A Technical Seminar report On PAPER BATTERY a a aaa BACHELOR OF TECHNOLOGY IN ELECTRONICS AND COMMUNICATION ENGINEERING Submitted by E.Bharathi 22BF1A0417 Under the esteemed guidance of Mr.L.MAHESH, M.Tech. Assistant Professor Department of ECE SV COLLEGES since 1981 SRI VENKATESWARA COLLEGE OF ENGINEERING DEPARTMENT OF ELECTRONICS AND COMMUNICATION ENGINEERING (AUTONOMOUS) Karakambadi Road, Tirupati-517507 2023-2024SRI VENKATESWARA COLLEGE OF ENGINEERING DEPARTMENT OF ELECTRONICS AND COMMUNICATION ENGINEERING (AUTONOMOUS) Karakambadi Road, Tirupati-517507 2023-2024 This is to certify that a seminar report entitled’PAPER BATTERY"a bonafide record of the technical seminar done and submitted by V.SRIJA bearing 22BF 1A041Tfor the partial fulfillment of the requirements for the award of B.Tech Degree in Electronics and Communication Engineering of Sri Venkateshwara College of Engineering, Tirupathi. SEMINAR COORDINATOR Head of the DepartmentACKNOWLEDGEMENT I would like to express my gratefulness and sincere thanks to Dr .D.Srinivasulu Reddy, Head ‘of the Department of ELECTRONICS AND COMMUNICATION ENGINEERING, for his kind support and encouragement during the course of my study and in the successful completion of the ‘technical seminar. I would like express gratitude to Mr.L.Mahesh, Assistant Professor, seminar coordinator, ECE Department for his continuous follow up and timely guidance in delivering seminar presentations effectively It’s my pleasure to convey thanks to Faculty of ECE department for their help in selection. ‘of right theme for the technical seminar. I have great pleasure in expressing my hearty thanks to our beloved Princ pal Dr.N.Sudhakar Reddy for his support and encouragement I would like to thank our parents and friends, who have the greatest contributions in all sy achievements,ABSTRACT ‘The Batteries form a significant part of many electronic devices. Typical electrochemical batteries or cells convert chemical energy into electrical energy. Batteries based on the charging ability are classified into primary and secondary cells. Secondary cells are widely used because of their rechargeable nature. Presently, battery takes up a huge amount of space and contributes to a large part of the device's weight. There is strong recent interest in ultrathin, flexible, safe energy storage devices to meet the various design and power needs of modern gadgets. New research suggests that carbon nanotubes may eventually provide the best hope of implementing the flexible batteries which can shrink our gadgets even more. The paper batteries could meet the energy demands of the next generation gadgets. A paper battery is a flexible, ultra-thin energy storage and production device formed by combining carbon nanotubes with a conventional sheet of cellulose-based paper. A paper battery acts as both a high-energy battery and super capacitor, combining two components that are separate in traditional electronics. This combination allows the battery to provide both long-term, steady power production and bursts of energy. Non-toxic, flexible paper batteries have the potential to power the next generation of electronics, medical devices and hybrid vehicles, allowing for radical new designs and medical technologies. The various types of batteries followed by the operation principle, manufacturing and working of paper batteries are discussed in detail.DECLARATION Engineering (AUTONOMOUS) and has not been submitted to any other course of university for the award of any degree. Signature of the Student E.Bharathi.Table of Contents Chapter 00a nto 1. Introduction to batteries, 1.1 Terminologies... 1. 2Principle of operation Of Call...ssssesssesersseveneearenversearesere essen ess MeL On ea ny octeeeereet esas ee eee teeta centres neneceettroeene 2. Paper Battery... Carbon nanotubes... 3, 1Properties of carbon nanotubes. @ }» Fabrication of paper battcrys....ssessssessssecsesesscasenaessesaraseesssseesssan Le op Working of paper Unter y iscesseensenetnnennenensnsmmnmnsensesemsrntseneetnenerers LS) }. Applications of papes battery...ssssscessssssssesesessyensnensesssensssssnenseneeDe, ypaenrnane . ConclusionList of Figures Figures Description Figure la... Symbolic View of the Battery Figure Ib... .. Conventional Battery i grey ez enema ....Principle Operation of Battery Figure 1.3a. ... Primary cell Figure 1.3b. ... Secondary cell HIS UTCH 4 neemteeeretties .. USB cell HAUGH es eementisereete tie .. Life of Battery Figure 1.6....c.ccceseees .. Electronic Waste Figure 2.. Paper Battery Figure 2ilvennnensaii . Types of CNTs Figure 3... Carbon nanotubes Figure 3.1...0.0.ccccccccceee LHI UL OS 2 eraser ....Relation b/w