SR_*CO-SC(MODEL-A&B,C) PTM-14 Date:11-11-23

Time: 3 Hrs JEE-MAIN Max. Marks: 300

KEY SHEET
PHYSICS
4 4 4 1 4 2 4 3 2 2
1-10
4 4 2 2 1 1 2 3 1 3
11-20
11 25 9 20 4 50 3 2 60 450
21-30

CHEMISTRY
31-40 3 3 3 2 2 1 4 1 4 4
41-50 1 2 1 1 1 4 2 1 3 1
51-60 80 2 2 800 309 3 8630 54 627 44

MATHS
1 4 2 2 4 3 3 4 1 2
61-70
2 2 2 3 4 2 2 3 4 1
71-80
2 1 4 9 3 6 121 529 348 7
81-90
Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL
HINTS & SOL

I 3mR 2 / 2 3R
1)4 T  2  2  2
mgl mgR 2g
L M
2)4 T  2 ,L 
2g Ad .
 f 0 200
3) 4 i) M    40
fe 5
 f0  f e  5  6
ii) for distinct vision M   1   , M  40 1  25  , M  40    48
fe D  5
4) 1 According to theory section,
1 BA2
f 
2 MV0

MV0 M  hA  Mh
 T  2 2
 2 2
 2
BA PA PA
5)4 Time period of mass oscillating on a spring is independent of g.
6)2 When the particle of mass m at O is pushed by y in the direction of A, the spring A will be
compressed by y while springs B and C will be stretched by y '  y cos 450 , so that the total
restoring force on the mass m along OA,
R.F .  FA  FB cos 450  FC cos 450
 ky  2ky 'cos 450
 ky  2k  y cos 450  cos 450  k ' y where k '  2 k
m m
 T  2  2
k' 2k

7)4 y  A sin  t   
A A
Here, y  ,  A sin  t    
2 2
 5
So,   t    or
6 6
A
So, the phase difference of the two particles when they are crossing each other at y  in
2
opposite directions are
5  2
  1   2   
6 6 3
T
8) 3 Time taken by the pendulum to move from A to O and from O to A  .
2
Time period of oscillation  L

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T1 L/4 1 T
   or T1 
T L 2 2
T
Time taken to complete half the oscillation 
4
T T 3T
Total time period of oscillation   
2 4 4
9)2 Here, V  x   A 1  cos px 
dv d
Force, F    A  A cos px 
dx dx
For small x, F   Ap2 x
F Ap 2 x
Acceleration, a  ……….. (i)
m m
The standard equation of SHM is, a   2 x
Comparing equations (i) and (ii), we get ……….. (ii)
2 2
Ap Ap
2  or  
m m
2 m
Period of oscillation, T   2
 Ap 2
5k 1 5k
10)4 K1  K 2  5 K  5K  3l   m 2  3l      f 
m 2 m

 A A
Sin  
11. 4) n   2 
A
S in
2
A A A A A
SinA = n Sin , 2S in Cos  nSin , n = Cos
2 2 2 2 2
A n 2  4  n2 
Sin = 1 , A = 2Sin 1  
2 4  4 
 
12.(4) For paraxial rays:
 2 1 2  1
  d
V U R
3 / 2 1 (3 / 2)  1
 
V  R
V  3R d’ 3R

d / 2 d1 / 2 2d
tan    d1 
3R 2R 3

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L
13) 2 I s  Mg sin   mgL sin 
2
M 
g  m
2 3 g  M  2m 
   2   
M  2 L  M  3m 
  mL
 3 
2 ( M  3m) L
T  2
3 ( M  2m ) g
14) 2, condition for SHM should be satisfied
15) 1

which may be a circle if ω = 1 and ellipse of ω 1.

