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Ullmann's Food and Feed, 3 Volume Set
Ullmann's Food and Feed, 3 Volume Set
Ullmann's Food and Feed, 3 Volume Set
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Ullmann's Food and Feed, 3 Volume Set

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A compilation of 58 carefully selected, topical articles from the Ullmann's Encyclopedia of Industrial Chemistry, this three-volume handbook provides a wealth of information on economically important basic foodstuffs, raw materials, additives, and processed foods, including a section on animal feed. It brings together the chemical and physical characteristics, production processes and production figures, main uses, toxicology and safety information in one single resource. More than 40 % of the content has been added or updated since publication of the 7th edition of the Encyclopedia in 2011 and is available here in print for the first time.
The result is a "best of Ullmann's", bringing the vast knowledge to the desks of professionals in the food and feed industries.
LanguageEnglish
PublisherWiley
Release dateDec 15, 2016
ISBN9783527695522
Ullmann's Food and Feed, 3 Volume Set

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    Ullmann's Food and Feed, 3 Volume Set - Wiley-VCH

    Contents

    Cover

    Series Page

    Title Page

    Copyright

    Preface

    Symbols and Units

    Conversion Factors

    Abbreviations

    Country Codes

    Periodic Table of Elements

    Volume 1

    Part I: Introduction

    Foods, 1. Survey

    1. Introduction

    2. History of Food Production and Preservation

    3. Components and Their Reactions

    4. Food Law

    5. Documentation

    References

    Foods, 2. Food Technology

    1. Introduction

    2. Food Preservation by Dehydration

    3. Food Preservation at Low Temperature

    4. Food Preservation by Heating

    5. Food Preservation by Ionizing Radiation

    6. Other Food Preservation Methods

    7. Nutrient Retention in Processed Foods

    References

    Foods, 3. Food Additives

    1. Introduction

    2. Food Law Requirements

    3. Reasons for Using Additives

    4. General Statements on Additives

    5. Annex

    References

    Foods, 4. Food Packaging

    1. Historical Aspects

    2. Definitions

    3. Economic Significance

    4. Objectives

    5. Properties of Packaging Materials

    6. Types of Packaging Materials

    7. Packaging Machines

    8. Interaction between Packaging and Food

    9. Packaging and the Environment

    Abbreviations Used in This Article:

