PROBLEMS FOR PRACTISE

1. A gas X at 1 atm is bobbled through a solutio o! a mi"ture o! 1 M # $ a d 1 M %$ at &'C. I! the redu(tio )ote tial is %*#*X them +A, # -ill o"idised X a d ot % +B, # -ill o"idi.e % a d ot X +C, # -ill o"idi.e both % a d % +/, # -ill redu(e both % a d % I the (ell rea(tio Cu+s, 0 &Ag0+a1, Cu&0+a1, 0 &Ag+s,2 E 3 (ell 4 3.56 b7 doubli g the (o (e tratio o! &0 Cu 2 E is +A, doubled +B, hal8ed +C, i (reases but less tha double +/, de(reases b7 a small !ra(tio :o- ma 7 (oulombs o! ele(tri(it7 are re1uired !or redu(tio o! o e mole o! M O5$ to M +A, ;6'33C +B, 1.;913' C +C, 5.<913' C +/, ;.6'136 C
&0

&.

9.

5.

The sta dard redu(tio )ote tial !or Cu&0=Cu is 3.95 > a d ?s) o! Cu+O:,& is 1.313$1; the redu(tio )ote tial o! Cu&0=Cu (ou)le at +): 4 15, is +A, $3.&&3' +B, 3.&&3' 8 +C, $3.9& 8 +/, @o e o! these Pt A :&+g,2 +1 atm, A :0 +a1, AA :0 +a1, A :&+g,2+1 atm, A Pt +):4&, +):49, The (ell rea(tio !or the gi8e (ell is +A, s)o ta eous +B, o $ s)o ta eous +C, e1uilibrium +/, o e For the et (ell rea(tio +E(ell 4 3.96>, is +A, 11&.' +C, $95.E9 o! (ell2 % +s,A %
0&

'.

6.

+a1, AACd0&AACd+s, B i

Cilo Doules at &' C

+B, 6;.5< +/, $6;.5< its solutio

E.

:o- mu(h -ill the redu(tio )ote tial o! a h7droge ele(trode (ha ge -he i itiall7 at ): 4 3 is eutrali.ed to ): 4E. +A, i (reases b7 3.3'; > +B, de(rease b7 3.3'; > +C, i (reases b7 3.51 > +/, de(rease b7 3.51 >

<.

A h7droge ele(trode )la(ed i a bu!!er solutio o! C: 9COOCIS a d a(eti( a(id i the ratioFs " G 7 a d 7 H " has ele(trode )ote tial 8alues E 1 8olt a d E& 8olts res)e(ti8el7 at &'C . The )?a 8alues o! a(eti( a(id is +E1 a d E& are o"$ )ote tial,

E1 + E & 3.11< E + E& +C, 1 3.11<

E & + E1 3.11< E E& +/, 1 3.11<

The sta dard o"idatio )ote tials o! the ele(trodes Ag=Ag 02 S =S &02 Ca=Ca&02 Pb=Pb&0 are $ 3.<2 $ 1.962 &.<6 a d 13.1& > res)e(ti8el7. The most )o-er!ul o"idi.i g age t amo g these metals is +A, Pb +B, Ca +C, S +/, Ag Ihe a a1ueous solutio (hloride is ele(trol7.ed usi g gra)hite ele(trodes2
FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Termina !, Ne" #e hi$%&,'h( )&*%*+,+, )&-&*%-), )&-*,%.), /a0( )&*%1+,)

13.