resistivity vs. temp. Figure 4... .Fabrication Process -Paper Battery -Sechemetic of fabrication processFigure 5..... ...working of paper battery Figure 5.1... ....Testing of paper battry1. INTRODUCTION TO BATTERIES An electrical battery is one or more electrochemical cells that convert stored chemical energy into electric 1800 by Al many household and industria energy. Since the invention of the first battery in indro Volta, batterie: have become a common power source for applications, Batteries are represented symbolically as Conventional battery Fig. la Symboli battery Electrons flow from the negative terminal towards the positive terminal. sed on the rechargeable nature batteries are classified as a. Non rechargeable or primary cells b. Rechargeable or secondary cells Based on the size they are classified as a, Miniature batteries Based on nature of electrolytea. Dry cell b. Wet cell 1.1 Terminologies Lil Accumulator - A rechargeable battery or cell 1.1.2. Ampere-Hour Capacity - The number of ampere-hours which can be delivered by a battery on a single discharge. 1.13 Anode - During discharge, the negative electrode of the cell is the mode. During charge, that reverses and the positive electrode of the cell is the anode. The anode gives up electrons to the load circuit and dissolves into the electrolyte. 1.14 Battery Capacity - The electric output of a cell or battery on a service test delivered before the cell reaches a specified final electrical condition and may be expressed in ampere-hours, watt- hours, or similar units. The capacity in watt-hours is equal to the capacity in ampere-hours multiplied by the battery voltage. 115 Cutoff Voltage final - The prescribed lower-limit voltage at which battery discharge is considered complete. The cutoff or final voltage is usually chosen so that the maximum useful capacity of the battery is realized.1 1 i, 1.6 C- Used to signify a charge or discharge rate equal to the capacity of a battery divided by 1 hour. Thus C for a 1600 mAh battery would be 1.6 A, C/Ss for the same battery would be 320 mA and C/10 would be 160 mA. 1.7 Capacity - The capacity of a battery is a measure of the amount of energy that it can deliver in a single discharge. Battery capacity is normally listed as amp-hours (or milli amp-hours) or as watt-hours. 18 Cathode - Is an electrode that, in effect, oxidizes the anode or absorbs the electrons. During discharge, the positive electrode of a voltaic cell is the cathode. When charging, that reverses and the negative electrode of the cell is the cathode. 1.9 Cycle - One sequence of charge and discharge. 1.10 Cycle Life - For charge/discharge cycles the cell can tain before its capacity rechargeable batteries, the total number of is significantly reduced. End of life is usually considered to be reached when the cell or battery delivers only 80% of rated ampere - hour capacity. that provides electrical energy storage through an electrochemical reaction, 1.11 Electrochemical Couple - The system of active materials within a cell .1.12 Electrode - An electrical conductor through which an electric current enters or leaves aconducting medium1.1.13 Electrolyte - A chemical compound which, when fused or dissolved in certain solvents, usually water, will conduct an electric current. 1.1.14 Internal Resistance - The resistance to the flow of an electric current within the cell or battery. 1.1.15 Open-Circuit Voltage - The difference in potential between the terminals of a cell when the circuit is open (i.e., a no-load condition). 1.1.16 Voltage, cutoff - Voltage at the end of useful discharge. (See Voltage, end-point.) L117 Voltage, end-point - Cell voltage below which the connected equipment will not operate or below which operation is not recommended. 1.2 Principal of Operation of cell A battery is a device that converts chemical energy directly to electrical energy. It consists of a number of voltaic cells. Each voltaic cell consists of two half cells connected in series by a conductive electrolyte containing anions and cations, One half-cell includes electrolyte and the electrode to which anions (negatively charged ions) migrate, i.e., the anode or negative electrode. The other half-cell includes electrolyte and the electrode to which cations (positively charged ions) migrate, ite., the cathode or positive electrode. In the redox reaction that powers the battery, cations are reduced (electrons are added) at the cathode, while anions re oxidized (electro re removed) at the anode. The electrodes do not touch each other but are electrically connected by the electrolyte. Some cells usetwo half-cells with different electrolytes. A separator between half