You are on page 1of 25

Edited by Foxit PDF Editor

Copyright (c) by Foxit Software Company, 2004 - 2007
For Evaluation Only.

Robac
Chemicals

Ref: 08/2003

8 Arbestab N NDBC NiDD ZDBC Arbestab Z NiDIBUD Thiurams……………………………………………………………………………. 4 BiDD CuDD ZBeD/ZBEC ZDBC ZDEC ZPD Arbestab Z Aqueous Dithiocarbamates……………………………………………………… 6 SDBC SDEC SDMC Robosol Robactivator Activated Dithiocarbamates……………………………………………………. 19 Applications in Automotive & Engineering Sectors………………………… 20 Applications in Personal Protective Equipment & Consumer Products… 21 Robinson Brothers Company Activities………………………………………. 22 . 10 P25 TBZTD TBUT TETD TMTD TMTM PTD Thioureas…………………………………………………………………………… 12 22 (ETU) PM DETU LATU TRIBTU DBTU Xanthogens………………………………………………………………………… 14 AS100 ZIX DIXD Special Products………………………………………………………………….Contents Introduction………………………………………………………………………… 3 Dithiocarbamates………………………………………………………………….. 16 Blowing Agents…………………………………………………………………….. 14 Delta Robosol Robactivator Robac PM Polymer Masterbatch Range………………………………………. 6 ZDBCX Antioxidant Dithiocarbamates…………………………………………………... 16 Chemicals for the Plastic Industry……………………………………………. 18 Applications in Rubber & Plastic……………………………………………….

.

For Latex: Arbestab Z Robac ZBeD Robac ZIX Robac AS100 Robosol Robactivator Arbestab 35% dispersion Robac AS100 60% emulsion For Dry Rubber: Robac AS100 Robac ZBeD PM70 Robac MBTS PM Arbestab Z PM Arbestab N SAA30 PM50 Robac MBT PM. feeding systems and toys with further products under development. Low Nitrosamine vulcanisation systems are available as preformulated blends.The Robac range of polymer chemicals and masterbatch (PM) products is listed in the following pages. Current related areas include Polymer Chemicals being used in medical devices. Robinson Brothers has particular expertise with the synthesis of pharmaceutical intermediates. -3- Introduction Safe and Non nitrosatable chemicals suitable for customers to prepare their own systems include: . Sustainability issues are being addressed with low temperature cure systems and heavy metal reductions. ZMBT PM. Specific customer requests for Chemicals not listed in these pages will also be considered. analytical method development and production. The Masterbatch (PM) range is comprehensive with customer specific vulcanising mixtures available. pilot plant trials. CBS PM. This encompasses functions of the company from marketing. Arbestab N PM may be considered as a low nitrosamine antidegradent for certain polymers. DOTG PM and TBZTD PM may also be used in dry rubber systems. TBBS PM. cost effective solutions to both application and legislative problems. DPG PM. Customers are invited to request specific Technical Booklets on the highlighted topics see index page. Pre-weighing to customer requirements may be a further option. This expertise is applied to the Polymer Chemicals business where there is an emphasis on finding novel. In addition to our activities in the Polymer-area. research and development.