+A, ): o! the resulti g solutio i (reases +B, ): o! the resulti g solutio de(reases +C, as the (urre t !lo-s2 ): o! the solutio arou d the (athode +/, @o e 11. Mobilit7 o! :0 +i a1ueous medium, is high be(ause +A, o! the small si.e o! :0 +B, o! the high h7dratio e erg7 o! 1 0 & +C, It has o ele(tro s +/, It e"hibits a (rothus t7)e o! (o du(tio A dilute a1ueous solutio o! sodium !luoride is ele(trol7.ed2 the )rodu(ts at the a ode a d (athode are +A, O&2 :& +B, F&2 :g +C, O&2 :g +/, F&2 :& The sta dard redu(tio )ote tial 8alue o! the three metalli( (atio s X. # a d % are 3.'&2 3.939 a d $1.1< 8 res)e(ti8e b7 the redu(i g )o-er o! the (orres)o di g metals is +A, #*%*X +B, X.#*X +C, %*XJ# +/, %*X*# Passage o! o e !arada7 o! (harge through a1ueous solutio o! Ag@O 92 CuSO52 Al+@O9,9 a d @aCl -ill de)osit metals at the (athode i the molar ratio o! +A, 1G&G9G1 +B, 6G9G&G6 +C, 6G9G3G3 +/, 9G&G1G3 Ihe a ele(tri( (urre t is )assed through a(idulated -ater2 11& ml o! : & gas at STP (olle(ts at the (athode i ;6' se(o d. The (urre t )assed i am)ere is +A, 1.3 +B, 3.' +C, 3.1 +/, &.3 1 (oulomb o! (harge )asses through solutio o! Ag@O9 a d CuSO5 (o e(ted i series a d the (o (e tratio o! t-o solutio bei g i the ratio 1G&. The ratio o! amou t o! Ag a d Cu de)osited i Pt ele(trode is +A, 13E.; G 69.'5 +B, '5G91.EE +C, 13E.;G 91.EE +/, '5G69.'5 The amou t o! sodium de)osited b7 ' am)ere (urre t !or 13 mi ute !rom !used @aCl is +A, 3.E1'gm +B, E1.' gm +C, '.1Egm +/, 3.'1Egm I! the solutio o! CuSO5 i -hi(h (o))er rod is immersed is diluted to 13 times2 the redu(tio ele(trode )ote tial E Cu+& = Cu 4 3.95 > +A, I (reases b7 3.39> +B, /e(reases b7 3.39> +C, I (reases b7 3.3';> +/, /e(reases b7 3.3';> The 8alue o! the rea(tio 1uotie t2 K !or the (ell % +s, A% &0 +3.31M, AA Ag0+1.&'M, A Ag+s, is +A, 1'6 +B, 1&' L& +C, 1.&' 13 +/, 6.5 13L9 For the (ell % +s, A % &0AACu&0ACu+s,2 the sta dard (ell 8oltage is 1.13 >. Ihe a (ell usi g these reage ts -as )re)ared i the lab2 the measured (ell 8oltage -as 3.;< >. O e )ossible e")la atio !or the obser8ed 8oltage is +A, There -ere &.33 mole o! % &0 but o l7 1.33 mole o! Cu&0 +B, The % ele(trode had t-i(e the sur!a(e o! the Cu ele(trode +C, The M% &0N -as larger tha the MCu&0N +/, The 8olume o! % &0 solutio -as larger tha the 8olume o! the Cu&0 solutio
FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Termina !, Ne" #e hi$%&,'h( )&*%*+,+, )&-&*%-), )&-*,%.), /a0( )&*%1+,)

1&.

19.

15.

1'.

16.

1E.

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&3.

&1.

Pt+Cl&, A :Cl +3.1M, A Pt+Cl&, P1 P& Cell rea(tio -ill be s)o ta eous i! +A, P1 4 P& +C, P& > P1

+B, P1 > P& +/, P1 4 P& 4 1 atm

&&.

/uri g ele(trol7sis o! a(idi!ied -ater2 O & gas is !ormed at the a ode. To )rodu(e O & gas at the a ode at the rate o! 3.&&5 (( )er se(o d at STP2 (urre t )assed is +A, 3.&&5 A +B, &.&5 A +C, ;.6' A +/, 9.<6 A Cu0 io is u stable i a1ueous solutio . E3 !or dis)ro)ortio atio o! Cu0 is 3 3 +Bi8e E Cu + & = Cu = 3.1' >2 E Cu + & = Cu + = 3.95 > , +A, L 3.1; > +B, L 3.9< > +C, 3.;5 > +/, 3.9< > The e.m.!. o! hal! (ell Pt:& +& atm, A :Cl +a 4 3.3&, O E3OP4 3 > is +A, 0 3.13; 8olt +B, 0 3.539 8olt +C, L 3.53; 8olt +/, L 3.13; 8olt Em! o! the (ell @i A @i&0 +3.1 M, AA Au90 +1.3 M, A Au -ill be Eo @i=@i& + 4 3.&'>2 +A, 1.E' > +C, 0 3.EE;' >
0 0& M O 5 0 <: 0 'Fe (o sta t is +A, 3.3';1 +C, 139

&9.