    References

    Feeds

    1. Introduction

    2. History

    3. Composition of Feeds and Feed Analysis

    4. Utilization of Feeds by Animals

    5. Systems of Energy Evaluation of Feeds

    6. Feed Characterization and Common Feeds

    7. Feed Additives

    8. Feed Hygiene and Feed Safety

    9. Future Developments in the Field of Feed Science

    10. Carryover of Feed Substances into Food of Animal Origin

    References

    Part II: Beverages

    Beer

    1. Introduction

    2. Raw Materials

    3. Production Technology

    4. Properties and Quality

    5. Analysis

    6. Economic Importance

    7. Physiology and Toxicology

    References

    Beverages, Nonalcoholic

    1. Introduction

    2. Mineral Water

    3. Fruit and Vegetable Juice Products

    4. Sweet Carbonated and Non-carbonated Beverages [106–108]

    5. Economic Aspects

    References

    Coffee

    1. Introduction [1–3]

    2. History [4]

    3. Green (Raw) Coffee

    4. Decaffeination [19]

    5. Roasting [37, 38]

    6. Brewed and Instant (Soluble) Coffee

    7. Composition [59]

    8. Consumption and Physiology [106–108]

    References

    Coffee-Based Beverages

    1. Overview

    2. Raw Materials and Intermediate Products

    3. Technological Aspects of Product Design

    4. Reconstitution

    5. Liquid Extracts and Canned Coffee Beverages

    6. Economic Aspects

    7. Product Adulteration

    References

    Milk and Dairy Products

    1. Introduction

    2. Historical Aspects [1,5]

    3. Composition of Milk [2, 5, 8, 9, 11, 18]

    4. Physical and Physicochemical Properties of Milk [7, 8, 47]

    5. Microbiology of Milk [49–51, 143]

    6. Nutritional Value of Milk [10, 11, 52, 53]

    7. Dairy Technology

    8. Fluid Milk

    9. Milk Products

    10. Quality Control

    11. Legislation

    12. Economic Aspects

    13. Acknowledgement

    References

    Spirits

    1. Introduction

    2. Types of Spirit Drinks

    3. Typical Production Processes

    4. World Production Figures

    5. Taxation

    6. Legislation

    7. Analysis

    References

    Tea

    1. Introduction

    2. History

    3. Major Tea Producers

    4. Growth and Manufacture

    5. Tea Trade

    6. Tea Market and Consumption

    7. Tea and Health

    References

    Wine, 1. Introduction and Classification

    1. Introduction

    2. Wine Classifications, Types, and Labels

    References

    Wine, 2. Chemical and Physical Composition

    1. Introduction

    2. Extract

    3. Physical Characteristics

    4. Chemical Composition

    References

    Wine, 3. Grapes, Viticulture, and Fermentation

    1. Grapes and Grape Varieties

    2. Viticulture

    3. Alcoholic Fermentation

    4. Secondary Fermentations

    5. Typicité and Style

    6. Sensory Evaluation

    7. Economic Aspects

    8. Wine and Health (For toxicology of ethanol, see → Ethanol)

    References

    Volume 2

    Part III: Bulk Food Component

    Bread and Other Baked Products

    1. Introduction

    2. Wheat Types and their Uses

    3. Wheat Breeding and Biotechnology

    4. Milling of Wheat

    5. Wheat Flour

    6. Evaluation of Flours

    7. Dough Formation

    8. Role of Bread Ingredients [162]

    9. Bread and Dough Making Processes

    10. Gas Production and Retention

    11. Molding and Proofing

    12. Baking

    13. Flavor of Baked Products

    14. Glass Transition and its Role in Baking

    15. Bread Varieties and Speciality Breads

    16. Soft Wheat Products

    17. Retention of Baked Product Quality

    18. Trends in Baking

    References

    Cereal Products

    1. Introduction

    2. Food Extrusion Technology

    3. Pasta

    4. Modified Flours

    5. Breakfast Cereals

    6. Reconstituted and Fortified Cereal Grains, e.g., Rice Kernels

    References

    Cereals

    1. Introduction

    2. Production

    3. Nutritional and Technological Properties

    4. Standards in Grain Trade

    5. Uses

    6. Processing

    7. Specific Properties and Use of Grains

    8. Economic Aspects and Outlook

    References

    Cheese, Processed Cheese, and Whey

    1. History of Cheese Making

    2. Definition of Cheese

    3. Classification of Cheese

    4. Production

    5. Analysis

    6. Flavor Components

    7. Processed Cheese

    8. Whey

    9. Economic Aspects

    10. Nutritional Value of Cheese

    References

    Chocolate

    1. Definitions

    2. Historical

    3. Raw Materials

    4. Fermentation and Drying

    5. Composition of the Fermented Cocoa Bean

