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Order of Amines by Base Strength

This document contains a self-assessment test on amines from Chapter 13 with multiple choice, very short answer, short answer, and long answer questions. The test covers topics like reactions of amines, IUPAC naming of amines, relative basic strengths of amines, and preparation of amines from related compounds through various reaction mechanisms. It contains 20 marks worth of questions testing the understanding of amine chemistry concepts and reactions.

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Aniket Kahate
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67 views2 pages

Order of Amines by Base Strength

This document contains a self-assessment test on amines from Chapter 13 with multiple choice, very short answer, short answer, and long answer questions. The test covers topics like reactions of amines, IUPAC naming of amines, relative basic strengths of amines, and preparation of amines from related compounds through various reaction mechanisms. It contains 20 marks worth of questions testing the understanding of amine chemistry concepts and reactions.

Uploaded by

Aniket Kahate
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

SELF ASSESSMENT TEST

Chapter 13 : Amines

Time : 1 Hour ]  [ Marks : 20

Notes :
1. All questions are compulsory.
2. Figures to the right indicate full marks.

SECTION – A

Q. 1. Multiple Choice Questions : (1 mark each)

(i) Identify ‘B’ in the following reactions :

JA J B
Na / C2H5OH NaCO2 / dil. HCl
CH3 – CN

(a) CH3 – CH2 – NH2 (b) CH3 – CH2 – NO2


+
(c) CH3 – CH2 N2 Cl – (d) CH3 – CH2 – OH [1]

(ii) Which of the following compounds contains azo linkage?


(a) Hydrazine (b) p-Hydroxyazobenzene
(c) N-Nitrosodiethylamine (d) Ethylenediamine [1]

(iii) n-propyl alcohol is obtained when HNO2 is treated with


CH3 CH3
(a) CH3 – CH2 – NH (b) CH3 – N – CH3

(c) CH3 – CH2 – CH2 – NH2 (d) (C2H5)2NH [1]

(iv) Which of the following amines is most basic in nature?


(a) 2, 4 - Dichloroaniline (b) 2, 4 - Dimethylaniline
(c) 2, 4 - Dinitroaniline (d) 2, 4 - Dibromoaniline [1]

Q. 2. Very Short Answer Questions (VSA) : (1 mark each)


(i) Write the IUPAC name of benzyl amine. [1]
(ii) Arrange the following compounds in decreasing order of basic strength
in their aqueous solutions :

NH3, C2H5NH2, (CH3)2NH, (CH3)3N [1]

SELF ASSESSMENT TEST : LEARN SERIES CHEMISTRY XII (PART – 2) (CHAPTER 13) 1
SECTION – B

Q. 3. Short Answer Questions (SA-I) : (2 marks each)


(i) How is ethyl amine obtained from phthalimide? [2]
(ii) How will you convert the following?
(a) Phenyl acetonitrile to  -phenylethyl amine.

(b) Acetamide to ethylamine. [2]

SECTION – C

Q. 4. Short Answer Questions (SA-II) : (3 marks each)

(i) Explain Hofmann’s exhaustive alkylation. [3]




(ii) What is the action of acetyl chloride (ethanoyl chloride) on :

(1) ethylamine (ethanamine)


(2) diethylamine (N-Ethylethanamine)

(3) triethylamine? [3]

SECTION – D

Q. 5. Long Answer Question (LA) : (4 marks)

How will you prepare propan-1-amine from (1) butane nitrile (2) 1-nitropropane

(3) propanamide (4) butanamide? [4]

__________

For Model Answers – Click here - https://bit.ly/3x7sZZs

2 SELF ASSESSMENT TEST : LEARN SERIES CHEMISTRY XII (PART – 2) (CHAPTER 13)

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