number: Na = 11, O = 8]
Pernyataan yang manakah benar bagi tindak balas antara atom natrium dengan atom
oksigen untuk membentuk natrium oksida ?
[Nombor proton : Na = 11, O = 8]
A One sodium atom donates one electron to one oxygen atom

Satu atom natrium menderma satu elektron kepada satu atom oksigen
B One sodium atom shares one electron with one oxygen atom
Satu atom natrium berkongsi satu elektron dengan satu atom oksigen
C Two sodium atom share one electron with one oxygen atom
Dua atom natrium berkongsi satu elektron dengan satu atom oksigen
D Two sodium atoms donate one electron each to one oxygen atom
Dua atom natrium menderma satu elektron setiap satu kepada satu atom oksigen
12 Diagram 2 shows a simple cell made up of magnesium plate and copper plate as
electrodes and copper(II) sulphate solution as the electrolyte.
Rajah 2 menunjukkan sebuah sel ringkas terdiri daripada kepingan magnesium dan
kepingan kuprum sebagai elektrod dan larutan kuprum(II) sulfat sebagai elektrolit.
Magnesium
Diagram 2
Rajah 2
Which of the following statements is true for the above reaction ?

Yang manakah pernyataan berikut adalah benar bagi tindak balas di atas ?
A The blue colour of the copper(II) sulphate solution remains unchanged

Warna biru larutan kuprum(II) sulfat tidak berubah
B Copper electrode is the positive terminal
Elektrod kuprum adalah terminal positif
C Magnesium electrode becomes larger in size
Saiz elektrod magnesium bertambah besar
D Colourless gas bubbles are produced at the copper electrode
Gelembung gas tanpa warna terhasil di elektrod kuprum
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13 Diagram 3 shows a set-up of apparatus of a redox reaction.

Rajah 3 menunjukkan susunan radas bagi tindak balas redoks.
G
P Q
Acidified Potassium manganate(VII)
Potassium Iodide Solution solution
Larutan Kalium Iodida Kalium mangganat(VII) berasid
Sulphuric acid
Asid sulfurik
Diagram 3
Rajah 3
Which of the following statements are correct ?
Manakah antara pernyataan berikut adalah benar?
I Iodide ion , I- is reduced
Ion Iodida, I- mengalami penurunan
II Electrons flow from electrode P to Q
Elektron mengalir dari elektrod P ke Q
III The purple colour of acidified potassium manganate (VII) solution becomes
colourless
Warna ungu larutan berasid kalium mangganat (VII) menjadi tanpa warna
IV Manganate(VII) ion, MnO4- acts as the reducing agent
Ion manganat(VII), MnO4- bertindak sebagai agen penurunan
A I and II only
B II and III only
C II and IV only
D I , II , III and IV
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14 Half equation below represents a reaction.

Setengah persamaan di bawah mewakili satu tindak balas.
2 I- I2 + 2e
What is meant by oxidation reaction based on the equation ?

Apakah yang dimaksudkan dengan tindak balas pengoksidaan berdasarkan persamaan
di atas?
A Electrons are received by iodine
Elektron diterima oleh iodin
B Electrons are received by iodide ions
Elektron diterima oleh ion iodida
C Electrons are released by iodine
Elektron dilepaskan oleh iodin
D Electrons are released by iodide ions
Elektron dilepaskan oleh ion iodida
15 Diagram 4 shows the set-up of apparatus for the electrolysis of molten lead(II) bromide.
Rajah 4 menunjukkan susunan radas bagi elektrolisis leburan plumbum(II) bromida.
Carbon electrodes
Elektrod karbon
heat
Diagram 4
Rajah 4
State the correct observation for the reaction.

Nyatakan pemerhatian yang betul bagi tindak balas ini
A Bromine is released at the anode
Bromin dibebaskan di anod
B Brown solid is deposited at the cathode
Pepejal perang terenap di katod
C Brown gas is released at the anode
Gas perang terbebas di anod
D The carbon electrode at anode is coated with grey metal
Elektrod karbon di anod disaluti dengan logam berwarna kelabu
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16 Which of the following reagents can change iodide ion to iodine?

Yang manakah antara reagen berikut dapat menukarkan ion iodida kepada iodin?
I Acidified potassium dichromate(VI ) solution

Larutan kalium dikromat(VI) berasid
II Iron(II) sulphate solution
Larutan ferum(II) sulfat
III Lead(II) nitrate solution
Larutan plumbum(II) nitrat
IV Bromine water
Air bromin
A I and II only
I dan II sahaja
B II and IV only
II dan IV sahaja
C I and IV only
I dan IV sahaja
D II and III only
II dan III sahaja
17 Lead(II) bromide is not able to conduct electricity in solid state but can conduct electricity
in molten state because
Plumbum(II) bromida tidak boleh mengalirkan arus elektrik dalam keadaan pepejal
tetapi boleh mengalirkan arus elektrik dalam keadaan lebur kerana
A bromide ions and lead(II) ions are able to move freely in the molten state
ion bromida dan ion plumbum(II) bebas bergerak dalam keadaan lebur
B the molecules in lead (II) bromide are able to move freely in the molten state
molekul plumbum(II) bromida bebas bergerak dalam keadaan lebur
C bromine and lead atoms are free to move

atom bromin dan plumbum bebas bergerak
D the bromide and lead(II) ions are held strongly together in the molten state
ion bromida dan ion plumbum(II) terikat kuat dalam keadaan leburan
10
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18 Table 3 shows the voltage produced by different type of cells. Based on this table , the
cell that can produce 2.00 V can be set up using
Jadual 3 menunjukkan bacaan voltan beberapa jenis sel. Berpandukan jadual ini, sel
yang boleh membekalkan 2.00V boleh dibina dengan menggunakan
Cell Voltage / V
Sel Voltan / V
Magnesium // Copper 2.70
Magnesium // kuprum
Zinc // Copper 1.15
Zink // kuprum
Lead // Copper 0.45
Plumbum // Kuprum
Iron // Copper 0.70
Ferum // Kuprum
Table 3
Jadual 3
A Magnesium // zinc
Magnesium // zink
B Iron // lead
Ferum // plumbum
C Magnesium // iron
Magnesium // ferum
D Magnesium // lead
Magnesium // Plumbum
19 Which of the following is true about weak acid?

Pernyataan yang mana benar tentang asid lemah ?
A Unable to neutralize alkali
Tidak boleh meneutralkan alkali
B The pH value is more than 7.
Nilai pHnya lebih dari 7
C Able to change red litmus paper to blue.
Dapat menukarkan warna kertas litmus merah ke biru
D Ionizes partially in water to produce hydrogen ions.
Mengion separa dalam air untuk menghasilkan ion hidrogen
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20 Diagram 5 shows the set-up of apparatus done by a student to coat tin plate with silver.
The electroplating process is however unsuccesful because
Rajah 5 menunjukkan susunan radas yang disediakan oleh seorang pelajar untuk
menyadurkan kepingan logam timah dengan argentum. Proses penyaduran didapati tidak
berjaya dilakukan kerana
silver chloride
argentum klorida
Diagram5
Rajah 5
A A rheostat is used instead of an ammeter

reostat digunakan dan bukannya ammeter
B silver chloride is used as the electrolyte
argentum klorida digunakan sebagai elektrolit
C silver plate is connected to the anode
kepingan argentum disambungkan ke anod
D silver plate used is impure
kepingan argentum yang digunakan tidak tulen
21 Which particle causes an aqueous solution of ammonia to exhibit alkaline properties?

Zarah yang manakah menyebabkan larutan ammonia memperlihatkan sifat-sifat
alkali?
A H3O+
B OH-
C NH4+
D NH3
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22 Which of the following methods is suitable to prevent rusting of iron?

Kaedah yang manakah sesuai untuk mencegah pengaratan besi?
A Painting the engine of a car

Mengecat enjin kereta
B Fixing bars of copper to the part of ship submerged in water
Menampal kepingan kuprum di bahagian kapal yang tenggelam dalam air
C Galvanizing the roof made of iron with tin
Menggalvani atap besi dengan logam timah
D Plating the metal surface with chromium
Menyadur permukaan logam dengan kromium
23 The equation shows the reaction between sulphuric acid and sodium hydroxide.
Persamaan di bawah menunjukkan tindakbalas di antara asid sulfurik dan natrium
hidroksida.
H2SO4 + 2NaOH → Na2SO4 + 2H2O
What is the volume of 1.0 mol dm-3 sodium hydroxide solution which can neutralize 25.0
cm3 of 1.0 mol dm-3 sulphuric acid?
Berapakah isipadu larutan natrium hidroksida 1.0 mol dm-3 yang diperlukan untuk
meneutralkan 25.0 cm3 1.0 mol dm-3 asid sulfurik ?
A 12.5 cm3
B 25.0 cm3
C 50.0 cm3
D 75.0 cm3
24 Both ethanoic acid and hydrochloric acid with concentration of 1 mol dm-3 have
Kedua-dua asid etanoik dan asid hidroklorik yang berkepekatan 1 mol dm-3 mempunyai
I the same concentration of hydrogen ions
kepekatan ion hidrogen yang sama
II different degree of ionisation in water
darjah pengionan dalam air yang berbeza
III different pH value
nilai pH yang berbeza
IV the same concentration of hydroxide ions
kepekatan ion hidroksida yang sama
A I and II only
B II and III only
C III and IV only
D I and IV only
13
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25 When solid R is heated strongly, it produces a residue which is brown in colour when hot
and turns yellow when cold. R may be
Apabila pepejal R dipanaskan dengan kuat, ia menghasilkan baki berwarna perang bila
panas dan kuning bila sejuk. R mungkin
A Lead(II) carbonate
Plumbum(II) karbonat
B Zinc carbonate
Zink karbonat
C Copper(II) nitrate
Kuprum(II) nitrat
D Iron(II) nitrate
Ferum(II) nitrat
26 Which of the following compounds are needed to prepare ammonium sulphate fertiliser?
Antara sebatian berikut, yang manakah diperlukan untuk menyediakan baja ammonium
sulfat?
A Ammonia solution and sodium sulphate

Larutan ammonia dan natrium sulfat
B Ammonium chloride and potassium chloride
Ammonium klorida dan kalium klorida
C Ammonia solution and sulphuric acid
Larutan ammonia dan asid sulfurik
D Ammonium nitrate solution and sulphuric acid
Larutan ammonium nitrat dan asid sulfurik
27 Which of the following salts is insoluble in water?

Antara garam berikut, yang manakah tidak larut dalam air?
A Silver nitrate
Argentum nitrat
B Calcium chloride
Kalsium klorida
C Ammonium sulphate
Ammonium sulfat
D Lead(II) carbonate
Plumbum(II) karbonat
14
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28 The equation below shows thermal decomposition of 12.4 g of copper(II) carbonate.

Persamaan di bawah menunjukkan penguraian haba ke atas 12.4 g kuprum(II)
karbonat.
CuCO3 (s)  CuO (s) + CO2 ( g)
What is the mass of copper(II) oxide formed ?

Apakah jisim kuprum(II) oksida yang terbentuk?
[ Relative atomic mass : Cu=64, O=16, C=12 ]
A 4.4 g
B 8.0 g
C 44.0 g
D 80.0 g
29 Which of the following ions form a white precipitate which is insoluble in excess
sodium hydroxide solution?
Antara ion-ion berikut, yang manakah membentuk mendakan putih yang tak larut dalam
larutan natrium hidroksida berlebihan?
A Al 3+
B Mg 2+
C Pb 2+
D Zn 2+
30 Paracetamol is an example of
Parasetamol ialah satu contoh
A an antibiotic
antibiotik
B an analgesic
analgesik
C a traditional medicine
ubat tradisional
D a psychotherapeutic medicine
ubat psikoterapeutik
15
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31 The chemical equation below shows the reaction between P and Q.

Persamaan kimia di bawah menunjukkan tindak balas di antara P dan Q.
P + Q → salt + H2O + CO2

P + Q → garam + H2O + CO2
Which of the following could be P and Q?
Yang manakah antara berikut mungkin P dan Q?
A Zinc and hydrochloric acid

Zink dan asid hidroklorik
B Lead(II) oxide and nitric acid
Plumbum(II) oksida dan asid nitrik
C Sodium carbonate and sulphuric acid
Natrium karbonat dan asid sulfurik
D Magnesium carbonate and sodium hydroxide
Magnesium karbonat dan natrium hidroksida
32 The equation below shows the oxidation of sulphur dioxide to sulphur trioxide in the
manufacturing of sulphuric acid.
Persamaan di bawah menunjukkan pengoksidaan sulfur dioksida kepada sulfur trioksida
dalam pembuatan asid sulfurik.
2SO2 + O2 → 2SO3
The reaction is catalysed by

Tindak balas ini dimangkinkan oleh
A Iron
Ferum
B Platinum
Platinum
C Vanadium(V) oxide
Vanadium(V) oksida
D Manganese(IV) oxide
Mangan(IV) oksida
33 Why are detergents more effective than soap?

Mengapakah detergen lebih berkesan daripada sabun?
A Detergents are soluble in grease, whereas soaps are insoluble in grease.
Detergen larut dalam gris, manakala sabun tidak larut dalam gris.
B Detergents reduce the surface tension of water whereas soaps do not.
Detergen mengurangkan ketegangan permukaan air manakala sabun tidak.
C Detergents are biodegradable whereas soaps are non-biodegradable.
Detergen boleh terurai secara biodegradasi manakala sabun tidak
D Detergents do not form scum in hard water, whereas soaps form scum in hard water.
Detergen tidak membentuk kekat dalam air liat manakala sabun membentuk kekat
dalam air liat.
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34 In the saponification process, concentrated sodium hydroxide solution is added to

boiling vegetable oils to produce X and soap. What is X?
Dalam proses saponifikasi, larutan natrium hidroksida pekat ditambahkan kepada
minyak sayuran yang mendidih untuk menghasilkan X dan sabun. Apakah X?
A Glycerol
Gliserol
B Ethanol
Etanol
C Propanoic acid
Asid propanoik
D Ethyl methanoate
Etil metanoat
35 Which of the following statements explains why ceramic is suitable to make an engine
block?
Yang manakah antara pernyataan berikut menerangkan mengapa seramik sesuai untuk
membina blok enjin?
A Ceramic is chemically inert

Seramik adalah lengai secara kimia
B Ceramic is an electric conductor
Seramik adalah konduktor elektrik
C Ceramic can withstand high temperature
Seramik boleh tahan suhu yang tinggi
D Ceramic has a low specific heat capacity
Seramik mempunyai muatan haba tentu yang rendah
36 Which of the following food additives can be used to make food stay fresh longer and taste
better?
Antara bahan tambah makanan berikut yang manakah boleh digunakan untuk
mengekalkan kesegaran makanan dan meningkatkan rasanya?
A Tartrazine and sodium benzoate

Tartrazina dan natrium benzoat
B Ascorbic acid and sodium benzoate
Asid askorbik dan natrium benzoat
C Monosodium glutamate and tartrazine
Mononatrium glutamat dan tartrazina
D Monosodium glutamate and ascorbic acid
Mononatrium glutamat dan asid askorbik
17
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37 Diagram 6 shows an energy level diagram

Rajah 6 menunjukkan gambar rajah aras tenaga.
Energy
H+ + OH-
∆H = -57 kJ mol-1
H2O
Diagram 6
Rajah 6
Based on Diagram 6, it can be concluded that
Berdasarkan rajah di atas, dapat disimpulkan bahawa
A the heat of neutralization is – 57 kJ mol-1

haba peneutralan ialah – 57 kJ mol-1
B 57 kJ of energy is needed for the reaction.
57 kJ tenaga diperlukan untuk tindak balas itu
C the products of reaction contain more energy than the reactants.
hasil tindak balas mengandungi lebih tenaga berbanding bahan tindak balas
D the temperature at the end of the reaction is lower than that at the beginning of the
reaction
suhu pada akhir tindak balas adalah lebih rendah berbanding pada awal tindak
balas
38 Which of the following changes can increase the amount of product formed in a chemical
reaction?
Antara perubahan berikut, yang manakah dapat meningkatkan jumlah hasil dalam suatu
tindakbalas kimia?
A Increase the concentration of the reactant

Meningkatkan kepekatan bahan tindak balas
B Reduce the mass of catalyst
Mengurangkan jisim mangkin
C Increase the size of a solid reactant
Meningkatkan saiz bahan tindakbalas
D Decrease the volume of reactant
Mengurangkan isipadu larutan bahan tindakbalas
18
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39 Diagram 7 shows the energy level diagram of a reaction.

Rajah 7 menunjukkan gambarajah aras tenaga bagi suatu tindak balas
Energy
Tenaga
HNO3 + NaOH
∆H = -57 kJ mol-1
NaNO3 + H2O
Diagram 7
Rajah 7
Which of the following acids is suitable to replace nitric acid, HNO3 to obtain the same ∆H
value?
Asid yang manakah sesuai untuk menggantikan asid nitrik, HNO3 bagi mendapatkan nilai
∆H yang sama?
A Ethanoic acid, CH3COOH
Asid etanoik, CH3COOH
B Hydrochloric acid, HCl
Asid hidroklorik, HCl
C Carbonic acid, H2CO3
Asid karbonik, H2CO3
D Sulphuric acid, H2SO4
Asid sulfurik, H2SO4
40 The following is the thermochemical equation for a reaction.

Berikut adalah persamaan termokimia bagi satu tindak balas.
Zn + CuSO4 ZnSO4 + Cu ∆H = -210 kJ mol-1
Calculate the heat change when 50 cm3 of 1.0 mol dm-3 copper(II) sulphate solution reacts
with excess zinc.
Hitung perubahan haba apabila 50 cm3 larutan kuprum(II) sulfat 1.0 mol dm-3 bertindak
balas dengan zink yang berlebihan.
A 10.5 kJ
B 105 kJ
C 420 kJ
D 4200 kJ
19
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41 Diagram 8 shows the set-up of the apparatus to determine the heat of precipitation of silver
chloride.
Rajah 8 menunjukkan gambar rajah susunan radas untuk menentukan haba pemendakan
bagi argentum klorida.
Thermometer
Termometer
28.0oC 28.0oC
Polystyrene cup
Cawan
Polistirena
+
25 cm3 of 1.0 mol dm-3 50 cm3 of 1.0 mol dm-3 of
of silver nitrate solution sodium chloride solution
25 cm3 larutan argentum 50 cm3 larutan natrium
nitrat 1.0 mol dm-3 klorida 1.0 mol dm-3
Thermometer
Termometer
Stir
31.0oC Kaca
Mixture of the solution

Campuran larutan
White precipitate
Mendakan putih
Diagram 8
Rajah 8
What is the heat of precipitation of silver chloride?

Berapakah haba pemendakan bagi argentum klorida?
[Specific heat capacity of solution = 4.2 Jg-1oC-1, density of solution = 1 g cm-3]
[Muatan haba tentu larutan = 4.2 Jg-1oC-1, ketumpatan larutan = 1 g cm-3]
A 37800 kJ mol-1
B 18900 kJ mol-1
C 18.9 kJ mol-1
D 37.8 kJ mol-1
20
SULIT 4541/1
42 The following equation shows the reaction between excess zinc powder and dilute
hydrochloric acid:
Persamaan berikut menunjukkan tindak balas antara serbuk zink berlebihan
dengan asid hidroklorik cair:
Zn + 2HCl  ZnCl2 + H2
Which of the following graphs represents the volume of hydrogen gas (V) released
against time (t)?
Antara graf berikut yang manakah mewakili isipadu gas hidrogen (V) yang
dibebaskan melawan masa (t)?
21
SULIT 4541/1
43 Diagram 9 shows the set-up of apparatus used to study the rate of reaction of
marble chips and nitric acid.
Rajah 9 menunjukkan susunan radas yang digunakan untuk mengkaji kadar tindak
balas antara ketulan marmar dengan asid nitrik
Diagram 9
Rajah 9
.
The rate of reaction in this experiment can be increased by

Kadar tindak balas bagi eksperimen ini boleh ditingkatkan dengan
A using the smaller sizes of marble chips

menggunakan saiz ketulan marmar yang lebih kecil
B using a larger conical flask.
menggunakan kelalang kon yang lebih besar
C adding water to the nitric acid.
menambahkan air ke dalam asid nitrik
D decreasing the temperature of the nitric acid
merendahkan suhu asid nitrik
44 Effective collision is the collision where

Perlanggaran berkesan ialah perlanggaran yang
A its energy is less than the activation energy and with correct orientation
tenaganya kurang daripada tenaga pengaktifan dan dalam orientasi yang
betul.
B has a low energy
mempunyai tenaga yang rendah
C its energy is equal to the activation energy
tenaganya sama dengan dengan tenaga pengaktifan
D its energy is greater than the activation energy with the correct orientation
tenaganya lebih besar daripada tenaga pengaktifan dan dalam orientasi yang
betul
22
SULIT 4541/1
45 Excess zinc granules are added to 50 cm3 of 0.1 mol dm-3 hydrochloric acid. The
hydrogen gas evolved is collected at 30 second intervals. The results are tabulated in
Table 4.
Butiran zink yang berlebihan ditambahkan kepada 50 cm3 asid hiroklorik 0.1 mol dm-3.
Keputusan dicatatkan di dalam Jadual 4.
Time /s 0 30 60 90 120 150
Masa/s
Total volume of H2 /cm3 0 11 18 22 24 24
Jumlah isipadu H2 /cm3
Table 4
Jadual 4
What information can you obtain from the results of this experiment?
Apakah maklumat yang boleh diperolehi daripada keputusan eksperimen ini?
I No hydrogen gas is released after 120 seconds

Tiada gas hidrogen dibebaskan selepas 120 saat
II The average rate of reaction is 0.16 cm3 s-1
Purata kadar tindak balas ialah 0.16 cm3 s-1
III The total volume of hydrogen gas collected is 99 cm3
Jumlah isipadu gas yang terkumpul ialah 99 cm3
IV The rate of hydrogen gas released decreases with time
Kadar pembebasan gas berkurang dengan masa
A IV only
B I and IV
C I, II and IV
D I, III and IV
46 The following chemical equation shows a reaction for ethanol.