3 White Powder PM70 20kg bag 25kg bag C C FDA BGA ZDBC Zinc dibutyl dithiocarbamate 105°C 1.6 White Powder 25kg bag C BGA Arbestab Z Zinc di-isononyl dithiocarbamate 74°C 0.Pt Relative Density Colour Forms Available Packaging Available BiDD Bismuth dimethyl dithiocarbamate >300°C 2.6 Brown Powder PM75 25kg bag 25kg bag C C FDA ZBeD/ZBEC Zinc dibenzyl dithiocarbamate 180°C 1.9 White Powder PM75 25kg bag C C Registered Approval 3 570 CH3 S Dithiocarbamates N C S Cu CH3 2 304 CH2 S N C S Zn CH2 2 610 C4H9 S N C S C4H9 Zn 2 474 C2H5 S N C S C2H5 Zn 2 362 S N C S Zn 2 386 C9H19 S N C C9H19 S Zn 2 755 -6- .2 White Powder O/T Powder PM 75 20kg bag 20kg bag 25kg bag C C C FDA BGA ZDEC Zinc diethyl dithiocarbamate 175°C 1.Chemical Molecular Weight CH3 S N C S Bi CH3 Trade Name Chemical Name M.5 White Powder O/T Powder PM 75 20kg bag 20kg bag 25kg bag C C C FDA BGA ZPD Zinc pentamethylene dithiocarbamate 220°C 1.1 Yellow Powder PM75 25kg bag 25kg bag C CuDD Copper dimethyl dithiocarbamate >200°C 1.

IRP moulding and both moulded and d. Suited to injection and transfer moulding. IIR. SBR. particularly in gum stocks. Used in NR. Fast at high vulcanisation temperatures. NBR. EPDM and NR latex compounds. Used in NR.v. footwear. High solubility in rubbers. SBR. High resistance to hydrolysis. SBR. Used in NR. Used in NR. Used in SBR C>V> extrusions. . Long chain dithiocarbamate. Will prevulcanise latex. low solubility in rubbers. Widely used active secondary accelerator for dry rubber. gives high modulus and transparency.Description Safe-processing secondary accelerator for use in black and dark colours. Used in latex. Maintains light colour. Used for latex work and as a synergistic secondary in EPDM. NBR. Used in NBR. Recognised to have low nitrosamine potential. SBR and latex. Will prevulcanise latex. Recognised to have low potential for nitrosamine generation. readily soluble in hydrocarbon polymers. Used in NR. Will prevulcanise latex systems. Used in IRP mouldings and extrusions and in latex compounds. Can act as primary in latex. Imparts good shelf life to dry rubber and latex compounds. Fast at higher vulcanisation temperatures. EPDM. Used in IRP and latex industry. Can be used as primary in latex. EPDM. Can be used as a primary accelerator in latex. SBR and EPDM. IIR. extrusions and latex. Safer processing secondary accelerator. -7- Dithiocarbamates Safe-processing secondary accelerator. Safe-processing secondary accelerator. Much used active secondary accelerator. Used in sheeting. Fast at high vulcanisation temperatures.

Chemical Molecular Weight Aqueous Dithiocarbamates C4H9 S N C S Na C4H9 Trade Name Chemical Name M.08 Pale Yellow to Yellow/ Green 22% aqueous solution 25kg S poly bottles S 218kg drums BGA SDMC Sodium dimethyl Dithiocarbamate Liquid 1.08 (solution) Yellow/ Green 45% aqueous solution 25kg poly bottles C C 218kg drums SDEC Sodium diethyl dithiocarbamate Liquid 1.09 Brown Liquid 25kg C poly bottles .18 Pale Yellow/ orange to green 40% aqueous solution C 25kg poly bottles C 218kg drums FDA BGA 20% active dispersion 25kg poly bottle 200kg C drum 1000kg IBC 50% active solution 25kg poly bottle 200kg C drum 1000kg IBC FDA BGA 227 C2H5 S N C S Na C2H5 225 H3C S N C S Na H3C 179 Robosol Robactivator Activated Dithiocarbamates Registered Approval S (C4H9)2N C S (C4H9)2NC S S Zn. (C4H9)2NH ZDBCX Amine-activated zinc dibutyl dithiocarbamate 603 -8- Liquid 1.Pt Relative Density Colour Forms Available Packaging Available SDBC Sodium dibutyl dithiocarbamate Liquid 1.

