Change the quiz from Thompson to thomson
QUANTUM
NUMBERS
QUANTUM MECHANICS
QUANTUM MECHANICS
• Originated in the works of Max Planck, Einstein
and Bohr
• From the word quanta, meaning, specific amount
• Focused on the determination of the behavior of
particles in the subatomic level
Wave-particle duality
BUBBLE CHAMBER PARTICLE
COLLIDER
ELEMENTARY
PARTICLES
QUANTUM NUMBERS
used to determine the size,
shape and orientation of the
orbitals of an atom
• PRINCIPAL QUANTUM NUMBER
• ANGULAR MOMENTUM QUANTUM NUMBER
• MAGNETIC QUANTUM NUMBER
• ELECTRON SPIN QUANTUM NUMBER
PRINCIPAL QUANTUM NUMBER
(n)
-will tell the size of the orbital
-the energy level of the orbital
-cannot be zero
-integers from 1 and so on
-will determine the shell (level)
ANGULAR MOMENTUM QUANTUM
NUMBER
(l)
-will tell the shape of the orbital
-integers between 0 and n-1
-divides the shell into subshells(sublevels)
l s- sharp
0 1 2 3 p-principal
Name of
d- diffuse
Orbital
s p d f f-fundamental
s- orbital p- orbital
(can hold a max. of (can hold a max. of 6 electrons)
2 electrons) -with 2 lobes - dumbbell shaped
Spherical in shape
d- orbital
(can hold a max. of
10 electrons)
-with 4 lobes
f- orbital
(can hold a
max. of 14
electrons)
-with 6 lobes
MAGNETIC QUANTUM NUMBER
( m l)
-will tell the orientation of the orbital
-divides the subshell into individual orbitals which
hold the electrons
- different orientations were observed under the
presence of a magnetic field
- (2l + 1) = number of orbitals per subshell
l 0 1 2 3
ml 0 -1 0 1 -2 -1 0 1 2 -3 -2-1 0 1 2 3
TOTAL
NO. OF
1 3 5 7
ORBITAL
ELECTRON SPIN QUANTUM NUMBER
( m s)
-moving charge
generates a magnetic
field
-electrons act like little
magnets
- one electron spins
clockwise and the
other counterclockwise
(+ ½ , - ½ )
QUANTUM NUMBER
NAME: GRADE AND SECTION SCORE:
PRINCIPAL QUANTUM ANGULAR MOMENTUM MAGNETIC QUANTUM ELECTRON SPIN QUANTUM
NUMBER QUANTUM NUMBER NUMBER NUMBER
(n) (l) (ml) (ms)
1
2
4
PAULI EXCLUSION
PRINCIPLE
-”No two electrons in an atom can have
the same four quantum numbers. “
FOR EXAMPLE:
GIVE THE FOUR QUANTUM NUMBERS
FOR AN ELECTRON IN A 3p orbital.
What is the total no. of orbitals
associated with the principal quantum
number n=3?
ELECTRON
CONFIGURATION
AND ORBITAL
DIAGRAMS
ELECTRON CONFIGURATION
-how the electrons are
distributed among the
various atomic orbitals
1s 1 No. of
electron
ENERGY per
LEVEL subshell
Name of orbital/
subshell
H -1s1
He -1s2
Li -1s22s1
Be -1s22s2
B -1s22s22p1
C -1s22s22p2
N -1s22s22p3
O -1s22s22p4
F 2 2
-1s 2s 2p 5
Ne -1s22s22p6
ORBITAL DIAGRAMS
-another method to determine
how the electrons are distributed No. of
among the various atomic orbitals
electron
through arrows representing the
number of electrons per
- Each box represents the subshell
subshell Name of orbital/
subshell
s
p
d
HUND’S RULE
-”Most stable arrangement of electrons
in subshells is the one with the greatest
number of parallel spins. “
1s1
H
He 1s2 Ne
Li
Be
B
C
N
O
F
Paramagnetic or
Diamagnetic
PARAMAGNETIC - SUBSTANCES THAT CONTAIN
NET UNPAIRED SPINS AND ARE ATTRACTED BY MAGNET
DIAMAGNETIC- SUBSTANCES THAT DO NOT
CONTAIN NET UNPAIRED SPINS AND ARE SLIGHTLY
REPELLED BY A MAGNET
H
He
Ne
Li
Be
B
C
N
O
F
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an exam
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