Persamaan kimia berikut menunjukkan satu tindak balas bagi etanol .
C2H5OH → C2H4 + H2O

What is the name of the reaction?
Apakah nama bagi tindak balas itu?
A Oxidation
Pengoksidaan
B Reduction
Penurunan
C Dehydration
Pendehidratan
D Fermentation
Penapaian
23
SULIT 4541/1
47 Hexene is classified as an unsaturated hydrocarbon because

Heksena dikelaskan sebagai hidrokarbon tidak tepu kerana
A it contains only carbon and hydrogen .
ia mengandungi karbon dan hidrogen sahaja.
B it is a liquid at room temperature.
ia adalah cecair pada suhu bilik.
C it is less dense than water.
ia kurang tumpat daripada air
D it has a double bond between carbon atoms.
ia mempunyai ikatan ganda dua di antara atom karbon
48 Diagram 10 shows the structural formula of a compound.

Rajah 10 menunjukkan formula struktur bagi suatu sebatian..
Diagram 10
Rajah 10
Name the compound using IUPAC nomenclature.
Namakan sebatian tersebut menggunakan penamaan IUPAC.
A 2,4-dimethylhexane
2,4-dimetilheksana
B 3,5-dimethylhexane
3,5-dimetilheksana
C 1,1,3-trimethylpentane
1,1,3-trimetilpentana
D 3,5,5-trimethylpentane
3,5,5-trimetilpentana
24
SULIT 4541/1
49 Which chemical formulae represent saturated hydrocarbon?

Formula kimia yang manakah mewakili hidrokarbon tepu?
I CH3CH(CH3)CH3
II CH3CH2CH2CH3
III CH2CHCH2CH3
IV CH3CHCHCH3
A I and II
I dan II
B I and III
I dan III
C II and III
II dan III
D II and IV
II dan IV
50 The molecular formulae of two molecules P and Q are as follows.

Formula molekul bagi molekul P dan Q adalah seperti berikut
CH3CH2OH CH3CH2CH2OH
P Q
Which of the following statements is true for both molecules P and Q?

Di antara pernyataan berikut yang manakah benar bagi kedua – dua molekul P
dan Q?
A They have different functional groups

Kedua – duanya mempunyai kumpulan berfungsi yang berlainan
B All their physical properties are similar
Semua sifat fiziknya sama
C All their chemical properties are different
Semua sifat kimianya berbeza
D They can be represented by the same general formula
Kedua – duanya boleh diwakili oleh satu formula am yang sama
END OF QUESTION PAPER

KERTAS SOALAN TAMAT
25
SULIT Nama
4541/2
Chemistry Tingkatan
Kertas 2
September
2 ½ jam
DENGAN KERJASAMA
____________________________________________________________
CHEMISTRY
Kertas 2
Dua jam tiga puluh minit
1. Kertas soalan ini mengandungi tiga bahagian: Untuk kegunaan pemeriksa

Bahagian A, Bahagian B and Bahagian C. Bahagian No. Markah
2. Jawab semua soalan dalam Bahagian A. Tulis 1
jawapan dalam Bahagian A dalam ruangan yang
2
disediakan..
3. Jawab satu soalan dalam Bahagian B dan satu 3
soalan dalan Bahagian C. Jawab saoalan dalam A 4
Bahagian B dan Bahagian C dengan terperinci. 5
Anda boleh menggunakan persamaan kimia, rajah, 6
jadual, graf dan kaedah yang bersesuaian untuk Jumlah
menerangkan jawapan anda. 7
4. Tunjukkan jalan kerja. Ia dapat membantu anda B 8
mendapat markah.
Jumlah
5. Rajah dalam soalan tidak dilukis mengikut skala.
6. Markah yang diperuntukkan bagi setiap soalan 9
ditunjukkan dalam kurungan. C 10
7. Anda boleh menggunakan kalkulator saintifik yang Jumlah
tidak diprogramkan. Jumlah Markah
8. Serahkan kertas jawapan pada akhir waktu
peperiksaan.
Kertas soalan ini mengandungi 24 halaman bercetak

[Lihat halaman sebelah
SULIT 2 4541/2

1. This question paper consists of three sections: Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan Bahagian C.
2. Answer all questions in Section A. Write your answers for Section A in the spaces
provided in the question paper.
Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam ruang
yang disediakan dalam kertas soalan.
3. Answer one question from Section B and one question from Section C.
Write your answers for Section B and Section C on the `writing paper’ (examination
pad)
Answer questions in Section B and Section C in detail.
You may use equations, diagrams, tables, graphs and other suitable methods to
explain your answer.
Jawab satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan
jawapan bagi Bahagian B dan Bahagian C pada kertas tulis (kertas jawapan). Jawab
Bahagian B dan Bahagian C dengan terperinci. Anda boleh menggunakan persamaan,
gambar rajah, jadual, graf dan cara lain yang sesuai untuk menjelaskan jawapan anda.
4. Show your working. It may help you to get marks.

Tunjukkan kerja mengira.Ini membantu anda mendapatkan markah.
5. If you wish to change your answer, neatly cross out the answer that you have done.
Then write down the new answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
6. The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.
7. Marks allocated for each question or part question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam
kurungan.
8. The time suggested to answer Section A is 90 minutes, Section B is 30 minutes and

Section C is 30 minutes.
Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B ialah 30
minit dan Bahagian C ialah 30 minit.

Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.
10. Hand in your answer sheets at the end of the examination.

Serahkan semua kertas jawapan anda di akhir peperiksaan.
SULIT 3 4541/2
Section A
Bahagian A
[ 60 marks ]
[ 60 markah ]
Answer all questions in this section

Jawab semua soalan dalam bahagian ini.
1 Table 1.1 shows the proton number and nucleon number of atom for the elements
carbon, oxygen, magnesium and sulphur.
Jadual 1.1 menunjukkan nombor proton dan nombor nukleon bagi atom unsur
karbon, oksigen, magnesium dan sulfur.
Elements Carbon Oxygen Magnesium Sulphur

Unsur Karbon Oksigen Magnesium Sulfur
Proton number
6 8 12 16
Nombor proton
Nucleon number
12 16 24 32
Nombor nukleon
Table 1.1
Jadual 1.1
(a) What is meant by proton number ? 1(a)

Apakah yang dimaksudkan dengan nombor proton ?
1(a)(ii)
............................................................................................................................... 1
[1 mark]
(b) State the type of particles consists in magnesium metal. 1(b)

Nyatakan jenis zarah yang terdapat dalam logam magnesium.
…………………………………………………………………………………… 1
[1 mark]
(c) (i) Write the electron arrangement for sulphur atom . 1(c)(i)
Tuliskan susunan elektron bagi atom sulfur.
1(a)(
1
……………………………………………………………………………...
[1 mark]
(ii) State the valence electron for sulphur atom. 1(c)(ii)
Nyatakan elektron valen bagi atom sulfur.
1
……………………………………………………………………………...
[1 mark]
SULIT 4 4541/2
(d) Carbon-12 and Carbon-14 are the isotopes of carbon.

Karbon-12 dan Karbon-14 adalah isotop karbon.
(i) What is meant by isotopes ? 1(d)(i)
Apakah yang dimaksudkan dengan isotop ?
1
.......................................................................................................................
[1 mark]
(ii) State the use of carbon-14 in archeology field.
Nyatakan kegunaan karbon-14 dalam bidang arkeologi 1(d)(ii)
……………………………………………………………………………...
[1 mark] 1
(e) Figure 1.1 shows the set-up of apparatus to study the heating of copper(II)
carbonate.
Rajah 1.1 menunjukkan susunan radas bagi mengkaji pemanasan
kuprum(II) karbonat.
Copper(II)
carbonate
Kuprum(II)
karbonat
Heat
Panaskan
Figure 1.1
Rajah 1.1
(i) Complete the set-up of apparatus in Figure 1.1 to test the gas liberated 1(e)(i)
when copper(II) carbonate is heated.
Lengkapkan susunan radas dalam Rajah 1.1 bagaimana menguji gas
2
yang terbebas apabila kuprum(II) karbonat dipanaskan
[2 marks]
(ii) Write the chemical equation for the reaction that takes place. 1(e)(ii)
Tuliskan persamaan kimia bagi tindak balas yang berlaku.
2
……………………………………………………………………………...
[2 marks]
Total A1
10
SULIT 5 4541/2
2 Diagram 2.1 shows part of the Periodic Table of the Elements.

Rajah 2.1 menunjukkan sebahagian Jadual Berkala Unsur.
1 18
2 13 14 15 16 17
A B C
D E F
G H
Diagram 2.1
Rajah 2.1
A, B, C, D, E , F , G and H are not the actual symbols of the elements.

A, B, C, D, E , F , G dan H bukan simbol sebenar bagi unsur.
Use these letters to answer the following questions.

Gunakan huruf-huruf ini bagi menjawab soalan yang berikut.
(a) (i) State which two elements have similar chemical properties.
Nyatakan dua unsur yang mempunyai sifat kimia yang serupa. 2(a)(i)
………………………………………………………………………………...
1
[1 mark]
(ii) Explain your answer in (a)(i).
Terangkan jawapan anda di (a)(i). 2(a)(ii)
……………………………………………………………………………….
1
[1 mark
(b) Which element forms an amphoteric oxide ? 2(b)
Unsur yang manakah menghasilkan oksida amfoterik?
1
………………………………………………………………………………...........
[1 mark]
(c) (i) Which element is chemically unreactive ?
Unsur yang manakah adalah lengai secara kimia? 2(c)(i)
…………………………………………………………………………………
[1 mark] 1
SULIT 6 4541/2
(ii) Give a reason for your answer in (c)(i).
Berikan satu sebab bagi jawapan anda di (c)(i).
2(c)(ii)
……………………………………………………………………………….
[1 mark]
1
(d) Arrange the elements A, B, C, D, E and F in the order of increasing atomic size.
Susunkan unsur-unsur A, B, C, D, E, dan F mengikut tertib saiz atom menaik.
2(d)
……………………………………………………………………………………...
1
[1 mark]
(e) (i) State one physical property of the compound formed when A reacts with F.
Nyatakan satu sifat fizik bagi sebatian yang terbentuk apabila A bertindak 2(e)(i)
balas dengan F.
………………………………………………………………………………… 1
[1 mark]
(ii) Draw the electron arrangement of the compound formed in(e)(i).

Lukiskan susunan elektron bagi sebatian yang terbentuk di (e)(i).
2(e)(ii)
[2 marks]
2
(iii) Name the type of chemical bond formed in the compound.

Namakan jenis ikatan kimia yang terbentuk dalam sebatian ini. 2(e)(iii)
…………………………………………………………………………………
1
[1 mark ]
Total A2
10
SULIT 7 4541/2
3 Table 3.1 shows the results of two tests done to hydrogen chloride in solvent X and
solvent Y.
Jadual 3.1 menunjukkan keputusan bagi dua ujian yang dijalankan ke atas hidrogen
klorida di dalam pelarut X dan pelarut Y.
Hydrogen chloride in
Test Hydrogen klorida dalam
Ujian Solvent X Solvent Y
Pelarut X Pelarut Y
A small piece of marble chip is No change Effervescence
added into hydrogen chloride Tiada perubahan occurs. A
Ketulan kecil marmar di colourless gas is
tambahkan ke dalam hidrogen liberated
klorida Pembuakan
berlaku. Gas tidak
berwarna
dibebaskan.
Reaction with blue litmus paper No change The colour of blue
Tindakbalas dengan kertas Tiada perubahan litmus paper turns
litmus biru red.
Warna kertas
litmus biru
bertukar merah
Table 3.1
(a) Name the type of particles of hydrogen chloride found in
Namakan zarah hidrogen klorida yang terdapat dalam
(i) Solvent X: (a)(i)

PelarutX : ………………………………………………………..................
[1 mark]
1
(ii) Solvent Y (a)(ii)

PelarutY :.......................................................................................................
[1 mark]
1
(b) Suggest a name for solvent Y. (b)

Cadangkan nama bagi larutan Y.
1
..................................................................................................................................
[1 mark]
SULIT 8 4541/2
(c) Explain why hydrogen chloride in solvent Y produce colourless gas while no
change is observed when hydrogen chloride is in solvent X.
Terangkan mengapa hidrogen klorida dalam pelarut Y menghasilkan gas tanpa
warna manakala tiada perubahan diperhatikan apabila hidrogen klorida dalam
pelarut X. (c)
..................................................................................................................................
2
..................................................................................................................................
[2 marks]
(d) Flow chart in diagram 3.2 shows a series of chemical changes of salt Q .
Carta alir dalam rajah3.2 menunjukkan siri perubahan kimia garam Q
Salt Q
Garam Q
Heated /
dipanaskan
Solid U + nitrogen dioxide + oxygen

(Solid U is yellow when hot, white when cold)
Pepejal U + nitrogen dioksida + oksigen

(Pepejal U berwarna kuning bila panas, putih bila sejuk)
Add dilute sulphuric acid

Tambah asid sulfurik cair
Solution Z
Larutan Z
Diagram 3.2
Rajah 3.2
(i) Name solid U. (d)(i)
Namakan pepejal U.
.....…………………………………………………………………………... 1
[1mark]
SULIT 9 4541/2
(ii) Write the chemical equation to represent the reaction when salt Q is heated
Tuliskan persamaan kimia bagi mewakili tindak balas pemanasan d(ii)
garam Q
………………………………………………………………………………
2
[2 marks]
(e) Solution Z is produced when solid U is reacted with dilute sulphuric acid.
Larutan Z terhasil apabila pepejal U bertindakbalas dengan asid sulfurik cair.
Describe the confirmatory test for the cation presents in solution Z.

Huraikan ujian pengesahan bagi kation yang hadir dalam larutan Z.
d(ii)
..................................................................................................................................
(e)
..................................................................................................................................
..................................................................................................................................
2
[2 marks]
Total A3
10
SULIT 10 4541/2
4 Diagram 4.1 shows the set-up of apparatus for two types of cells.
Rajah 4.1 menunjukkan susunan radas bagi dua jenis sel.
salt bridge
silver titian garam
zinc
argentum zink
silver nitrate zinc sulphate

argentum nitrat zink sulfat
Beaker 1 Beaker 2
Bikar 1 Bikar 2
Cell 1
Sel 1
carbon
karbon
copper(II) sulphate
kuprum(II) sulfat
Cell 2
Sel 2
Diagram 4.1
Rajah 4.1
(a) Name the type of cells in cell 1 and cell 2.

Namakan jenis bagi Sel 1 dan Sel 2. 4(a)
1(a)(ii)
Cell 1 : Cell 2 :
2
Sel 1: …………………………….. Sel 2 : …………………………………
[ 2 marks]
(b) State the energy change that takes place in cell 2. 4(b)
Nyatakan perubahan tenaga yang berlaku dalam sel 2.
1
…………………………………………………………………………………...
[1 mark]
SULIT 11 4541/2
(c) (i) State the product formed at the negative terminal of Cell 1.
Nyatakan hasil yang terbentuk di terminal negatif Sel 1.
4(c)(i)
………………………………………………………………………………….
[1 mark] 1
(ii) Write the half equation for the reaction at the negative terminal.
Tuliskan persamaan setengah bagi tindak balas berlaku di terminal negatif . 4(c)(ii)
………………………………………………………………………………….
1
[ 1 mark]
(d) Draw the direction of the flow of electron in Cell 1 in the diagram above. 4(d)
Lukiskan arah pengaliran elektron pada Sel 1 dalam rajah di atas.
[ 1 mark]
1
(e) State all the ions present in the electrolyte in Cell 2.

Nyatakan semua ion yang hadir di dalam elektrolit Sel 2 . 4(e)
………………………………………………………………………………. . .
1
[ 1 mark]
(f) The circuit in Cell 2 is completed and the current is allowed to flow for 10
minutes.
Litar di dalam Sel 2 dilengkapkan dan arus elektrik dibenarkan mengalir selama
10 minit. 4(f)(i)
(i) State the observation at the cathode of this cell.
Nyatakan pemerhatian pada katod sel ini.
1
…………………………………………………………………………………
[ 1 mark]
(ii) Explain your answer in f(i) above.

Terangkan jawapan anda di f(i) di atas. 4(f) (ii)
……………………………………………………………………………
[ 1 mark] 1
SULIT 12 4541/2
(g) What is the difference between Cell 1 and Cell 2 in terms of their structures?
Apakah perbezaan struktur yang terdapat pada Sel 1 dan Sel 2?
4(g)
………………………………………………………………………………………
1
………………………………………………………………………………………
[ 1 mark]
Total A4
10
SULIT 13 4541/2
5 (a) Table 5.1 shows the stages and reactions in the manufacture of sulphuric acid in
industry.
Jadual 5.1 menunjukkan peringkat dan tindak balas dalam pembuatan asid sulfurik
secara industri.
Stage Reactions
Peringkat Tindak balas
1 S + O2 → SO2
Cataylst X
Mangkin X
2
……… + ………. 2SO3
3 SO3 + H2SO4 → H2S2O7

4 H2S2O7 + H2O → 2 H2SO4
Table 5.1
Jadual 5.1
(i) Name the process to manufacture sulphuric acid.

Namakan proses pembuatan asid sulfurik. 5(a)(i)
…………………………………………………………………………………...
[1 mark] 1
(ii) Complete the chemical equation in stage 2.

Lengkapkan persamaan kimia dalam peringkat 2. 5(a)(ii)
[2 marks]
2
(iii) Name the catalyst X used for the reaction in stage 2 .

Namakan mangkin X yang digunakan dalam tindak balas peringkat 2. 5(a)(iii)
...............................................................................................................................
1
[1 mark]
(iv) State one use of sulphuric acid.

Nyatakan satu kegunaan asid sulfurik. 5(a)(iv)
...............................................................................................................................
1
[1 mark]
SULIT 14 4541/2
(b) The equation below shows how a cleaning agent X can be prepared.
Persamaan di bawah menunjukkan bagaimana agen pencuci X disediakan
Palm oil + Sodium hydroxide  cleaning agent X + Glycerol

Minyak sawit + Natrium hidroksida  agen pencuci X + Gliserol
(i) What is the name of this reaction ?

Apakah nama tindakbalas ini ? 5(b)(i)
…………………………………………………………………………………..
1
[1 mark]
(ii) State the name of cleaning agent X. 5(b)(ii)
Nyatakan nama agen pencuci X.
…………………………………………………………………………………... 1
[1 mark]
(iii) Sodium chloride is added to the mixture to complete the preparation of the
cleaning agent X. Explain why. 5(b)(iii)
Natrium klorida ditambahkan ke dalam campuran untuk melengkapkan
penyediaan agen pencuci X. Terangkan mengapa.
1
…………………………………………………………………………………...
[1 mark]
(iv) Two cleaning agents, J and K, are used to wash clothes in sea water and tap
water. Table 6.2 shows the result obtained.
Dua agen pencuci , J dan K digunakan untuk mencuci kain dalam air laut dan
air paip. Jadual 6.2 menunjukkan keputusan yang diperolehi
Cleaning agent Sea water Tap water
Agen pencuci Air laut Air paip
Forms scum Does not form scum
J
Skum terbentuk Skum tidak terbentuk
Does not form scum Does not form scum
K
Skum tidak terbentuk Skum tidak terbentuk
State the type of cleaning agents J and K.

Nyatakan jenis agen pencuci J dan K.
5(b)(iv)
J: ………………………………………………………………………………
2
K: ………………………………………………………………………………
[2 marks]
Total A5
10
SULIT 15 4541/2
6 Diagram 6.1 shows the flow chart of a series of conversion of compounds starting
from propene.
Rajah 6.1 menunjukkan carta alir bagi suatu siri penukaran sebatian bermula dari
propena.
Process I Process II
Propene Alcohol P Substance Q
Propena Alkohol P Bahan Q
C3H6 Process IV Ethanoic acid
Asid Etanoik
acidified potassium dichromate (VI)
Process III catalyst T
Kalium dikromat(VI) berasid
Mangkin T
Substance R, C2H5COOH
Bahan R, C2H5COOH
Diagram 6.1
Rajah 6.1
Based on Diagram 6.1, answer the following questions:
Berdasarkan Rajah 6.1,jawab soalan berikut:
(a) Name alcohol P. 6(a)

Namakan alkohol P.
............................................................................................................................... 1
[1 mark]
(b) Write a chemical equation for the conversion reaction in Process I.

Tuliskan persamaan kimia untuk tindakbalas yang berlaku dalam Proses I. 6(b)
...........................................................................................................................
[1 mark] 1
SULIT 16 4541/2
(c) Alcohol P undergoes Process IV to form propene.

Alkohol P menjalani Proses IV untuk membentuk propena.
(i) Name Process IV.

Namakan Proses IV. 6(c)(i)
.......................................................................................................................
[1 mark] 1
(ii) Draw a labelled diagram to show how Process IV can be carried out in the
laboratory.
Lukiskan gambarajah berlabel bagaimana Proses IV dapat dijalankan di
dalam makmal.
6(c)(ii)
[2 marks] 2
(d) (i) What is the role of acidified potassium dichromate (VI) solution in
Process III? 6(d)(i)
Apakah peranan larutan kalium dikromat(VI) berasid dalam Proses III?.
....................................................................................................................... 1
[1 marks]
(ii) Name the type of reaction that has taken place in Process III
Namakan jenis tindakbalas yang berlaku dalam Proses III. 6(d)(ii)
.......................................................................................................................
[1 mark] 1
(iii) State the observation that occurs in Process III.

Nyatakan pemerhatian yang diperolehi dalam Proses III. 6(d)(iii)
.......................................................................................................................
1
[1 mark]
SULIT 17 4541/2
(e) Substance Q is produced when alcohol P is reacted with ethanoic acid in the
presence of concentrated sulphuric acid in Process II .
Bahan Q dihasilkan apabila alkohol P bertindak balas dengan etanoik asid
dalam kehadiran asid sulfurik pekat dalam Proses II.
(i) Name the reaction that takes place in Process II.
Namakan tindak balas yang berlaku dalam Proses II. 6(e)(i)
.......................................................................................................................
[1 mark] 1
(ii) Write the chemical formula for substance Q.

Tuliskan formula kimia bagi Q. 6(e)(ii)
.......................................................................................................................
[1 mark] 1
Total A6
10
SULIT 18 4541/2
Section B
[20 marks]
Answer any one question.