Secondary accelerator for latex. Has been used to boost cure speed in heavily filled SBR latex compounds. Used in NR. Applications: NR examination gloves XNBR examination gloves SBR and SBR/NR foamed latex applications Aqueous Dithiocarbamates Description Fast primary and secondary accelerator. sealants and doughs. SBR. Good solubility in the polymer. SBR. NBR. Fast primary and secondary accelerator for latex. Does not need Zinc oxide to be effective. -9- Activated Dithiocarbamates Primary thioamine water soluble booster for SNR. Has been used to boost vulcanisation in heavily filled SBR latex. Good solubility in polymers. Used in SBR latex Safer nitrosamine latex accelerator system. .Fast primary and secondary accelerator in latex. Can prevulcanise latex compounds. Used in NR. Synergises strongly with ZIX to vulcanise rubbers at room temperature. Gives light colour and good transparency in unfilled vulcanisates. Easily added by simple dilution and stirring. CR latex. Easily added by simple dilution and stirring. Used in NR. Used in conjunction with latex. Liquid form facilitates use in adhesives. Readily emulsified for use in latex. Low solubility in the polymer. Easily added by simple dilution and stirring. Synergises with TETD to give low modulus compounds from CR latex. NR and XNBR latex. Can rapidly prevulcanise latex compounds. Can prevulcanise latex compounds.

7 Green PM75 ECO PM75 25kg bag ZDBC Zinc dibutyl dithiocarbamate >105°C 1.10 - FDA BGA .3 Green PM75 25kg bag C NiDD Nickel dimethyl dithiocarbamate >330°C 1.2 White Powder O/T Powder PM75 25kg bag 25kg bag 25kg bag C C C Arbestab Z Zinc di-isononyl dithiobarbamate 74°C 0.Chemical Molecular Weight Antioxidant Dithiocarbamates CH2 H N C S CH2 M.Pt Relative Density Colour Forms Available Packaging Available Arbestab N Nickel di-isononyl dithiocarbamate 154°C Green Powder PM70 ECO 25kg bag 25kg bag C C NDBC Nickel dibutyl dithiocarbamate 85°C 1.9 White Powder PM75 25kg bag C C Powder PM70 ECO 25kg bag C Trade Name Chemical Name N H Registered Approval 748 C4H9 S N C S Ni C4H9 2 467 CH3 S N C S Ni CH3 2 299 C4H9 S N C S Zn C4H9 2 474 C9H19 N S C S Zn C9H19 2 755 (CH3)2CHCH2 S N (CH3)2CHCH2 C S Ni 2 NiDIBUD Nickel di-isobutyl dithiocarbamate 467 .

Protects against thermal and UV degradation. Protects against thermal and UV degradation. NBR . NBR.P. Used in CR. Good antioxidant for NR adhesives and certain T. Suitable for white and clear compounds. High solubility in hydrocarbon polymers. Protects against heat and UV degradation. ECO.P. NBR. Antioxidant for synthetic rubbers. Maintains good colour on ageing. Used in cables and polyolefins and has been recommended as an anti-glaze additive for NBR rollers. Good antioxidant in adhesives. Good solubility in rubbers.P. High solubility in hydrocarbon polymers. EPDM. High solubility in polymers.E. NBR and polyolefins. NBR.Long chain dithiocarbamate with powerful antioxidant properties. Used in cables and I. EPDM/EP (peroxide and sulphur cured) and in polyolefins. Protects against thermal degradation. under-bonnet applications. Low solubility in hydrocarbon polymers.s. polyolefins and certain T. Potentially low safer nitrosamine generation. ECO. CR. hose. potentially safer nitrosamine generation. Used in CSM.11 - Antioxidant Dithiocarbamates Description . Powerful antioxidant in rubber and polyolefin systems. CR. Antioxidant for synthetic rubbers. ECO. Protects against degradation in high temperature melt processes.E’s. Resistant to extraction by oils and fuels. Protects against thermal degradation.R. EPDM. Used in cables. Good solubility in rubbers. ECO. Used in CR. Used in CSM. Resistant to extraction by oils and fuels. EPDM/EP. Low.

