Date : 11-05-2011 Duration : 3 Hours Max. Marks : 360
QUESTIONS & SOLUTIONS OF AIEEE 2011PART-II PAPER-1
IMPORTANT INSTRUCTIONS
1.
Immediately fill the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen. Use ofpencil is strictly prohibited.
2.
The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, takeout the Answer Sheet and fill in the particulars carefully.
3.
The test is of
3 hours
duration.
4.
The Test Booklet consists of
90
questions. The maximum marks are
360.5.
There are three parts in the question paper A, B, C consisting of
Chemistry, Physics and Mathematics
having 30 questions in each part of equal weightage. Each question is allotted
4 (four)
marks for eachcorrect response.
6.
Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each ques-tion.
¼ (one fourth)
marks will be deducted for indicating incorrect response of each question. No deductionfrom the total score will be made if no response is indicated for an item in the answer sheet.
7.
There is only one correct response for each question. Filling up more than one response in each question willbe treated as wrong response and marks for wrong response will be deducted accordingly as per instructions6 above.
8.
Use
Blue/Black Ball Point Pen only
for writing particulars/marking responses on
Side-1
and
Side-2
of theAnswer Sheet.
Use of pencil is strictly prohibited.9.
No candidate is allowed to carry any textual material, printed or written, bits of papers, paper, mobile phone,any electronic device, etc., except the Admit Card inside the examination hall/room.
10.
Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is givenat the bottom of each page and in 3 pages at the end of the booklet.
11.
On completion of the test, the candiate must hand over the Answer Sheet to the Invigilator on duty in theRoom/Hall. However, the candidates are allowed to take away this Test Booklet with them.
12.
The CODE for this Booklet is A. Maken sure that the CODE printed on
Side-2
of the Answer Sheet is thesame as that on this booklet. In case of discrepancy, the condidate should immediately report the matter tothe Invigilator for replacement of both the Test Booklet and the Answer Sheet.
13.
Do not fold or make any stray marks on the Answer Sheet.
Name of the Candiate (in Capital letters) : ____________________________________________________________ Roll Number : in figures : in words : _______________________________________________ Examination Centre Number :Name of Examination Centre (in Capital letters) : ________________________________________ Candidate's Signature : ______________________________ Invigilator's Signature : ___________________________________
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Page # 2
PART-A (CHEMISTRY)
1.
Identify the incorrect statement from the following:(1) Ozone absorbs the intense ultraviolet radiation of the sun.(2) Depletion of ozone layer is because of its chemical reactions with chlorofluoro alkanes.(3) Ozone absorbs infrared radiation.(4) Oxides of nitrogen in the atmosphere can cause the depletion of ozone layer.
Ans.
(3)
Sol.
Layer of O
3
in upper atmosphere absorbs UV radiations from sun, thus protects the human being living on theearth.Nitrogen oxides (particularly nitric oxide) combine very rapidly with ozone and there is, thus, the possibilitythat nitrogen oxides emitted from the exhaust systems of supersonic jet aeroplanes might be slowly depletingthe concentration of the ozone layer in the upper atmosphere.The use of chlorofluoro carbon in aerosol and refrigerator and there, subsequent escape into the atmosphereis responsible for making holes in the ozone layer. Ozone at all does not absorb infrared radiation.
2.
When r, P and M represent rate of diffusion, pressure and molecular mass, respectively, then the ratio of therates of diffusion (r
A
/r
B
) of two gases A and B, is given as:(1) (P
A
/P
B
) (M
B
/M
A
)
1/2
(2) (P
A
/P
B
)
1/2
(M
B
/M
A
)(3) (P
A
/P
B
) (M
A
/M
B
)
1/2
(4) (P
A
/P
B
)
1/2
(M
A
/M
B
)
Ans.
(1)
Sol.
r
Mp
BA
rr
=
ABBA
MMpp
3.
Consider thiol anion (RS
) and alkoxy anion (RO
). Which of the following statements is correct ?(1) RS
is less basic but more nucleophilic than RO
.(2) RS
is more basic and more nucleophilic than RO
.(3) RS
is more basic but less nucleophilic than RO
.(4) RS
is less basic and less nucleophilic than RO
.
Ans.
(3)
Sol.
RS
is more nucleophilic than R
–
O
due to larger size of orbitals and polarization but RS
is less basic thanR
–
O
as the negative charge get stabilized due to larger size of sulphur atom.
4.
The change in the optical rotation of freshly prepared solution of glucose is known as:(1) racemisation(2) specific rotation(3) mutarotation(4) tautomerism
Ans.
(3)
Sol.
Freshly prepared glucose solution get equilibriated to an unequal mixture of (+) and (
–
) glucose. This phe-
nomenon is called mutarotation.
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Page # 35.
The molality of a urea solution in which 0.0100 g of urea, [(NH
2
)
2
CO] is added to 0.3000 dm
3
of water at STPis:(1) 5.55
× 10
–
4
(2) 33.3 m(3) 3.33
× 10
–
2
m(4) 0.555 m
Ans.
(1)
Sol.
Molality =
3.060 / 01.0
=
3.060
01.0
;d = 1 g/ml= 5.55
× 10
–
4
m
6.
The molecular velocity of any gas is:(1) inversely proportional to absolute temperature.(2) directly proportional to square of temperature.(3) directly proportional to square root of temperature.(4) inversely proportional to the square root of temperature.
Ans.
(3)
Sol.
v =
MRT8
Tv
7.
The correct order of acid strength of the following compounds:(A) Phenol(B) p-Cresol(C) m-Nitrophenol(D) p-Nitrophenolis :(1) D > C > A > B(2) B > D > A > C(3) A > B > D > C(4) C > B > A > D
Ans.
(1)
Sol.
Therefore acidity order is :D > C > A > B
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