The time suggested to answer this section is 30 minutes.
7 Table 7.1 shows the data obtained in an experiment to investigate the effect of
concentration of sodium thiosulphate solution on the rate of reaction when reacted with
an acid
Jadual 7.1 menunjukkan data yang diperolehi daripada satu eksperimen yang dijalankan
untuk mengkaji kesan kepekatan larutan natrium tiosulfat ke atas kadar tindak balas
apabila bertindak balas dengan asid
Experiment 1 2 3 4 5 6
Eksperimen
Concentration of sodium 0.20 0.16 0.12 0.08 0.04 0.02
thiosulphate solution / mol dm -3
Kepekatan larutan natrium
tiosulfat / mol dm -3
Time for ‘X’ to disappear from 17 21 30 45 80 100
sight / s
Masa untuk tanda ‘X ’ tidak
kelihatan / s
Table 7.1
Jadual 7.1
(a) (i) What is meant by ‘rate of reaction’ in this experiment?
Apakah yang dimaksudkan dengan kadar tindak balas di dalam eksperimen ini?
(ii) Name the precipitate formed in the reaction.

Namakan mendakan yang terbentuk dalam tindak balas yang berlaku.
(iii) Write the ionic equation for the reaction in (a)(ii).

Tuliskan persamaan ion bagi tindak balas di (a)(ii).
[3 marks]
(b) (i) Plot the graph of concentration of sodium thiosulphate solution against time
on a piece of graph paper.
Lukiskan graf kepekatan larutan natrium tiosulfat melawan masa di atas kertas
graf.
[3 marks]
SULIT 19 4541/2
(ii) Based on the graph obtained and using the collision theory, explain how
concentration of sodium thiosulphate solution affects the rate of reaction.
Berdasarkan graf yang diperolehi dan menggunakan teori perlanggaran ,
terangkan bagaimana kepekatan larutan natrium tiosulfat mempengaruhi kadar
tindak balas.
[5 marks]
(c) (i) State three characteristics of catalysts.
Nyatakan tiga ciri bagi mangkin.
(ii) Name two examples of catalysts and the reactions that are catalysed by them.
Namakan dua contoh mangkin dan tindak balas yang dimangkinkan oleh
mangkin-mangkin tersebut.
(iii) Sketch an energy profile diagram of an exothermic reaction showing the effect of
catalyst on the activation energy.
Lakarkan gambar rajah profil tenaga bagi suatu tindak balas eksotermik yang
menunjukkan kesan mangkin ke atas tenaga pengaktifan.
[9 marks]
8 (a) Table 8.1 shows some of the physical properties of group 17 elements.
Jadual 8.1 menunjukkan sebahagian daripada sifat fizik unsur kumpulan 17.
Group 17 Physical Properties

Elements Sifat Fizik
Unsur Kumpulan Electronegativity Melting Boiling Densities /
17 Keelektronegatifan Points / oC Points /oC gcm-3
Takat Takat Ketumpatan/
Lebur /oC Didih/ oC gcm-3
Flourine 4.0 -220 -188 0.0017
Flourin
Chlorine 3.0 -101 -35 0.0032
Klorin
Bromine 2.8 -7 59 3.13
Bromin
Iodine 2.5 114 184 4.94
Iodin
Table 8.1
Jadual 8.1
(i) By referring to the table, explain the trend of change in the physical properties of
the group 17 elements as we down the group in the Periodic Table.
Dengan merujuk kepada jadual ini, terangkan pola perubahan sifat fizik unsur-
unsur kumpulan 17 apabila kita menuruni kumpulan ini dalam Jadual Berkala.
[10 marks]
SULIT 20 4541/2
(ii) Compare the reactivity of the reactions of chlorine, bromine and iodine when
heated with iron. Give the observations for these reactions.
Bandingkan kereaktifan tindak balas klorin, bromin dan iodin dengan besi.
Berikan pemerhatian bagi tindak balas-tindak balas ini.
[ 4 marks]
(b) The statement below refers to the reaction of chlorine with sodium.
Pernyatan di bawah merujuk kepada tindak balas klorin dengan natrium .
When heated, sodium reacts rapidly with chlorine to form

sodium chloride compound
Apabila dipanaskan, natrium bertindak balas secara pantas dengan

klorin menghasilkan sebatian natrium klorida
Based on the above statement,

Berdasarkan pernyataan di atas ,
(i) Name the type of chemical bond formed in this compound.

Namakan jenis ikatan kimia yang terbentuk di dalam sebatian ini.
(ii) Draw the electron arrangement of the formation for this compound.
Lukiskan susunan elektron bagi pembentukan sebatian ini.
(iii) Predict the electrical conductivity of this compound in the solid and molten
state and give reasons for your prediction.
[ Proton Number : Na ; 11 , Chlorine ; 17 ]
Ramalkan kekonduksian elektrik sebatian ini dalam keadaan pepejal dan
leburan dan berikan sebab-sebab bagi ramalan anda.
[ Nombor Proton : Na ; 11, Klorin : 17]
[6 marks]
SULIT 21 4541/2
Section C
[20 marks]

9 (a) (i) What is meant by salt?

Apakah yang dimaksudkan dengan garam?
[1 mark]
The table shows the names for two type of salts.
Jadual berikut menunjukkan nama bagi dua jenis garam.
Lead(II) chloride Copper(II) sulphate

Plumbum(II) klorida Kuprum(II) sulfat
(ii) Which of the salts given is an insoluble salt?

Name the reaction used to prepare insoluble salt.
Di antara garam yang diberikan di atas, yang mana merupakan garam yang tak
terlarutkan?
Namakan tindak balas bagi menyediakan garam yang tak terlarutkan.
[2 marks]
(iii) Describe how you would prepare the insoluble salt above in the laboratory. In
your answer, write the ionic equation to represent the reaction.
Huraikan bagaimana anda boleh menyediakan garam tak terlarutkan yang
disebutkan di atas dalam makmal. Dalam jawapan anda, tuliskan persamaan ion
bagi mewakili tindakbalas tersebut.
[7 marks]
(b) You are given solid potassium chloride salt. Describe how you would prepare
potassium chloride solution of concentration 0.5 mol dm-3 using a 250 cm3 volumetric
flask in laboratory
[Relative atomic mass ; K= 39 , Cl = 35.5]
Anda diberikan pepejal garam kalium klorida. Huraikan bagaimana anda boleh
menyediakan larutan kalium klorida dengan kepekatan 0.5 mol dm-3 menggunakan
kelalang volumetrik berisipadu 250 cm3 di dalam makmal
[Jisim atom relatif ; K=39, Cl = 35.5]
[10 marks]
SULIT 22 4541/2
10 (a) What is meant by heat of neutralisation?

Apakah yang dimaksudkan dengan haba peneutralan?
[2 marks]
(b) Two experiments were carried out to determine heat of neutralisation between two
different acids and an alkali. Table 10.1 shows the results of the experiments.
Dua experimen telah dijalankan untuk menentukan haba peneutralan antara dua asid
yang berbeza dan suatu alkali. Jadual 10.1 menunjukkan keputusan eksperimen
tersebut
( Specific heat capacity of water; 4.2 J g-1 oC-1 ; Density of water : 1 g cm-3)
(Muatan haba tentu air; 4.2 J g-1 oC-1 ; Ketumpatan air : 1 g cm-3)
Experiment Substance Volume Concentration Heat of

Eksperimen Bahan Isipadu Kepekatan neutralisation,
/ cm3 / mol dm-3 Haba
Peneutralan,
∆H (kJ/mol)
Hydrochloric
acid
25.0 2.0
Asid
hidroklorik
I Sodium -57
hydroxide
25.0 2.0
Natrium
hidroksida
Ethanoic acid
Asid etanoik
25.0 2.0
II
-55
Sodium
hydroxide
25.0 2.0
Natrium
hidroksida
Table 10.1
Jadual 10.1
SULIT 23 4541/2
(i) Write a chemical equation for the reaction in experiment I .

Tuliskan persamaan kimia bagi tindak balas dalam eksperimen 1.
[2 marks]
(ii) Calculate the heat change in experiment I .

Hitungkan perubahan haba dalam eksperimen I.
[2 marks]
(iii) Draw an energy level diagram for experiment I .
Lukiskan gambarajah aras tenaga bagi eksperimen 1.
[2 marks]
(iv) Based on the data provided in Table 10.1, explain why heat of neutralisation for
Experiment II is lower than in Experiment I.
Berdasarkan data dalam Jadual 10.1, terangkan mengapa haba peneutralan
bagi eksperimen II lebih rendah berbanding eksperimen 1.
[2 marks]
(c) Describe a laboratory experiment to determine the heat of neutralisation between

ethanoic acid and sodium hydroxide. Your answer should contain of the following:
Huraikan satu eksperimen makmal bagi menentukan haba peneutralan antara asid
etanoik dengan natrium hidroksida. Jawapan anda mestilah mengandungi perkara
berikut:
 List of materials and apparatus

Senarai bahan dan radas
 Procedures of the experiment
Kaedah eksperimen
 Precautionary steps
Langkah berjaga-jaga
[10 marks]

KERTAS SOALAN TAMAT
PERIODIC TABLE OF ELEMENTS
1 18
SULIT
1 11  Proton Number 2
 Symbol of
H Na Elements He
Hydrogen 2 Sodium  Name of the element 13 14 15 16 17 Helium
1 23  Relative atomic mass 4
3 4 5 6 7 8 9 10
Li Be B C N O F Ne
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
7 9
3 4 5 6 7 8 9 10 11 12 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Transition Al Si S Cl Ar
Mg Elements
P
Sodium Magnesium Aluminum Silicon Phosphorus Sulfur Chlorine Argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 26 27 28 29 30 31 32 33 34 35 36
25
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Germaniu
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Kobalt Nickel Copper Zinc Gallium Arsenic Se len iu m Bromine Krypton
m
39 40 45 48 51 52 55 56 59 59 64 65 70 75 79 80 84
73
45
37 38 39 40 41 42 43* 44 46 47 48 49 50 51 52 53 54
24
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Rhodiu
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Pa ll adi um Silver Cad miu m Indium Tin Antimony Tellurium Iodine Xenon
88 91 96 98 101 m 106 112 122 128
85.5 89 93 108 115 119 127 131
103
55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
Cesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Po lon iu m Astatine Radon
144 137 139 178.5 181 184 186 190 192 195 197 201 204 207 209 210 210 222
87 88 89 105* 107* 109*

104* 106* 108*
Fr Ra Ac *Unq *Unp *Unh *Uns *Uno *Une
Francium Radium Actinium
223 226 227
* - Not exist naturally
* - elements not yet discovered
59 62 63 64 67
58 60 61* 65 66 68 69 70 71
Lanthanide Series Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
4541/2
Praseodimiu Samariu Europiu Gadoliniu Holmiu

Cerium Neodymium Promethium Terbium Dysprosium Erbium Tulium Ytterbium Lutetium
m m m m m
140 144 147 159 162.5 167 169 173 175
141 150 152 157 165
90 91 92 93* 94* 95* 96* 97* 98* 100* 102* 103*
99* 101*
Actinide Series Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
Lawrenciu
Thorium Protactinium Uranium Neptunium Plutonium Americium Kurium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium
m
232 231 238 237 242 243 247 247 251 254 253 256 254 260

Nama
4541/3
Chemistry 33
Kelas
Kertas 3
September
2010
1 ½ jam
DENGAN KERJASAMA
____________________________________________________________
SIJIL PELAJAR AN MALAYSIA 2010
CHEMISTRY
Kertas 3
Satu jam tiga puluh minit
1. Tuliskan nama dan tingkatan pada ruang

yang disediakan. Untuk kegunaan pemeriksa sahaja
Markah Markah
Soalan
2. Kertas soalan ini adalah dalam dwi bahasa. Penuh diperolehi
3. Calon hendaklah membaca arahan pada 1 33

halaman 2 .
2 17
Jumlah 50
4541/3 [ Lihat sebelah

SULIT
2
SULIT
1. This question paper consists of two questions. Answer all questions.

Kertas soalan ini mengandungi dua soalan. Jawab semua soalan.
2. Write your answer for Question 1 in the spaces provided in the question paper.
Tulis jawapan anda bagi Soalan 1 pada ruang yang disediakan dalam kertas soalan ini.
3. Write your answers for Question 2 on the writing paper .

Tulis jawapan anda bagi Soalan 2 pada kertas tulis.
4. You may use equations, diagrams, tables, graph and other suitable methods to explain
your answer.
Anda boleh menggunakan persamaan , rajah, jadual, graf dan cara lain yang sesuai
untuk menjelaskan jawapan anda.
5. Show your working, it may help you to get marks.

Tunjukkan kerja mengira, ini membantu anda mendapatkan markah.
6. If you wish to change your answer, cross out the answer that you have done. Then write
down the new answer.
Jika anda hendak menukar jawapan, batalkan jawapan yang telah dibuat. Kemudian tulis
jawapan yang baru.
kurungan.
8. The time suggested to answer each of the questions is 45 minutes.

Masa yang dicadangkan untuk menjawab setiap soalan ialah 45 minit.

Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogram.

Serahkan kertas jawapan anda di akhir peperiksaan
4541/3 [Lihat sebelah

SULIT
3
SULIT
Answer all question

Jawab semua soalan
1 Table 1 shows the data collected by a student to determine a relationship between the For
Examiner’s
concentration of nitric acid with pH value. 250 cm3 of 0.1 mol dm-3 standard solution is Use
prepared. The acid solution is then diluted to produce four solutions with different

concentrations. pH value for each solution is determined by using pH meter.
Jadual 1 menunjukkan data yang dikumpul oleh seorang pelajar bagi menentukan

hubungan antara kepekatan asid nitrik dengan nilai pH. 250 cm3, 0.1 mol dm-3 larutan
piawai telah disediakan. Larutan asid itu kemudian dicairkan untuk mendapatkan

empat larutan yang berbeza kepekatan. Nilai pH bagi setiap larutan ditentukan

menggunakan meter pH.
Concentration /
mol dm-3 0.1 0.01 0.001 0.0001 0.00001
-3
Kepekatan / mol dm
pH value 1.1 2.2 3.1 4.3 5.1
Nilai pH
Table 1
Jadual 1
(a) Based on data in Table 1, complete the table below.
Berdasarkan data dalam Jadual 1, lengkapkan jadual di bawah.
Variables Action to be taken
Manipulated variable
Method to manipulate variable
Pembolehubah dimanipulasi
Kaedah memanipulasikan pemboleh
ubah
………………………………………... ..............................................................
………………………………………... ………………………………………..
Responding variable What to observe in the responding
Pembolehubah bergerak balas variable
Perkara yang perlu diperhati dalam
………………………………………... pembolehubah bergerak balas
………………………………………... ..............................................................
..............................................................
Constant variable Method to maintain constant variable
Pembolehubah dimalarkan Kaedah untuk menetapkan pemboleh
ubah dimalarkan
………………………………………... ..............................................................
1(a)
………………………………………... ..............................................................
[3 + 3 marks]
6

SULIT
4
SULIT
(b) State the hypothesis for this experiment. For

Examiner’s
Nyatakan hipotesis bagi eksperimen ini. Use
....................................................................................................................................
……………………………………………………………………………………… 1(b)
[3 marks]
3
(c) Predict the concentration of nitric acid solution if the pH value is 6.2
Ramalkan kepekatan larutan asid nitrik jika nilai pH adalah 6.2
………………………………………………………………………………………. 1(c)
[3 marks]
3
(d) Calculate the volume of the standard solution needed to prepare 250cm3 of 0.001
mol dm-3 nitric acid solution.
Hitungkan isipadu larutan piawai yang diperlukan untuk menyediakan 250cm3,
0.001 mol dm-3 larutan asid nitrik.
1(d)
[3 marks]
3
(e) The student then carry out an experiment to determine the end point for
neutralisation reaction between the standard solution of nitric acid and sodium
hydroxide solution. Two drops of phenolphthalein indicator is added to sodium
hydroxide solution in a conical flask. The nitric acid is added carefully from the
burette into the conical flask until the mixture changes in colour. The titration is
repeated three times using the same volume and concentration of sodium
hydroxide solution.
Pelajar tersebut seterusnya menjalankan eksperimen untuk menentukan takat
akhir tindak balas peneutralan antara larutan piawai asid nitrik dan larutan
natrium hidroksida. Dua titis penunjuk fenoftalin ditambah ke dalam kelalang kon
yang berisi larutan natrium hidroksida. Asid nitrik dalam buret ditambahkan ke
dalam kelalang kon sehingga campuran berubah warna. Pentitratan diulang tiga
kali menggunakan isipadu dan kepekatan larutan natrium hidroksida yang sama.

SULIT
5
SULIT
Figure 1 shows the initial and final burette readings for the experiment. For
Examiner’s
Rajah 1 menunjukkan bacaan awal dan bacaan akhir buret bagi eksperimen Use
tersebut.
First titration
Titratan pertama
1 25
2 26
Initial burette reading : Final burette reading :

Bacaan awal buret : Bacaan akhir buret :
………………….. ……………………
Second titration
Titratan kedua
0
24
1 25

………………….. ……………………

SULIT
6
SULIT
Third titration For

Examiner’s
Titratan ketiga Use

2 27
3
28

………………….. ……………………
Figure 1
Rajah 1
Record all the burette readings for the experiment in Figure 1.

Catatkan semua bacaan buret bagi eksperimen tersebut dalam Rajah1. 1 (e)
[3 marks]
3
(f) Construct a table to record the initial burette readings, final burette readings and
the volume of nitric acid used in the experiment.
Bina satu jadual bagi merekodkan bacaan awal buret, bacaan akhir buret dan
isipadu asid nitrik yang digunakan dalam eksperimen tersebut.
1(f)
3
[3 marks]

SULIT
7
SULIT
(g) State the colour change of phenolphthalein in the titration. For

Examiner’s
Nyatakan perubahan warna fenolftalin dalam titratan tersebut. Use
.................................................................................................................................
1(g)
[3 marks]
3
(h) Based on the experiment, give the operational definition for the end point of
neutralization.
Berdasarkan eksperimen, berikan definasi secara operasi bagi takat akhir tindak
balas peneutralan.
.....................................................................................................................................
.....................................................................................................................................
1(h)
....................................................................................................................................
[3 marks]
3
(i) If the nitric acid is replaced with sulphuric acid of the same concentration, it is
found that the volume of the sulphuric acid used in the titration is half of the
volume of nitric acid. Explain why.
Jika asid nitrik digantikan dengan asid sulfurik yang sama kepekatan , didapati
isipadu asid sulfurik yang digunakan dalam titratan adalah separuh daripada
isipadu asid nitrik. Terangkan.
……………………………………………………………………………………….
………………………………………………………………………………………. 1(i)
……………………………………………………………………………………….
[3 marks] 3

SULIT
8
SULIT
(j) Below are some example of acids. For

Examiner’s
Berikut adalah contoh beberapa asid. Use
Sulphuric acid, nitric acid and hydrochloric acid

Asid sulfurik, asid nitrik dan asid hidroklorik
Classify the acids given into monoprotic acid and diprotic acid.
Kelaskan asid yang diberi kepada asid monobes dan asid dwibes.
1(j)
[3 marks] 3
Total
1
33

SULIT
9
SULIT
2 Answer one of the following questions. For

Examiner’s
Jawab satu daripada dua soalan berikut. Use
Question A
Soalan A
Experiment Apparatus arrangement

Eksperimen Susunan radas
Electric current is flow
through the molten lead(II)
bromide.
Arus elektrik dialirkan
menerusi leburan
plumbum(II) bromida.
Electric current is flow

through the molten
sulphur.
Arus elektrik dialirkan
menerusi leburan sulfur.
Based on the information given, plan a laboratory experiment to investigate the

difference in electrical conductivity between an ionic compound and a covalent
compound.
Berdasarkan maklumat yang diberi, rancang satu eksperimen dalam makmal untuk
mengkaji perbezaan sifat kekonduksian elektrik di antara sebatian ionik dan sebatian
kovalen.

SULIT
10
SULIT
For
Examiner’s
Your planning should include the following aspects: Use
Perancangan anda hendaklah mengandungi aspek-aspek berikut:
(a) Problem of statement

Pernyataan masalah
(b) All the variables
Semua pembolehubah
(c) Hypothesis
Hipotesis
(d) List of materials and apparatus
(e) Procedure
Prosedur 2(A)
(f) Tabulation of data
Penjadualan data
[17 marks] 17

SULIT
11
SULIT
Question B For
Examiner’s
Soalan B Use
A more electropositive metal acts as a sacrificial metal which

corrodes itself to protect iron from rusting.
Logam yang lebih elektropositif bertindak sebagai logam korban yang

akan terkakis untuk melindungi besi daripada berkarat.
You are given iron nails, magnesium ribbon and copper strip. Referring to the situation
above, plan a laboratory experiment to investigate the effect of other metals on the
rusting of iron.
Anda diberi paku besi, pita magnesium dan kepingan kuprum. Berdasarkan situasi di
atas, rancang satu eksperimen dalam makmal untuk mengkaji kesan logam lain ke atas
pengaratan besi.
Your planning should include the following aspects:
(a) Statement of problem

Pernyataan masalah
Semua pembolehubah
(c) Hypothesis
Hipotesis
(e) Procedure
Prosedur
Penjadualan data 2(B)
[17 marks]
17
KERTAS SOALAN TAMAT

SULIT
SULIT 4541/1 dan 2

4541/1 dan 2
Chemistry
Mark Scheme
Paper 1 and 2

DENGAN KERJASAMA
____________________________________________________
CHEMISTRY
Mark Scheme
Paper 1 and Paper 2
SET 1
Skema Pemarkahan ini mengandungi 11 halaman bercetak.

