Time Allowed: 3 hours Maximum Marks: 70 General Instructions: Read the following instructions carefully, (i) There are 35 questions in this question paper with internal choice. (ii) SECTION A consists of 18 multiple-choice questions carrying 1 mark each. (ii) SECTION B consists of 7 very short answor questions carrying 2 marks each. (io) SECTION C consists of 5 short answer questions carrying 3 marks each. (0) SECTION D consists of 2 case- based questions carrying 4 marks each (vi) SECTION E consists of 3 long answer questions carrying 5 marks eact. (oii) AU questions are compulsory. (viii) Use of log tables and calculators is not allowed Section - A ‘Questions 1-14 are Multiple Choice Questions (1 mark each) ‘L._ Which of the following represents Archenius equations ? (A) k= AeeatT (B) k= Ac t8T (C) k= AcE {D) die = AcE 1 2. Write the formula of an oxo-anion of Manganese (Mn) in which it shows the oxidation state equal to its group number. (A) KMn0, (B) MnO, (C)Mn,0, (P) Mncl, 1 3. Which of the following amines can be prepared by Gabriel synthesis ? (A) sobutylamine (8) Toluene (©) N-methylbenzylamine (D) Aniline 1 4, The oxidation of Niin [Ni(CO4)] is: (a) 0 (B)2 (3 (D)4 a1 5. The IUPAC name of the compound shown below is: OL,(A) 2-bromo-6-chloroeyelohex-t-ene 1B) 6-bromo-2-chlorocyclohexene (C) 3-bromo-L-chloroeyclohexene {D) L-brumo-3-chlarocyclohexene a 6. The electronic configuration of Cu(ll is 34” whereas that of Cui) is 3d". Which of the following is correct? (A) Culll) is more stable (B) Cuqty is tess stable (C)Cud) and Coq) are equally stable (D) Stability of Cu(l) and Cu(tl) depends on nature of capper salts ao 7. Which of the following reactions are correct ? H, H KOH. (A) P—Cl+ NH, ~b On + NEC o ,p>-aH ae - o>osrO OWN + HNO, Seo apt 8. Methylamine reacts with HNO, to form (a)CH,-O—N=0 (B)CH,—O—CH, ([Link],OK (0) CH;CHO 1 9. In which of the following molecules carbon atom marked with asterisk (*) is asymmetric? @ i ww i oY % 0 \~a os Br Br ii) i (ivy r c ct NN on” \ om a GBs GH; (A) (i), (i), (ii), Gv) (8) (0, Gi), ii) () (i), (ii), Gv) (©) (), Gil), G4) maa 10. Write the major product (s) in the following: cr, co, BVM, ON (A) 4£(2-Bromoethy!) nitrobenzene (8) 1-Bromoethy! nitrobenzene (©) 4-(1-Bromoethy!) nitrobenzene {D) None of the above a ‘LL. Which of the following is a 3° amine? (A) L-methyleydohexylamine (8) Trimethylamine (©) tert-butylamine (D) N-methylaniline 1 12. Which of the following is most acidic? (A) Benzyl alcohol (B) Cyclohexanol (D) m-Chlorophenol 1 (C) Phenol 13. Generally, transition elements form coloured salts due to the presence of unpaired electrons. Which of the following compounds will be coloured in solid state? (A) Ag2SO, (© ZnF, (6) CuP, ©) CuCl, 114. Write down the decreasing order of reactivity of sodium metal towards primary, secondary and tertiary alcohols (Ay ValeeYate< Pate {B) 1ale>Vale>3%ale (Cy Pale< Mate c2ake (D) Bale>1*ale < Pale 1 Questions 15-18 are Assertion and Reasons Questions: {A) Both assertion (A) and reason (R) are correct statements, and reason (R) is the correct explanation of the assertion. (B) Both assertion (A) and reason (R) are correct statements, but reason (R) is not the correct explanation of the assertion (C) Assertion (A) is correct, but reason (R) is the wrong statement. {D) Assertion (A) is wrong, but reason (R) is the correct statement. 15. Assertion (A): o-Nitrophenol is more soluble in water than the m- and p-isomers. Reason (R): m- and p-Nitrophenols exist as associated molecules. 1 16. Assertion (A): Toxic metal ions are removed by the chelating ligands, Reason (R): Chelate complexes tend to be more stable. 1 17. Assertion (A): Dimethyl ether is less volatile than ethyl alcohcl. Reason (R); Dimethyl ether has greater vapour pressure than ethyl alcohol. 1 18. Assertion (A): Elementary reactions have same value of order and molecularity. Reason (R): Molecularity is the number of molecules that participate in the reaction, while order isan experimental quantity. 4 Section - B 19. (a) Why do amines behave as a Lewis base? (b) Write the reaction involved in the diazotisation of aniline. 2 20. State Raoult’s law for a solution containing volatile components. Write two characteristics of the solution which ‘obeys Raoult's law at all concentration, wae 21. Identify the following: (2) Oxoanion of chromium whichis stablein acidic medium. (b) The lanthanoid element that exhibits +4 oxidation state. 22. Explain why on addition of 1 mol glucose to 1 litre water the boiling point of water increases. 2 OR Why a mixture of carbon disulphide and acetone shows positive deviation from Reoult's law ? What type of azeotrope is formed by this mixture? 2 23. What is meant by ‘disproportionation’ ? Give an example of a disproportionation reaction in aqueous solution. 2 OR Suggest reasons for the following features of transition metal chemistry: (a) The transition metals and their compounds are usually paramagnetic. {b) The transition metals exhibit variable oxidation states. @iz 24, Write the structures and IUPAC names of the cross aldol condensation products only of ethanal and propanal. 