    6. Chocolate Production [4], [12]

    7. Other Chocolate Processes

    8. Packaging, Storage, Spoilage, Analysis

    9. Economic Aspects

    References

    Confectionery

    1. History

    2. Raw Materials

    3. Properties and Microbiology of Confectionery

    4. Types of Confectionery

    5. Processes and Machinery for Confectionery Production

    6. Packaging, Storage, and Economic Aspects

    References

    Dairy Products, Imitation

    1. Introduction

    2. Definition of Imitation Milk

    3. Ingredients

    4. Manufacture

    5. Products

    6. Standards and Quality Control

    7. Nutrition

    8. Toxicology

    9. Economic Aspects and Sustainability

    References

    Fats and Fatty Oils

    1. Introduction

    2. Composition

    3. Physical Properties [11]

    4. Chemical Properties

    5. Manufacture and Processing

    6. Refining

    7. Fractionation

    8. Hydrogenation [53, 54]

    9. Interesterification

    10. Environmental Aspects

    11. Standards and Quality Control

    12. Storage and Transportation [62]

    13. Individual Vegetable Oils and Fats

    14. Individual Animal Fats

    15. Toxicology and Occupational Health

    16. Abbreviations of Triacylglycerols

    References

    Fatty Acids

    1. Introduction

    2. Properties

    3. Production of Natural Fatty Acids

    4. Production of Synthetic Fatty Acids

    5. Analysis

    6. Storage and Transportation

    7. Environmental Protection, Toxicology, and Occupational Health

    8. Uses

    References

    Glucose and Glucose-Containing Syrups

    1. Introduction and History

    2. Properties of Glucose

    3. Raw Materials

    4. General Principles of Starch Hydrolysis

    5. Production of Solid Glucose

    6. Glucose – Fructose Syrups

    7. Analysis

    8. Legal Aspects

    9. Storage and Transportation

    10. Uses

    11. Economic Aspects

    12. Physiological Properties and Toxicology of Glucose

    References

    Ice Cream and Frozen Desserts

    1. Introduction and Classification

    2. Quality Specifications and Analyses

    3. Mix Ingredients

    4. Manufacture of Mix

    5. Freezing Mix to Produce Ice Cream

    6. Physical Structure and Properties

    7. Storage and Transportation

    8. Legal Aspects

    9. Economic Aspects

    References

    Margarines

    1. History of Margarine

    2. Properties of Margarine

    3. Composition

    4. Processing

    5. Specialty Margarines for Baking and Cooking, Shortenings, and Structured Oils

    6. Packaging

    7. Sustainability and Consumption Aspects

    8. Acknowledgment

    References

    Meat and Meat Products

    1. Definitions

    2. History

    3. Composition of Meat

    4. Meat Production and Slaughtering

    5. Fresh Meat Processing

    6. Processing Techniques

    7. Types of Meat Products

    8. Manufacturing of Meat Products

    9. Meat Species Identification

    10. World Meat Production

    11. Meat Grading

    References

    Proteins

    1. Introduction

    2. Plant Protein Products

    3. Animal Proteins

    4. Protein Hydrolysates and Derivatives

    References

    Sugar

    1. Terms, Distinguishing Criteria, Uses, Nutritional Physiology

    2. History [27]

    3. Properties

    4. Sucrochemistry, Chemical and Enzymatic Synthesis

    5. Methods of Analysis

    6. Sugar Beets: Cultivation, Harvesting, Preparation

    7. Production of Juice (Extraction)

    8. Juice Purification

    9. Evaporation of Thin Juice

    10. Production of Sugar from Thick Juice

    11. Separation of Sugar from Massecuite

    12. Preparation of Refined and White Sugar

    13. Working Schemes of Various Sugar Factories [149, 159]

    14. Ion-Exchange Processes in the Sugar Industry [160]

    15. Production of Special Types of Sugar

    16. Storage of White Sugar

    17. Auxiliary Facilities in a Sugar Factory

    18. Desugarization of Molasses

    19. Sugar Yield, Energy Requirements, Processing Aids, Water, and Working Time

    20. Cane Sugar

    21. Sugar from other Plants

    22. Quality Demands on Sugar and Side Products of Sugar Production

    23. Economic Aspects

    References

    Vinegar

    1. Introduction

    2. Historical Outline

    3. General Aspects of Acetic Acid Fermentation

    4. Resources of Raw Materials

    5. Production

    6. Uses

    7. Nutritional Aspects

    8. Analysis

    9. Storage and Transportation

    10. Legal Aspects

    11. Economic Aspects

    12. Environmental Impact

    References

    Yeasts

    Introduction [1]