3 White to off white Powder O/T Powder Pellet PM75 25kg bag 25kg bag 25kg bag 25kg bag C C C C FDA BGA TMTM Tetramethyl thiuram monosulphide 105°C 1.1 Brown Liquid 60% active powder TETD Tetraethyl thiuram disulphide 65°C 1.12 - .35 Cream Powder PM 25kg bag 25kg bag C S Registered Approval FDA BGA Thiurams 545 C4H9 S N C S C4H9 2 25kg bottle C 25kg bag C 409 C2H5 S N C S C2H5 2 296 CH3 S TMTD Tetramethyl thiuram disulphide N C S CH3 2 240 CH3 S N C CH3 2 208 S N C S2 2 385 .Chemical Molecular Weight S N C Sx 2 CH2 S N C S CH2 2 Trade Name Chemical Name M.4 Yellow Powder PM25 25kg bag 25kg bag C C FDA BGA PTD Dipentamethylene thiuram disulphide 120°C 1.3 White to off white Powder PM75 25kg bag 25kg bag C C FDA BGA 138°C 1.4 White Powder O/T Powder PM70 25kg bag 25kg bag 25kg bag S S S TBUT Tetrabutyl thiuram disulphide Liquid* 1.Pt Relative Density Colour Forms Available Packaging Available P25 (DPTT) Dipentamethylene thiuram tetra/ hexasulphide 115°C 1.5 Cream to beige Powder O/T Powder PM70 PM75 25kg bag 25kg bag 25kg bag 25kg bag C C C C TBZTD Tetrabenzyl thiuram disulphde 124°C 1.

CSM. systems (MRPRA Publications). *Solid/Liquid at ambient temperature . very soluble in hydrocarbon polymers. Widely used in tyre and IRP.refer to specification. Will not vulcanise rubber in the absence of elemental sulphur. Used in NR. Very low activity as a vulcanising agent. NBR. IIR. Effective at low and high temperatures. Low potential for nitrosamine generation. EPDM. Used in cables. Will act as a vulcanising agent but less active than TMTD. IIR. along with DOTG and sulphur in circumstances where ETU is not acceptable. Low activity as a vulcanising agent.v. more soluble in rubber than TMTD. Used in IRP. NBR. Useful secondary accelerator. Used in NR. NBR. SBR. Used in tyres and IRP. Liquid secondary accelerator. Synergises with SDBC to give fast low modulus systems for CR latex. Used as a vital constituent in soluble e. Retarder in CR vulcanisation. May partially replace TMTD where nitrosamines are a sensitive issue. extrusions and latex. . much safer-processing than TMTD. General purpose secondary accelerator. EPDM. IRP mouldings.13 - Thiurams Less active secondary accelerator. IIR.Description Powerful primary and secondary accelerator. EPDM. Used in NR. SBR. Used in NR. General purpose secondary accelerator. Primary and secondary accelerator Heat resistant compounds and pharmaceutical closures Used: NR. Will vulcanise rubber in the absence of elemental sulphur. NR. NBR. Synergises in blended vulcanisation systems. Will vulcanise rubber in the absence of elemental sulphur. Used in mercaptan-modified CR. Natural Latex . SBR. SBR. Used in CR.

Pt Relative Density Colour Forms Available Packaging Available 22 (ETU) PM Ethylene thiourea 2-Mercaptoimidazoline 195°C 1.94 Brown Liquid only 65°C Off white Powder Registered Approval 102 C4H9 H N C S C4H9 N H DETU Diethyl thiourea 132 Thioureas Generalised C2H5 H N C S C4H9 N H 160 C4H9 H N C S C4H9 N C4H9 Quadritainers 20kg drums C 244 C4H9 H N C S C4H9 N H DBTU Dibutyl thiourea 188 .0 Pale brown to Pale Green Liquid only 25kg C TRIBTU 1.14 - 25kg bag C .1 White Powder flake PM 25kg bag 25kg bag 25kg bag S C C LATU Liquid Dialkyl thiourea Viscous Liquid 1.3 White to off white PM only 25kg bag C 74°C 1.1.3 Tributyl thiourea Liquid 0.Chemical Molecular Weight CH2 H N C S CH2 N H Trade Name Chemical Name M.

