h) DECARBOXYLATION REACTION:
CET 4 giao SOKBE Cy 4 nig, Cy t
i) COUPLING REACTION:
Gy + ron 8S Grn Grout
d en
CONC + G-NH, OST, CN iy NH,
aquebenrene
p) DIAZOTIZATION REACTION! wivecs hect
Nano, +Hcg ——? ToNestee
HH,
+Hono tHe 22% C+ 2H0
1) ETARD REACTION : , -otebx)eh,) Cuo
cS £tr8,0h [ ~eesconrey, | As
way? Hebel gsi g
w o Broun Complex, enealde
Q) FINKELSTEIN REATION :
CyHs- By +-Nar Acefone/a CyHy -T + NaBr
mm) FITTIG REACTION;
id fais UE te OD +4Nacl
nm) FRIEDAL CRAFT REACTION:
i) — 2 di) Aeylation coon,
G) + che ach 4? Oc Greco a +He)
Aphenone
0) GATTERMANN REACTION:
Ny, Cul HCH
cl iene a +N, rreage Subscribe GB Bare Ferre! ine
“mS
ah, ROAD MAP 4 04
Hy50y
et
Ho
503K
oNa
>.
2
ie
er
a
u as é ps Phensride
t
No, Q cine
oH a
Noe NO, Gy cooly Salicylic,
l - | as
NO, : 5
2G 6- Trinihe phenet oO G faceshen|
cPiede Add) Phevel ou
cuo
ey Salicyldebyale
org
Hs
O af
by
Wease Subscvibe GB shane Panchal- ghemitirr ma ez: a
*
y . %
ster vom mz,
G)
ene, p-con —“l> [Link] > R- COOH
TH
+Zn0
Genaene
Red, Alcohol Atolebyde Cove Acid. 2
Renn, ¢ Sp dted Beni
Arade
th
r——> Ree KOH, BocH,-0H 7
R-CHy Co}
Oxidabe
ce P-fO iy aan Rn120075 «fl Roo
wh Aldehyde Pp) GABRIEL PHTHALIMIDE SYNTHESIS:
Co,
err thot ee SNK + GHe-d =>
Prtnabienide Pets Prthatimide
cow ut Cook Ge MH,
Ceo" Hs ayo “> Leow *
N-Eby! phHrabimide Phthalic Aeiol
q) GATTERMANN KOCH REACTION :
@ +CO + HO Mey Gut, £2} ix, Renaldede
FY HNZ REACTION CHell Volhard Zelinsky Reachon)
chcoow +c, S$ coc, coow acl, 845 chcucoox
c- CoOW ch, fell
5) HOFMANN AMMONOLYSIS: 5, wniliea
HN+RK CONH, +By, + 4KOH Se NH, 2KGr+ CO, + 44,0
u) HUNSDIECKER REACTION :
R-COOAg + Br, oo R-By +CO, + Ag Br.
¥) KOLGE'S REACTION >
Ong
61+ Far? a ao a, Orem CSalieglic Acid)
w) Seen. TIEMANN REACTION : 0
pre T dren cont Ef eccon), > ~~)
cho BLHa,
errs oe € Salicgldehyde) #02. RESONANCE
Positive Resonance Negakve Resonance
Positive resonance effect (+R effect) Negative resonance effect (-A effect) in nitrobenzene
ee Bay? “Py BYP thy? Sag
o-o- -p-6-< §& o-d-d-8+ 6
TR eechavng pope ~COOH,~CHO€*° -CS,-NO;
& these are ovtho and para ly ‘these are rela - - dfrecting
diecking
Roap nar 404 CDiazonium SALT)
acy | Gattermann 2, ] \ Gatermann |
x°| date a,
@ | i. os:
7 Coutsling @x4 P fryl groups are Mort ACidte than alkyl groubs.
a ni =i) 0 ) Flechan Donating Grtupe
waeaerrrar | hy od, Meare +t effect hence
decrase acidic Shreng ita
acai ae a ee In evease Gasic Shengin
son xy? Slaten eartndrasing grou
Mewtase -I elect thence
Pnerease acidic shengén
Moaty acoraeng ‘Atay group} ryt. qrowp (ie)
Kao Acidic shengha and decree atic siregh
eKa ¢ | __. Ko basic Strength
Aerdic Shremg a_i
( tf asic Strengn
# Organic Reagants anp Rearions
Reductng Prgents a
wm Boil ¥ Yont of Caybo lic. Acial
Ci lic acids have high 8
than aldehyde, ketones and eyen of comparable molecular Fass
due do more exienstve association of theiy molecuks +hz04gh
thier muleculay H-Gonding. The H-Gonds Are viet broken Cample tely
even th dheiy Vapour Phare.
B® Qoil’ng Point and Solubility of Amines
("and 2° Qmineo have higher GM than othey argdnic
compound due to Hydsogen Bonding,
Potomy Oud secondo amines ave doluble
Tn water clue to H-Ganding oyu SNH, $4.0 molecule
# Acipie AND Basic CHARACTER
Baste Character of Amines , qa"
hing ave basic in nakere dug to the prtsente of
(one pair of €@ on nihogen alm
- Aliphak’c amines are stronger bases tran ammonia due to
4T effect of alkyl grup present [n Amines.
* Avomah'c amines qye weaker baseo than ammonia dye h
I effect of qry(, group: .
* Resiceo Inductive eect there ave efecs Line stsic
CHeck , Solvation effect resonanee effect usbafela
affect the boasic shrength of amines. .
- In gaseous phase, the order of basicity
2° abner > 2° amine > 1 amines >NK,
“TM aqueous phase, despike Q inductive eftect, solvation
eHect and Stic Mindrante alto playe an fra geahert
rule. Thus ; the ovde of basicity of amlneo to
Cotte), NH > (Gls), N > GHeNH, > ANH
BPS CDH > Fe NH few SNH AROMATIC CONVERSIONS
NO,
Sn,HY oO Nibobenseme soit
50% Subleste
Sy.
ROAD MAP #02 cu
a 2
Oe) pete (fe Cho Q an ©) Taluene
BiPhow! Ss thier w
Pheny | oy ger gor io wenzene wy |
O So le Ge 54
Phere A. Ot
on dua 8
epod 42 To sa \o
©) ae eae [oy een
aoe’ Nin'te cKeH cHe
Geni