    2. The Yeast Cell

    3. Food and Feed Yeast [2]

    4. Yeast-Derived Products

    References

    Volume 3

    Part IV: Food Additives

    Citric Acid

    1. Introduction

    2. Physical Properties

    3. Chemical Properties

    4. Resources of Raw Materials

    5. Production

    6. Environmental Protection

    7. Quality Specifications and Uses

    8. Toxicology and Occupational Health

    9. Economic Aspects

    References

    Cyclodextrins

    1. History

    2. Structure

    3. Properties

    4. Production [5]

    5. Inclusion Complexes

    6. Derivatives

    7. Uses

    8. Economic Aspects

    9. Toxicology [21]

    References

    Flavors and Fragrances, 1. General Aspects

    1. History

    2. Definition

    3. Physiology

    4. Natural, Nature-Identical, and Artificial Products

    5. Sensory Properties and Structure

    6. Volatility

    7. Threshold Concentration

    8. Odor Description

    9. Analytical Methods/Quality Control

    10. Safety Evaluation and Legal Aspects

    References

    Flavors and Fragrances, 2. Aliphatic Compounds

    1. Introduction

    2. Aliphatic Compounds

    3. Acyclic Terpenes

    4. Cyclic Terpenes

    5. Other Cycloaliphatic Compounds

    References

    Flavors and Fragrances, 3. Aromatic and Heterocyclic Compounds

    1. Aromatic Compounds

    2. Phenols and Phenol Derivatives

    3. N and N,S Heterocycles

    References

    Flavors and Fragrances, 4. Natural Raw Materials

    1. Introduction

    2. Isolation of Natural Fragrance and Flavor Concentrates

    3. Survey of Natural Raw Materials

    Functional Foods

    1. Introduction

    2. Definitions and Categories of Functional Foods

    3. Prebiotics, Probiotics, and Synbiotics

    4. Functional Foods Containing Phytochemicals

    5. Functional Foods with Modified Fatty Acid Profiles

    6. Regulation of Functional Foods

    7. Outlook

    References

    Gelatin

    1. Introduction

    2. Structure and Properties

    3. Raw Materials and Production

    4. Uses

    5. Economic Aspects

    References

    Inulin

    1. Introduction

    2. Chemical Structure

    3. Physical and Chemical Properties

    4. Physiological Properties

    5. Resources and Raw Materials

    6. Production

    7. Uses

    8. Analysis

    9. Legal Aspects

    10. Economic Aspects and Trade Names

    References

    Lecithin

    1. Introduction

    2. Production

    3. Commercial Grades of Lecithin

    4. Physical Properties

    5. Chemical Properties

    6. Uses

    7. Quality Specifications and Analysis

    References

    Monosodium Glutamate

    1. Introduction

    2. Properties

    3. Production

    4. Uses

    5. Toxicology

    6. Economic Aspects

    References

    Seasonings

    1. Introduction

    2. Uses

    3. Resources and Raw Materials

    4. Production

    5. Storage and Transportation

    6. Quality Specifications

    7. Economic Aspects

    References

    Sweeteners

    1. Introduction

    2. Sensory Properties

    3. Uses

    4. General Toxicology and Physiology

    5. Food Legislation

    6. Substances Commonly Used as Sweeteners

    7. Other Sweeteners

    8. Substances Formerly Used as Sweeteners

    References

    Vitamins, 1. Introduction

    1. Definition [1]

    2. Substances with Vitamin-Like Character

    3. History

    4. Determination of Requirement

    5. Application and Tolerance

    6. Studies with Vitamins

    7. Use of Vitamins in Food- and Feedstuffs

    8. Antivitamins

    9. Analysis of Vitamins

    10. Production

    References

    Vitamins, 2. Vitamin A (Retinoids)

    1. Introduction

    2. Historical Aspects

    3. Physical Properties

    4. Chemical Properties

    5. Occurrence

    6. Biosynthesis

    7. Production

    8. Metabolism and Physiological Functions

    9. Deficiency Symptoms and Requirements

    10. Analysis and Standardization

    11. Trade Names and Economic Aspects

    12. Tolerance

    References

    Vitamins, 3. Vitamin D

    1. Introduction

    2. History

    3. Structure and Nomenclature

    4. Chemical and Physical Properties

    5. Biosynthesis and Occurrence

    6. Vitamin D Requirements

    7. Pharmacological Effects and Uses

    8. Synthesis

    9. Assays for Vitamin D and Metabolites

    10. Trade Names and Economic Aspects

    References

    Vitamins, 4. Vitamin E (Tocopherols, Tocotrienols)

    1. Introduction

    2. History

    3. Physical Properties

    4. Chemical Properties

    5. Metabolism and Importance in the Organism

    6. Deficiency, Requirement, and Application

    7. Analysis and Standardization

    8. Occurrence

    9. Economic Aspects

    10. Biosynthesis

    11. Production

    References

    Vitamins, 5. Vitamin K

    1. Introduction; History

    2. Physical Properties

    3. Chemical Properties [7]

    4. Occurrence

    5. Biosynthesis

    6. Chemical Synthesis

    7. Analysis

    8. Metabolism

    9. Importance for the Organism

    10. Deficiency Symptoms

    11. Requirement

    12. Application

    13. Tolerance

    14. Trade Names and Economic Aspects

    References

    Vitamins, 6. B Vitamins

    1. Vitamin B1 (Thiamin)

    2. Riboflavin

    3. Vitamin B6

    4. Vitamin B12 (Cobalamins)

    References

    Vitamins, 7. Vitamin C (L-Ascorbic Acid)