cells allows ions to flow, but prevents mixing of the electrolytes. Fig, 1.2 principle operation Each half cell has an electromotive force (or emf), determined by its ability to drive electric current from the interior to the exterior of the cell. The voltage developed across a cell’s terminals depends on the energy release of the chemical reactions of its electrodes and electrolyte. Alkaline and carbon-zine cells have different chemistries but approximately the same emf of 1.5 volts. Likewise NiCd and NiMH cells have different chemistries, but approximately the same emf of 1.2 volts. On the other hand the high electrochemical potential changes in the reactions of lithium compounds give lithium cells emf of 3 volts or more. 13 Types of batteries Batteries are classified into two broad categories. Primary batteries irreversibly (within limits of practicality) transform chemical energy to electrical energy. When the initial supply of reactants is exhausted, energy cannot be readily restored to the battery by electrical means. Secondary batteries can be recharged. That is, they can have their chemical reactions reversed by supplying electrical energy to the cell, restoring their original composition. Primary batteries: This can produce current immediately on assembly. Disposable batteries are intended to be used once and discarded. These are mostcommonly used in portable devices that have low current drain, are only used intermittently, or are used well away from an alternative power source, such as in alarm and communication circuits where other electric power is only intermittently available. Disposable primary cells cannot be reliably recharged, since the chemical reactions are not easily reversible and active materials may not return to their original forms. Battery manut urers recommend against attempting recharging primary cells. Common types of disposable batteries include zinc- carbon batteries and alkaline batteries. Secondary batteries: These batteries must be charged before use. They are usually assembled with active materials in the discharged state. Rechargeable batteries or secondary cells can be recharged by applying electric current, which reverses the chemical reactions that occur during its use. Devices to supply the appropriate current are called chargers or rechargers. Fig. 1.3a Primary cell Fig. 1.3b Secondary cell 1.4 Recent developments, Recent developments include batteries with embedded functionality such as USBCELL, with a built-in charger and USB connector within the AA format,enabling the battery to be charged by plugging into a USB port without a charger USB Cell is the brand of NiMH rechargeable battery produced by a company called Moixa Energy. The batteries include a USB connector to allow recharging using a powered USB port. The product range currently available is 1300 mAh. mited to a Fig. 1.4 USB cell 15 Life of battery Even if never taken out of the original package, disposable (or "primary") batteries can lose 8 to 20 percent of their original charge every year at a temperature of about 20°-30°C. [54] This is known as the "self-discharge" rate and is due to non-current-producing "side" chemical reactions, which occur within the cell even if no load is applied to it. The rate of the side reactions is reduced if the batteries are stored at low temperature, although some batteries can be damaged by freezing. High or low temperatures may reduce battery performance. This willaffect the initial voltage of the battery. For an AA alkaline battery this initial voltage is approximately normally distributed around 1.6 volts. Fig 5 Life cycle Rechargeable batteries self-discharge more rapidly than disposable alkaline batteries, specially nickel-based batteries a freshly charged NiCd loses 10% of its charge in the first 24 hours, and thereafter discharges at a rate of about 10% a month. Most nickel- based batteries are partially discharged when purchased, and must be charged before first ee 1.6 Hazards related to batteries 1.6.1 Explosion A battery explosion is caused by the misuse or malfunction of a battery, such as attempting to recharge a primary (non-rechargeable) battery, or short circuiting a battery. 1.6.2 Corrosion Many battery chemicals are corrosive, poisonous, or both. If leakage occurs, either spontaneously or through accident, the chemicals released may be dangerous1.6.3 Environmental pollution The widespread use of batteries has created many environmental concerns, such as toxic metal pollution. Battery manufacture consumes resources and often involves hazardous chemicals. Used batteries alsa contribute to electronic waste. Americans purchese nearly three billion batteries annually, and abaut 179,000 tons of those end up in landfills across the country. 