Acceleration-displacement graph is straight and acceleration time graph is sinusoidal

16) Total mechanical energy in SHM is constant

17)
18) 3
19)1
20)3
sol: apply m=f/(f-u)

121 100
21) 11 T1  2 , T2  2
g g
Let shorter pendulum makes n vibrations; then the longer will make one less than n to come
in phase again.
nT2   n  1 T1
100 121
Or n.2   n  1 2
g g
Solving, we get; n  11
22) 25 F1  k1 x , F2  k2 x
k  k 
f1    1  x ; f 2    2  x
m m
or f1  12 x ; f 2  22 x

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Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL
now, resultant force F  F1  F2  k1 x  k2 x
or kx  k1 x  k2 x
or k  k1  k2
or m 2  m12  m22
or  2  12  22
2 2 2
 2   2   2 
or      
 T   T1   T2 
1 1 1
or 2
 2 2
T T1 T2
T1T2
 T
T12  T22
4 3

3 5 12
  sec
2
 4 3
2 25
   
5 5
23) 9 Errors are random in nature
T 1 l 1 g
  
T 2 l 2 g
0.02 1 0.1 1 g
  
0.5 2 10 2 g
g  0.02 0.1 
%   2    100
g  0.5 10 
= 8 + 1=9
24) 20

25) 4
Sol : The particle is moving along y-axis.
y  t   a cos wt  b sin t

y  a 2  b 2 sin t  0 
Where tan 0  a / b
y  a 2  b 2 sin t  tan 1 a / b 
comparing with y  a sin t   
2 2
r    sec
 2
A  a 2  b 2  32  4 2  5m
 max   2 A  4  5  20m / s 2  2 101 m / s
26) 50
A  100   1

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v   A2  x 2  1 1002  x2
 502  1002  x 2  x  50 3cm
27) 3
By conservation of energy the speed of each particle just before strikes = gR
By conservation of linear momentum, after collision speed = 1 gR
3
gR
 Aw
3
gR g
A
3 R
R
 A
3
28) 2
Sol : K eff  k  k cos2 
29) 60
1 1 1
Sol. In first case  (1.5  1) (  )
15 R1 R2

1  1.5  1 1 
In second case,   1   
f  4 / 3   R1 R2 

dividing, we get f = 60 cm

30. ) 450
sol: Differentiate apparent height equation w.r.t time

CHEMISTRY
31. When enthanlpy of combustions are given,
H r  H Reactants - H Products
3 C2 H 2 
 C6 H 6
 

3  1300  3268
H r  632 kJ mole
32. If T = 315k ; G   ve
T = 280k ; G   ve
T = 320k ; G  0
3
At 350k, G  120  350
8
= -11.25 kJ/mole
G  11.25, G  0
Amount of y will be greater than its equilibrium constant.

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Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL
33. w  nRT nV2  nRT nV1
y  mx  c
So, slope of curve 2 in more than covre 1 and intercept of curve is 2 more negative than
curve 1

34. Workdone = Area under curve

35. H Neutralization = H ionzation H r
-51.34 = x -55.84 ; x = 4.5 kJ/mol
C p ,m R
36.   ; C p ,m  Cv , m  R ; Cv ,m 
Cv ,m  1
Cv
Cv , m  and Cv  m  Cv
n
R m  Cv R
  M ; Cv 
 1 m   1 M
T2 P
37. s  nC p ,m n  nR n 1
T1 P2
7  596  1
 3 R    3 R n
2  298  4
= -6.3cal/k
38. C3 H 8 g   5O2 g   3CO2 g   4 H 2 O  
 6  BE C 0 

 8 BE 0  H 
H C  8BE C  H   2 BEC C   5 BE 0 0    
 3 RE of CO2
 4  H  H O 
 vap 2

39. xg  3 in opt (4)

4
40. w  4   dv  4  3 100
1

 1.2 103 J
nRT 100  0.0821 T
41. V  T
P 8.21
V
42. W  nRT n 2
V1
W = -11.488J
43. Method of preparation of colloid
44. FeCl3
45. Bredig’s Arc method
46. When FeCl3 is added to NaOH solu then negatively cherged sol is fomed. So Al 3 with more
concentration has high coagulation power