    1. Introduction

    2. History [4]

    3. Physical and Chemical Properties [5, 6]

    4. Analysis [8, 9]

    5. Occurrence and Sources of Vitamin C

    6. Biosynthesis [10]

    7. Manufacture of Vitamin C

    8. Absorption and Metabolism

    9. Medical Aspects of Vitamin C

    10. Industrial Uses [12–14]

    11. Economic Aspects

    References

    Vitamins, 8. Pantothenic Acid

    1. Introduction

    2. History

    3. Physical and Chemical Properties

    4. Occurrence

    5. Biosynthesis

    6. Production

    7. Metabolism and Importance for the Organisms; Coenzyme A and its Precursors

    8. Deficiency Symptoms, Requirement, and Application

    9. Analysis

    10. Economic Aspects

    References

    Vitamins, 9. Biotin

    1. Introduction

    2. History

    3. Physical and Chemical Properties

    4. Occurrence

    5. Biosynthesis

    6. Function as Prosthetic Group

    7. Isolation and Production

    8. Metabolism and Importance for the Organism

    9. Deficiency Symptoms, Requirement, and Application

    9.1. Symptoms and Therapy in Humans

    9.2. Symptoms and Therapy in Animals

    10. Biotin Analogs

    11. Analysis and Standardization [2]

    12. Uses and Economic Aspects

    13. Tolerance and Environmental Protection

    References

    Vitamins, 10. Folic Acid

    1. Introduction

    2. Historical Notes

    3. Properties

    4. Content in Food and Bioavailability

    5. Biosynthesis

    6. Chemical Synthesis

    7. Metabolism and Biochemical Functions

    8. Nutritional Requirements and Medical Use

    9. Analysis

    10. Economic Aspects

    References

    Author Index

    Subject Index

    End User License Agreement

    List of Tables

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    Ullmann's Food and Feed

    Volume 1

    Wiley Logo

    Editor-in-Chief:

    Dr. Barbara Elvers, Hamburg, Germany

    All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editors, and publisher do not warrant the information contained in these books, including this book, to be free of errors. Readers are advised to keep in mind that statements, data, illustrations, procedural details or other items may inadvertently be inaccurate.

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    Preface

    This handbook features selected articles from the 7th edition of ULLMANN'S Encyclopedia of Industrial Chemistry, including newly written articles that have not been published in a printed edition before.

    True to the tradition of the ULLMANN'S Encyclopedia, food and feed are addressed from an industrial perspective, including production figures, quality standards and patent protection issues where appropriate. Safety and environmental aspects which are a key concern for modern process industries are likewise considered.

    More content on related topics can be found in the complete edition of the ULLMANN'S Encyclopedia.

    About ULLMANN'S

    ULLMANN'S Encyclopedia is the world's largest reference in applied chemistry, industrial chemistry, and chemical engineering. In its current edition, the Encyclopedia contains more than 30,000 pages, 15,000 tables, 25,000 figures, and innumerable literature sources and cross-references, offering a wealth of comprehensive and well-structured information on all facets of industrial chemistry.

    1,100 major articles cover the following main areas:

    Agrochemicals

    Analytical Techniques

    Biochemistry and Biotechnology

    Chemical Reactions

    Dyes and Pigments

    Energy

    Environmental Protection and Industrial Safety

    Fat, Oil, Food and Feed, Cosmetics

    Inorganic Chemicals

    Materials

    Metals and Alloys

    Organic Chemicals

    Pharmaceuticals

    Polymers and Plastics

    Processes and Process Engineering

    Renewable Resources

    Special Topics

    First published in 1914 by Professor Fritz Ullmann in Berlin, the Enzyklopädie der Technischen Chemie (as the German title read) quickly became the standard reference work in industrial chemistry. Generations of chemists have since relied on ULLMANN'S as their prime reference source. Three further German editions followed in 1928 – 1932, 1951 – 1970, and in 1972 – 1984. From 1985 to 1996, the 5th edition of ULLMANN'S Encyclopedia of Industrial Chemistry was the first edition to be published in English rather than German language. So far, two more complete English editions have been published in print; the 6th edition of 40 volumes in 2002, and the 7th edition in 2011, again comprising 40 volumes. In addition, a number of smaller topic-oriented editions have been published.

    Since 1997, ULLMANN'S Encyclopedia of Industrial Chemistry has also been available in electronic format, first in a CD-ROM edition and, since 2000, in an enhanced online edition. Both electronic editions feature powerful search and navigation functions as well as regular content updates.

    Symbols and Units

    Symbols and units agree with SI standards (for conversion factors see page XI). The following list gives the most important symbols used in the encyclopedia. Articles with many specific units and symbols have a similar list before the references.

    Conversion Factors

    Powers of Ten

    Abbreviations

    The following is a list of the abbreviations used in the text. Common terms, the names of publications and institutions, and legal agreements are included along with their full identities. Other abbreviations will be defined wherever they first occur in an article. For further abbreviations, see page IX, Symbols and Units; page XVII, Frequently Cited Companies (Abbreviations), and page XVIII, Country Codes in patent references. The names of periodical publications are abbreviated exactly as done by Chemical Abstracts Service.

    Frequently Cited Companies (Abbreviations)

    Country Codes

    The following list contains a selection of standard country codes used in the patent references.