1.64 Ingestion Small button/disk batteries can be swallowed by young children. While in the digestive tract the battery's electrical discharge can burn the tissues and can be serious enough to lead to death. Fig 1.6 Electronic waste 2. PAPER BATTERYEnergy has always been spotlighted. In the past few years a lot of inventions have been made in this particular field. The tiny nuclear batteries that can provide energy for 10 years, but they use radioactive elements and are quite expensive. Few years back some researchers from Stanford University started experiments concerning the ways in which a copier paper could be used as a battery source. After a long way of struggle they, recently, concluded that the idea was right. The batteries made from a plain copier paper could make for the future energy storage that is truly thin. ‘The anatomy of paper battery is based on the use of Carbon Nanotubes tiny cylinders to collect electric charge. The paper is dipped in lithium containing solution, The nanotubes will act as electrodes allowing storage device to conduct electricity. It’s astounding to know that all the components of a conventional battery are integrated in a single paper structure; hence the complete mechanism for a battery is minimized to a size of paper. One of the many reasons behind choosing the paper as a medium for battery is the well-designed structure of millions of interconnected fibers in it. These fibers can hold on carbon nanotubes easily. Also a paper has the capability to bent or curl. You can fold it in different shapes and forms plus it as light as feather. Output voltage is modest but it could be increased if we use a stack of papers. Hence the voltage issues can be easily controlled without difficulty. Usage of paper as a battery will ultimately lead to weight diminution of batteries many times as compared to traditional batteries. It is said that the paper battery also has the capability of releasing the energy quickly. That makes it best utilization for devices that needs burst of energy,mostly electric vehicles. Further, the medical uses are particularly attractive because they do not contain any toxic materials. se oe Utes 2s comm SEDER 2 Fig.2 Papper Battry A paper battery is a flexible, ultra-thin energy storage and production device formed by combining carbon nanotubes with a conventional sheet ofcellulosebased paper. A paper battery acts as both a highenergy battery and super capacitor, combining two discrete components that are separate in traditional electronics. Paper Battery= Paper (Cellulose) + Carbon Nanotubes Cellulose is a complex organic substance found in paper and pulp; not digestible by humans. A Carbon NanoTubes (CNT) is a very tiny cylinder formed from a single sheet of carbon atoms rolled into a tiny cylinder. These are stronger than steel and more conducting than the best semiconductors. They can be Single- walled or Multi-walled. Mayer-rod-coated on the paper substrate with an effective thickness of 10 _m. The wet PVDF functions as a glue to stick the double layer films on paper. The concentration of PVDF in N-methyl-2-pyrrolidone (NMP) was 10% by weight the double layer films were laminated on the paper while the PVDF/ NMP was still wet, During this process, a metal rod rolls over the films to remove air bubbles trapped between films and the paper separator. Afier laminating LTO/CNT on oneside of the paper, the same process was used to put LCO/CNT on the opposite side of the paper to complete the Li-ion battery fabrication. Figure Id,e shows the scheme and a final device of the Li-ion paper battery prior to encapsulation and cell testing. Althougha paper-like membrane has been used as the separator for other energy storage systems including supercapacitors, it is the first demonstration of the use of commercial paper in Li-ion batteries, 12 where paper is used as both separator and mechanical support. Fig2.1 Types of CNTs 3. CARBON NANOTUBES Carbon nanotubes (CNTs) are allotropes of carbon with a cylindrical nanostructure. Nanotubes have been constructed with length-to-diameter ratio of up to 132,000,000:1, significantly larger than any other material. These cylindrical carbon molecules have novel properties, making them potentially useful in many applications in nanotechnology, electronics, optics, and other fields of materials science, as well as potential uses in architectural fields. They may also have applications in the construction of body armor. They exhibit extraordinary strength and unique electrical properties, and are efficient thermal conductors.Their name is