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Preliminary Note
Uranium analysis
In view of the novel deep geological origin of the oil being drilled for in the Gulf of
Mexico and the concerns about the effects of the accident, it was of interest to
examine the radioactivity content of samples of the oil. Samples of oil the Deepwater
Horizon oil spill were collected from the first oil contamination which came ashore on
the coast of Florida and analysed for radioactivity and total Uranium in the laboratory
of Green Audit and at the Scientifics Ltd Laboratory at Harwell, Oxfordshire.
Uranium was analysed by Inductively Coupled Plasma Mass Spectrometry ICPMS
using an Agilent 7500CE quadrupole instrument. Results for the first sample
examined showed the Uranium concentration to be 0.073mg/kg (mean of 3
determinations, SD 0.008). This is about 500 times the concentration of Uranium in
seawater which is reported to be 0.00015mg/kg (Weast, 1986). The total radioactivity
of the Uranium 238, Pa234m, Th234 and U-234 series will thus be 3.62Bq/kg oil.
Since this oil is from undisturbed deep strata there will also be Radium-226 and
daughters in secular equilibrium at a minimum activity of 0.9Bq/kg.
Gamma radioactivity was examined on three different samples of the oil. Samples
were examined by low resolution gamma counting for 12 hours using a 2” Scionix
NaI(Tl) scintillation crystal in conjunction with a Mini MCA spectrum analyser.
Decay products of the Uranium and Radium series were detected but levels of
Thorium-232 decay series (Ac-228) were not found above the limit of detection. Thus
the samples seemed to show no significant excess gamma radiation (less than
200mBq/l). Tritium (H-3) and Carbon-14 analysis was not carried out but further
work is in progress and results will be reported.
Refs:
Busby Chris and Schnug Ewald (2008) Advanced biochemical and biophysical aspects of
uranium contamination. In: (Eds) De Kok, L.J. and Schnug, E. Loads and Fate of Fertilizer
Derived Uranium. Backhuys Publishers, Leiden, The Netherlands, ISBN/EAN 978-90-5782-
193-6.
Busby C, Yablolov AV, Schmitz Feuerhake I, Bertell R and Scott Cato M (2010) ECRR2010 The
2010 Recommendations of the European Committee on Radiation Risk. The Health Effects of
Ionizing Radiation at Low Doses and Low Dose Rates. Brussels: ECRR; Aberystwyth Green
Audit. Uranium Chapter is a free download from www.euradcom.org
Weast RC (1986) CRC Handbook of Chemistry and Physics 1986 p F204 Boca Raton: CRC
Press