    Part I

    Introduction

    Foods, 1. Survey

    W. Frank Shipe, Cornell University, Ithaca, New York 14853, United States

    1. Introduction

    2. History of Food Production and Preservation

    3. Components and Their Reactions

    3.1. Water

    3.2. Proteins (→ Amino Acids; → Proteins); [6, 7, 29, 37–44]

    3.3. Lipids (→ Fats and Fatty Oils; → Fatty Acids), [6, 7, 29–31, 35]

    3.4. Carbohydrates (→ Carbohydrates), [6, 23, 24, 35]

    3.5. Mineral Components

    3.6. Vitamins

    3.7. Enzymes

    3.8. Miscellaneous Components

    3.8.1. Flavor Components

    3.8.2. Natural Pigments [6, 7, 35]

    3.8.3. Undesirable or Potentially Undesirable Constituents

    4. Food Law

    5. Documentation

    References

    1. Introduction

    Foods are mixtures of chemicals that are consumed by humans to satisfy their appetites for nourishment and pleasure. The nature and reactivity of the chemical constituents determine the properties of foods. The sensory properties, i.e., appearance, flavor, and texture, determine the acceptance of food and the pleasure derived from consuming it. Water-soluble components (salts, sugar, acids, and bitter substances) determine the taste, and volatile compounds determine the aroma. The texture is due to insoluble complexes or compounds such as proteins and polysaccharides; in some foods, lipids contribute to texture. Pigments are critical contributors to appearance. Most of the nutrients are provided by proteins, vitamins, and minerals, whereas carbohydrates and fats provide the energy. The ideal food should be both delicious and nutritious. Unfortunately, many nutritious foods are considered unappetizing by many people.

    The following procedures or processes have been used to produce appealing, nutritious foods (for details, see → Foods, 2. Food Technology):

    mixing products, e.g., fruit salads, vegetable salads, and fruit yogurts

    adding seasonings or other materials, e.g., adding soy protein to sausage or smoking meats

    fractionating to produce new products, e.g., separating milk to yield cream and skim milk

    homogenizing to produce a more uniform product, e.g., peanut butter or milk

    fermenting and pickling to produce new and more stable products, e.g., cheese manufacture

    enzymatic treatment, e.g., enzymatic modification of starch to produce corn syrups of varying sweetness

    thermal processing including cooking and baking, to destroy undesirable microbes, enzymes, and antinutrients such as trypsin inhibitors and enhance sensory appeal.

    2. History of Food Production and Preservation

    In the beginning, foods were selected from available natural products [1–8]. This led to the development of regional eating habits. The origin of modern economic plants was possibly as follows [1]:

    At first, selection of food from the available supply was based primarily on sensory properties. By trial and error, people learned that some products satisfied their appetites while others adversely affected their health. The people who made the right choices lived to pass on the information to the next generation.

    In the days when humans were merely hunters or gatherers of foods, the adequacy of diet depended on the types and quantity of available plants and animals. The need to develop methods for preserving food for use throughout the year became obvious. Concern over the quantity and quality of food increased as population increased. These food problems stimulated development of methods for producing and preserving foods (→ Foods, 2. Food Technology). The progression of civilization from the food gathering stage to the early food production era, i.e., from the Old Stone Age to 400 AD, is shown in Table 1.

    Table 1. History of growing, processing, and preserving food [1]

    In Germany, substantial increases in agricultural production occurred after the introduction of the iron plow in the 6th century, the horseshoe in the 9th century, and the horsecollar soon after. The threefold rotation system (one-third of the land remained fallow, summer crops were raised on another third, and winter crops on the other third) also increased production.

    During the Middle Ages the variety of available foods increased as a result of increased traveling and trading. The discovery of America had a pronounced effect on the variety of food with the introduction of potatoes and corn, as well as other native American products, such as tomatoes, peanuts, lima beans, and turkeys.

    The 16th century marked the beginning of the so-called Golden Age of Science, [1], [6–10]. During this time, scholars investigated the nature and composition of foods. Some of the components discovered are listed in Table 2. These discoveries gave credibility to the scientific approach to biological problems and stimulated further research and technical developments (Table 3).

    In the last two centuries considerable progress has been made in increasing the quantity and improving the quality of food [11, 12].

    Table 2. Some components isolated from foods prior to 1800

    Table 3. Chronology of some developments in food technology

    Food Quantity. Quantitative increases in the food supply have resulted from the following:

    The use of better breeding practices and careful genetic selection, which led to the development of high yielding varieties of wheat and rice.