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47. Hardy schuze - Rule
no.of moles of electrolyte required
48. Coagulation value =
vol. of colloidal solution  in litre 
10  0.5
 1000  100
50
49. Fog is liquid in gas colloid
50. No.of milli moles of two reactants should be taken
51. Rxn is spontaneous in a direction in which gibbs free energy decreases. Hence, two statements
(ii) and (iii) are correct
1
52. Coagulating power ×
Coagulating value
Coagulating power of AlCl3 Coagulating value of NaCl
=
Coagulating power of NaCl Coagulating value of NaCl
50.04
x= =556
0.09
53. x=4;y=3
54. Let B.E of A2  x kJ/mole
B.E of B2 0.5 x kJ/mole
A2  B2  2 AB; H R  400 kJ mole
x 0.5 x  2 x
-400 = x + 0.5x -2x
-400 = -0.5x
x = 800 kJ/mole
55. SF6 g   S g   6 F g 
H r  6  B  E S  F 
H r  H f S g   6H f F g   H f SF6 g 
H r  275  6  80  1100  1855kJ
1855
B  ES  F   309.17  309 kJ mole
6
56. H  U  ngRT
H  3300 cal
G  H  J S
 2.7 Kcal
V
57. W = -2.303 nRT log 2
V1
 20 
W = 2.303  5  8.3  300log  
 10 
W = 8630 J
58. HNO3  NaOH  NaNO3  H 2O
120mmol 40mmol 40m.mol
80mmol 0
3
 40 10 moles are reacting.

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H r  40  103  57  103 J  2280 J
q  mcT  q  H r 
2280  1000  4.2  T ; T  54  102C
59. Paints, milk, hair cream, froth, soaplather have liquid dispersion medium
60. Hydrated metallic oxides, TiO2 sol, methylene blue are positively charged sols.

MATHS

61.Sol: From the diagram, AOB  BOC  COD  600  YOD 
6
Let X be the centre of right hand circle, OX sin 300  a
 OX  2a
Now
r  OY  2a  a
r
a
3
62.Sol: AO 2  OB 2  OC 2
 2  4   2  4    
     (if    then no triangle is formed)
ABC is right angled triangle at A
  , 2  is orthocentre   3,   2
 vertices are (3, 2), (3, - 2) and (-3, 2)
63.Sol:
15 / 2 15
tan   
4 8
4
In RSQ tan  
RS
15 4 32
   RS 
8 RS 15

64.Sol:
2 2
DE  Ak   r1  r2    r2  r1   2 r1r2
Similarly , BL  EF  2 r2 r3
Let APD   and PD  x, then
AD BE CF
tan    
PD PE PF
r r2 r3
1   k  say 
x x  2 rr
1 2 x  2 rr
1 2  2 r2r3

r2  r1 r3  r2
r1  kx, r2  kx  2k rr
1 2 , r3  kx  2k rr
1 2  2k r2r3 ;   r2  rr
1 3  49  6
2 rr12 2 r r
2 3

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5/ 2
65.Sol: sin 600 
a
5 2
a
3
3 2 25
Area of PQR = a 
4 2 3
66.Sol:
AB  x  2 y  1  0
AC  2 x  y  1  0
So A 1,1
Altitude from B is BH  x  2 y  7  0  B  3, 2 
Altitude from C is CH  2 x  y  7  0  C  2,3
Centroid of ABC  E  2, 2  OE  2 2
67.Sol: Let B  x1 , x1  2 
2 2 29
 x1  4    x1  2  3  
3
Squaring on both side
18 x12  162 x1  340  0
51 10
x1  or x1 
9 3
33 4
y1  or y1 
9 3
 10 4 
Option(C) will satisfy  , 
 3 3
68.Sol:
x y 1
1
Given 1  1 1 1
2
4 3 1
1 1 1
1
& 2  4 3 1
2
2 5 1
1 4 2 x  5 y  7 4
Given   
2 7 36 7
 14 x  35 y  95........... 1
Equation of BC is 4 x  y  13.......  2 
Solve equation (1) & (2)
 20 11 
Point P  , 
 7 7 
 1  1 
Here point Q  , 0  & R  , 0 
 2  2 
1 1
So area of triangle AQR   1 1 
2 2