An active thiourea. Used in certain tyre sidewalls. Active liquid thiourea. Medium speed of vulcanisation. Also acts as corrosive inhibitor for mild and stainless steel treatments. .v processes. Useful non-staining antiozonant for unsaturated rubbers. Will act as a slow accelerator for the vulcanisation of CR.Description The most widely used general purpose accelerator for CR. . . NBR. SBR. Can activate thiazoles strongly in sulphur vulcanisation. ECO. footwear etc. which is a very fast accelerator for mercaptan modified polychloroprene. Can be used to boost EPDM sulphur vulcanisation systems. Good compression set and general physical properties. Readily incorporated into adhesive formulations.15 - Thioureas The most active thiourea for the vulcanisation of CR. Used in CR. medium and high temperatures. Gives rapid vulcanisation at low.Also acts as an anticorrosive agent. Used in NR. Used in CR. Particularly suited to high speed c. Used in adhesives and doughs. Used in CR. Medium speed in vulcanisation. Used in general purpose moulding and extrusion compounds.

5 White OTD Powder only 25kg bag C DIXD Di-isopropyl xanthogen disulphide 54% Yellow Granuals 25kg bag C Delta Activated dithiocarbamate N/A 2.Pt Relative Density Colour Liquid 1.0 Green PM only 25kg bag C 336 CH3 S H C O C S CH3 2 Special Products 270 N/A 20% active dispersion Robosol 25kg poly bottle 200kg drum C 1000kg IBC 25kg poly bottle 50% active dispersion Robactivator 200kg drum C 1000kg IBC .3 Amber Forms Available Packaging Available Liquid 25kg poly bottles PM40 25kg bag 10% emulsion 334 CH3 ZIX Zinc isopropyl xanthate S H C O C S CH3 Zn 2 Registered Approval C 25kg poly bottles C 200kg drum 149°C 1.Xanthogens Chemical Molecular Weight CH3 Trade Name Chemical Name S H C O C S S CH3 2 AS100 Di-isopropyl xanthogen polysulphide M.16 - FDA BDA .

Nitrogen-free in its structure. Used in NR. Safer nitrosamine latex accelerator system.Fast primary and secondary accelerator for unsaturated polymers. EPDM. All ingredients have LD50 in excess of 2000mg/kilo. Used in SBR. Boosts MBT in latex vulcanisation. Used in conjunction with Robosol. ZDBCX/ZIX may be regarded as the most active system for low temperature vulcanisation. Is a sulphur donor but is best used with low levels of elemental sulphur.17 - Special Products Main use in polymerisation modifiers Stabilisation for hypalon (CSM) polymer Secondary accelerator Anti oxidant for oils . Xanthogens Description Active boost for use in EPDM vulcanisation. NR and XNBR latIces. May discolour white and light colours. Applications: NR examination gloves XNBR examination gloves SBR and SBR/NR foamed latex applications Primary thioamine water soluble booster for SBR. NBR. Synergises strongly with dithiocarbamates and activated dithiocarbamates to give fast vulcanisation at room temperature. Used in NR. May be used to formulate nil/low nitrosamine vulcanising systems. EPDM. Synergises strongly with AS100 in low nitrosamine systems. NBR. Active secondary accelerator. Used in adhesives and coatings. NBR. Very soluble in polymers. Can be used to boost vulcanisation in synthetic rubbers. Best in black and dark colours. Used in high temperature cv systems. . Used in moulding and extrusion compounds.