&5.

&'.

E = 1 .' > Au +9 = Au

+B, 0 1.EE;' > +/, L 1.EE;' >

&6.

'Fe09 0 M

0 5:&OP E3 (ell = 3.3';1 2 he (e e1uilibrium +B, 13& +/, 13'

&E.

I! the solutio o! CuSO5 i -hi(h (o))er rod is immersed is diluted to 13 times2 the redu(tio ele(trode )ote tial E Cu +& = Cu 4 3.95 > +A, I (reases b7 3.39> +B, /e(reases b7 3.39> +C, I (reases b7 3.3';> +/, /e(reases b7 3.3';> Bi8e M&0 0 &e M2 E 4 3.9' > M&0 0 e M02 E 4 3.1' > :e (e EM +2M -ill be e1ual to +A, 3.6' +C, 3.''
3

&<.

+B, 3.3' > +/, 3.<' >

&;.

Cu0 io is u stable i a1ueous solutio . E3 !or dis)ro)ortio atio o! Cu0 is 3 3 +Bi8e E Cu + & = Cu = 3.1' >2 E Cu +& = Cu + = 3.95 > , +A, L 3.1; > +B, L 3.9< > +C, 3.;5 > +/, 3.9< > A solutio o! sodium sul)hate i -ater is ele(trol7.ed usi g i ert ele(trodes. The )rodu(ts at the (athode a d a ode are res)e(ti8el7 +A, :&2O& +B, O&2 @a +C, O&2SO& +/, O&2:&

93.

FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Termina !, Ne" #e hi$%&,'h( )&*%*+,+, )&-&*%-), )&-*,%.), /a0( )&*%1+,)

91.

A gas X at 1 atm is bubbled through a solutio (o tai i g a mi"ture o! 1 M # $ a d 1 M%$ at &'C. I! the redu(tio )ote tial o! % * X * # the +A, # -ill o"idi.e X a d ot % +B, # -ill o"idi.e % a d ot X +C, # -ill o"idi.e both X a d % +/, # -ill redu(e both X a d % For ele(tro(hemi(al (ell
MA M0 A X$=X 2 EM+ = M = 3.55 > a d E " = " = 3.99 > !orm this date2 o e (a dedu(e that

9&.

+A, M 0 X M0 0 X$ is the s)o ta eous rea(tio +B, M0 0 X$ M 0 X is the s)o ta eous +C, ECell 4 3.EE> +/, ECell 4 $ 3.EE > 99. For the (ell2 Tl = Tlt +3.331M, AA Cu&0 +3.1 M, =Cu is 3.<9 >. ECell (a be i (reasi g +A, B7 i (reasi g MCu&0N +B, B7 i (reasi g MTl0N +C, B7 de(reasi g MCu&0N +/, @o e A h7droge ele(trode )la(ed i a bu!!er solutio o! C:9COO@a a d C:9COO: i the ratioFs "G 7 a d 7G " has ele(trode )ote tial 8alues E 1 8olt a d E& 8olt res)e(ti8el7 at &'C. The )?a 8alues o! a(eti( a(id +E1 a d E& are o"idatio )ote tial, +A,

95.

E1 + E & 3.11<

+B, +/,

E & E1 3.11<

E1 + E & +C, 3.11<

E1 E & 3.11<

+C&, A % +s,2 the B o! the (ell -ill be egati8e2 i! +B, C1 * C& +/, @o e

96.

For Cu001e$ Cu2 E 4 "1 8olt Cu0& 0 &e$ Cu+s, E 4 "& 8olt2 the !or Cu0& 1e$ Cu02 E -ill be +A, "1 $ &"& +C, "1 $ "&

+B, "1 0 &"& +/, &"& $ "&

9E.

