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IIT JEE 2011 Paper1 Solutions

IIT JEE 2011 Paper1 Solutions

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Published by Ashish Kumar
TIME Institute IIT JEE 2011 Paper 1 Solutions
TIME Institute IIT JEE 2011 Paper 1 Solutions

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Published by: Ashish Kumar on Apr 10, 2011
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MODEL SOLUTIONS TO IIT JEE 2011
Paper I
1 2 3 4 5 6 7
A D A B D C C
8 9 10 11
A, B, D A, D A, C, D A, B, C
12 13 14 15 16
D B B A C
17 18 19 20 21 22 23
9 5 5 4 6 5 7Section I
1. Al
2713
+ He
42
P
3015
+ )Y(n
10
 
 
 Si
3014
+ )X(H
11
Si
3014
+ )Z(e
01
 2. Since the mobility of K
+
is nearly same as that ofAg
+
which it replaces, the conductance willremain as more or less constant and willincrease only after the end point.3.
CNHCOO
KOH
 
CNKCOO
CH
2
ClBr
 
CNCOOCH
2
Br 4. [NiCl
4
]
2– 
is tetrahedral, [Ni(CN)
4
]
2– 
is squareplanar & [Ni(H
2
O)
6
]
2+
is octahedral.5. Ba(N
3
)
2
Ba + 3N
2
 Very pure N
2
is produced by the thermaldecomposition of Barium or sodium azide.6. M =
1120100015.12
××
 = 2.05 M7. o-hydroxy benzoic acid: pKa = 2.99p–hydroxy benzoic acid: 4.58p–toluic acid = 4.34p–nitrophenol = 7.15
Section II
8. Adsorption is always exothermic.Chemisorption is more exothermic thanphysisoprtion and it requires activation energy.
 
 
9. A, D10. Cassiterite contain 0.5 – 10% of metal as SnO
2
the rest being impurities of pyrites of Fe, Cu &wulframite.11. In a, b & c all atoms are in the same plane.
Section III
12.
H
3
C CH
3
CH
3
CC CH(P)
dil.H
2
SO
4
HgSO
4
 
H
3
C CH
3
CH
3
CCOCH
3
(i) NaBH
4
(ii) dil.acid
 
H
3
C CH
3
CH
3
CCCH
3
HOH(Q) 13.H
3
C CH
3
CH
3
CCCH
3
H
 
OH
H
+
(-H
2
O)
 
H
3
C CH
3
CH
3
CH
1, 2-shiftof -CH
3
C CH
3
(2°)
 
CH
3
CH
3
CHCH
3
CCH
3
-H
+
 
CH
3
CH
3
CCCH
3
CH
3
ozonoly
 
sis
 
H
3
CCH
3
2CO
 
14. 2AgNO
3
+ Cu
Cu(NO
3
)
2
+
21AgThe metal dipped is Cu.Blue colour due to formation of Cu
2+
 15. The solution in which the metal is dipped inAgNO
3
.16. The deep blue colour due to formation of[Cu(NH
3
)
4
]
2+
and the white precipitate of AgCldissolve due to formation of [Ag(NH
3
)
2
]
+
 
Section IV
17. Maximum no. of electron with n = 3 is 18, ofwhich are having21
spin18. 3Na
2
CO
3
+ 3Br
2
 
5NaBr + NaBrO
3
+ 3CO
2
 19. 
CH
3
CH
2
CCH
2
CH
2
CH
3
Br
alc.KOH
 
CH
3
CHCCH
2
CH
2
CH
3
(2 isomers)
 
CH
3
CH
2
CCHCH
2
CH
3
(2 isomers)
 
CH
3
CH
2
CCH
2
CH
3
(1 isomer)CH
2
 20. h
υ
=
199834
106.110300 10310626.6
××××××
 = 4.14 eVE = h
υ
– h
υ
0
 For Li, Na, K and Mg h
υ
0
values are less than4.14 eV21. Let the number of glycine units be xTotal mass of the hydrolysed products= 796 + 9
×
18 = 958% by mass of glycine =958100x75
×
= 47
x = 622.
264
OS has sulphur atoms with oxidation states‘0’ & +5.23. Vol. of 0.1 mole at 0.32 atm =32.024.2= 7 L
 
 
PART II
24 25 26 27 28 29 30
D D D A A A B
31 32 33 34
B, D A, B, C, D A, B, C, D A
35 36 37 38 39
C B D C B
40 41 42 43 44 45 46
3 5 6 3 9 4 1Section I
24. x component of area vector is2aE2a
202
=φ
 25. T sin
θ
= m
ω
2
Lsin
θ
 
ω
=5.05.0 324
×
 = 3626. Position (1): Let charge on 2
µ
F be Q. Thenenergy =4Q
2
µ
JPosition (2): C
eq
= 10
µ
FTotal charge = Q.
Energy =20Q
2
µ
JLoss % = 80%27. n =41(
Θ
22.4
λ
= 1 mole)W = nC
V
T = T.R2341
×
 T
1
V
1
γ 
 
1
= T
2
V
2
γ 
 
1
 
 T
2
= 4T
1
 
 
T = 3T
1
 28. f’ =
  
+×
  
cv1cv1f
0s
 =
( )
10320103208
+×
 29.
  
=λ
221
3121R1 
  
=λ
2222
4121RZ1 
λ
2
=
λ
1
 
×
 
2
2163365
×
 = 1215
0
A30.24815210X
++=
 
Section II
31.T =qBm2
π
, different for them.32.dtdQis same for A and E and both are maximum.Thermal resistances
  
KA
λ
are as below.54R,21R,34R,81R
DCBA
====
 R
E
=241. So C is also correct.
mg
θ
 LTR
B
 R
C
 R
D
 R
E
 R
A
 
B
 electronproton
 

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