    Replacing draft animals with mechanical power increased the acreage that could be farmed and released millions of hectares of land that had been devoted to raising feed for horses. However, mechanization of agriculture increased fossil fuel consumption.

    Irrigation has converted vast areas from desert or semidesert to profitable food producing areas. Unfortunately, continuous irrigation has caused water logging and increased soil salinity.

    The use of chemical fertilizers has created remarkable increases in production (→ Fertilizers). The gains have been partially offset by the cost of the fertilizers in terms of dollars and expenditure of fossil fuel. In some cases the runoff of chemical fertilizers has polluted drinking water and increased the growth of algae in the streams, which has killed fish.

    The use of pesticides has also contributed to the world food supply by eliminating pests that reduce yields or pests that consume harvested foods (→ Crop Protection). Because pesticides contribute to pollution and are hazardous to some species of animal life, alternative pest control methods have been and are being sought. Some success has been achieved in breeding disease-resistant varieties of plants and in developing biological methods, e.g., microbial parasites, that destroy the pests.

    Reduction in postharvest losses has been achieved by using storage facilities and packages that protect the food from biological, chemical, and physical damage (→ Foods, 4. Packaging). In developing countries, postharvest losses can be as high as 50% for some commodities [13].

    Recovery of foods and ingredients from underutilized products. For example, recovery of proteins from whey and blood [14–17], underutilized meats from chicken [18, 19] and fish [20, 21].

    Food Quality. Much of the progress in solving food quality problems can be attributed to basic scientific studies that have identified the causes for changes in quality, e.g., LOUISPASTEUR's studies, which led to pasteurization (→ Foods, 2. Food Technology). In the process of studying the mechanism of thermal destruction of microbes, researchers noted that in some cases thermal processing also affected flavor, color, and texture [6], [7], [22–24]. Heating fluid dairy products produced cooked (custardlike) flavor, which was found to be due to the release of sulfhydryl groups from proteins [25]. More drastic heating of milk or other foods containing carbonyl and amino groups caused both flavor and color changes. In 1908, A. R. LING described this reaction, and in 1912 L. C. MAILLARD investigated the mechanism [26]. Direct heating of products with high sugar content produced both caramel color and flavor. Heating affected the texture of meat and eggs by altering the proteins. It was found that the activity of many endogenous food enzymes could be controlled by thermal processing [27], [28]. The importance and nature of enzymatic changes are discussed in Section 3.7 (→ Enzymes, 1. General).

    Scientific studies have shown that many changes in food quality are due to either oxidative or hydrolytic reactions, and therefore, controlling them is important [6, 7, 29–31]. Oxidative changes have been minimized by (1) storing food in a controlled atmosphere, (2) using packages that are impervious to oxygen, (3) inactivating oxidative enzymes, (4) avoiding contamination with catalytic metals, or (5) addition of antioxidants (→ Antioxidants ; → Foods, 3. Food Additives). Hydrolytic changes have been inhibited by (1) inactivating hydrolytic enzymes, (2) maintaining the integrity of cell walls or membranes, which protect the substrate, or (3) adding inhibitors [32].

    3. Components and Their Reactions

    Foods range in complexity from a single compound (e.g., sugar) to multicomponent mixtures (e.g., meat). The properties of foods reflect the properties of the individual components and their interactions. Food interactions include all types of noncovalent (van der Waals, hydrogen, ionic, and hydrophobic) and covalent bonds. These interactions contribute to a variety of structural features such as cell walls, micelles, fat globules, fat globule membranes, three-dimensional gel structures, muscle fibers, and curds.

    The reactions of components in foods are affected by pH, temperature, concentration of reactants, available water, catalysts, activators, and inhibitors. They may be catalyzed by light, enzymes, and nonenzymatic materials such as metals. Inhibitors can be substances that chelate metal catalysts or that interact with one of the reactants. Chelating agents can react with calcium or iron and thus reduce their nutritional availability. The nutritional quality of foods can also be reduced by oxidation of essential fatty acids or other nutrients, or by the interaction of proteins with tannins. The optimal sensory and nutritional properties can be obtained by controlling the reactions of the components.

    3.1. Water

    Occurrence. Water [7732-18-5] is one of the basic and most ubiquitous constituents of living organisms, [6, 7, 33–36]. The water content of raw fruits, vegetables, and meats exceeds 50 wt %, but the concentration in cereals, nuts and many processed foods is lower (→ Foods, 2. Food Technology).