ANSWERS FOR CHEMISTRY PAPER 1

(SET 1)
1 B 2 C 3 B 4 A 5 C
6 B 7 A 8 B 9 C 10 A
11 D 12 B 13 B 14 D 15 C
16 C 17 A 18 C 19 D 20 B
21 B 22 D 23 C 24 B 25 A
26 C 27 D 28 B 29 B 30 B
31 C 32 C 33 D 34 A 35 C
36 D 37 A 38 A 39 B 40 A
41 D 42 C 43 A 44 D 45 B
46 C 47 D 48 A 49 A 50 D
SECTION A
1 (a) Number of proton in an atom 1

(b) Atom 1

(c) (i) 2.8.6 1
(ii) 6 1

(d) (i) Atoms of the same element with different numbers of neutrons// 1
Atoms of the same element with different nucleon number //
Atoms that has the same number of proton but different number
of neutron
(ii) Estimate the age of fossils/artefacts 1

(e) (i) 1. Functional diagram 1
2. Labeled CaCO3 1 2

(ii) 1. Correct formula of reactant
2. Correct formula of products
3. Balance the equation
CuCO3 → CuO + CO2 2

Total 10
2 (a) (i) F ,H 1
(ii) They have same valence electron 1
(b) E/Aluminium 1
(c) (i) C 1
(ii) Achieved stable /octate electron arrangement 1
(d) C, B, A, F ,E ,D 1
(e) (i) Low boiling point // insoluble in water// soluble in inorganic solvent// 1
cannot conduct electricity ( any other acceptable physical properties
(ii) [1. correct number of occupied electron shells and correct electrons 1
in each shells for all the atoms, nuclei shown ]
[2. four atoms of F combine covalently (sharing a pair of 1
electrons)with one atom of A ]
(iii) Covalent bond 1

Total 10

3 (a) (i) Molecule 1
(ii) Ions 1
(b) Water 1
(c) 1. In solvent X hydrogen chloride exists as molecules// in solvent Y 1

hydrogen chloride ionize to produce hydrogen ions
2. Hydrogen ions react with marble chips to produce carbon dioxide gas 1 2
(d) (i) Zinc oxide 1
(ii) 1. Correct formula for reactants and products 1

2. Balance the equation 1 2
2Zn(NO3)2 → 2ZnO + 4NO2 + O2
(e) -add sodium hydroxide/ ammonia solution to solution Z until excess 1

-white precipitate soluble in excess sodium hydroxide/ soluble in 1 2
excess ammonia solution
10
4 (a) Cell 1 : Chemical cell /Voltaic cell Cell 2 : Electrolytic Cell 2
(b) Electrical energy to Chemical energy 1

(c) (i) zinc ions 1
(ii) Zn Zn 2+ + 2e 1
(d) [arrow from the zinc electrode to the silver electrode through the external 1
circuit]
(e) Cu2+, SO42-, H+, OH- 1
(f) (i) Brown solid deposited at the cathode 1
(ii) Cu2+ in the electrolyte accepts electron and forms copper atoms 1
(g) 1
Cell1 Cell 2
No dry cells Has dry cells
Electrodes are made up of Electrodes are made up of carbon
different metals Only one electrolyte
Has two different electrolytes No salt bridge
Presence of salt bridge
[ any 1 pair ]
Total 10
5 (a) (i) Contact Process 1
(ii) 1. Correct formula of reactants 1

2. Balance the equation 1 2
2SO2 + O2 → 2SO3
(iii) Vanadium(V) oxide/ Vanadium pentoxide 1
(iv) Any suitable correct uses 1
Manufacture of paint/electrolyte

(b) (i) Saponification 1
(ii) Soap 1
(iii) Reduce solubility of soap in mixture 1
(iv) J : Soap 1
K : Detergent 1 2

Total 10

6 (a) Propanol 1
(b) 1
C3H6 + H2O → C3H7OH
(c) (i) Dehydration 1
(ii) -functional apparatus 1

-labeled diagram : glass wool soaked with alcohol P/ propanol, 1
Porcelain chips, delivery tube, a test tube invert in a basin of water to
collect propene.
(d) (i) Oxidizing agent 1

(ii) Oxidation 1
(iii) Orange to green 1
(e) (i) Esterification 1
(ii) CH3COOC3H7OH 1
10
SECTION B
7 (a) (i) Fixed mass of sulphur produced per time 1

(ii) Sulphur 1
(iii) S2O32- + 2H+ S + SO2 + H2O 1 3
(b) (i) 1. Axis labelled and with units 1

2. Scales appropriate (size: min ¾ of graph paper) and 1
consistent 1 3
3. Points correctly plotted and smooth curve drawn
(ii) 1. As concentration of sodium thiosulphate increases, the 1
time taken for the reaction decreases
2. Increase in concentration of sodium thiosulphate will 1
increase the number of thiosulphate ions/ions per unit
volume 1
3. Frequency of collision between thiosulphate ions and
hydrogen ions increases 1
4. Frequency of effective collision increases 1 5
5. Increase in concentration of sodium thiosulphate
increases the rate of reaction
(c) (i) 1. Only a small amount of catalyst is needed to increase
the rate of reaction.
2. Catalyst remained chemically unchanged
3. Catalyst undergoes physical changes during a chemical
reaction.
4. Catalyst changes only the rate of reaction but not the
amount of product.
5. Catalyst is specific in its reaction
6. Increase the catalyst will increase the rate of reaction
[ Any 3 ] 3
(ii) Catalyst Reaction

Nickel -Manufacture of margarine
-Hydrogenation of alkene to
form alkane
Vanadium (V) oxide -Contact Process / sulphur

dioxide reacts with oxygen to
form sulphur trioxide
[ or any correct examples of 2+2

catalysts and their responding
reactions]
(iii) 1. Y-axis labelled energy , X-axis labelled progress of 1

reaction .
2. Activation energy with catalyst is drawn lower than the 1 9
activation energy without catalyst for an exothermic
reaction
Total 20
8 (a) (i) 1. Electronegativity decreases down the group 1
2. atomic radius /size becomes larger down the group 1
3. the force of attraction between nucleus and 1
electrons become weaker
4. Melting points and boiling points increases down the 1
group because
5. molecular size increases down the group, 1
6. attraction forces between molecules become stronger // 1
intermolecular forces become stronger
7. more heat is needed to overcome this force of attraction 1
8. The density of halogens increases down the group 1
because
9. even though both atomic mass and volume(size) of 1
halogens increases down the group
10 The increase in atomic mass is bigger than volume 1 10
(size).
(ii) 1. Reaction of chlorine , bromine and iodine with iron :

Reactivity of chlorine > bromine>iodine 1
Halogen Observation
Chlorine Iron (wool) ignites rapidly
with bright flame, brown 1
solid formed.
Bromine Iron (wool) glows brightly ,
brown solid formed 1
Iodine Iron (wool) glows dimly,
brown solid formed. 1 4
(b) (i) 1. Ionic bond 1 1
(ii) 1. [correct number of occupied electron shells, correct 1

electrons in each shell and nuclei shown for both ions ]
2. [one sodium ions combine with one chloride ions, 1
charges of ions shown ]
3. can conduct electricity in the molten state 1

4. cannot conduct in the solid state 1
5. in molten state the ions are free to move 1
6 in solid state ions are not free to move but held fixed in 1 Max 5
lattice
Total 20
SECTION C
9 (a) (i) Compound formed when hydrogen ion from an acid is 1

replaced by metal ions or ammonium ions
(ii) Lead(II) chloride 1
Double decomposition 1
(iii) 1. Pour [50-100 cm3] [0.5-2.0 mol dm-3] lead(II) nitrate solution in a 1
beaker
2. Add [50-100 cm3] [0.5-2.0 mol dm-3] sodium chloride / any 1
soluble salts solution contain chloride ions into the beaker
3. Stir the mixture 1
4. filter the mixture 1
5. Rinse the residue with distilled water 1
6. dry the salt with filter paper 1
7. Equation: 1
Pb2+ + Cl - → PbCl2
(b) [Calculate the molar mass of KCl required] 1

1. Molar mass of KCl = 39 + 35.5 = 74.5 g mol-1
[Calculate number of mole of KCl require] 1
2. No. of mole = (MV)/1000 = (0.5 x 250)/1000 = 0.125 mol
[Calculate mass of KCl required] 1
3. Mass = 0.125 x 74.5 = 9.3125 g
4. Weigh out 9.3125 g of KCl 1
5. Dissolve the solid KCl with a little distilled water in a beaker 1

6. Transfer the solution into 250 cm3 volumetric flask using filter 1
funnel.
7. Rince the beaker and filter funnel with distilled water and add 1
the washing to the flask
8. Add distilled water into the flask slowly until the graduation 1
mark.
9. Closed the flask with stopper 1
10. Shake well//invert several time until the solution mixed well 1
10
Total 20
10
10 (a) Heat change/release when 1 mol of water formed from the reaction 1
between an acid and alkali.
(b)(i) 1. Correct formula of reactants

2. Correct formula of product
HCl + NaOH → NaCl + H2O 2
(ii) 1. No. of mole = (2.0x 25.0)/1000 = 0.05 1

2. Heat change = 0.05 x 57 = 2.85 kJ /2,850 J 1 2
(iii) 1. Vertical exes labeled energy with two energy level 1

2. Energy level of reactants is higher than products and ∆H= -57 kJmol-1 1 2
Energy
HCl + NaOH
∆H = -57 kJmol-1
NaCl + H2O
(iv) 1. Ethanoic acid is weak acid// Ethanoic acid ionize partially in water 1
2. Heat absorbed to ionized ethanoic acid 1 2
(c) 1. Materials: sodium hydroxide, hydrochloric acid 1

2. 50 cm3 of 2 mol dm-3 sodium hydroxide solution is measured using a 1
measuring cylinder and poured into a plastic cup.
3. 50 cm3 of 2 mol dm-3 hydrochloric acid is measured using another 1
measuring cylinder and poured into a plastic cup.
4. The initial temperature of the solutions are measured after a few 1
minutes.
5. The hydrochloric acid is then poured quickly and carefully into the 1
sodium hydroxide solution
6. The mixture is stirred using a thermometer and the highest 1
temperature reached is recorded.
7. Results: 1
Initial temperature of sodium hydroxide solution = T1 0C.
Initial temperature of hydrochloric acid = T2 0C
Highest temperature = T 3 0C
11
Calculations
8. Average temperature of acid and alkali = T1 + T2 1
2
0
= Tx C
9. Increase in temperature = (T3-Tx) = Ø 0C 1
10. Heat released in the reaction = (50 +50) ( C ) Ø
= P Joule 1
11. Number of mole of sodium hydroxide and hydrochloric acid
= 50 x 2
1000 1
= 0.1 mol
12. Heat of neutralisation, ΔH = P /(0.1x1000) kJmol-1 1
Max 10
Total 20
SKEMA PEMARKAHAN TAMAT

4541/3
Chemistry 3
September
2010

DENGAN KERJASAMA
____________________________________________________________
CHEMISTRY 3
PERATURAN PEMARKAHAN
Skema Pemarkahan ini mengandungi 15 halaman bercetak

Question Details Score

Able to state all the three variables and all the three actions
correctly.
Sample answer:
Name of variable Action to be taken

(i) Manipulated variable: (i) Method to manipulate
Concentration of acid variable:
Use different concentration
1. (a) of acid / dilute the acid 3+3
(ii) Responding variable: (ii) What to observe in the
pH value responding variable:
pH meter reading
(iii) Controlled variable: (iii) Method to maintain

Type of acid / Nitric acid constant variable:
Use same type of acid
Able to state any two variables and any two actions correctly. 2+2
Able to state any one variable and any one action correctly. 1+1
No response or wrong response 0
Able to state the relationship correctly between the manipulated

variable and the responding variable with direction.
(b) 3
Sample answer:
The higher the concentration of nitric acid, the lower the pH value.
Able to state the relationship between the manipulated variable

and the responding variable without direction.
2
Sample answer:
Concentration of acid affect the pH value.

Able to state the idea of hypothesis
Sample answer: 1
Acid have pH value
0
No response or wrong response
Able to predict the concentration correctly with unit.
(c) Sample answer: 3

0.000001 moldm-3 / 1.0 X 10-6 mol dm-3
Able to predict the concentration correctly without unit.
Sample answer: 2
0.000001 / 1.0 X 10-6
Able to predict the concentration in range form.
Sample answer: 1
Lower than 0.000001
0
Able to show how to calculate the volume correctly and answer

with unit.
Sample answer:
(d) M1V1 = M2V2 3
(0.1) V1 = (0.001) (250)
V1 = 0.250 / 0.1
= 2.5 cm3
Able to give the volume correctly with unit.
Sample answer: 2
2.5 cm3

Able to give the volume correctly without unit.
Sample answer: 1
2.5
0
Able to record all readings accurately to two decimal point with

unit.
Sample answer:
Initial burette Final burette

(e) 3
readings readings
First titration 1.20 cm3 25.30 cm3
Second titration 0.55 cm3 24.60 cm3
Third titration 3.00 cm3 27.20 cm3
Able to record all readings correctly.

# readings to one decimal point with unit
# readings to two decimal point without unit
Sample answer:

readings readings
First titration 1.2 cm3 25.3 cm3
Second titration 0.5 / 0.6 cm3 24.6 cm3
Third titration 3.0 cm3 27.2 cm3 2
Or

readings readings
First titration 1.20 25.30
Second titration 0.55 24.60
Third titration 3.00 27.20
Able to record three to five readings correctly. 1
0
Able to construct a table that contains:

1. Correct titles
2. Readings and unit
Sample answer:
(f) 3
Titration number 1 2 3
Final burette reading / cm3 25.30 24.60 27.20
Initial burette reading / cm3 1.20 0.55 3.00
Volume of nitric acid / cm3 24.10 24.05 24.20
Able to construct a less accurate table that contains the following:

1. Titles
2. Readings
Sample answer:
Titration number 1 2 3 2
Final burette reading 25.30 24.60 27.20
Initial burette reading 1.20 0.55 / 3.00
0.60
Volume of nitric acid 24.10 24.05 24.20
Able to construct a table with at least one title / reading.
Sample answer:
1
Final burette readings
Initial burette readings
0

Able to state the colour change accurately.
(g) Sample answer: 3

The colour of phenolphthalein change from pink to colourless.
Able to state the the colour change inaccurately.
Sample answer: 2
Change to colourless.
Able to state an idea about the observation.
Sample answer: 1
The colour changes // pink
0
Able to give the operational definition accurately by stating the

following three information.
1. Volume of sulphuric acid added
2. Neutralize sodium hydroxide solution completely
3. Phenolphthalein change from pink to colourless
(h) 3
Sample answer:
Volume of sulphuric acid added to neutralize the sodium
hydroxide solution completely and the colour of phenolphthalein
change from pink to colourless.
Able to give the operational definition correctly by stating any

two of the information above.
Sample answer:
The end point of neutralization is the volume of sulphuric acid
added to neutralize the sodium hydroxide solution completely.
2
Or
The end point of neutralization is the volume of sulphuric acid

added and the phenolphthalein colour change from pink to
colourless.

Able to give the operational definition correctly by stating any one
of the information above.
Sample answer:
volume of sulphuric acid added.
Or
1
sodium hydroxide solution being neutralize completely.
Or
phenolphthalein change from pink to colourless.
0
Able to give all two explanations correctly.
Sample answers:
1. Sulphuric acid is diprotic acid, nitric acid is monoprotic
(i) 3
acid,
2. The volume of sulphuric acid is half the volume of nitric
acid to produce the same concentration of hydrogen ions.
Able to give any one correct explanations.

2
Able to give incomplete explanation.
Sample answer: 1
Sulphuric acid is diprotic acid / nitric acid is monoprotic acid
0
Able to classify all the three acids correctly.
Sample answer:
(j) Monoprotic acid Diprotic acid

Nitric acid Sulphuric acid 3
Hydrochloric acid

Able to classify any two acids correctly.
Sample answer:
Monoprotic acid Diprotic acid 2

Nitric acid Sulphuric acid
Hydrochloric acid
Able to classify any one acid correctly.
Sample answer:
Monoprotic acid Diprotic acid 1

Hydrochloric acid Nitric acid
Sulphuric acid
0
Able to give the statement of the problem accurately and response

is in question form.
2(A) (a) 3
Sample answer:
What is the difference in electrical conductivity between ionic
compound and covalent compound?
Able to give the statement of the problem correctly.
Sample answer: 2
How does type of compound affect electrical conductivity?
Able to give an idea of statement of the problem correctly.
Sample answer: 1
To investigate the difference in electrical conductivity between
ionic compound and covalent compound.
0

Able to state the three variables correctly.
Sample answer:
Manipulated variable: Ionic compound and covalent compound /
lead(II) bromide and sulphur.
(b) 3
Responding variable: Ammeter reading / electrical conductivity
Constant variable: mass of lead(II) bromide and mass of sulphur /

state of ionic compound and covalent
compound.
Able to state any two variables correctly

2
Able to state any one variables correctly
1
0

and the responding variable correctly with direction.
Sample answer:
(c) Molten ionic compound can conduct electricity while molten 3
covalent compound cannot conduct electricity. / Molten lead(II)
bromide can conduct electricity while molten sulphur cannot
conduct electricity.

and the responding variable with direction.
Sample answer: 2
Ionic compound can / cannot conduct electricity // Covalent
compound cannot / can conduct electricity.
Able to state the idea of hypothesis.
Sample answer: 1
Different compound have different properties in electrical
conductivity.
0
10
Able to give adequate list of materials and apparatus.
Sample answer:
Materials
1. Lead(II) bromide
2. Sulphur
Apparatus
(d) 1. Crucible 3
2. Batteries
3. Ammeter
4. Carbon electrodes
5. Tripod stand
6. Bunsen burner
7. wire gauze
8. connecting wire
Able to give a list of materials and apparatus.
Sample answer:
Materials
1. Lead(II) bromide / any ionic compound
2. Sulphur / any covalent compound
Apparatus
2
1. Any container
2. Batteries
3. Ammeter / bulb / voltmeter
4. Electrodes
5. Bunsen burner
6. connecting wire
Able to give an idea of materials and apparatus.
Sample answer:
Material
Any ionic or covalent compound 1
Apparatus
1. Ammeter / bulb / voltmeter
2. Electrodes
11
0
Able to state the following six steps:
Sample answer:
1. Fill a crucible with solid lead(II) bromide until it is half
full.
2. Connect the circuit.
(e) 3
3. Heat the solid lead(II) bromide until it melts.
4. Observe whether the needle of ammeter deflect or not /
observe the ammeter reading.
5. Record the observation.
6. Repeat steps 1 to 5 using solid sulphur.
Steps 1, 2, 3, and 6
2
Step 2 and 3
1
0
Able to tabulate the data completely
Sample answer:
Type of compound Observation

(f) 2
Ionic compound
Covalent compound
Able to tabulate the data incompletely
Sample answer:
Compound Observation 1
12
0
Able to give the statement of the problem accurately and response

is in question form.
2(B) (a) Sample answer: 3

How do different types of metals in contact with iron affect
rusting?

2
Sample answer:
How do different types of metals affect rusting?
Sample answer:
1
Do metal affect rusting//
To investigate/study the effect of other metal on the corrosion of
iron.
0
Sample answer:
Manipulated variable: Different metal in contact with iron
(b) 3
Responding variable: Rusting of iron // Rate of rusting
Controlled variable: Iron nails// medium in which the iron
nails are kept // temperature

2
1
0
13


When a more/less electropositive metal is in contact with iron, the
metal inhibits/speeds up rusting.

Sample answer: 2
The metal inhibits/speeds up rusting when a more / less
electropositive metal is in contact with iron.

1
Sample answer:
Different types of metals speeds up / inhibits rusting
0
Sample answer:
Materials
1 Iron nails
2 Magnesium ribbon, copper strip
3 Hot jelly solution with a little potassium
(d) 3
hexacyanoferrate(III) and phenolphthalein
4 Sand paper
Apparatus
1 Test tubes
2 Test tube rack
14

Sample answer:
Materials
1 Iron nails
2 Magnesium/ copper strip 2
Apparatus
Test tube/beaker/any container
Sample answer:
Material
Any metal 1
Apparatus
Test tube/beaker/ any container
0
Able to state the following six steps:
Sample answer:
1 Clean all the three iron nails, magnesium ribbon and
copper strip with sand paper
2 Coil two iron nails tightly with magnesium ribbon and
copper strip respectively
(e) 3 Place all the iron nails in the different test tubes. 3
4 Pour hot jelly solution containing potassium
hexacyanoferrate(III) and phenolphthalein indicator into
the test tubes until completely cover the nails.
5 Keep the test tubes in a test tube rack and leave them aside
for a day.
6 Record the observations.
Steps 2,3,4 and 6

2
Step 3
1
0
15

Able to tabulate the data that includes the following information :
(f) 1. Correct titles
2. Complete list of iron and the metals in contact with iron.
Sample answer :
Test tube Observation // Intensity of blue colouration // 2

presence of pink colouration
Fe
Fe + Mg
Fe + Cu
Able to construct a table with:

1. At least one title
2. Incomplete list of iron and the metals in contact with iron.
Sample answer :
Test tube/ Observation // Intensity of blue colouration //
1
metal presence of pink colouration
Fe only
Fe + Mg /
Cu
0
END OF MARK SCHEME

4541/1
Chemistry
Paper 1
September
1 1/4 jam

DENGAN KERJASAMA
____________________________________________________
CHEMISTRY
Kertas 1
Satu jam lima belas minit

2. Jawab semua soalan.
5. Rajah tidak dilukis mengikut skala kecuali dinyatakan
This question paper consists of 26 printed pages

Kertas soalan ini mengandungi 26 halaman bercetak.
SULIT 4541/1
1. This question paper consists of 50 questions.
2. Answer all questions.
3. Answer each question by blackening the correct space on the answer sheet.
4. Blacken only one space for each question.
5. If you wish to change your answer, erase the blackened mark that you have made.
Then blacken the space for the new answer.
6. The diagrams in the questions provided are not drawn to scale unless stated.
2. Jawab semua soalan
5. Sekiranya anda hendak menukarkan jawapan, padamkan tanda yang telah dibuat.
Kemudian hitamkan jawapaan yang baru.
6. Rajah yang mengirimi soalan tidak dilukis mengikut skala kecuali dinyatakan.
Question 1 to Question 50 are followed by four options A, B, C or D.