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6 9.Sol: Given circle x 2  y 2  2 gx  6 y  19c  0
Passes through (6, 1)
12g + 19 c = 43 ………..(1)
Centre (g, - 3) lies on given line
So, g + 6c = 8 ………….. (2)
Solve equation (1) & (2)
c=1&g=2
equation of circle x 2  y 2  4 x  6 y  19  0
Length of intercept on x-axis
 2 g 2  c  2 23
2 2
70.Sol :  a  1  4   b  1  16
2 2
  a  1   b  1

ab > 0
2 2
 b  1  4 &  a  1  16
 b  1 2 a  1 4
 3, 1  5, 3
A  5, 3 

For a  5, B  3,5   (not possible)
C  5,3 
For a = 3, b = 1
 A  3,3

 B  1,5  (possible)

C  3, 1
1
Line AP : y  1    x  1
2
x  2 y  3.......  i 
Line BC:
B  1,5  , C  3, 1

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6
y 5   x  1
2
3x  y  8......  ii 
x  2y  3
3x  y  83  2
13
  7 x  13  x 
7
39 17
y 8 
7 7
4
k1  k 2  x  y 
7
71.Sol: m1m2  1 , for square a, b, c, d
Let A 10  cos   sin   ,10  sin   cos   
Diagonal :  cos   sin   x   sin   cos   y  10
BD (diagonal)
Dist. Of BD from A is
2 2
10  cos   sin    10  sin   cos    10 a

2 2
10 a
  a  10
2 2
Also, a 2  11a  3  m12  m22   220
 210  3  cm12  cm22   220
10
m12  m22 
3
Also, m1m2  1
1 10
 m2  2 
m 3
1
or  3,
3
1
m  3,
3
10 100 10 8
 4 
10 1
m4  m2  1  0  m2  3 9  3 3  3,
3 2 2 3
1
m   3, 
3
Diagonal AC :
 sin   cos   x   cos   sin   y
 10 cos 2  10 cos 2  0
sin   cos  tan   1  
Slope of AC    tan       300
cos   sin  1  tan  4

750

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Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL
1 9  720
?  72     100  30  13   83  128
 16 16  16
72.Sol: From the figure

2
22   y1  1  y12
4  y12  1  2 y1  y12
5
5  2 y1 and y1 
2
Equation of the line from (2, 5/2) to the given base is
5
y   2  x  2
2
or 2 y  5  4  x  2 
at y  1
3 5
  x  2 or x 
4 4
73.Sol: Let the slope of L be m then
m 3
 tan 600  3
1  3m
 m  3  3 1  3m  
 m  0 or m  3
But m  0 as L intersects x-axis
Hence equation of L is
y  2  3  x  3
or y  3 x  2  3 3  0
74.Sol:
x 3 y 4

cos  sin 
3 4
PR  , PS 
cos  sin 
RS  PS  PR

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Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL
75.Sol:

3h  4k  9 4h  3k
k   3
5 5
9  3h  4k 4h  3k
k   3
5 5
h  2k  6  x  2 y  6
x y
76.Sol: Let the equation of AB   1 1
a b
Let p(h, k) locus of midpoint of AB.
a = 2h, b = 2k substitution in (1)
x y 1
   1   kh  hy   hk and passes through the point (x, y) = (8, 4)
2h 2k 2
1
  8k  4h   hk  2h  4k  hk  2 x  4 y  xy
2
The locus of p is xy – 2x – 4y = 0
77.Sol :  2a  3b  c  3a  b  c   0  2a  3b  c  0 or 3a  b  c  0
78.Sol:

3.3 9
mL1  
10 10
6.3 18
mL2  
5 5
y   m1  m2 
9
y x
2
 10 45 
Point of intersection with L is  , 
7 7 
2 2
79.Sol: equation of circle x  y  2 x  y  5  0
5
R
2

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Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL

Length of PR = QR = S1
81 2 9 5
 4  25 
16 4 4
5 125
.
RL3 2 64  5
Area of triangle PQR  2 
R  L2 25  25 8
4 16
 7 3
80.Sol: pt   , 
 3 

x cos   y sin   7
7
x-intercept 
cos 
7
y-intercept 
sin 

 7   7 
A:  , 0  B :  0, 
 cos    sin  

Locus of mid ptM : (h, k)