2 25. State two points of difference between Molarity and Molaity. 2Section -C 26. Wiite tne final product(s fn each of the following reactions CH; I (®) cHy—¢—o—c1,+ i> | CH; () CH—CH,—cH—cH, —UK I OH (CHE y+gRHOH (© GH, — oH SCs ans oR How are the following conversions carried out? (a) Propene to propane-2-01 (©) Benzyl chloride to Benzyl alcohol (©) Anisole to p-Bromoanisole 27. What happens when (a) Chlorobenzene is treated with ClyFeCly (b) Ethyl chloride is treated with AgNO, (©) 2bromopentane is treated with alcoholic KOH ? Write the chemical equations in support of your answer. OR Write the major product () in the following: @® cry — cx, BRO HEMY, 5 LY ON ) 2cH,—cH— cH ae 7 a () CH,—CH,— Br 8S, 7 3 28. (a) Why pK, of F-CH,- COOH is lower than that of Cl-CH,-COOH? (b) Write the product in the following reaction. () DALH (CH,-CH = CH-CH,CN ano? ? (6) How can you distinguish between propanal and propanone ? 3 29. (a) Wile the main structural difference between DNA and RNA. Or the two bases, thymine and uracil, which one is presentin DNA? (b) Which of the two components of starch are water soluble ? as 30. Write chemical equations for the following reactions: (a) Propanone is treated with dilute Ba(OH),- (b) Acetophenone is treated with Zn(Hgy Cone. HCL as (c) Benzoyl chloride is hydrogenated in presence of Pa/BaSO,Section - D 31. Read the passage given below and answer the fallowing questions: Galvanic ells traditionally are used as sonees af DC electrical power. 4 simple galvanic cell may contain on, one electrolyte separate by a semi pois membrane, while a more camplex version involves Wo separate ha, cells connected by a salt beg, The salt bilge contain an inert electrolyte ke potassium sulfate whore fan diffuse into the separate half-cells to balance the building, charges at the electrodes. A galvanic cll consists of a metalic zine plate immersed in 0.1 M Zin(NO,) solution and metalic Plate of led ig 0.02 M PO(NO,), solution, (a) How will the cell be represented ? : (b) What product is obtained at cathode ? : (©) Calculate the emf of the cel. 7 OR Do inert electrodes participate in the redox reaction? What is the role of an inert electrode [Link]? 32. Read the passage given below and answer the following questions: Glycosidic bonds and peptide bonds are two types of covalent bonds which can be found in living systems. The formation of both of these bonds involves the removal of a water molecule and this process is called dehydration reactions (also known as condensation reactions). But these two bonds are very different from each other. The key difference between Glycosidic bonds play a very special role in the existence of living organisms on the earth since they are important for the structure of all substances Glycosidic bond: Glycosidic bonds can be found in the sugar which we eat, trunks of trees, the hard exoskeleton of lobsters and also in the DNA of our body. Peptide bond: general, peptide bonds are found in proteins and nucleic acids, DNA and hair. (a) Name the linkage connecting monosaccharide units in polysaccharides, 1 (b) Whatare reducing sugars? 1 (c)__ Differentiate between peptide linkage and glycosidic linkage. Give two points. 2 OR What happens when glucose reacts with acclic acid? What does it suggest about the structure of glucose? 2 Section - E 33. (a) How isa double salt different from a complex ? (b)_ What is the denticty of coordination compound used for the treatment of lead poisoning ? {@)_ Write the coordination number and oxidation state of platinum in the complex [Pt(en},Ch). {@) What is meant by chelate effect ? is OR (a) Write the IUPAC name of the following complex: [Pe(NH3},Ch) {b) Write the formuta for the following: ‘Tetraammincaquachloridocobalt (IJ) nitrate (c) Hows stepwise stability constants and overall stability constant formed are related ? Explain with an example. 534. (2) (by o (ay 35. (a) ) Write the rate law for a first order reaction, Justify the statement that half life for a first order reaction ts independent of the initial concentration of the reactant. Explain awhy H, and O; do not react at raom temperature Write the rate equation for the reaction Ay + 30; -» 2G, if overall orcr of the reaction is zero. Write the unit of rate cons nt for zero onder reaction. 5 nereases 1.5 times Solutions of wwo electrolytes W’ and 'W’ are diluted, The limiting molar conductivity of 8" While that of © increases 25 times, Which of the two Is a strong electrolyte ? Justify your answer. The electrical resistance of a column of 0.05 M KOH solution of diameter 1 em and length 45.5 cm is ASS x 108 ohm. Calculate its molar conductivily. OR Calculate the standard cell potentials of galvanic cells in which the following reactions take place (a) 2Cx(s) + 3Ca?* (aq) > 2Cr3*(aa) + BCA () Fe (aq) + Ag+ (aq) > Fe" (aq) + ARGS) Calculate the ArGQ and equilibrium constant of the reactions, s