Class 11th JEE

(Weekend)

MRJM/11 Milestone Test-01 Phase-2

DATE: 17/07/2024

ANSWER KEY

PHYSICS CHEMISTRY MATHEMATICS

1. (3) 31. (1) 61. (2)
2. (1) 32. (3) 62. (4)
3. (1) 33. (3) 63. (3)
4. (3) 34. (1) 64. (4)
5. (4) 35. (2) 65. (4)
6. (4) 36. (3) 66. (2)
7. (3) 37. (1) 67. (2)
8. (3) 38. (4) 68. (3)
9. (4) 39. (3) 69. (1)
10. (3) 40. (1) 70. (2)
11. (2) 41. (3) 71. (2)
12. (2) 42. (1) 72. (1)
13. (1) 43. (2) 73. (4)
14. (1) 44. (4) 74. (1)
15. (1) 45. (4) 75. (1)
16. (4) 46. (4) 76. (3)
17. (4) 47. (2) 77. (2)
18. (2) 48. (1) 78. (3)
19. (1) 49. (3) 79. (4)
20. (2) 50. (1) 80. (1)
21. (5) 51. (12) 81. (4)
22. (4) 52. (56) 82. (60)
23. (3) 53. (8) 83. (4)
24. (4) 54. (9) 84. (8)
25. (5) 55. (9) 85. (1)
26. (2) 56. (80) 86. (16)
27. (140) 57. (4) 87. (1)
28. (25) 58. (100) 88. (8)
29. (4) 59. (6) 89. (5)
30. (56) 60. (18) 90. (4)
 SECTION-I (PHYSICS)
1. (3) 5
and S5 = 140 ⇒ (2a + 4d ) = 140 …(ii)
Given, p + q = 2 2
and p4 + q4 = 272 Solving eq. (i) and (ii), we get, a = 8, d = 10

( ) ∴ S20 – S6 = 14a + 175d = 1862

2
Now, p 2 + q 2 − 2 p2q2 =
272
2
⇒ ( p + q ) 2 − 2 pq  − 2 p 2 q 2 =
272 6. (4)
  Displacement of the body
Let pq = t ⇒ (4 – 2t)2 – 2t2 = 272 = 16 – 8 + 16 – 8 = 16m
2t2 –16t – 256 = 0 Distance travelled by the body
⇒ t2 – 8t – 128 = 0 = ∑ area = 48 m
⇒ (t –16)(t + 8) = 0
displacement 1
⇒ t = pq = 16 ⇒ =
Distance 3
Hence, the required equation is x2 – 2x +16 = 0

7. (3)
2. (1)
[ A − x]
(A- Q) [F ] =
dx [ B ][t ]
= slope ≥ 0 always increasing
dt
⇒ [ B]
=
[ L]
=  M −1T 1 
(B- S)  MLT −2  [T ]  
 
dx dx
< 0 ; and at t → ∞ → 0
dt dt
(C- R) 8. (3)
At the point A, the tangent to the curve is parallel to
dx dx
> 0 for first half < 0 for second half. time axis. So, velocity at A is zero. But
dt dt
acceleration is not zero. Note that the displacement
(D- P)
corresponding to the point A is not zero.
dx
= constant
dt
9. (4)
Let us suppose ball B travels (180 – 100) = 80 m in
3. (1)
t second. Then ball A travels the same distance in
ymax = 8 at x = 1
(t + 2)s.
According to the question, for ball A.
4. (3)
1
Given AB = x and BC = x 80= g × (t + 2)2
2
 AB + BC + CD = 3x
1
⇒ 80 = × 10 × (t + 2) 2
⇒ 2x + CD = 3x 2
∴ CD = x ⇒ t = 2 sec
Average speed For ball B
3x 3v1v2 v3 1
=<v> = 80= ut + gt 2
x x x v2 v3 + v1v3 + v1v2
+ + 2
v1 v2 v3 1
80 = u × 2 + × 10 × (2) 2
2
5. (4) 1
⇒ 80 = 2u + × 10 × 4
S10 = 530 ⇒ 5(2a + 9d) = 530 2
2a + 9d = 106 …(i) ⇒ 60 = 2u ⇒ u = 30 ms–1