7 7
h ,k 
2 cos  2sin 

7 7 3 3 
  sin    
2 cos  3 2 3
7
 7
2cos 

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Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL
81.Sol:

 1  cos  3
tan  
2 sin  4
82.Sol:

Since DBCA = 900

Points A, O, B, C are concyclic
Let DAOC = q
DBOC = DBAC
  5
tan     
2  12
x 5
  12 x  5 y  0
y 12
83.Sol: Let B(a, b), C(c, b), A(a, d)
ac 
Then D (mid point of BC) is  ,b 
 2 
 bd 
E (mid point of AB) is  a, 
 2 
bd
b
Given slope of CE = 1  2  1  b  d   2
ca ca
bd b  d   4
Slope of AD  2
ac ca
a
2
84.Sol: Let PQRS be the square inscribed in ABC with side ‘a’. Let P= (p, 0). Then Q = (p + a, 0), R =
(p + a, a), S= (p, a) respectively.
x
Equation of AB is y  and S lies on it.
2
p
a  or p  2a again equation to BC is x + y = 3 and R= (p + a, a) lis on it.
2
3 9 3 96 3
a  . Now side of square =   
4 4 2 4 4
9
Area = A = or 16 A  9
16

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Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL
85.Sol: Let vertices be A(3, -1), B  x1 , y1  and C  x 2 , y2  . C lies on angular bisector
imply x2  4 y2  10  0 ……(1)
Similarly mid point of AC lies on median imply 3 x2  5 y2  55  0 ………(2)

Hence C = (10, 5) and equation to AC is 6x – 7y = 25
a + 4b + c = 6 – 28 + 25 = 3
86.Sol: suppose ABCD be the square with A and C on axes
5 7 5
A = (5, 0), C = (0, 7) and E =  ,  be mid point of AC. Slope BD=  tan 
 2 2 7
Equation of BD is
5 7
x y
2 2  r where r   AC
cos sin  2
74
i.e. r  
2
Solving B = (6, 6) and D = (-1, 1)
a bcd
6
2
87.Sol:

2 2
Let equation of circle is  x  a    y  a   a 2
Which is passing through P  ,  
2 2
Then   a      a   a 2
 2   2  2 a  2 a  a 2  0
Here equation of AB is x + y = a
Let Q  ',  ' be foot of perpendicular of P on AB
 '   '       a 
 
1 1 2
2 1 2 1 2
PQ 2   '      '        a       a 
4 4
1 2
121      a 
2
242  2
   121

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Narayana IIT Academy 11-11-2023_SR.IIT_*CO-SC(MODEL-A&B,C)_JEE-MAIN_PTM-14_KEY&SOL
88.Sol:
A & C point will be (- 4, 5) & (3, 2)
 1 7
Mid point of AC will be   , 
 2 2
Equation of diagonal BD is
7
7  1
y  2 x 
2 1  2
2
 7x  y  0
23
Distance of A from diagonal BD = d=
50
2
 50d 2   23
50d 2  529
89.Sol: point of intersection of 1 : 3 y  2 x  3
The lines  2 : x  y  1  0 is P   0,1
Which lies on  3   x   y  17  0
   17
Calculated by formulae
x   1 y  0  2  3 
  2  
2 3  13 
Now Q’ lies on  3   x   y  17  0
  7
Now  2   2      348

2 2
90.Sol: Circle  x  a    y  a   a 2

x 2  y 2  2ax  2ay  a 2  0
int ercept  2
 2 a2  d 2  2

Where d = perpendicular distance of centre from li ne x + y = 2

2
aa2
2
 2 a   2
 2 
2

a 2

 2a  2   1  2 a 2  4 a 2  8a  4  2
2
 2 a  8a  6  0  a 2  4 a  3  0
2

 r1  r2  4 and r1r2  3
2
 r12  r2 2  r1r2   r1  r2   3r1r2
 16  9  7

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