Choose the best option for each question and blackened the corresponding space on
the objective answer sheet.
Bagi Soalan 1 hingga Soalan 50, tiap-tiap soalan diikuti oleh empat pilihan jawapan A,
B, C dan D. Pilih satu jawapan yang terbaik bagi tiap-tiap soalan dan hitamkan ruangan
yang sepadan pada kertas jawapan objektif anda
4541/1 2 SULIT
SULIT 4541/1
1 Which of the following process occurs when iodine is heated?

Proses yang manakah berlaku apabila iodin dipanaskan?
A Melting
Peleburan
B Sublimation
Pemejalwapan
C Condensation
Kondensasi
D Boiling
Pendidihan
2 Which of the following statement provides the best evidence that matter exists as
tiny particles moving at random ?
Pernyataan yang manakah memberikan bukti yang dapat menunjukkan jirim terdiri
daripada zarah halus yang bergerak rawak?
A Metals can conduct electricity
Logam boleh mengkonduksi arus elektrik
B A thin layer is formed when oil is dropped onto water
Satu lapisan nipis terbentuk apabila minyak dititiskan di atas permukaaan air
C The smell of perfume is detected in all parts of the room when the bottle is opened
Bau harum minyak wangi tersebar ke seluruh ruang apabila penutup botol dibuka
D A small volume of water produces a large volume of steam
Isipadu kecil air dapat menghasilkan isipadu stim yang lebih besar
3 Which of the following process will increase the kinetic energy of the particles of a
substance ?
Proses yang manakah antara berikut akan meningkatkan tenaga kinetik zarah-zarah bagi
suatu bahan
A Condensation
Kondensasi
B Freezing
Pembekuan
C Boiling
Pendidihan
D Crystallization
Penghabluran
4 Which of the following substance consists of molecules?
Manakah bahan berikut mengandungi molekul?
A Naphthalene
Naftalena
B Copper
Kuprum
C Sodium chloride
Sodium chloride
D Lead(II) iodide
4541/1 3 SULIT
SULIT 4541/1
Plumbum(II) iodida
5 Diagram 1 shows the heating curve for substance P.

Rajah 1 menunjukkan lengkung pemanasan bagi bahan P.
TemperatureoC
Suhu/oC
Diagram 1 Time/s
Masa/s
Rajah 1
Which of the following gives the correct states of matter for substance P at X, Y and Z ?
Pernyataan manakah benar bagi menunjukkan keadaan rupa bentuk jirim bagi bahan P
pada X, Y dan Z ?
X Y Z
A Solid Liquid Gas
Pepejal Cecair
B Solid Solid and liquid Gas
Pepejal Pepejal dan cecair
C Solid Solid and liquid Liquid
Pepejal Pepejal dan cecair Cecair
D Liquid Liquid and gas Solid
Cecair Cecair dan gas Pepejal
6 An atom of element X has 13 protons and 14 neutrons in its nucleus. Which of the
following is the electron arrangement of atom X ?
Atom bagi unsur X mempunyai 13 proton dan 14 neutron di dalam nukleusnya. Yang
mana antara berikut merupakan susunan electron bagi atom X.
A 2.3
B 2.4
C 2.8.4
D 2.8.3
4541/1 4 SULIT
SULIT 4541/1
7 Statements below show the contribution of a scientist to the development of the Periodic
Table of elements.
Pernyataan berikut menunjukkan sumbangan seorang ahli sains dalam perkembangan
Jadual Berkala Unsur.
 Arranged all the known elements according to the ascending order of their
atomic masses
 Menyusun semua unsur yang diketahui berdasarkan susunan menaik jisim

atom masing-masing
 Showed that a periodic pattern existed among the elements using Law of
Octaves
 Menunjukkan corak berulang di antara unsur menggunakan Hukum Oktaf
Who is the scientist ?

Siapakah ahli sains tersebut?
A Lothar Meyer
B John Newlands
C Antoine Lavoisier
D John W. Dobereiner
8 Table 1 shows the proton number of five elements. Which elements are in the same
group in the Periodic Table?
Jadual 1 menunjukkan nombor proton bagi lima unsur.Unsur manakah berada di dalam
kumpulan yang sama dalam Jadula Berkala?
Element R S T U V
Unsur
Proton number 9 11 12 15 17
Nombor proton
Table 1
Jadual 1
A S and T
B R and S
C R and V
D S and U
4541/1 5 SULIT
SULIT 4541/1
9 Table 2 shows the electron arrangement of atom R, S, T and U.

Jadual 2 menunjukkan susunan elektron bagi atom R, S , T dan U..
Atom Arrangement of electron

Atom Susunan elekkton
R 2.4
S 2.6
T 2.8.1
U 2.8.7
Table 2
Jadual 2
Which of the following atoms can form ionic bond?

Antara pasangan atom-atom berikut, yang manakah boleh membentuk ikatan ionik?
A T and U
B R and U
C S and U
D R and S
10 Diagram 2 shows the set-up of the apparatus to determine the empirical formula of a metal oxide.
Rajah 2 menunjukkan susunan radas untuk menentukan formula empirik suatu oksida logam.
Metal oxide
Oksida logam
Hydrogen gas
Gas hidrogen
Diagram 2
Rajah 2
Which of the following metal oxide is suitable to be used in the experiment?

Antara oksida logam yang berikut, yang manakah sesuai digunakan dalam eksperimen tersebut?
A Magnesium oxide
Magnesium oksida
B Sodium oxide
Natrium oksida
C Zinc oxide
Zink oksida
D Lead(II) oxide
Plumbum(II) oksida
4541/1 6 SULIT
SULIT 4541/1
11 Diagram 3 shows a set-up of apparatus of a redox reaction.

Rajah 3 menunjukkan susunan radas untuk tindakbalas redoks.
Diagram 3
Rajah 3
Which of the following changes in the oxidation numbers of the reactants are true?
Manakah antara pernyataan berikut adalah benar?
Chromium in Acidified Potassium

Iodide ion in Potassium Iodide solution Dichromate (VI)
Ion Iodida dalam Larutan kalium iodida Kromium dalam Larutan kalium
dikromat (VI) berasid
A 0 → -1 +6 → +3
B -1 → 0 +6 → +3
C 0 → -1 +3 → +6
D -1 → 0 +3 → +6
12 Which of the following chemical equation represents a redox reaction ?

Yang manakah antara persamaan kimia berikut mewakili tindak balas Redoks?
A HCl + NaOH NaCl + H2O
B NaCl + AgNO3 AgCl + NaNO3
C Ba(OH)2 + K2SO4 BaSO4 + 2 KOH
D H2 + Cl2 2 HCl
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13 Which of the following metals can be extracted from their ores by reduction of metal
oxides using carbon ?
Yang manakah antara logam berikut boleh diekstrak dari bijihnya melalui tindak balas
penurunan oksida logam dengan karbon?
I Iron
Besi
II Tin
Timah
III Aluminium
Aluminium
IV Magnesium
Magnesium
A I and II only
B II and IV only
C III and IV only
D I, II and III only
14 The rusting of an iron nail in a test tube containing water can be speed up by
Pengaratan paku besi dalam tabung uji berisi air dapat dipercepatkan dengan
A coiling it with a more electropositive metal

melilit paku itu dengan logam yang lebih elektropositif daripadanya
B placing the test tube in a refrigerator

meletakkan tabung uji itu ke dalam peti sejuk
C adding sodium chloride into the test tube

menambah natrium klorida ke dalam tabung uji
D pouring a layer of oil on top of the water in the test tube

menuang selapisan minyak ke atas air dalam tabung uji itu
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15 Diagram 4 shows a set-up of apparatus for an electrolysis process

Rajah 4 menunjukkan susunan radas bagi suatu proses elektrolisis
Diagram 4
Rajah 4
The bulb in the circuit will light up if

Mentol di dalam litar ini akan bernyala jika
A the carbon electrodes are replaced by metals
karbon elektrod digantikan dengan logam
B the ethanoic acid is replaced by hydrochloric acid
asid etanoik digantikan dengan asid hidroklorik
C xylene is replaced by water
xylene digantikan dengan air
D hydrogen bromide in xylene is heated during the electrolysis process
hidrogen bromida dalam xylene dipanaskan semasa proses elektrolisis ini
16 Calculate the mass of sodium hydroxide present in 100 cm3 of 0.5 mol dm-3 sodium
hydroxide solution.
Hitung jisim natrium hidroksida yang hadir dalam 100 cm3 0.5 mol dm-3 larutan natrium
hidroksida.
[Relative atomic mass: H,1; O,16; Na,23]
A 0.4 g
B 0.5 g
C 1.0 g
D 2.0 g
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17 Table 3 shows the result of an experiment to construct the electrochemical series by

displacement of metals from their salt solutions by a more elektropositive metal.
Jadual 3 menunjukkan keputusan bagi suatu eksperimen untuk membina Siri Elektrokimia
melalui tindak balas penyesaran logam daripada larutan garamnya oleh logam yang lebih
elektropositif.
Solution P(NO3)2 Q(NO3)2 R(NO3)2

Larutan
Metal
Logam
P √ √
Q X √
R X X
√ - displacement reaction occurs X - no displacement reaction

penyesaran berlaku penyesaran tidak berlaku
Table 3
Jadual 3
Which of the following metals could be X, Y and Z ?

Yang manakah antara logam-logam berikut mungkin X,Y dan Z ?
P Q R
A Mg Ag Sn
B Mg Zn Cu
C Ag Sn Mg
D Zn Cu Mg
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18 Diagram 5 shows the set-up of apparatus for the electrolysis of dilute sodium chloride
solution using carbon as electrodes.
Rajah 5 menunjukkan susunan radas bagi elektrolisis larutan natrium klorida cair
menggunakan karbon sebagai elektrod.
Diagram 5
Rajah 5
Which of the following statement is true for the electrolysis process ?

Yang manakah antara pernyataan –pernyataan berikut adalah benar bagi proses
elektrolisis ini?
A The ions present in the electrolyte are sodium ions and chloride ions
Ion-ion yang hadir dalam eletrolit ialah ion natrium dan ion klorida
B Hydrogen gas is produced at the anode
Gas hidrogen dihasilkan di anod
C The factor that affects the product formed at the cathode is the concentration of
electrolyte.
Faktor yang mempengaruhi hasil yang dibentuk di katod ialah kepekatan elektrolit
D When the gas collected at the cathode is tested with burning splinter, a ‘pop’ sound is
produced.
Apabila gas yang dikumpulkan di katod diuji dengan kayu uji bernyala, bunyi ‘pop’
dihasilkan
19 M oxides can react with carbon to form metal M and carbon dioxide gas.The reactivity of
the reaction is most reactive when the oxide of metal M is
Oksida logam M boleh bertindak balas dengan karbon untuk menghasilkan logam M dan
gas karbon dioksida. Kereaktifan tindak balas ini paling cergas apabila oksida logam M
ialah
A Tin oxide
Timah oksida
B Iron oxide
besi oksida
C Copper (II) oxide
Kuprum(II) oksida
D Magnesium oxide
Magnesium oksida
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20 The chemical equation below represents the displacement reaction of Iodine from its halide
solution using bromine.
Persamaan kimia di bawah mewakili tindak balas penyesaran Iodin daripada larutan
halidanya oleh bromin.
2 KI + Br2 I2 + 2KBr
Which of the following statements are true for the reaction ?

Yang manakah di antara pernyataan –pernyataan berikut adalah benar bagi tindak balas
ini?
I Bromine is reduced to bromide ion
Bromin diturunkan kepada ion bromida
II Bromine acts as the oxidising agent
Bromin bertindak sebagai agen pengoksidaan
III The oxidation number of bromine changes from 0 to -2
Nombor pengoksidaan bromin bertukar dari ) ke -2
IV Iodide ions release electron in the reaction to form Iodine
Ion iodida melepaskan elektron dalam tindak balas untuk menghasilkan Iodin
A I and II only
B III and IV only
C I, II and IV only
D I, II , III and IV
21 Which of the substance below can be used to neutralize the insect sting which is
alkaline?
Bahan yang manakah antara berikut paling sesuai digunakan untuk meneutralkan
sengatan serangga yang bersifat alkali?
A Carbon
Karbon
B Vinegar
Cuka
C Common salt
Garam
D Sodium bicarbonate
Natrium bikarbonat
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22 Diagram 6 shows a set-up of the apparatus of a chemical cell .

Rajah 6 menunjukkan susunan radas bagi suatu sel kimia.
Diagram 6
Rajah 6
The following statements are true for the reaction in this chemical cell except
Pernyataan-pernyataan berikut adalah benar untuk tindak balas yang berlaku di dalam sel
kimia ini kecuali
A magnesium electrode increases in size

saiz elektrod magnesium bertambah
B the intensity of the blue colour of copper (II) sulphate solution decreases
keamatan warna biru larutan kuprum (II) sulfat berkurangan
C Copper acts as the positive terminal in the chemical cell
Kuprum bertindak sebagai terminal positive dalam sel kimia ini
D The flow of electron is from magnesium electrode to copper electrode in the external
circuit.
Pengaliran eletron adalah dari elektrod magnesium ke elektrod kupprum dalam litar
luar
23 Which of the following acid is a weak acid?

Antara asid berikut, yang manakah merupakan asid lemah?
A Hydrochloric acid
Asid hidroklorik
B Ethanoic acid
Asid etanoik
C Nitric acid
Asid nitrik
D Sulphuric acid
Sulfurik asid
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24 Diagram 7 shows the flow of ammonia gas into distilled water which contains a few drops
of phenolphthalein.
Rajah 7 menunjukkan gas ammonia yang dialirkan ke dalam air suling yang mengandungi
beberapa titik fenolftalein.
NH3
Diagram 7
Rajah 7
distilled water
+
phenolphthalein
Which of the following is the correct observation of the solution?

Yang mana antara berikut menunjukkan pemerhatian yang betul bagi larutan tersebut?
A The solution remains colourless.
Larutan itu kekal menjadi tidak berwarna
B Red solution turns purple.
Larutan merah mejadi ungu
C Green solution turns to red.
Larutan hijau menjadi merah.
D The colourless solution turns pink.
Larutan tanpa warna menjadi merah jambu.
25 A precipitate is formed when hydrochloric acid is added to solution X. Which of the

following solution is most probably solution X?
Mendakan terbentuk apabila asid hidroklorik ditambah kepada larutan X. Antara larutan
berikut, yang manakah mungkin larutan X?
A Zinc nitrate
Zink nitrat
B Silver nitrate
Argentum nitrat
C Calcium nitrate
Kalsium nitrat
D Magnesium nitrate
Magnesium nitrat
26 A beaker contains 100 cm3 of 0.5 mol dm-3 sodium chloride solution.
Calculate the number of moles of sodium chloride in the beaker.
Sebuah bikar mengandungi 100 cm3 larutan natrium klorida 0.5 mol dm-3. Hitung bilangan
mol bagi natrium klorida dalam bikar.
A 0.05
B 0.50
C 5.00
D 50.0
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27 Table 4 shows the volume and the type of acid in four different beakers.
Jadual 4 berikut menunjukkan isipadu dan jenis asid yang diisi ke dalam empat bikar yang
berasingan.
Beaker A Beaker B Beaker C Beaker D

25cm3 1 moldm-3 25 cm3 1moldm-3 25 cm3 1 moldm-3 25 cm3 1 moldm-3
hydrochloric acid. sulphuric acid. ethanoic acid. nitric acid.
25 cm3 1 moldm-3 25 cm3 1 mol dm3 25 cm3 1 moldm-3 25 cm3 1 moldm-3
asid hidroklorik asid sulfurik, asid etanoik asid nitrik
Table 4
Jadual 4
Which of the acid has the highest concentration of hydrogen ions?
Larutan asid yang manakah mengandungi kepekatan ion hidrogen yang paling tinggi?
A Beaker A
B Beaker B
C Beaker C
D Beaker D
28 200 cm3 of 0.5 moldm-3 hydrochloric acid was prepared from a standard solution 2 moldm-3
hydrochloric acid. Calculate the volume of the standard solution of 2 moldm-3 hydrochloric
acid needed to be diluted with water.
200 cm3 0.5 moldm-3 larutan asid hidroklorik disediakan daripada larutan piawai asid
hidroklorik berkepekatan 2 moldm-3. Hitung isipadu larutan piawai yang diperlukan untuk
pencairan tersebut.
A 50 cm3
B 75 cm3
C 100 cm3
D 150 cm3
29 Which of the following pairs of compounds are in the same homologous series?
Manakah antara pasangan sebatian berikut berada dalam siri homolog yang sama?
Compound 1 Compound 2
Sebatian 1 Sebatian 2
A C2H4 C4H10
B C2H6 C6H6
C C2H5OH CH3CH2CH2OH
D C2H5OH C2H5COOH
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30 Diagram 8 shows the observation for the comformation test for nitrate ion.
Rajah 8 menunjukkan pemerhatian bagi ujian pengesahan ion nitrat.
Brown ring
Cincin perang
Diagram 8
Rajah 8
Which of the solutions are used to produce the brown ring?

Larutan yang manakah boleh digunakan untuk menghasilkan cincin perang tersebut?
I Dilute sulphuric acid

Larutan asid sulfurik cair
II Iron(II) sulphate solution
Larutan ferum(II) sulfat
III Nitric acid solution
Larutan asid nitrik
IV Concentrated sulphuric acid
Larutan asid sulfurik pekat
A I dan III only

B I, II dan III only
C II dan IV only
D I, II dan IV only
31 The equation below shows the reaction between copper(II) oxide and dilute nitic acid.
Persamaan dibawah menunjukkan tindakbalas di antara kuprum(II) oksida dan asid nitrik
cair.
CuO + 2HNO3 → Cu(NO3)2 + H2O
Calculate the mass of copper(II) nitrate salt formed when 3.2g of copper(II) oxide powder
reacts with excess dilute nitric acid.
Hitung jisim garam kuprum(II) nitrat yang akan terbentuk apabila 3.2 g serbuk kuprum(II)
oksida bertindakbalas dengan asid nitric cair berlebihan.
[relative atomic mass : Cu = 64 ; O = 16 ; N=14 ]
A 3.76 g
B 4.90 g
C 5.04 g
D 7.52 g
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32 Vanadium(V) oxide is a catalyst that is used in

Vanadium(V) oksida ialah mangkin yang digunakan dalam
A Haber process
Proses Haber
B Contact Process
Proses Sentuh
C Oswald Process
Proses Oswald
D Hydrogenation process
Proses penghidrogenan
33 All the following medicines relieve pain except

Semua ubat berikut mengurangkan kesakitan kecuali
A aspirin
aspirin
B codeine
kodeina
C paracetamol
parasetamol
D streptomycin
streptomisin
34 Choose the statements that are true about detergent

Pilih pernyataan yang benar mengenai detergen
I Detergent is non-biodegradable
Detergen tidak terbiodegradasi
II Detergent is still effective in hard water
Detergen masih berkesan dalam air liat
III Detergent clean better compared to soap
Detergen membersih lebih baik berbanding sabun
IV Detergent can be custom-made for a specific cleaning task.
Detergen boleh dihasilkan untuk tujuan pembersihan tertentu
A I and II only
B III and IV only
C II, III and IV only
D I, II, III and IV
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35 The following word equation shows the preparation of soaps.

Persamaan perkataan berikut menunjukkan proses penyediaan sabun.
Fats + sodium hydroxide → glycerol + soaps

Lemak + natrium hidroksida → gliserol + sabun
What is the name of the process shown by the above equation?

Apakah nama proses yang ditunjukkan dalam persamaan di atas?
A Saponification
Saponifikasi
B Dehydration
Pendehidratan
C Neutralization
Peneutralan
D Fermentation
Penapaian
36 When 25 cm3 of 0.25 mol dm-3 silver nitrate solution is added into 25 cm3 of 0.25 mol
dm-3 sodium chloride solution, the temperature of the mixture rises by 3oC. What is the
quantity of heat released in this experiment?
Apabila 25 cm3 of 0.25 mol dm-3 larutan argentum nitrat ditambah ke 25 cm3 of 0.25
mol dm-3 larutan natrium klorida, suhu campuran tersebut meningkat sebanyak 3oC.
Apakah kuantiti haba yang dibebaskan di dalam eksperimen ini.
(Specific heat capacity of water = 4.2 J g-1 oC-1)

(Muatan haba tentu air = 4.2J g -1 o C -1 )
A 25 x 4.2 x 0.25 x 3.0 J

B 50 x 4.2 x 3.0 J
C 50 x 4.2 x 0.25 x 3.0 J
D 25 x 4.2 x 3.0 J
37 The time taken for the reaction between lumps of marble with sulphuric acid can be shorten by
Masa yang diambil untuk tindak balas antara ketulan marmar dengan asid sulfurik boleh
dipendekkan dengan
A adding distilled water
menambahkan air suling
B adding concentrated of sulphuric acid
menambahkan asid sulfurik pekat
C Using the bigger size of marbles
menggunakan saiz marmar yang lebih besar
D keeping the mixture of the reaction in refrigerator
meletakkan campuran tindak balas di dalam peti sejuk
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38 The thermochemical equation represents the precipitation of lead(II) sulphate :

Persamaan termokimia mewakili tindak balas bagi pemendakan plumbum(II) sulfat:
Pb2+(aq) + SO42-(aq)  PbSO4(s) ΔH = – 42 kJ mol-1
Which energy level diagram is correct ?

Gambar rajah aras tenaga manakah yang betul ?
PbSO4(s)
Energy
Tenaga ΔH = – 42 kJ mol-1
2+ 2-
Pb (aq) + SO4 (aq)
PbSO4(s)
Energy
Tenaga ΔH = + 42 kJ mol-1
Pb2+(aq) + SO42-(aq)
Energy
Tenaga ΔH = + 42 kJ mol-1
PbSO4(s)
D
Energy
Tenaga ΔH = – 42 kJ mol-1
PbSO4(s)
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39 The thermochemical equation for displacement of copper by zinc is given below.

Persamaan termokimia bagi penyesaran kuprum oleh zink diberikan seperti dibawah.
Zn(s) + CuSO4 (aq)  ZnSO4 (aq) + Cu(s) ΔH = – 210 kJ mol-1
What is the mass of copper, Cu formed when 84 kJ of heat is released?