derived from their size, since the diameter of a nanotube is on the order of a few nanometers (approximately 1/50,000th of the width of a human hair), while they can be up to 18 centimeters in length (as of 2010). Nanotubes are categorized as single-walled nanotubes (SWNTs) and multi-walled nanotubes (MWNTS). In theory, metallic nanotubes can carry an electric current density of 4 x 109 A/cm2 which is more than 1,000 times greater than metals such as copper, where for copper interconnects current densi ies are limited by electro mig In paper batteries the nanotubes act as electrodes, allowing the storage devices to conduct electricity. The battery, which functions as both a lithium-ion battery and a super capacitor, can provide a long, steady power output comparable to a conventional battery, as well as super capacitor’s quick burst of high energy and while a conventional battery contains a number of separate components, the paper battery integrates all of the battery components in a single structure, making it more energy efficient. Carbon nanotubes have been implemented in Nano electromechnical systems, including mechanical memory elements(NRAM being developed by Nantero Inc.) Fig 3. Carbon nanotubes3.1 Properties of Carbon Nanotubes: * Ratio of Width: Length: 1:107 * High tensile Strength (Greater than Steel). + Low Mass density & High Packing Density. + Very Light and Very Flexible, * Very Good Electrical Conductivity (better than Silicon). * Low resistance (~33 ohm per sq. inch). + Output Open Circuit Voltage(O.C.V); 1.5-2.5 V (For a postage stamp sized) * The O.C.V. of Paper Batteries s directly proportional to CNT concentration, * Stacking the Paper and CNT layers multiplies the Output Voltage; Slicing the Paper and CNT layers divides the Output Voltage. * Thickness: typically about 0.5-0.7mm. + Nominal continuous current density: 0.1 mA/cm2/ active area, + Nominal capacity; 2.5 to 5 mAh/em2/ active area, * Shelf life (RT): 3 years, + Temperature operating range: -75°C to +150°C. + No heavy metals (does not contain Hg, Pb, Cd, etc.) * No safety events or over-heating in case of battery abuse or mechanical damage + No safety limitations for shipment, packaging storage and disposal. = thot CNT(nn) > Fig3.1 Variation of Resistance with Width of CNTResistivity ‘Temperature > Fig3.2. Variation of Resistivity with Temperature 4, FABRICATION OF PAPER BATTERY ‘The materials required for the preparation of paper battery are a. Copier paper b. Carbon nano ink c. Oven The steps involved in the preparation of the paper battery are as follows Step 1: The copier paper is taken. Step 2: carbon Nano ink which is black in color is taken. Carbon nano ink is a solution of nano rods, surface adhesive agent and ionic salt solutions. Carbon nano ink is spread on one side of the paper. Step 3: the paper is kept inside the oven at 150C temperature. This evaporates the water content on the paper. The paper and the nano rods get attached to each other. Step 4: place the multi meter on the sides of the paper and we can see voltage drop is generated.Fig 4. Fabrication process After drying the paper becomes flexible, light weight in nature. The paper is scratched and rolled to protect the nano rods on paper. Fig4.1 Paper BattryLTO/CNT Figure 4.2, (a) $ double layer thin films. The CNT film is doctor-bladed onto the § hematic of fabrication process for free-standing LCO/CNT or LTO/CNT substrate and dried. An LTO or LTO slurry is then doctor-blade-coated on top of CNT film and dried, The whole T or LCO/ CNT can substrate, substrate is immersed into DI water, and the double layer of LTO) bo the be easily peeled off due to the poor adhesion of (b) (Left) § in. _ § in, LTO/CNT double layer film coated on double layer film can be easily separated from the SS substrate in DI water; (right) the final S substrate; (middle) the free-standing filmafter drying. (c) Schematic of the lamination process: the freestanding film is laminated on paper with a rod and a thin layer of wet PVDF on paper. (d) Schematic of the final paper Li-ion battery device structure, with both LCO/CNT and LTO/CNT laminated on both sides of the paper substrate. The paper is used as both the separator and the substrate. (e) Picture of the Li-ion paper battery before encapsulation for measurement.5. WORKING OF PAPER BATTERY The battery produces electricity in the same way as the conventional lithium- ion batteries that power so many of today's gadgets, but all the components have been incorporated into a lightweight, flexible sheet of paper. The devices are formed by combining cellulose with an infusion of aligned carbon nanotubes. The carbon is what gives the batteries