[2]
10. (3) ⇒ [β] = L2T–2
Formula, Least count (LC) = 1 MSD – 1 VSD Substituting β in (1), we get
Given, 20 VSD = 19 MSD
( M 1L1T −2 )( L2T −2 )
Where, VSD = Vernier scale division [ ]
α =
MSD = Main scale division ( L2T −2 )2
LC = Least count ⇒ [α] = M 1L−1T 0
19
1 VSD = MSD
20 16. (4)
19
∴= LC 1 MSD − MSD =
y
x
+4
20 3
1
LC = MSD ( 1 MSD = 0.1 cm)
20 17. (4)
= 0.05 × 0.1 A. Torque ⇒ S : kg m2 s–2
LC = 0.005 cm
B. Energy density ⇒ P : kg m–1 s–2
C. Pressure gradient ⇒ R : kg m–2 s–2
11. (2)
If acceleration is variable (depends on time) then D. Impulse ⇒ Q : kg ms–1

at2
∫ ( f ) dt = u + ∫ ( a t ) dt = u +
v= u +      18. (2)
2
Units of a and PV2 are same and equal to
12. (2) dyne × cm4.
1 light year = 9.46 × 1015 m
1 parsec = 3.08 × 1016 m 19. (1)
π
l Au = 1.496 × 1011 m πt t 2 
Therefore, Au < ly < Parsec ∫  2 − 2 dt

0 
π
13. (1)  π  t 2  t3 
=   − 
 2 2  6 
   0
14. (1)
A = l × b = 3.124 × 3.002 π3 π3 π3
= − =
= 9.378248 m2 4 6 12
= 9.378 m2
(rounding off to four significant digits) 20. (2)
At maximum height, velocity is zero so,
15. (1)
0 u 2 − 2 gh or u = 2 gh
=
1 h 1
As =s ut + at 2 = so, 2 ght − gt 2
2 3 2
2h
gt 2 − 2 2 ght + = 0
3
[ F ] V 2 
⇒ [α ] = …(1)
2 2 gh ± 8 gh −
8 gh
β2 
  or t= 3

Also,
[ 2π][β] = 1 2g
V 2  8 gh
  2 2 gh − 8 gh −
t1 3 3− 2
[1][β] = 1 = =
⇒ t2 8 gh 3+ 2
2 2 gh + 8 gh −
L2T –2 3

[3]
21. (5) ∴ [ML2T–2]a [L]b [T]c = [M]
By comparing the given equation with standard Equating the powers we get,
equation a = 10, b = −25, and c = 5. a = 1, b = −2 and c = 2
−b c
α + β = ; αβ =
a a 27. (140)
1 1 α+β 25 Area between v-t graph and time axis
+= = = 5.
α β αβ 10 × 5 1 1
× 2 × 20 + 20 × 2 + 3 × 20 + 2 × × 1 × 20
10 2 2
= 20 + 40 + 60 + 20
22. (4) = 140 m.
v1 + v2 + v3 3 + 4 + 5
=
Average velocity = = 4 m/s
3 3 28. (25)
Distance between the balls = Distance travelled by
23. (3) first ball in 3 seconds – Distance travelled by second
We have ball in 2 seconds
y = 2x2 – 5x + 4 1 2 1
= g ( 3) − g ( 2 ) = 45 − 20 = 25 m
2
dy 2 2
⇒ = 4x − 5
dx
dy 29. (4)
At point (2, 2), we have = tan θ = 4(2) – 5
dx y = sin x
⇒ tan θ = 3 dy 1 1 1 1
= × × cos x × ×
dx 2 sin x 2 x
24. (4)
M M 1 cos x 1 cos x
 Density, =
ρ = = × × cos =
x ×
V πr 2 L 4 x sin x 4 x tan x
∆ρ ∆M ∆r ∆L
⇒ = +2 +
ρ M r L 30. (56)
0.003 0.005 0.06 Distance travelled by the particle is
= + 2× +
0.3 0.5 6 x =40 + 12t − t 3
= 0.01 + 0.02 + 0.01 = 0.04 We know that, speed is rate of change of distance
∴ Percentage error i.e.
∆ρ v=
dx
= × 100 = 0.04 × 100 = 4%
ρ dt

25. (5)
∴v =
d
dt
( )
40 + 12t − t 3 = 0 + 12 − 3t 2

a 1 But final velocity v = 0

S∞ = =
1− r  1 ∴12 − 3t 2 = 0
1−  − 
 4 12
⇒ t2 = = 4 ⇒ t = 2s
4 3
= . Hence, distance travelled by the particle before
5
coming to rest is given by
x = 40 + 12 ( 2 ) − ( 2 ) = 40 + 24 − 8 = 64 − 8 = 56 m
3
26. (2)
[E]a [L]b [T]c = [M]

[4]
 SECTION-II (CHEMISTRY)
31. (1) 37. (1)
−3
Number of atoms in O2 = 11.2 × 10 × 6.023 × 10 × 2
23
mmoles of conc. HCl = mmoles of dil. HCl;
1 22.4
10 × 10 = V ×
10 = 6.023 × 1020
∴ V = 1000 mL 0.014 × 2 × 6.023 × 1023
Number of atoms in CO =
Thus, 990 mL of water should be added to 10 mL 28
of conc. HCl to get decimolar solution. = 6.023 × 1020

32. (3) 38.