    Water exists naturally as an intracellular or extracellular component in plants and animal products. It is used as a solvent for sugars, salts, and acids in some foods, as a dispersing medium for hydrophilic macromolecular carbohydrates or proteins, and as a dispersed phase in emulsified products such as butter and margarine.

    Properties. Compared to other substances with similar molecular masses, water is unique (→ Water). Its ability to engage in three-dimensional hydrogen bonding enables it to bond with organic molecules that contain nitrogen, oxygen, fluorine, or chlorine. The dissolution of sugar is because of bonding between water and the polar groups of the sugar. Dissolution of salts involves electrostatic forces between water and the positive ions which are greater than the attraction between ions.

    Effect on Food. Water acts as a dispersing medium for amphipathic molecules, such as polar lipids, which have both hydrophilic and hydrophobic groups. The water associates with the hydrophilic moieties, such as phosphate groups, to solubilize the molecules. The amphipathic molecules form macromolecular aggregates, which are called micelles. Introducing hydrophobic substances, such as apolar groups of fatty acids, amino acids, and proteins, into water leads to an association of the apolar groups, i.e., hydrophobic interactions.

    Water may be present in food as free water or bound water. Free water behaves like pure water, whereas the behavior of bound water is limited. Bound water has been defined as water that is not available as a solvent and does not freeze at − 40 °C, although some scientists have suggested other definitions. The term water binding has been defined as the tendency of water to associate, with various degrees of tenacity, to hydrophilic substances. Water-holding capacity has been used to describe the ability of a matrix of molecules to entrap a large amount of water in such a manner that exudation is prevented [7]. Although the entrapped water does not flow freely from the product, it behaves very much like pure water during processing. The water-holding capacity of meats and gels have a profound effect on rheological properties. The water-holding capacity of meats is affected by pH and salts, especially phosphates. A classification of water–protein thermodynamic associations is as follows [34]:

    Structural water is water that is hydrogen-bonded to specific groups; it participates in stabilization of structure and is unavailable for chemical reaction.

    Hydrophobic hydration water is structured cagelike water surrounding apolar residues; like structural water, it is very much involved in stabilizing protein structure.

    Monolayer water is the first adsorbed water monolayer; it is hydrogen-bonded and is unavailable as solvent, but may be available for chemical reactions; ranges from 4 to 9 g/100 g protein.

    Unfreezable water includes roughly all water (structural monolayer, and perhaps some adsorbed multilayer water) that does not freeze at normal temperature; amounts to 0.3–0.5 g/g of protein and corresponds to water up to aw= 0.9; amount varies with polar amino acid content and includes some water available for chemical reactions.

    Capillary water is water that is held physically in clefts or by surface forces in the protein molecule (e.g., water entrapped in gels or cheese curd); its physical properties are similar to those of bulk water.

    Hydrodynamic hydration water loosely surrounds the protein and is transported with the protein during diffusion (centrifugation); it has properties typical of normal water.

    Water Activity [6]. A complete discussion of water activity can be found under → Foods, 2. Food Technology.

    Perishability. A general correlation exists between the perishability of food and water content, but a better correlation exists between perishability and water activity (→ Foods, 2. Food Technology). Both enzymatic and nonenzymatic reactions tend to increase as water activity increases. However, enzymatic reactions are less sensitive to water activity changes. Nonenzymatic browning reactions reach a maximum rate at aw≈ 0.80. Lipid oxidation is inhibited by increasing water content. Under some conditions water may form a protective film around the fat. The destruction of vitamin C and chlorophyll increases rapidly as the water activity increases. The rate of vitamin B1 destruction reaches a maximum at aw≈ 0.5 [7].

    Food Quality. A complete discussion of the effect of freezing the water in food has on food quality can be found under → Foods, 2. Food Technology.

    3.2. Proteins (→ Amino Acids; → Proteins); [6, 7, 29, 37–44]

    Structure. Proteins are polymers composed of amino acids linked together by peptide bonds. Proteins constitute ca. 50% of the dry matter of living cells and perform a vital role in the function and structure of the cells. Proteins containing only amino acids are called homoproteins, whereas those containing additional groups (i.e., prosthetic groups) are called heteroproteins. The heteroproteins include lipoproteins, glycoproteins, phosphoproteins, hemoproteins, metalloproteins, and nucleoproteins.

    The complexity of proteins depends on the number and types of amino acids and other groups. The primary, secondary, and tertiary structures of proteins are discussed under → Proteins. The structural properties of some major food proteins are shown in Table 4.

    Table 4. Structural properties of some major food proteins [7]

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