1 mol o! ele(tro s )asses through ea(h o! the solutio o! Ag@O 92 CuSO5 a d AlCl92 -he Ag2Cu O Al de)osited2 their molar ratio -ill be +A, 1 G 1 G 1 +B, 6 G 9 G & +C, 6 G 9 G1 +/, 1 G 9 G 6 I! a stead7 (urre t o! 1' A is )assed through a a1ueous solutio o! CuSO 52 ho- ma 7 mi utes -ill it taCe to de)osit 3.&' mole o! (o))er at the (athode2 assumi g 133 Q e!!i(ie (7. +A, 9.&1E139 +B, 1.619139 +C, '9.61 +/, 3.<;9 Assume that duri g ele(trol7sis o! Ag@O92 o l7 :&O i ele(trol7sed a d O& is !ormed asG &:&O 5:0 0 O& 0 5e$ O& !ormed at @TP due to )assage o! & am)eres o! (urre t !or ;6' se(o ds +A, 3.11& L +B, 3.&&5 L +C, 11.& L +/, &&.5 L
FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Termina !, Ne" #e hi$%&,'h( )&*%*+,+, )&-&*%-), )&-*,%.), /a0( )&*%1+,)

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9;.

53.

For the let (ell rea(tio (ell2 % +s,A % +E(ell 4 3.96>, is +A, 11&.' +C, $95.E9

0&

+a1, AACd0&AACd+s, B i Cilo Doules at &'C +3.96&, +B, 6;.5< +/, $6;.5< its solutio

51.

:o- mu(h -ill the redu(tio )ote tial o! a h7droge ele(trode (ha ge -he i itiall7 at ): 4 3 is eutrali.ed to ): 4E. +A, i (reases b7 3.3'; > +B, de(rease b7 3.3'; > +C, i (reases b7 3.51 > +/, de(rease b7 3.51 >

5&.

The sta dard redu(tio )ote tial 8alues o! the eleme ts A2 B O C are 0 3.6<2 $&.'3 O $&.3 > res)e(ti8el7. The order o! their redu(i g )o-er is +A, A * B * C +B, A * C * / +C, C * B * A +/, B * C * A Em! o! the (ell @i A @i&0 +3.1 M, AA Au90 +1.3 M, A Au -ill be Eo @i=@i& + 4 3.&'>2 +A, 1.E' > +C, 0 3.EE;' >

59.

4 1.' > +B, 0 1.EE;' > +/, L 1.EE;' >

Eo Au=Au9 +

55

I! the solutio o! CuSO5 i -hi(h (o))er rod is immersed is diluted to 13 times2 the redu(tio ele(trode )ote tial +Bi8e G E Cu +& = Cu 4 3.95 >, +A, I (reases b7 3.39> +B, /e(reases b7 3.39> +C, I (reases b7 3.3';> +/, /e(reases b7 3.3';> The sta dard redu(tio )ote tial o! &:&O 0 &eL :& 0 &O:L at &;< ? is +A, 3.<&< > +B, L 3.<&< > +C, 3.515 > +/, L 3.515> Co))er dis)la(es -hi(h o! the metal !rom the salt solutio sR +A, Ag@O9 +B, % SO5 +C, FeSO5 +/, All o! the abo8e
3 3 o I! EFe & + = Fe is "12 EFe 9 + = Fe is X& the EFe 9 + = Fe & + -ill be +A, 9"& L &"1 +B, "&L"1 +C, "& 0 "1 +/, &"1 0 9"& :o- mu(h (urre t is e(essar7 to )rodu(e h7droge gas at a rate o! 11&33 (( )er se(o d at @TP (o ditio sR +A, ;6'33 am)ere +B, 5<&'3 am)ere +C, <.616 am)ere +/, 15<33 am)ere

5'.

56.

5E.

5<.

5;.

The e.m.!. o! hal! (ell Pt:& +& atm, A :Cl +a 4 3.3&, O E3OP4 O> is +A, 0 3.1; 8olt +B, 0 3.539 8olt +C, L 3.53; 8olt +/, L 3.13; 8olt
3 3 Bi8e E Ag = Ag = +3.E;; > O E % +A, Ag0 (a be redu(ed b7 :& +C, % &0 (a be redu(ed b7 :&
+

'3.

&+

=%

= 3.E69 > . The

FIITJEE Ltd., ICES House, Sarvapriya Vihar (Near Hauz Khas Bus Termina !, Ne" #e hi$%&,'h( )&*%*+,+, )&-&*%-), )&-*,%.), /a0( )&*%1+,)