NBR 75 25kg bag Copper dimethyl dithiocarbamate EP 75 25kg bag Delta Proprietary activated dithiocarbamate EP 80 25kg bag DETU Diethyl thiourea EP 75 25kg bag DOTG Di-o-tolyl guanidine EP 70 25kg bag DPG Diphenyl guanidine EP 75 25kg bag DTDM 4.NBR 75 25kg bag TMTM Tetramethyl thiuram monosulphide EP 75 25kg bag ZBED Zinc dibenzyl dithiocarbamate EP 75 25kg bag ZDBC Zinc dibutyl dithiocarbamate EP 75 25kg bag ZDEC Zinc diethyl dithiocarbamate EP 75 25kg bag ARBESTAB Z Zinc di-isononyl dithiocarbamate EP 75 25kg bag ZDMC Zinc dimethyl dithiocarbamate EP. 25kg bag 75 PVI N-(cyclohexylthio) phthalimide EP 75 25kg bag Sulphur Sulphur EP 80 25kg bag TBBS N-tertiary butyl-2-benzthiazole sulphenamide EP 75 25kg bag TBZTD Tetrabenzyl thiuram disulphide EP 70 25kg bag TETD Tetraethyl thiuram disulphide EP 75 25kg bag TMTD Tetramethyl thiuram disulphide EP.4-disulphonhydrazide EP Slab 75 25kg box TSH PM75 p-Toluene sulphonhydrazide EP Slab 75 25kg box .NBR 75 25kg bag ZMBT Zinc salt of MBT EP 75 25kg bag 22 (ETU) Ethylene thiourea EP 75 25kg bag Robac AZ04 PM75 Azodicarbonimide EP Slab 75 25kg box Robac AZ 2 PM75 Azodicarbonimide EP Slab 75 25kg box Robac AZOR PM75 Azodicarbonimide Formulation EP Slab 75 25kg box Robac OBSH PM75 Diphenyloxide-4.NBR 75 25kg bag MBS 2-(Morpholinothio) benzthiazole EP 75 25kg bag NDBC Nickel dibutyl dithiocarbamate EP 75 25kg bag NiDIBUD Nickel di-isobutyl dithiocarbamate ECO 70 25kg bag NiDD Nickel dimethyl dithiocarbamate EP 75 25kg bag ARBESTAB N Nickel di-isononyl dithiocarbamate EP.18 - .ECO 70 25kg bag P25 (DPTT) Dipentamethylene thiuram tetra/hexa sulphide EP 70.Composition of Active Chemical BiDD Bismuth dimethyl dithiocarbamate CBS N-Cyclohexyl-2-benzthiazole sulphenamide CuDD Binder PM Activity Robac PM Polymer Masterbatch Range Blowing Agents Trade Name Packs EP 75 25kg bag EP.NBR 75 25kg bag MBTS Dibenzthiazyl disulphide EP.4’-dithiodimorpholine EP 75 25kg bag MBT 2-Mercaptobenzthiazole EP.

2 Violet [C2H4OC2H4NS]2 136 1.3 Orange [(CH3)2NCS]2S 208 1.3 White [(C4H9)2NCSS]2Zn 474 1.3 Dark Green [(C4H9)2NCSS]2Ni 467 [(CH3)2NCSS]2Ni 299 [(C9H19)2NCSS]2N 748 [C5H10NCSSS]2 385 1.3 White with yellow seed [(CH3)2NCSS]2Zn 755 0.2 Blue 304 1.2 Off-white 1.2 White with grey seed 1.5 Dark Green Dark Green C6H4NCSSNHC(CH3)3 238 1.2 White with blue seed [(C2H5)2NCSS]2Zn 362 1.5 Green C6H4NCSSNC2H4OC2H4 252 1.3 Yellow [(C6H5CH2)2NCSS]2Zn 610 1.1 White with brown seed (C6H4CH3NH)2CNH 239 1.1 Yellow with orange seed 264 1.15 White .28 Yellow 1.25 Yellow 1.63 Bright Green (C2H5NH)2CS 132 1.WT Relative Density of Active of PM Form Chemical .19 - Robac PM Polymer Masterbatch Range [(CH3)2NCSS]3Bi Colour Code Blowing Agents Formula MOL.9 White [(C4H9)2NCSS]2Zn 306 1.3 Yellow 1.8 Yellow Dark Green 1.5 White with red seed [C6H4NCSS]2Zn 398 1.6 Cream with brown seed [CH2NH)2CS 102 1.2 White with orange seed [(CH3)2NCSS]2 240 1.2 Red [(C4H9)2NCSS]2Ni 467 1.2 White with green/violet seed C6H4NCSSH 167 1.1 White with violet seed (C6H5NH)2CNH 211 1.2 White 1.C6H4NCSSNHC6H11 [(CH3)2NCSS]2Cu 570 2.6 Dark brown 1.4 Cream with green seed C6H4(CO)2NSC6H11 261 1.4 White [(C2H5)2NCSS]2 296 1.3 Off-white-cream [(C6H5CH2)2NCSS]2 545 1.4 Brown [C6H4NCSS]2 333 1.

