Ti sao FeF4- bn hn FeCl4-? nhng ti sao CuF2- km bn hn CuI2- ?

Gii thch:
phn ng th nht ta lu bn hn c ngha l cht c to thnh nhiu hn (kh thy phn hn )hy lu F>Cl do cht FeF4- km d mt electron nhiu hn do vy n l base mnh hn (c trng bi dng in Fe) nn bn hn to thnh nhiu hn Ngc li vi CuF2- th ta c c s gii thch nh sau Cu+ l acid mm I- l base mm nn kt hp li cho hc bn

 Khng gii thch c nh s hnh thnh pi cho nhn) nng lng gn nhau th hnh thnh s xen ph pi gn nhau

Cu+: 18 4s0 3d9(ngha l cn d 1AO trng) Fe3+: 18 4s2 3d3 (cn d 2AO trng)

Ti sao Fe khng to pi cho nhn vi F C th l do chnh lch nng lng ln

B: 1s2 2s2 2p3

Khi to thnh lin kt BF3 th ta c B tr thnh 1s2 2s2 cn trng 3 Ao p nng lng gn gn nhau nn to pi cho nhn lm cho nguyn t trung tm giu mt in tch m lm tnh base cng yu. M chng ta khng nn ng nhn tnh acid base v mnh ca acid base l t l thun vi nhau