[Relative atomic mass: Cu = 64]
Berapakah jisim kuprum, Cu yang terbentuk apabila 84 kJ haba dibebaskan?
[Jisim atom relatif: Cu = 64]
A 3.3 g
B 25.6 g
C 160.0 g
D 0.4 g
40 Which acid produces the highest rate of reaction when reacts with 2 g of magnesium?
Asid manakah menghasilkan kadar tindak balas yang paling tinggi apabila bertindak balas
dengan 2 g magnesium ?
A 100 cm3 of 0.1 mol dm-3 nitric acid

100 cm3 asid nitrik 0.1 mol dm-3
B 100 cm3 of 0.1 mol dm-3 sulphuric acid
100 cm3 asid sulfurik 0.1 mol dm-3
C 100cm3 of 0.1 mol dm-3 ethanoic acid
100 cm3 asid etanoik 0.1 mol dm-3
D 100 cm3 0.1 mol dm-3 hydrochloric acid
100cm3 asid hidroklorik 0.1 mol dm-3
41 The following information shows the effect of concentration on the rate of reaction.
Kenyataan berikut menunjukkan kesan kepekatan terhadap kadar tindak balas.
When the concentration of sodium thiosulphate, Na2S2O3 solution increases, the time taken
for the mark ‘X’ to disappear from sight becomes shorter.
Which of the following statement best concludes about the information above?
Manakah antara yang berikut merupakan kesimpulan terbaik tentang kenyataan di atas?
A The concentration is directly proportional to the time taken
Kepekatan berkadar terus dengan masa
B The rate of reaction is directly proportional to the time taken
Kadar tindak balas berkadar terus dengan masa
C The rate of reaction is directly proportional to the concentration
Kadar tindak balas berkadar terus dengan kepekatan
D The rate of reaction is inversely proportional to the concentration
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Kadar tindak balas berkadar songsang dengan kepekatan

42 The molecular formula of an organic compound is C4H10.
Formula molekul sebatian organik adalah C4H10.
Which of the following is the isomer for the above molecular formula?
Antara yang berikut, yang manakah isomer bagi formula molekul di atas?
A CH2= CH-CH2-CH3
B CH3-CH=CH-CH3
C CH3-CH- CH3
CH3
D
CH3-CH2- CH2
CH3
43 Photochromic glass darkens on exposure to sunlight. The salt used to make photochromic
glass is
Kaca fotokromik menjadi gelap apabila didedahkan kepada cahaya matahari. Garam
yang digunakan untuk membuat kaca fotokromik ialah
A Silver chloride
Argentum klorida
B Iron(II) sulphate
Ferum (II) sulfat
C Lead(II) nitrate
plumbum(II) nitrat
D Copper(II) sulphate
Kuprum(II) sulfat
44 Which of the following pairs of compounds are in the same homologous series?
Manakah antara pasangan sebatian berikut berada dalam siri homolog yang sama?
Compound 1 Compound 2
Sebatian 1 Sebatian 2
A C2H4 C4H10
B C2H6 C6H6
C C2H5OH CH3CH2CH2OH
D C2H5OH C2H5COOH
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45 Diagram 9 shows the graph of total volume of carbon dioxide against time for the
reaction of calcium carbonate with dilute acid for experiment P and experiment Q.
Rajah 9 menunjukkan graf bagi jumlah isipadu karbon dioksida melawan masa
bagi tindak balas kalsium karbonat dengan asid cair bagi eksperimen P dan
eksperimen Q.
cm3
Diagram 9
Rajah 9
Which of the following explains the differences between both curves from the
experiments?
Antara berikut, yang manakah menerangkan perbezaan antara dua lengkungan
bagi eksperimen tersebut?
I The mixture of the reaction in experiment P is being heated compared to

experiment Q
Campuran tindak balas dalam eksperimen P dipanaskan berbanding
eksperimen Q
II Catalyst is used in experiment P but not in experiment Q
Mangkin digunakan dalam eksperimen P tetapi tidak dalam eksperimen Q
III Quantities of calcium carbonate and acid used in experiment P are more than
that in experiment Q
Kuantiti kalsium karbonat dan asid yang digunakan dalam eksperimen P
melebihi daripada eksperimen Q
IV The size of calcium carbonate used in experiment P is smaller than
experiment Q
Saiz kalsium karbonat yang digunakan dalam eksperimen P lebih kecil
daripada eksperimen Q
A III and IV only

B I, II and III only
C I, II and IV only
D I, II , III and IV
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46 The following equation represents the reaction between propene and bromine.
Persamaan berikut mewakili tindak balas antara propena dan bromin.
Propene + Br2 → X
Propena + Br2 → X
What is the IUPAC name of compound X?

Apakah nama IUPAC bagi sebatian X?
A Tetrabromopropane
Tetrabromopropana
B 1-bromopropane
1-bromopopana
C 1,1-dibromopropane
1,1-dibromopropana
D 1,2-dibromopropane
1,2-dibromopropana
47 Which of the following food additives is an antioxidant?

Antara bahan tambah makanan berikut yang manakah adalah pengantioksida?
A Aspartame
Aspartam
B Monosodium glutamate
Mononatrium glutamat
C Ascorbic acid
Asid askorbik
D Benzoic acid
Asid benzoik
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48
Diagram 10
Rajah 10
Diagram 10 shows the set-up of apparatus to prepare an organic compound in the

laboratory.
Rajah 10 menunjukkan susunan radas untuk menyediakan suatu sebatian organik dalam
makmal.
Which of the following statements are true about the experiment?

Manakah antara berikut benar mengenai eksperimen?
I The water is in from X and is out from Y.
Air masuk melalui X dan keluar melalui Y.
II Concentrated sulphuric acid is used as a catalyst.
Asid sulfurik pekat digunakan sebagai mangkin.
III The distillate collected is an ester
Hasil sulingan yang diperolehi adalah dari ester
IV The porous pot chips are added to prevent bumping when boiling the mixture.
Serpihan pasu berliang dimasukkan untuk mencegah pembuakan ketika pendidihan
campuran.
A I and II
B I and IV
C I, II and III
D II, III and IV
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49 Part of the structure of polymer is shown below .