Improved UV protection over traditional chemicals in combination with flame retarders.CR Exceptionally effective photostabliser. High Thermal Stability. Robinson Brothers are an Independent Family Owned company established in 1869. We offer a technical hands on Service Web Site www. Used in any emulsion process DIXD Powder Molecular weight Control CR. Outstanding for its ability to UV protect polymers in presence of flame retarders and when exposed to pesticidal chemicals. for innovators . UK.025-0.robac.25-1%.co. Innovation. TBUT 100% liquid. Easily emulsified. Aqueous Solution Efficient at low concentrations 0. combined with effective light stabilisation properties.20 - Cost competitive. Used to protect silver from oxidation (Metal Can lower processing temperature Polish) Acts as a molecular weight regulator AND Chain Stopper Issues being worked on at Robinson Brothers Limited Please talk to us to add your concerns or wishes Heat and UV stabilisation UV Degradation Biodegradable Polymers Easily Emulsified. FeDD Powder Effective photo pro-oxidant (Controllable degradation). EPDM. easily emulsified to SBR. Effective at low concentrations (0. Low odour and easily emulsified with both anionic and cationic surfactants . Synergises well with traditional Effective photo-pro-oxidant and photo curing systems. low volatility. characteristics. SDMC Aqueous Solution Chain Stopper. Degrades polyolefinic films in sunlight CuDD Powder and PM Efficient radical generator under UV conditions. works at plastics in presence of sunlight). Synergises with low concentrations 0.1% iron dithiocarbamates to allow controllable degradation MUNDA Powder Exceptional Chain Transfer activity.Polymer chemicals for the Rubber and Plastics industry from Robinson Brothers Ltd. Will replace hindered phenols. Arbestab N Powder 70% PM ECO Thermal stabiliser for PVC/NBR. It is well suited for emulsion polymerisation process ODM Liquid Effective molecular weight modifier and shows Effective at low concentrations improved chain transfer activity over traditional 0.11%.uk Chemicals for The Plastics Industry Product Form Functions Advantages Arbestab Z Powder Free Flowing crystal Extremely effective high temperature processing stabiliser and thermal anti-oxidant. Does not cause discolouration.1% ) Synergises most effectively with hydroxybenzophenones.3%). and synergises (improves) traditional systems Exceptional Antioxidant even at low levels (0. dynamic applications in NR. EDPM and Chloroprene polymerisation Metone A Powder Very Effective photo-pro-oxidant (degrades Contains no metal ions. of inks. giving excellent control of the process AND the molecular weight of the polymer.025-0.ECO. In combination with iron dithiocarbamates provides a fully controllable photo degradation system for polyolefinic films. Effective at low concentrations.1-0. 60% dry dispersion Soluble EV. non toxic. Particularly suited Cost Effective. ISO 9001:2000 and 14001 accredited. ODM and the polymers made from it have excellent odour thiols.