their black color. These tiny filaments act like the electrodes found in a traditional battery, conducting electricity when the paper comes into contact with an ionic liquid solution. Tonic liquids contain no water, which means that there is nothing to freeze or evaporate in extreme environmental conditions. As a result, paper batteries can function between =75 and 1500C. The paper is made conducting material by dipping in ink. The paper works as a conductive layer. Two sheets of paper kept facing inward act like parallel plates (high energy electrodes). It can store energy like a super capacitor and it can discharge bursts of energy because of large surface area of nano tubes. Paper battery Conventional battery Wire Electrolyte | Fig.5 working of a paper batteryChlorine ions flow from the positive electrode to the negative one, while electrons travel through the external circuit, providing current. The paper electrode stores charge while recharging in tens of seconds because ions flow through the thin electrode quickly. In contrast, lithium batteries take 20 minutes to recharge. ‘The sheets can be rolled, twisted, folded, or cut into numerous shapes with no loss of integrity or efficiency, or stacked like printer paper to boost total output. ‘The components are molecularly attached to each other: the carbon nanotube print is embedded in the paper, and the electrolyte is soaked into the paper batteries produce electrons through a chemical reaction between electrolyte and metal in the traditional battery, Chemical reaction in the paper battery is between electrolyte and carbon nanotubes. Hectrons collect on the negative terminal of the battery and flow along a connected wire to the positive terminal Electrons must flow from the negative to the positive terminal for the chemical reaction to continue. re oresesd FigS.1 Paper battryFigure 5.2 (a) Lighting a red LED with a Li-ion paper battery which is encapsulated with _10_m PDMS. (b) Flexible Li-ion paper batteries light an LED device. (c) Galvanostatic charging/discharging curves of a laminated LTO_LCO paper batteries, a structure as in Figure 1d, (d) Self-discharge behavior of a full cell after being charged to 2.6 V. The initial drop is due to the IR drop after turning off the charging current, Inset: cycling performance of LTO_LCO full cells. (c) Comparison of our paper Li: ion battery with a polymer paper battery. The green arrow indicates the target of the paper battery. (f) Schematic for stacked cells separated by 10_m plastic paper. An individual cell is made with laminated LTO/CNT and LCO/CNT on either side of a piece of Xerox paper. A small piece of Cu is connected on the LTO/CNTT side and Al on the LCO/CNT side6. ADVANTAGES © The flexible shape allows the paper battery to be used small or irregularly- shaped electronics: One of the unique features of the paper battery is that it can be bent to any such shape or design that the user might have in mind. The battery can easily squeeze into tight crevasses and can be cut multiple times without ruining the battery's life. For example if a battery is cut in half, each piece will function, however, each piece will only contain 1/2 the amount of original power. Conversely, placing two sheets of paper battery on top of one-another will double the power. © The paper battery may replace conventional batteries completely: By layering sheets of this paper, the battery's voltage and current can be increased that many times. Since the main components of the paper battery are carbon nanotubes and cellulose, the body structure of the battery is very thin, "paper-thin". Thus to maximize even more power, the sheets of battery paper can be stacked on top of one another to give off tremendous power. This can allow the battery to have a much higher amount of power for the same size of storage as a current battery and also be environmentally friendly at the same time. © Supply power to an implanted pacemaker in the human body by using the electrolytes in human blood: An improvement in the techniques used in the health field can be aided by the paper battery. Experiments have taken place showing that batteries can be energized by the electrolyte emitted from one’s own blood or body sweat, This can conserve the usage of battery acid and rely on an environmental friendly mechanism of fueling battery cells with the help from our bodies.e The paper battery can be molded to take the shape of large objects, like a car door: As stated earlier, the key characteristics that make the paper battery very appealing are that it can be transformed into any shape or size, it can be cut multiple times without damaging it, and it can