Struktur sebahagian daripada suatu polimer ditunjukkan di bawah
H CH3 H H H CH3
│ │ │ │ │ │
~~~~C ─ C ─ C─ C ─ C ─ C ~~~~
│ │ │ │ │ │
H H H CH3 H H
Which of the following is the monomer of the polymer?

Di antara berikut yang manakah monomer bagi polimer tersebut?
A
H H H
│ │ │
C = C ─ C─ H
│ │
H H
B
H H
│ │
C = C ─ H
│
H
C
H H H H
│ │ │ │
C = C ─ C─ C ─H
│ │ │
H H H
D
H H H H H
│ │ │ │ │
C = C ─ C─ C ─C─H
│ │ │ │
H H H H
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50 In an experiment, hydrogen peroxide, H2O2 solution decomposes completely to

produce oxygen gas.
Dalam suatu eksperimen, larutan hidrogen peroksida, H2O2 terurai dengan lengkap
menghasilkan oksigen.
Diagram 11 shows an energy profile diagram. Ea is the activation energy for the
decomposition of hydrogen peroxide.
Rajah 11 _menunjukkan suatu gambar rajah profil tenaga. Ea ialah tenaga
pengaktifan bagi penguraian hidrogen peroksida
Energy
Tenaga
Ea
p
r s
Reaction path
Lintasan tindak balas
Diagram 11
Rajah 11
Which of the following is the activation energy for the dissociation of hydrogen
peroxide when manganese(IV) oxide is added?
Antara berikut yang manakah tenaga pengaktifan bagi penguraian hidrogen peroksida
apabila mangan(IV) oksida ditambahkan?
A p
B q
C r
D s

KERTAS SOALAN TAMAT
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SULIT Nama
4541/2
Chemistry Tingkatan
Kertas 2
September
2 ½ jam
DENGAN KERJASAMA
____________________________________________________________
CHEMISTRY
Kertas 2
Dua jam tiga puluh minit
1. Kertas soalan ini mengandungi tiga bahagian: Untuk kegunaan pemeriksa

Bahagian A, Bahagian B and Bahagian C. Bahagian No. Markah
2. Jawab semua soalan dalam Bahagian A. Tulis 1
jawapan dalam Bahagian A dalam ruangan yang
2
disediakan..
3. Jawab satu soalan dalam Bahagian B dan satu 3
soalan dalan Bahagian C. Jawab saoalan dalam A 4
Bahagian A dan Bahagian B dengan terperinci. 5
Anda boleh menggunakan persamaan kimia, rajah, 6
jadual, graf dan kaedah yang bersesuaian untuk Jumlah
menerangkan jawapan anda. 7
4. Tunjukkan jalan kerja. Ia dapat membantu anda B 8
mendapat markah.
Jumlah
5. Rajah dalam soalan tidak dilukis mengikut skala.
6. Markah yang diperuntukkan bagi setiap soalan 9
ditunjukkan dalam kurungan. C 10
7. Anda boleh menggunakan kalkulator saintifik yang Jumlah
tidak diprogramkan. Jumlah Markah
8. Serahkan kertas jawapan pada akhir waktu
peperiksaan.

SULIT
SULIT 2 4541/2

1. This question paper consists of three sections: Section A, Section B and Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, Bahagian B dan Bahagian C.
2. Answer all questions in Section A. Write your answers for Section A in the spaces provided
in the question paper.
Jawab semua soalan dalam Bahagian A. Tuliskan jawapan bagi Bahagian A dalam ruang yang
disediakan dalam kertas soalan.
3. Answer one question from Section B and one question from Section C.
Write your answers for Section B and Section C on the `writing paper’ provided by the
invigilators.
Answer questions in Section B and Section C in detail.
You may use equations, diagrams, tables, graphs and other suitable methods to explain your
answer.
Jawab satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan jawapan
bagi Bahagian B dan Bahagian C pada kertas tulis yang disediakan. Jawab Bahagian B dan
Bahagian C dengan terperinci. Anda boleh menggunakan persamaan, gambar rajah, jadual, graf
dan cara lain yang sesuai untuk menjelaskan jawapan anda.
4. Show your working. It may help you to get marks.

Tunjukkan kerja mengira.Ini membantu anda mendapatkan markah.
5. If you wish to change your answer, neatly cross out the answer that you have done. Then
write down the new answer.
Sekiranya anda hendak membatalkan sesuatu jawapan, buat garisan di atas jawapan itu.
6. The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala kecuali dinyatakan.
Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan.
8. The time suggested to answer Section A is 90 minutes, Section B is 30 minutes and Section
C is 30 minutes.
Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B ialah 30 minit dan
Bahagian C ialah 30 minit.

Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan.

Serahkan semua kertas jawapan anda di akhir peperiksaan.

SULIT 3 4541/2
Section A
Bahagian A
[ 60 marks ]
[ 60 markah ]
Answer all questions in this section

Jawab semua soalan dalam bahagian ini.
1 Diagram 1.1 shows the graph temperature against time when liquid naphthalene is
cooled
Rajah 1.1 menunjukkan graf suhu melawan masa apabila cecair naftalena
disejukkan
Temperature / 0C
Suhu /oC
B C
T1
D
T0
Time/s
Masa/s
Rajah 1.1
` (a State the freezing point of naphthalene.

Nyatakan takat beku bagi naftalena 1(a)
……………………………………………………………………………….........
1
[1mark]
(b) What is the physical state of naphthalene at:
Apakah keadaan fizik bagi naftalena pada 1(b)(i)(ii)
(i) AB :…………………………………………………………………………..
2
(ii) CD :…………………………………………………………………………
[2marks]

SULIT 4 4541/2
(c) Explain why there is no change in temperature from B to C.

Terangkan mengapa tiada perubahan suhu dari B ke C
1(c)
..............................................................................................................................
2
..............................................................................................................................
[2marks]
(d) Draw the arrangement of naphthalene particles at CD
Lukiskan susunan zarah naftalena pada CD
1(d)
1
[1mark]
(e) Table 1.2 shows four substances and their respective formulae.
Jadual 1.2 menunjukkan empat bahan dan formula kimianya.
Substances Chemical formula

Bahan Formula kimia
Bromine Br2
Bromine
Iron Fe
Besi
Naphthalene C10H8
Naftalena
Copper(II) sulphate CuSO4
Kuprum(II) sulfat
Table 1.1
Use information from Table 1.1 to answer the following questions.

Gunakan maklumat daripada Jadual 1.1 untuk menjawab soalan berikut
(i) State one compound which exist as a molecule. 1(e)(i)

Nyatakan satu sebatian yang wujud dalam bentuk molekul
....................................................................................................................... 1
[1mark]
(ii) Which substance can conduct electricity in the solid state? 1(e)(ii)
Bahan yang manakah dapat mengalirkan arus elektrik dalam keadaan pepejal ?
1
........................................................................................................................
[1mark]
SULIT 5 4541/2
(iii) What type of particles are present in copper(II) sulphate?

Apakah jenis zarah yang terdapat dalam kuprum(II) sulfat ? 1(e)(iii)
........................................................................................................................
1
[1mark]
(f) A few drops of liquid bromine are dropped into a gas jar. The brown bromine vapour
spreads to the upper part of the gas jar.
Beberapa titik cecair bromin dimasukkan ke dalam balang gas. Warna perang gas
bromin memenuhi bahagian atas balang gas tersebut.
Name the process that occurs.

Namakan proses yang berlaku 1(f)
……………………………………………………………………………………… 1
[1mark]
Total A1
10
2 The diagram 2.1 shows the electron arrangements for five atoms of elements found
in the Periodic Table.
Rajah 2.1 menunjukkan susunan elektron bagi lima atom unsur yang terdapat di
dalam Jadual Berkala Unsur.
Diagram 2.1
Rajah 2.1
(a) (i) State the position of element M in the Periodic Table of Elements.
Nyatakan kedudukan unsur M di dalam Jadual Berkala Unsur. 2(a)(i)
……………………………………………………………………………...
1
[1mark]

SULIT 6 4541/2
(ii) Which of these elements have the same chemical properties. 2(a)(ii)
Yang manakah antara unsur-unsur berikut mempunyai sifat kimia yang sama?
1
………………………………………………………………………………
[1mark]
(b) (i) State one observation when element L reacts with water.
Nyatakan satu pemerhatian apabila unsur L bertindak balas dengan air.
……………………………………………………………………………… 2(b)(i)
………………………………………………………………………………
[1 mark] 1
(ii) Write the chemical equation for the reaction in (b)(i).
Tuliskan persamaan kimia bagi tindak balas di (b)(i).
2(b)(ii)
……………………………………………………………………………….
[2 marks] 2
(c) Which of these elements will form amphoteric oxide?

Yang manakah antara unsur-unsur tersebut menghasilkan oksida amfoterik? 2(c)
................................................................................................................................. 1
[1mark]
(d) (i) State the type of chemical bond that forms between element K and element N.
Nyatakan jenis ikatan kimia yang terbentuk di antara unsur K dan unsur N . 2(d)(i)
…………………………………………………………………………………….
[1mark] 1
(ii) Draw the electron arrangement for the compound that forms in (d)(i).
Lukiskan susunan elektron bagi sebatian yang terbentuk di (d)(i).
2(d)(ii)
[2marks] 2

SULIT 7 4541/2
(iii) Give one physical property of the compound formed.

Berikan satu sifat fizik bagi sebatian yang terbentuk itu. 2(d)(iii)
……………………………………………………………………………….
1
[1mark]
Total A2
10

SULIT 8 4541/2
3 Step 1 and step 2 in diagram 3.1 show the steps in preparation of copper (II)
carbonate from copper (II) oxide, whereas step 3 shows the thermal decomposition of
copper(II) carbonate to copper (II) oxide
Langkah 1 dan langkah 2 dalam rajah 3.1 menunjukkan langkah-langkah dalam
penyediaan kuprum (II) karbonat daripada kuprum (II) oksida, sementara langkah 3
menunjukkan penguraian secara pemanasan kuprum (II) karbonat kepada kuprum
(II) oksida
.
Step 1
Copper (II) oxide Langkah 1 Salt solution X
Kuprum (II) oksida Larutan garam X
Sulfuric acid
Asid sulfurik
Step 2 Solution Y
Langkah Larutan Y
Step 3
Langkah 3
Copper (II) carbonate
Kuprum (II) karbonat
Diagram 3.1
Rajah 3.1
(a) State the colour of copper (II) oxide.
Nyatakan warna kuprum (II) oksida.. 3(a)
……………………………………………………………………………….........
1
[1mark]
(b) Name salt solution X.
Namakan larutan garam X 3(b)
…………………………………………………………………………………
[1mark] 1
(c) (i) Suggest solution Y that is required to be added to solution X to produce copper
(II) carbonate.
Cadangkan larutan Y yang perlu ditambah kepada larutan X untuk
menghasilkan kuprum (II) karbonat. 3(c)(i)
……………………………………………………………………………
[1mark] 1

SULIT 9 4541/2
(ii) Write an ionic equation for the formation of copper (II) carbonate in (c) (i).
Tuliskan persamaan ion bagi pembentukan kuprum (II) karbonat in (c)(i)..
3(c)(ii)
…………………………………………………………………………………
[1mark] 1
(d) In step I, 50 cm3 of 0.2 moldm-3 sulphuric acid reacts with excess copper (II) oxide.
50 cm3 asid sulfurik 0.2 mol dm-3 bertindak balas dengan kuprum (II) oksida yang
berlebihan.
(i) Write the chemical equation for the reaction that takes place.
Tuliskan persamaan kimia bagi tindak balas yang berlaku. 3(d)(i)
............................................................................................................................... 1
[1mark]
(ii) Calculate the mass of salt X produced
Hitungkan jisim garam X yang terhasil.
[ Given that relative atomic mass Cu=64 , S=32 ,O=16 ]

[ Diberi jisim atom relatif Cu=64 , S=32 ,O=16 ]
3(d)(ii)
[3 marks] 3
(e) Draw a labelled diagram of the set-up of apparatus to convert copper (II) carbonate to
copper (II) oxide.
Lukis susunan radas berlabel untuk penukaran kuprum(II) karbonat kepada kuprum
(II) oksida .
3(e)
[2marks]
Total A3
10

SULIT 10 4541/2
4 The diagram 4.1 below shows the set-up of apparatus for two types of cells.
Rajah 4.1 di bawah menunjukkan susunan radas bagi dua jenis sel.
Cell 1
Sel 1
Cell 2
Sel 2
Diagram 4.1
Rajah 4.1
(a) Name the type of cells in cell 1 and cell 2.
Namakan jenis Sel 1 dan Sel 2.
4(a)
Cell 1 : Cell 2 :
Sel 1 : ……………………………. Sel 2 : …………………………….. 2
[ 2 mark]

SULIT 11 4541/2
(b) State the energy change that takes place in cell 1.

Nyatakan perubahan tenaga yang berlaku dalam Sel 1.
4(b)
…………………………………………………………………………………...
[1 mark] 1
(c) (i) State one observation in the electrolyte you would expect in beaker 2 of
cell 1.
Nyatakan satu pemerhatian yang dijangkakan di dalam elektrolit dalam bikar
2 Sel 1.
……………………………………………………………………………….
4(c)(i)
………………………………………………………………………………. 1
[1mark]
(ii) Explain your answer in 1(c)(i) .
Terangkan jawapan anda di 1(c) (i) .
…………………………………………………………………………… 4(c)(ii)
……………………………………………………………………………. 1
[1mark]
(d) Label the negative terminal of cell 1 in the diagram 4.1
Labelkan terminal negatif bagi sel 1 di rajah 4.1 4(d)
[1mark]
1
(e) State all the ions present in the electrolyte in cell 2 .

Nyatakan semua ions yang hadir dalam elektrolit di dalam sel 2 . 4(e)
………………………………………………………………………………. ….. 1
[1mark]
(f) The circuit in cell 2 is completed and the current is allowed to flow for ten minutes.
Litar dalam sel 2 dilengkapkan dan arus elektrik dibenarkan mengalir selama 10
minit.
(i) State the observation at the anode of this cell.

Nyatakan pemerhatian di anod bagi sel ini.
4(f)(i)
……………………………………………………………………………
…………………………………………………………………………….
1
[1mark]
(ii) Write the half equation for the reaction at the anode.
SULIT 12 4541/2
Tulis setengah persamaan bagi tindak balas di anod. 4(f)(ii)
…………………………………………………………………………… 1
[1mark]
(g) Give one similarity between Cell 1 and Cell 2 in terms of their redox reaction.
Berikan satu persamaan di antara Sel 1 dan Sel 2 dari segi tindak balas redoksnya.
…………………………………………………………………………………… 4(g)
………………………………………………………………………………… 1
[1mark]
Total A4
10
5 Diagram 5.1 shows the conversion of organic compounds from one homologous series to
another.
Rajah 5.1 menunjukkan perubahan sebatian organik dari satu siri homolog ke siri
homolog yang lain .
I II
Ethane Ethene 1,2-dibromoethane
III
IV
Ethanoic acid
Ethanol
Diagram 5.1
Rajah 5.1

SULIT 13 4541/2
(a) (i) Name the reaction that occurs in Conversion I

Namakan tindak balas yang berlaku dalam Perubahan I ? 5(a)(i)
…………………..…………..………………………………………………… 1
[1 mark]
(ii) Name the reagent used in Conversion II.

Namakan bahan tindak balas yang digunakan dalam Perubahan II. 5(a)(ii)
………….……………………………………………………………………… 1
[1 mark]
(b) Write the chemical equation for Conversion II.
Tuliskan persamaan kimia untuk Perubahan II . 5(b)
…….……………………………………………………………………………… 1
[1 mark]
(c) Name the catalyst used in Conversion III.

Namakan mangkin yang digunakan dalam Perubahan III . 5(c)
.............................……………………………………………………………………
1
[1 mark]
(d) Acidified potassium dichromate (VI) solution is used for Conversion IV.
Larutan kalium dikromat(VI) berasid digunakan untuk Perubahan IV.
(i) State the observation for this reaction.

Nyatakan pemerhatian bagi tindak balas ini . 5(d)(i)
……………………………………………………………………………..…… 1
[1 mark]
(ii) Write the chemical equation for Conversion IV.
Tuliskan persamaan kimia untuk Perubahan IV . 5(d)(ii)
…………………………………………………………………………………... 1
[1 mark]
(e) In conversion V, ethanol reacts with ethanoic acid to produce X.
Dalam perubahan V, etanol bertindak balas dengan etanoik asid untuk menghasilkan
X.
(i) Name the reaction in Conversion V
Namakan tindak balas dalam Perubahan V. 5(e)(i)
…………….………………………………………………………………… 1
[1 mark]
SULIT 14 4541/2
(ii) State one physical properties of X

Nyatakan satu sifat fizik bagi X. 5(e)(ii)
.…………………………….………………………………………………… 1
[1mark]
(iii) Name and draw the structural formula for X.

Nama dan lukiskan formula stuktur bagi X
5(e)(iii)
2
[2 mark]
Total A5
10

SULIT 15 4541/2
6 Diagram 6.1 shows a flow chart for the industrial manufacture of compound Z from
sulphuric acid and ammonia.
Rajah 6.1 menunjukkan carta aliran bagi pembuatan secara industri bahan Z daripada
asidsulfrik dan ammonia.
Contact Process Sulphuric acid

Proses Sentuh Asid Sulfurik
Reaction X
Tindak balas X Compound Z
Sebatian Z
Haber Process Ammonia

Proses Haber Ammonia
Diagram 6.1
Rajah 6.1
(a) Ammonia is produced in Haber Pocess.

Ammonia dihasilkan di dalam Proses Haber.
(i) State two reactants that are used in the reaction to manufacture ammonia. 6(a)(i)
Nyatakan dua bahan tindak balas yang digunakan dalam pembuatan
ammonia. 1
……………………………………………………………………………...
[1mark]
(ii) Write the chemical equation for the reaction.
Tuliskan persamaan kimia bagi tindak balas tersebut.
6(a)(ii)
...............................................................................................................................
[2marks] 2
(b) In diagram 6.1, sulphuric acid reacts with aqueous ammonia to form compound Z.
Dalam rajah 6.1 , asid sulfurik bertindak balas dengan larutan ammonia
membentuk sebatian Z
(i) Name reaction X.

Namakan tindak balas X
6(b)(i)
................……………………………………………………….................
[1 mark] 1

SULIT 16 4541/2
(ii) Write the chemical equation for the reaction.

Tuliskan persamaan kimia bagi tindak balas X
6(b)(ii)
……………………………………………………………………....................
[1 mark] 1
iii) State one of the uses of compound Z in daily life.

Nyatakan satu kegunaan sebatian Z dalam kehidupan seharian. 6(b)(iii)
………………………………………………………………………............ 1
[1 mark]
Diagram 6.2 shows the structural formula of two cleaning agent

(c) Rajah 6.2 menunjukkan formula struktur bagi dua agen pencuci
O
//
C
O-
Part P Part Q Part P Part Q

A B
Diagram 6.2
Rajah 6.2
(i) State which cleaning agent is a soap.

Nyatakan agen pencuci yang manakan sabun
6(c)(i)
……………………………………………………………………………
[1 mark] 1
(ii) Differentiate the cleaning agent molecules based on these aspects :

Bezakan molekul agen pencuci tersebut berdasarkan aspek-aspek berikut:
A B
Name of part Q
Nama bahagian Q
Sources
Sumber
Effectiveness in hard
water
Keberkesanan dalam air 6(c)(ii)
liat
3
[ 3 marks]
SULIT 17 4541/2
Total A6
10

SULIT 18 4541/2
Section B
[20 marks]

7 Table 7.1 shows the data obtained in an experiment when 5g of small-sized marble chips
react with 50 cm 3 1.0 moldm-3 hydrochloric acid.
Jadual 7.1 menunjukkan data yang diperolehi daripada satu eksperimen apabila 5g
serpihan marmar bertindak balas dengan 50 cm3 1.0 moldm-3 asid hidroklorik
Time/s 0 30 60 90 120 150 180 210

Burette reading / cm3 50.00 42.00 34.90 29.40 25.40 21.90 19.40 17.40
Volume of carbon dioxide 0.00 8.00 15.10 20.60 24.60 28.10 30.60 32.60
gas / cm3
Table 7.1
Jadual 7.1
(a) (i) What is meant by rate of reaction in this experiment?

Apakah yang dimaksudkan dengan kadar tindak balas di dalam eksperimen ini?
[1mark]
(ii) Write the ionic equation for the reaction that takes place.
Tuliskan persamaan ion bagi tindak balas yang berlaku.
[2marks]
(b) (i) Plot the graph of volume of carbon dioxide against time on a piece of graph
paper.
Plotkan graf isipadu gas karbon dioksida melawan masa di atas kertas graf.
[4marks]
(ii) Based on the graph plotted, calculate the rate of reaction at 60 seconds and 120
seconds. Comment on these values obtained and give explanation for the
different rates of reactions.
Berdasarkan graf yang diplot, kira kadar tindak balas pada 60 saat dan 120
saat. Komen ke atas nilai-nilai yang didapati dan terangkan mengapa perbezaan
kadar tindak balasnya.
[7 marks]

SULIT 19 4541/2
(c) Sketch on the same graph, the curve that would be obtained if large-sized marble
chips are used to replace the small-sized marble chips. By using the collision
theory, explain the effect of the size of marble chips used on the rate of reaction.
Lakarkan pada graf yang sama , lengkung yang akan didapati jika ketulan
marmar besar digunakan bagi menggantikan ketulan marmar kecil. Dengan
menggunakan teori perlanggaran, terangkan kesan saiz ketulan marmar yang
digunakan ke atas kadar tindak balas.
[6 marks]
8 (a) Table 8.1 shows the atomic radii and melting points of part of group 18
elements.
Jadual 8.1 menunjukkan jejari atom dan takat lebur sebahagian unsur18
kumpulan .
Physical Properties
Group 18 Sifat Fizik
Elements Atomic radius/ nm Melting Point / oC
Unsur Jejari atom / nm Takat Lebur /oC
Kumpulan 18
Helium 0.050 -270
Helium
Neon 0.070 -248
Neon
Argon 0.094 -189
Argon
Krypton 0.109 -156
Krypton
Table 8.1
Jadual 8.1
(i) By referring to the table, describe and explain the trend of change in the physical
properties of the Group18 elements as we down the group in the Periodic Table.
Dengan merujuk kepada jadual ini, huraikan dan terangkan pola perubahan sifat
fizik unsur-unsurKumpulan 18 apabila kita menuruni kumpulan ini dalam
Jadual Berkala.
[6marks]
(ii) Give the uses of the Group 18 elements in table 8 in our daily life.
Berikan kegunaan unsur-unsur Kumpulanr 18 dalam jadual 8 dalam kehidupan
seharian kita.
[4marks]

SULIT 20 4541/2
(b) (i) Explain why Group 18 gases are monoatomic whereas Group 17 gases are
diatomic.
Terangkan mengapa gas-gas Kumpulan 18 adalah monoatom manakala gas-
gas Kumpulan 17 dwiatom.
[3marks]
(ii) Describe briefly the chemical reactivity of group 17 elements as we go down the
group in the Periodic Table.
Huraikan secara ringkas kereaktifan tindak balas kimia unsur-unsur kumpulan
17 apabila kita menuruni kumpulan ini dalam Jadual Berkala.
[4marks]
(iii) Draw the electron arrangement of the compound formed when chlorine reacts
with sodium and name the chemical bond in this compound.
[ Proton Number : Na ; 11, Cl ; 17 ]
Lukiskan susunan elektron bagi sebatian yang terbentuk apabila klorin bertindak
balas dengan natrium dan namakan ikatan kimia dalam sebatian ini.
[ Nombor Proton : Na ;11 , Cl; 17 ]
[3marks]

SULIT 21 4541/2
Section C
[20 marks]
9 (a) Magnesium hydroxide is one of the substances that are added in tooth paste. Write the
chemical formula for magnesium hydroxide and state its function in tooth paste.
Magnesium hidroksida merupakan salah satu bahan yang terdapat dalam ubat gigi.
Tuliskan formula kimia bagi magnesium hidroksida dan nyatakan fungsinya dalam ubat
gigi.
[ 2 marks]
(b) Table 9.1 shows the concentration and pH values for solution P and solution Q. Solution
P is a strong acid solution while solution Q is a weak acid solution.
Jadual 9.1 menunjukkan kepekatan dan nilai pH bagi larutan P dan larutan Q. Larutan P
ialah larutan asid kuat manakala larutan Q ialah larutan asid lemah.
Solution Concentration / mol dm-3 pH value

Larutan Kepekatan / mol dm-3 Nilai pH
P 0.1 1.0
Q 0.1 3.0
Table 9.1
Jadual 9.1
(i) Name an example of a strong acid and a weak acid.

Namakan satu contoh asid kuat dan satu contoh asid lemah.
[2 marks]
(ii) Explain why the pH values for these solutions are different.
Terangkan mengapa nilai pH bagi kedua-dua larutan ini adalah berbeza.
[5 marks]
(c) You are required to prepare dry zinc sulphate salt. The chemical substances
supplied are
 zinc nitrate solution
 dilute sulphuric acid
 sodium carbonate solution
Describe a laboratory experiment to prepare the salt. In your description, include
chemical equations involved.

SULIT 22 4541/2
Anda dikehendaki menyediakan garam zink sulfat yang kering. Bahan-bahan kimia
yang diberikan adalah
 larutan zink nitrat
 larutan asid sulfurik cair
 larutan natrium karbonat
Huraikan satu eksperimen makmal bagaimana anda boleh menyediakan garam

tersebut. Dalam penerangan anda, sertakan persamaan kimia yang terlibat.
[11 marks]
10 (a) In an experiment to determine the heat of precipitation of lead (II) carbonate, 50.0 cm3 of
2.0 mol dm-3 lead(II) nitrate solution is reacted with 50.0 cm3 of 2.0 mol dm-3 sodium
carbonate solution. Increment of the temperature in the mixture is 10 oC.
Dalam satu eksperimen untuk menentukan haba pemendakan bagi plumbum(II)

karbonat, 50.0 cm3 larutan plumbum(II) nitrat 2.0 mol dm-3 bertindak balas dengan 50.0
cm3 larutan natrium karbonat 2.0 mol dm-3. Peningkatan suhu campuran ialah 10oC.
The equation for the reaction is :

Persamaan kimia bagi tindak balas ialah:
Pb(NO3)2 + Na2CO3  PbCO3 + 2NaNO3
Calculate the value of the heat of precipitation of lead(II) carbonate in this reaction.
[Specific heat capacity of water is 4.2 J g -1 oC-1 ]
Hitungkan nilai haba pemendakan bagi plumbum(II) karbonat dalam tindak balas ini.
[Muatan haba spesifik bagi air ialah 4.2 J g-1 oC-1]
[4 marks ]
(b) Table 10.1 shows the molecular formula and heat of combustion of three types of
alcohol.
Jadual 10.1 menunjukkan formula molekul dan haba pembakaran bagi tiga jenis alcohol.
Alcohol Molecular formula Heat of combustion/kJ mol -1

Alkohol Formula Molekul Haba pembakaran/kJ mol-1
Methanol
CH3OH 725
Metanol
Ethanol
C2H5OH 1 376
Etanol
Propan-1-ol
C3H7OH 2 015
Propan-1-ol
Table 10.1
Jadual 10.1

SULIT 23 4541/2
(i) What is the meaning of the ‘heat of combustion of an alcohol’?

Apakah yang dimaksudkan dengan ’haba pembakaran alkohol’ ?
[1 mark]
(ii) Explain why there are differences in the value of heat of combustion of the
alcohols in Table 10.1
Terangkan kenapa terdapat perbezaan dalam nilai haba pembakaran bagi alcohol-
alkohol dalam Jadual 10.1
[3 marks]
(c) Describe an experiment that you can carry out in your school laboratory to determine the
heat of combustion of ethanol. Your description should include precautionary steps and
the steps involved in the calculation.
Huraikan satu eksperimen yang dapat anda jalankan dalam makmal sekolah bagi
menentukan haba pembakaran etahol. Huraian anda hendaklah merangkumi langkah
berjaga-jaga dan langkah-langkah pengiraan yang berkaitan.
[12marks]

SOALAN TAMAT

SULIT 24 4541/2


Nama
4541/3
Chemistry Kelas
Kertas 3
September
2010
1 1/2 jam

DENGAN KERJASAMA
____________________________________________________________
CHEMISTRY
Kertas 3
Satu jam tiga puluh minit
1. Tuliskan nama dan tingkatan pada ruang

yang disediakan. Untuk kegunaan pemeriksa sahaja
Markah Markah
Soalan
2. Kertas soalan ini adalah dalam dwi bahasa. Penuh diperolehi
3. Calon hendaklah membaca arahan pada 1 33

halaman 2 .
2 17
Jumlah 50
4541/3 [ Lihat sebelah

SULIT
2
SULIT
1. This question paper consists of two questions. Answer all questions.

Kertas soalan ini mengandungi dua soalan. Jawab semua soalan.
2. Write your answer for Question 1 in the spaces provided in the question paper.
Tulis jawapan anda bagi Soalan 1 pada ruang yang disediakan dalam kertas soalan ini.
3. Write your answers for Question 2 on the writing paper provided by the invigilators.
Tulis jawapan anda bagi Soalan 2 pada kertas tulis yang disediakan.
4. You may use equations, diagrams, tables, graph and other suitable methods to explain
your answer.
Anda boleh menggunakan persamaan , rajah, jadual, graf dan cara lain yang sesuai
untuk menjelaskan jawapan anda.
5. Show your working, it may help you to get marks.

Tunjukkan kerja mengira, ini membantu anda mendapatkan markah.
6. If you wish to change your answer, cross out the answer that you have done. Then write
down the new answer.
Jika anda hendak menukar jawapan, batalkan jawapan yang telah dibuat. Kemudian tulis
jawapan yang baru.
kurungan.
8. The time suggested to answer each of the questions is 45 minutes.

Masa yang dicadangkan untuk menjawab setiap soalan ialah 45 minit.

Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogram.

Serahkan kertas jawapan anda di akhir peperiksaan

SULIT
3
SULIT
Answer all question
Jawab semua soalan
1 An experiment is carried out to determine the end point of a neutralisation process. For
25.00 cm3 of aqueous potassium hydroxide 0.1 mol dm-3 is titrated using hydrochloric acid Examiner’s
Use
with an unknown concentration using phenolphthalein as an indicator. Hydrochloric acid is
added until the end point of titration is reached.
Table 1 shows the three burette readings for the titration that have been conducted.
Satu eksperimen telah dijalankan untuk menentukan takat akhir bagi proses peneutralan.
25.00 cm3 larutan kalium hidroksida 0.1 mol dm-3 dititratkan dengan asid hidroklorik yang
kepekatannya tidak diketahui dengan menggunakan penunjuk fenolftalein. Asid hidroklorik
ditambah sehingga takat akhir pentitratan dicapai.
Jadual 1 menunjukkan tiga bacaan buret bagi pentitratan yang telah dijalankan.
Titration I II III
Number.
Bilangan Titratan
Initial Burette
Reading
Bacaan Awal
Buret
………….. ………….. …………..
Final Burette
Reading
Bacaan akhir
buret
………….. ………….. …………..

Table 1
Jadual 1

SULIT
4
SULIT