ltd .Product Arbestab N ECO PM Arbestab N Powder Arbestab Z Dispersion Arbestab Z FF Arbestab Z Powder AS100 AS100 Em ulsion AS100 PM 40 DELTA DBTU DETU DETU PM LATU FeDD Robac P25 Robac P25 PM Robactivator Robasol SAA30 PM 50% SAA30 Powder TBUT 100% Liquid TBUT 60% Powder TRIBTU ZDBCX ZIX ZPD NR IR SBR NBR / PVC R ubbers EPDM CR ECO CSM 11R APPLICATIONS IN RUBBER AND PLASTIC NBR NR ro b in s o n b r o th e rs ltd CR A dh es iv e Polyolefins O thers w w w .ro b in so n b ro th e rs . w es t b ro m w ic h B 7 0 0 A H XNBR Latex SBR .u k p h o e n ix s tre e t.

u k W hite W all Trim s p h o e n ix s tre e t.ZDBCX ZIX ZPD TRIBTU TBUT 100% Liquid TBUT 60% Powder SAA30 PM 50% SAA30 Dispersion SAA30 Powder Robactivator Robasol Robac P25 Robac P25 PM DBTU DETU DETU PM LATU DELTA AS100 AS100 Em ulsion AS100 PM 40 Arbestab Z Dispersion Arbestab Z FF Arbestab Z Powder Arbestab N ECO PM Arbestab N Powder Product Extru ded Seats H os es O R in gs Pro files Eng in e M ou nts Flo or M ats B ridg e C om veyor Seat Insu latio n Co m po site B ea ring s System s APPLICATIONS IN AUTOM OTIVE AND ENGINEERING SECTORS Tank Lin in g ro b in s o n b r o th e rs ltd C orrosio n A dh es iv e R etre ad s Inh ib itor w w w .ltd .ro b in s on b ro th e rs. w es t b ro m w ic h B 7 0 0 A H .

Product Arbestab N ECO PM Arbestab N Powder Arbestab Z Dispersion Arbestab Z FF Arbestab Z Powder AS100 AS100 Em ulsion AS100 PM 40 DELTA DBTU DETU DETU PM LATU Robac P25 Robac P25 PM Robactivator Robasol SAA30 PM 50% SAA30 Powder TBUT 100% Liquid TBUT 60% Powder TRIBTU ZDBCX ZIX ZPD Exam in ation G lovers Surgeo ns G loves C on do m s B ab y Teats / Soo th ers Syrin ge Stopp ers Tu bing Fo otw ear APPLICATIONS IN PERSONAL PROTECTIVE EQUIPM ENT AND CONSUM ER PRODUCTS H ou sehold G loves ro b in s o n b r o th e rs ltd w w w . w es t b ro m w ic h B 7 0 0 A H G arm en t Elastics .u k p h o e n ix s tre et.ro b in so n b ro th e rs .ltd .

Custom synthesis is an important part of the business and enquiries can be assured of a confidential and thorough assessment of their proposals. Similarly hydrogen sulphide is employed in thiolation processes to provide thio– and mercaptoproducts.RBL Companay Activities RBL have long-established experience in the environmentally acceptable handling of carbon disulphide and other reactants which others could find problematic especially when handled in multitonne quantities. thiuram sulphides and alkyl thioureas plus several key pharmaceutical intermediates. Specialised units are available designed to carry out reactions involving challenging gaseous reactants such as phosgene as part of a series of unit operations. Catalytic reduction processes are another established area of expertise and our range of production scale autoclaves is being constantly expanded in line with customer demands. Also in place is chiral reductions using stereospecific catalyst complexes. Elemental bromine can be similarly handled in fully authenticated plant. Literature descriptive of RBL non-polymer range of chemicals is available on request. Thus carbon disulphide is used in a variety of thiocarbonylation reactions to manufacture a range of dithiocarbamates. . We are actively seeking opportunities to develop further this relatively new area of chemical synthesis.