be fueled through various ways besides the typical harmful battery acid that is used in the current day battery, 7. LIMITATIONS + Presently, the devices are only a few inches across and they have to be scaled up to sheets of newspaper size to make it commercially viable. * Carbon nanotubes are very expensive, and batteries with large enough power are unlikely to be cost effective. + Cutting of trees leading to destroying of the nature, 8. APPLICATIONS The paper-like quality of the battery combined with the structure of the nanotubes embedded within gives them their light weight and low cost, making them attractive for portable electronics, aircraft, automobiles, and toys (such as model aircraft), while their ability to use electrolytes in blood make them potentially useful for medical devices such as pacemakers. The medical uses are particularly attractive because they do not contain any toxic materials and can be biodegradable; a major drawback of chemical cells. However, Professor Sperling cautions that commercial applications may be a long way away, because nanotubes are still relatively expensive to fabricate. Currently they are making devices a few inches in size. In order to be commercially viable, they would like tobe able to make them newspaper size; a size which, taken all together, would be powerful enough to power a car. With the developing technologies and reducing cost of CNTs, the paper batteries will find applications in the following fields: 1. In Electronics: + in laptop batteries, mobile phones, handheld digital cameras: The weight of these devices can be significantly reduced by replacing the alkaline batteries with light- weight Paper Batteries, without compromising with the power requirement. Moreover, the electrical hazards related to recharging will be greatlyreduced. * in calculators, wrist watch and other low drain devices. + in wireless communication devices like speakers, mouse, keyboard Bluetooth headsets etc. + in Enhanced Printed Circuit Board(PCB) wherein both the sides of the PCB can be used: one for the circuit and the other side (containing the components )would contain a layer of customized Paper Battery. This would eliminate heavy step- down transformers and the need of separate power supply unit for most electronic circuits. 2. In Medical Sciences: + in Pacemakers for the heart + in Artificial tissues (using Carbon nanotubes)+ in Cosmetics, Drug-delivery systems + in Biosensors, such as Glucose meters, Sugar meters, etc. 3. In Automobiles and Aircrafts: + in Hybrid Car batteries + in Long Air Flights reducing Refueling * for Light weight guided missiles + for powering electronic devices in Satellite programs 9. CONCLUSION One of the major problems bugging the world now is Energy crisis. Every nation needs energy and everyone needs power. And this problem which disturbs the developed countries perturbs the developing countries like India to a much greater extent. Standing at a point in the present where there can’t be a day without power, Paper Batteries can provide an altogether path-breaking solution to the same. Being Biodegradable, Light-weight and Nontoxic, flexible paper batteries have potential adaptability to power the next generation of electronics, medical devices and hybrid vehicles, allowing for radical new designs and medical technologies. But India still has got a long way to go if it has to be self-dependant for its energy solution. Literature reflects that Indian researchershave got the scientific astuteness needed for such revolutionary work. But what hinders their path is the lack of facilities and funding. Of course, the horizon of inquisitiveness is indefinitely vast and this paper is just a single step towards this direction We have discussed the various terminologies, principle of operation of a battery and recent developments related to it. The life of a battery is an important parameter which decides the area of application of the battery. Increased use of batteries gives rise to E-waste which poses great damage to our environment. In the year 2007 paper battery was manufactured. The technology is capable of replacing old bulky batteries. The paper batteries can further reduce the weight of the electronic gadgets. The adaptations to the paper battery technique in the future could allow for simply painting the nanotube ink and active materials onto surfaces ‘These surfaces can produce energy. REFERENCES ¢ Thin, Flexible Secondary Li-Ion Paper Batteries Liangbing Hu, Hui Wu, Fabio La Mantia, Yuan Yang, and Yi Cui Department of Materials Science and Engineering, Stanford University, Stanford, California 94305. * David Linden “Handbook of batteries”