(a) State one observations at the end-point of this experiment.
Nyatakan satu pemerhatian pada takat akhir eksperimen ini
……………………...…………………………………………………………………….
……………………………………………………………………………………………
[3 marks] 3
(b) Record all the burette readings in the spaces provided in Table 1.
Rekodkan semua bacaan buret pada ruang yang disediakan dalam Jadual 1
[3 marks] 3
(c) Construct a table and record the initial burette reading, final burette reading and
volume of hydrochloric acid used for each titration.
Bina satu jadual dan rekodkan bacaan awal buret, bacaan akhir buret dan isipadu
asid hidrokorik yang digunakan bagi setiap pentitratan.
[3 marks] 3
(d) (i) Calculate the average volume of hydrochloric acid used in the experiment?
Hitungkan isipadu purata asid hidroklorik yang digunakan dalam eksperimen ini
[3 marks] 3

SULIT
5
SULIT
(ii) The chemical equation for the reaction is :
Persamaan kimia bagi tindak balas ini ialah:
KOH + HCl → KCl + H2O
Determine the concentration of hydrochloric acid used.

Tentukan kepekatan asid hidroklorik yang digunakan.
[3 marks] 3
(e) (i) If the hydrochloric acid is replaced by sulphuric acid of the same
concentration, predict the volume of sulphuric acid required to neutralise
25.0 cm3 of the potassium hydroxide solution.
Jika asid hidroklorik itu di gantikan dengan asid asid sulfurik berpekatan yang
sama, ramalkan isipadu asid sulfurik yang diperlukan untuk meneutralkan
25.0 cm3 larutan kalium hidroksida itu.
……………………………………………………………………………………...
………………………………………………………………………………….......
[3 marks] 3
(ii) Explain your answer in (e) (i).

Terangkan jawapan anda dalam (e) (i)
...................................................................................................................................
...................................................................................................................................
...................................................................................................................................
……………………………………………………………………………………...
3
[3 marks]

SULIT
6
SULIT
In the next experiment, a student carried out an experiment to investigate the relationship
between the concentration of an alkali solution with its pH value. The pH values of three
different concentrations of potassium hydroxide are determined using pH meter.
Dalam eksperimen lain, seorang pelajar telah menjalankan satu eksperimen untuk mengkaji
hubungan antara kepekatan larutan alkali dengan nilai pH larutan itu. Nilai pH bagi tiga
kepekatan yang berbeza larutan kalium hidroksida telah ditentukan menggunakan meter pH.
Table 2 shows the pH readings of different concentration of solution in this experiment.

Jadual 2 menunjukkan bacaan pH bagi larutan-larutan yang diperolehi dalam eksperimen
ini.
Concentration (mol dm-3)

Kepekatan (mol dm-3)
0.1 0.01 0.001
Table 2
Jadual 2
(f) State a hypothesis for this experiment.
Nyatakan satu hipotesis untuk eksperimen ini.
……………………………………………………………………………………………
……………………………………………………………………………………………
[3 marks] 3
(g) State the variables for this experiment.

Nyatakan pembolehubah-pembolehubah dalam eksperimen ini.
(i) Manipulated variable:
Pembolehubah dimanipulasikan:
.....................................................................................................................
(ii) .
Responding variable:
Pembolehubah bergerak balas:
(iii) .....................................................................................................................
Constant variable:
Pembolehubah dimalarkan:
3
.....................................................................................................................

SULIT
7
SULIT
[3 marks]
(h) Predict the pH value of 0.0001 mol dm-3 potassium hydroxide.

Ramalkan nilai pH bagi larutan kalium hidroksida 0.0001 mol dm-3.
……………………………………………………………………………………………
[3 marks] 3
(i) Classify the following alkalis into strong alkali and weak alkali.
Kelaskan alkali-alkali berikut kepada alkali kuat dan alkali lemah.
 Sodium hydroxide solution

Larutan natrium hidroksida
 Ammonia solution
Larutan ammonia
 Calcium hydroxide solution

Larutan kalsium hidroksida
 Potassium hydroxide solution

Larutan kalium hiroksida
 Sodium hydrogen carbonate solution

Larutan natrium hidrogen karbonat

[3 marks] 3
Total
1

SULIT
8
SULIT
2 Choose one of the following tasks:

Pilih satu daripada tugasan berikut:
Task 1
Tugasan1
Diagram 1
Gambarajah 1
Diagram 1 shows the apparatus set-up for an experiment to compare the electrical
conductivity between two types of chemical compound, P and Q.
Rajah 1 menunjukkan susunan radas bagi satu eksperimen untuk membezakan
kekonduksian elektrik di antara 2 jenis sebatian kimia, P dan Q.
Refering to the situation above, plan a laboratory experiment to differentiate between 2

types of named chemical compound based on electrical conductivity.
Merujuk kepada situasi di atas, rancang satu eksperimen dalam makmal untuk
membezakan 2 jenis sebatian kimia yang dinamakan berdasarkan kekonduksian elektrik.
Task 2
Tugasan 2
Photograph 1
Photograph 1 shows a tourist ship in the middle of the ocean. The ship body is made of
iron. To prevent from rusting the ship body is covered with the more electropositive metal.
This metal acts as a sacrificial anode thus the iron is protected.
Gambarfoto 1 menunjukkan sebuah kapal pelancongan di tengah lautan. Badan kapal
diperbuat daripada besi. Bagi mengelakkan pengaratan, badan kapal dilapisi dengan
logam yang lebih elektropositif. Logam ini bertindak sebagai logam korban yang dapat
melindungi besi.
You are given some iron nails, magnesium ribbon and copper strip.
Refering to the situation above, plan a laboratory experiment to investigate the effect of
other metal on the corrosion of iron.
Anda diberi paku besi, pita magnesium, dan kepingan kuprum.
Merujuk kepada situasi di atas, rancang satu eksperimen dalam makmal untuk mengkaji
kesan logam lain terhadap pengaratan besi.

SULIT
9
SULIT
Your planning should include the following aspects:

(a) Problem statement

Pernyataan masalah

Semua pembolehubah
(c) Hypothesis
Hipotesis

(e) Procedure
Prosedur

Penjadualan data
[17 marks]

KERTAS SOALAN TAMAT

SULIT
SULIT
4541/1
4541/2
Chemistry
Mark Scheme
Paper 1 and 2

DENGAN KERJASAMA
____________________________________________________
CHEMISTRY
Mark Scheme
Paper 1 and Paper 2
SET 2
Skema Pemarkahan ini mengandungi 11 halaman bercetak.

Answers for Chemistry Paper 1
1 B 2 C 3 C 4 A 5 C
6 D 7 B 8 C 9 A 10 D
11 B 12 D 13 A 14 C 15 C
16 D 17 B 18 D 19 C 20 C
21 B 22 A 23 B 24 D 25 B
26 A 27 B 28 A 29 C 30 D
31 D 32 B 33 D 34 D 35 A
36 B 37 B 38 D 39 B 40 B
41 C 42 C 43 A 44 C 45 C
46 D 47 C 48 D 49 A 50 A
2
Answers for Chemistry Paper 2
SECTION A
1 (a) T1 oC 1
(b)(i) AB : liquid 1
(ii) CD : solid 1
(c) 1. Heat energy loss to the surrounding 1
2. balanced by heat energy liberated by particles 1
(to attract one another to form solid)
(d)
1
1
(e)(i) Naphthalene / bromine 1

(ii) Iron
1
(iii) Ions
1
(f) Diffusion
TOTAL 10
3
2 (a) (i) Group 13, Period 3 1

(ii) J and L 1
(b) (i) Burns with yellow flame // produces ‘hiss’ sound 1
(ii) 2L + 2H2O 2 LOH + H2 2
(c) M 1
(d) (i) Covalent bond 1
(ii) [1. correct number of occupied electron shells and correct 1
electrons
in each shell for all the atoms, nuclei shown ] 1
[2. four atoms of N combine covalently (sharing a pair of
electrons) with one atom of K ]
(iii) Low boiling point // insoluble in water// soluble in inorganic 1

solvent// cannot conduct electricity ( any other acceptable physical
properties
Total 10
4
3 (a) Black 1
(b) Copper(II) sulphate 1
(c) (i) Sodium / potassium carbonate or any suitable carbonate salts 1
solution
(ii) Cu 2+ + CO3 2- → CuCO3 1
(d) (i) CuO + H2SO4 → CuSO4 + H2O 1
(ii) No of mol acid = 0.2 x 50 // 0.01 mol 1

1000
No of mol of CuSO4 = 0.01 mol 1
Mass= 0.01 x 160 // 1.6 g 1
(e)
Copper(II) carbonate / salt Q

Functional apparatus 1
Labelled – heat, copper(II) carbonate, limewater 1
Total 10

4 (a) Cell 1 : Chemical cell // Voltaic Cell Cell 2 : Electrolytic Cell 2
(b) Chemical energy to Electrical Energy 1
(c) (i) The intensity of blue colour of electrolyte decreases 1
(ii) The concentration of Cu2+ ions decreases in the electrolyte 1
(d) Magnesium electrode 1
(e) Cu2+, SO42-, H+, OH- 1
(f) (i) Colourless gas bubbles released 1
(ii) 4 OH- O2 + 2H2O 1
(g) In both cells, oxidation occurs at the anode // reduction occurs at the 1
cathode // electrons flow from anode to cathode
Total 10

5 (a) (i) Hydrogenation 1
(ii) Bromine 1
(b) C2H4 + Br2 → C2H4Br2 1
(c) Concentrated phosphoric acid 1
5
(d) (i) Colour change from orange to green 1

(ii) C2H5OH + 2[O] → CH3COOH + H2O 1
(e) (i) Esterification 1
(ii) Pleasant / fruity smell 1
(iii) Ethyl ethanoate 1
1

Total 10

6 (a) (i) Hydrogen and nitrogen 1
(ii) 3H2 + N2  2NH3 [ 1. correct reactants and products 1+1
2. balanced equation ]
(i) Neutralization 1
(b)
(ii) H2SO4+ 2NH3  (NH4)2SO4 1
//H2SO4+ 2NH4OH  (NH4)2SO4 + H2O
(iii) Fertilizer 1
(c)
(i) B 1
A B
(ii)
Name of part Q Sulphonate Carboxylate 1
Sources petroleum Oil // Fat

1
Effectiveness in hard Effective Not effective
water
1
TOTAL 10
6
SECTION B
7 (a) (i) Change of volume of carbon dioxide per unit time 1 1
(ii) CO32- + 2H+ CO2 + H2O
[ 1. correct reactants and products 1

2. balanced equation ] 1 2
(b) (i) 1. Axis labelled and with units 1

2. Scales appropriate (size: min ¾ of graph paper) and 1
consistent
3. Points correctly plotted 1 4
4. Smooth curve graph drawn 1
(ii) 1. Tangents of curves drawn at 60s and 120 s 1
2. calculation of rate of reaction at 60s ; 120s 1+1
3. correct values and units for rates of reactions at 60s ; 120s 1+1
4. rate of reaction at 60s is higher than at 120s 1
5. concentration of hydrochloric acid decreases with time 1 7
(c) Volume of gas / cm3
Small marble chips
Large marble chips
Time / s
[1. curve with less steep slope drawn on the same graph and 1
labelled
[2. the final part of the slope is still increasing ( no plateau)] 1
3. small size marble chips have larger total surface area over 1
volume exposed for collisions
4. frequency of collisions between carbonate ions and 1
hydrogen ions is higher
5. frequency of effective collisions increases 1
6. The rate of reaction will increase 1 6

Total 20
8 (a) (i) 1. Atomic radius increases as 1

2. more number of shells is needed to fill the increasing 1
7
number of electrons present in the atoms

3. Melting points increases down the group 1
4. atomic size increases down the group, 1
5. attraction forces between atoms become stronger 1
6. more heat is needed to overcome this stronger force of 1 6
attraction
(ii) 1. Helium - gas used to fill airships / weather // fill up the 1
diver’s oxygen tank // to cool metals to make
superconductors
2. Neon - used in advertising lights / television tubes 1
3. Argon - used o fill up light bulbs // provide inert 1
atmosphere for welding at high temperature
4. Krypton - used in lasers to repair retina of the eye // used 1 4
to fill up photographic flash lamps.
(b) (i) 1. The valence electrons in the group 18 atoms are stable / 1
(duplet and octet) while in group 17 , the atoms have 7
valence electrons.
2. In order to achieve stable electron arrangement, each 1
atom of Group 17 elements need to share its valence
electron with another atom.
3. For group 18 elements, the atoms need not have to share 1 3
their valence electrons.
(ii) 1. The reactivity decreases 1

2. In chemical reaction, halogen atoms need to gain one 1
electron (into their outermost shell.)
3. The atomic size of halogens increases down the group// 1
the outermost occupied shell of each atom becomes
further from nucleus
4. The strength of nucleus to attract electron becomes 1 4
weaker
(ii) 1. Ionic bond 1
2. [- correct number of occupied electron shells, correct 1
electrons in each shell and nuclei shown for both
ions ]
-one sodium ion combine with one chloride ion, 1 3
correct charges of ions written]
Total 20
8

SECTION C
9 (a) Mg(OH)2 1
To neutralise the acid produced by bacteria 1 2
(b) (i) Sulphuric / hydrochloric / nitric acid 1
Ethanoic acid or any suitable weak acid 1 2
(ii) 1. Strong acid ionises completely in water 1
2. to produce high concentration of hydrogen ions 1
3. Weak acid ionises partially in water 1
4. to produce low concentration of hydrogen ions 1
5. The higher the concentration of hydrogen ions, the lower 1
the pH value // The lower the concentration of hydrogen
ions, the higher the ph value 5
(c) 1. Pour [20-100]cm3 of zinc nitrate solution [0.1-1.0]mol dm-3 1

into a beaker
2. Add [20-100]cm3 of sodium carbonate solution [0.1-1.0]mol 1
dm-3
3. Stir and filter the mixture to get the precipitate/residue 1
4. Pour [20-100]cm3 dilute / [0.1-1.0]mol dm-3 sulphuric acid into 1
a beaker
5. Add the residue/precipitate into the acid until in excess 1
6. Stir and filter the mixture 1
7. Heat the filtrate until saturated solution obtained / 1/3 of 1
original volume 1
8. Cool the saturated solution 1
9. Filter and dry the crystal 1
10. Zn(NO3)2 + Na2CO3  ZnCO3 + 2NaNO3 1 11
11. ZnCO3 + H2SO4  ZnSO4 + H2O + CO2
Total 20
10 (a) 50 x 2
Number of mole of lead(II) nitrate = 1000 = 0.1 mol
or
50 x 2
Number of mole of sodium carbonate = 1000 = 0.1 mol
1
Ratio of mole :
9
1 mol Pb(NO3)2 / Na2CO3 → 1 mol PbCO3

 0.1 mol Pb(NO3)2 / Na2CO3 → 0.1 mol PbCO3 1
Energy change/heat given off = (50+50) × 4.2 × 10

= 4200 J 1
4200
Heat of precipitation of PbCO3 = 0 .1
= 42000 J mol-1 / 42 kJ mol-1

1…4
(b) (i) The heat given off when one mole of an alcohol is burnt
completely in an excess of oxygen. 1
(ii) As the number of carbon atom increase, the value of heat combustion 1
increase.
The greater the number of carbon atoms, the more products will be 1
obtained. 1…3
More heat is released for the formation of bonds
(c) Procedure :
1. Measure [100 -250] cm3 of water and pour it into the copper
container /aluminium can 1
2. Measure and record the initial temperature of the water. 1
3. Fill the small lamp with alcohol* then weigh it and record the
initial mass. 1
4. Light the wick of the lamp. 1
5. Place the lamp as near as possible to the copper container.//
[ Diagram : Using wooden block ] 1
6. [The apparatus is protected by a wind shield] // [Diagram] 1
7. Stir the water continuously. 1
8. Put out / blown out the flame when the temperature rises [ 10 –
30 ] oC and record the highest temperature of the water. 1
9. Weigh the lamp as quickly as possible and record the final mass. 1
Result :
Initial temperature of the water/ oC = T1
Highest temperature of the water/ oC = T2
Temperature rise of the water/ oC = T2 – T1

1
Initial mass of lamp + ethanol / g = m1
Final mass of lamp + ethanol / g = m2
Mass of ethanol that was burnt / g = m1 – m2
Calculation :
10
Energy chage/heat given off = 200 × 4.2 × (T2 – T1) 1
m1 – m2
Number of mole of alcohol = 1
Mr of ethanol
Energy
Heat of combustion of alcohol*, ΔH =
Number of mole of
l h l
200 × 4.2 × (T2 – T1)

= m1 – m2 1
Mr of ethanol
13…12
TOTAL 20
SKEMA PEMARKAHAN TAMAT
11
4541/3
Chemistry 3
September
2010

DENGAN KERJASAMA
____________________________________________________________
CHEMISTRY 3
PERATURAN PEMARKAHAN
SET 2
Skema Pemarkahan ini mengandungi 14 halaman bercetak


No.
Able to state the observation before and after the end-point
1 (a) correctly
3
Sample answer
The colour of the solution changes from pink to colourless
[Able to state an observation ]

2
Sample answer
The solution turns colourless
Able to give an idea of observation

1
Sample answer
The solution change colour
(b) Able to record all the volumes accurately to two decimal 3

places with unit
Initial burette readings: 0.50 cm3, 5.00 cm3, 0.00 cm3

Final burette readings : 24.50 cm3, 30.00 cm3, 26.00 cm3
Able to record all the volumes correctly to one decimal place 2

wihout unit.
Initial burette readings: 0.5, 5.0, 0.0

Final burette readings : 24.5, 30.0, 26.0
Able to write at least four readings of the volumes accurately. 1

Question
Details Score
No.
(c) Able to construct a table correctly containing :
(i) three labelled columns with units.
(ii) record all the burette readings.
(iii) volume of acids used accurately.
Sample answer
Titration No. I II II 3
Initial burette 0.50 5.00 0.00
reading/cm3
Final burette 24.50 30.00 26.00
reading/cm3
Volume of acid 24.00 25.00 26.00
used/cm3
Able to construct a table correctly containing:
(i) three labelled columns without units

(ii) record all the burette readings 2
(iii) volume of acids used
Able to construct a table with at least three labels and four 1

correct readings
(d) Able to calculate the average volume of acid used correctly

and with unit.
Sample answer:
Volume of acid used = 24.00 + 25.00 + 26.00 3
3
= 25.00 cm3
(i)
Able to calculate the average volume of acid correctly without
unit. 2
Able to show the calculation of average volume of acid used

but incorrect answer 1


No
Able to calculate the concentration of potassium hydroxide
with units correctly
Sample answer:
HCl + KOH KCl + H2 O .........................1
1 mol 1 mol
(ii) 3
MaVa = MbVb
0.1 x 25.00 = Mb x 25.00 ......................... 1
Mb = 0.1 mol dm-3 ...........................1
Able to calculate the concentration of potassium hydroxide

correctly without unit
Sample answer:
Mb = 0.1 x 25.0 2
25.0
= 0.1
Able to show the calculation or the concentration of

potassium hydroxide without unit 1
Sample answer:
No of mole = 0.1 x 25.0 // 0.1
25.0
(e) Able to predict the volume of sulphuric acid accurately to 2

decimal places with unit
3
Answer:
(i)
12.50 cm3
Able to predict the volume of sulphuric acid accurately

without unit
Answer:
2
12.50

No
Able to predict the volume of sulphuric acid without units
Answer:
12.5
1
(e) Able to state all the three following informations correctly

Sample answer:
(ii) 1 Hydrochloric acid is a monoprotic acid
2 Sulphuric acid is a diprotic acid 3
3 The concentration of H+ ions in sulphuric acid is twice than
the concentration of H+ ions in hydrochloric acid
Able to state any two points correctly

2
Able to state at least one point correctly 1
(f) Able to state the hypothesis accurately with direction

Sample answer:
The higher/ the lower the concentration of OH- ions, the
3
higher / lower the pH value.
Able to state the hypothesis without direction

2
Sample answer:
The pH value depends on the concentration of alkali /
the higher the concentration of potassium hydroxide the lower
the pH value
Able to give an idea of the hypothesis of the experiment

Sample answer:
1
Different concentration affects pH value

(g) Able to state all the three variables correctly
Answer:
Manipulated variables: Concentration of potassium
hydroxide solution
Responding variables : pH value 3
Controlled variables: Type of alkali
[Able to state any two variables correctly]

2
[Able to state at least one variable correctly]
1
(h) Able to predict the pH value correctly

Answer:
3
pH value = 10.0
Able to predict the pH range correctly

2
Sample answer: Lower than 11.0
Able to give an idea about the pH value
1
Sample answer: The pH value change
(i) Able to classify all the five alkalis into strong alkalis and weak
alkalis correctly
Sample answer:
Strong Alkali Weak Alkali
3
Sodium hydroxide solution Sodium hydrogen
Calcium hydroxide solution carbonate solution
Potassium hydroxide solution Ammonia solution
Able to classify the four alkalis into strong alkali and weak
2
alkalis correctly

No
Able to classify the three of alkalis into strong alkalis and
1
weak alkalis correctly
[No response or wrong response] 0
Task1 Details
Question Score
No
Able to give the problem statement accurately and in question
form. 3
2 (a) Sample answer:

What is the differences in electrical conductivity between ionic
compound and covalent compound?

2
Sample answer:
How do different types of chemical compounds affect the
electrical conductivity?
Sample answer: 1
To compare/investigate/study the electrical conductivity
between different type of chemical compound
Able to state all the three variables correctly.
Sample answer:
3
Manipulated variable: Type of chemical compound
(b) Responding variable : Electrical conductivity / the light of
the bulb
Controlled variable : Mass of the substance

2
Able to state at least one variable correctly
1

and the responding variable correctly.

Ionic / covalent compound conduct electricity, covalent
compound / ionic does not conduct electricity

and the responding variable .
Sample answer: 2
Covalent / ionic compound conduct / does not conduct
electricity
Able to state the idea of the hypothesis.

1
Sample answer:
Different compound gives different conductivity
Sample answer:
Materials
1 Any ionic compound
2 Any covalent compound
Apparatus
1 Crucible
(d) 3
2 Batteries
3 Bulb
4 Switch
5 Carbon electrodes
6 Tripod stand
7 Bunsen Burner
8 Pipe-clay triangle
9 Crocodile wire
Sample answer:
Materials
1 Any ionic compound
2 Any covalent compound
2
Apparatus
1 Any container
2 Batteries
3 Bulb/voltmeter/ammeter
4 Electrodes
5 Bunsen Burner
6 Crocodile wire
Sample answer:
Material
Any ionic/covalent compound
1
Apparatus
1 Ammeter/bulb/voltmeter
2 Electrodes
Able to state the following seven steps:
Sample answer:
1 Fill a crucible with a solid lead(II)bromide, PbBr2 until it
is half full.
2 Dip into the solid lead(II)bromide, PbBr2 with carbon
electrodes.
(e) 3
3 Connect the electrodes with bulb.
4 Heat the solid lead(II)bromide until it melts.
5 Turn on the switch.
6 Record the observation.
7 Repeat steps 1 to 6 / the experiment using naphthalene,
C10H8
Able to state at least the following steps:
Sample answer: 2
Steps 4 and 6
10
Able to state at least the following steps:
Sample answer: 1
Step 4
(f) Able to tabulate the data that includes the following

information:
1. Correct titles
2. Complete list of chemical compound
Sample answer :
3
Chemical compound Observation
Lead(II)bromide
Naphthalene

2. Incomplete list of chemical compound
Sample answer :
2
Observation
lead(II)bromide/
Naphthalene

1. Heading for observation
Sample answer :
1
Observation

11
Task 2
No
Able to give the statement of the problem accurately and
response is in question form.
Sample answer:
2 (a)
How do different types of metals in contact with iron affect 3
rusting?

2
Sample answer:
How do different types of metals affect rusting?
Sample answer:
1
Do metal affect rusting//
To investigate/study the effect of other metal on the corrosion
of iron.
Sample answer:
3
Manipulated variable: Different metal in contact with iron
(b) Responding variable: Rusting of iron // Rate of rusting
Controlled variable: Iron nails// medium in which
the iron nails are kept // temperature

2
1

0
12
Question Details
Score
No

When a more/less electropositive metal is in contact with iron,
the metal inhibits/speeds up rusting.

Sample answer:
2
The metal inhibits/speeds up rusting when a more / less
electropositive metal is in contact with iron.
Sample answer: 1
Different types of metals speeds up / inhibits rusting
Sample answer:
Materials
1 Iron nails
2 Magnesium ribbon, copper strip
(d) 3
4 Sand paper
Apparatus
10 Test tubes
11 Test tube rack
13
Sample answer:
Materials
1 Iron nails
2 Magnesium/ copper strip 2
Apparatus
Test tube/beaker/any container
Sample answer:
Material
Any metal 1
Apparatus
Test tube/beaker/ any container
Able to state the following five steps:
Sample answer:
1 Clean all the three iron nails, magnesium ribbon and
copper strip with sand paper
2 Coil two iron nails tightly with magnesium ribbon and
copper strip respectively
(e) 3 Place all the iron nails in the different test tubes. 3
4 Pour hot jelly solution containing potassium
hexacyanoferrate(III) and phenolphthalein indicator
into the test tubes until completely cover the nails.
5 Keep the test tubes in a test tube rack and leave them
aside for a day.
6 Record the observations.
Steps 2,3,4 and 6

2
Step 3
1

14
Able to tabulate the data that includes the following

(f) information :
1. Correct titles
2. Complete list of iron and the metals in contact with iron.
Sample answer :
Test tube Observation // Intensity of blue colouration // 3
presence of pink colouration
Fe
Fe + Mg
Fe + Cu

2. Incomplete list of iron and the metals in contact with iron.
Sample answer :
Test tube/ Observation // Intensity of blue colouration //
2
Fe only
Fe + Mg /
Cu
Able to construct a table

1. Heading for observation
Sample answer :
Test tube/ Observation // Intensity of blue colouration // 1
Fe
END OF MARK SCHEME

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PERSIDANGAN KEBANGSAAN PENGETUA-PENGETUA

JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

Kertas soalan ini mengandungi 25 halaman bercetak.

INFORMATION FOR CANDIDATES

1. This question paper consists of 50 questions.

2. Answer all questions.

4. Blacken only one space for each question.

7. You may use a non-programmable scientific calculator.

MAKLUMAT UNTUK CALON

1. Kertas soalan ini mengandungi 50 soalan.

2. Jawab semua soalan

3. Jawab dengan menghitamkan ruangan yang betul pada kertas jawapan.

4. Hitamkan satu ruangan sahaja bagi setiap soalan.

7. Anda dibenarkan menggunakan kalkulator saintifik yang tidak boleh diprogramkan

Question 1 to Question 50 are followed by four options A, B, C or D.

1 Which of the following substances undergoes sublimation process when heated?

2 Diagram 1 shows the set-up of the apparatus to study Process I.

4 Which of the following substances consists of atoms?

5 The graph below shows the cooling curve of naphthalene.

Number of protons Number of neutrons Number of electrons

8 The following statements are true about lead-acid accumulator except

A lead plate is the negative terminal

10 Table 2 shows the electron arrangement of atoms P , Q , R and T

A One sodium atom donates one electron to one oxygen atom

Which of the following statements is true for the above reaction ?

A The blue colour of the copper(II) sulphate solution remains unchanged

13 Diagram 3 shows a set-up of apparatus of a redox reaction.

B II and III only

14 Half equation below represents a reaction.

What is meant by oxidation reaction based on the equation ?

State the correct observation for the reaction.

16 Which of the following reagents can change iodide ion to iodine?

I Acidified potassium dichromate(VI ) solution

C bromine and lead atoms are free to move

19 Which of the following is true about weak acid?

A A rheostat is used instead of an ammeter

21 Which particle causes an aqueous solution of ammonia to exhibit alkaline properties?

22 Which of the following methods is suitable to prevent rusting of iron?

A Painting the engine of a car

H2SO4 + 2NaOH → Na2SO4 + 2H2O

A Ammonia solution and sodium sulphate

27 Which of the following salts is insoluble in water?

28 The equation below shows thermal decomposition of 12.4 g of copper(II) carbonate.

CuCO3 (s)  CuO (s) + CO2 ( g)

What is the mass of copper(II) oxide formed ?

[ Relative atomic mass : Cu=64, O=16, C=12 ]

31 The chemical equation below shows the reaction between P and Q.

P + Q → salt + H2O + CO2

A Zinc and hydrochloric acid

The reaction is catalysed by

33 Why are detergents more effective than soap?

34 In the saponification process, concentrated sodium hydroxide solution is added to

A Ceramic is chemically inert

A Tartrazine and sodium benzoate

37 Diagram 6 shows an energy level diagram

A the heat of neutralization is – 57 kJ mol-1

A Increase the concentration of the reactant

39 Diagram 7 shows the energy level diagram of a reaction.

40 The following is the thermochemical equation for a reaction.

Zn + CuSO4 ZnSO4 + Cu ∆H = -210 kJ mol-1

Mixture of the solution

What is the heat of precipitation of silver chloride?

The rate of reaction in this experiment can be increased by

SPM Trial 2010 Che Q&A (Melaka)

SPM Trial 2010 Che Q&A (Melaka)