(4)
Symbols K L M N By Heisenberg’s uncertainty principle
h
19 X = 2 8 8 1 ∆x ⋅ m∆V =
4π
21 Y = 2 8 9 2
500 × 0.005
25 Z 2 8 13 2 = ∆V 0.005% of = 500 m/s = 0.025
100
Hence, the order of number of electrons in N shell
6.6 × 10−34
is ∆x × 9.1 × 10−31 × 0.025 =
4 × 3.14
Z=Y>X
6.6 × 10−34
Hence, ∆x =
33. (3) 4 × 3.14 × 0.025 × 9.1 × 10−31
2 ×1 = 2.31 × 10−3 m.
The mass of KI in 2g salt = = 0.02 g
100
39. (3)
0.02
= mol CaCO3 → CaO + CO2
39 + 127
2KOH + CO2 → K2CO3 + H2O
0.02
= × 6.02 × 1023 ions 2 mol 1 mol
166
2 mol 22.4 L
= 7.2 × 1919 ions per day
0.5 mol 5.6 L
∴ = 7 × 7.2 × 1019 ions per week. 1 mol KOH = 56 g
= 5.04 × 1020 ions per week.
∴ 0.5 mol KOH = 28 g KOH is required

34. (1)
40. (1)
As the energy of transition increases wave number
For n = 3, value of  are 0, 1, 2
increases.
i.e. 3s, 3p, 3d.

35. (2)
41. (3)
Since, the molecular formula is n times the
Mole = 4;
empirical formula, therefore, different compounds
Wt. of solvent = 1000 g;
having the same empirical formula must have
∴ Wt. of solution = 1000 + 4 × 40 = 1160 g
different molecular weights.
1160
∴ Volume of solution = mL
1.110
36.
(3)
4
The smallest amount of energy that an electron in ∴M= = 3.83
1160
H atom will emit
1.110 × 1000
= E3 − E2
−13.58  −13.58 
= −  42. (1)
9  4 
N ⋅ hc
E=
= 1.89 eV λ

[5]
43. (2) 49. (3)
x mol (NH4)3PO4 = 12x mol H atoms = 3.18 mol 28
g atom of N = =2
3.18 14
∴= x = 0.265 mol
12 80
g atom of oxygen = =5
Thus, N − atoms = 3x mol = 0.265 × 3 = 0.795 mol 16

44. (4) 50. (1)

According to Bohr’s model of hydrogen atom, the Rutherford gold foil experiment.
energy of electrons in the orbit is quantised, the
electron in the orbit nearest to nucleus has lowest 51. (12)
energy and electrons revolve in different orbits Six with C12 as C12O16O16, C12O16O17, C12O17O17
C12O18O18, C12O16O18, C12O17O18 and six with C13
around the nucleus. Whereas according to
Heisenberg’s uncertainty principle position and
52. (56)
velocity of the electrons in the orbit cannot be
In 100 tonnes of Fe2O3, pure Fe2O3
determined simultaneously.
100 × 20
= 100 − = 80 tonnes
100
45. (4)
Fe2O3 + 3H2 ⟶ 2Fe + 3H2O
3BaCl2 + 2Na 3 PO 4 → Ba 3 (PO 4 ) 2 + 6NaCl
∵ 160 g Fe2O3 gives Fe = 2 × 56 g
3 mol 2 mol 1 mol
2 × 56 × 80
2 mol 3 mol ? ∴ 80 tons Fe2O3 will give Fe =
160
3 mol BaCl2 react to form = 1 mol Ba3(PO4)2 = 56 tonnes
2 mol BaCl2 react to form = 0.66 mol of Ba3(PO4)2
3 mol Na3PO4 react to form = 1.5 mol Ba3(PO4)2 53. (8)
Thus, BaCl2 is the limiting reactant and Na3PO4 h h
=λA =
and λ B
left unreacted. mA vA mB vB
= (3 – 1.33) = 1.67 mol λ A mB vB
=
λ B mA vA
46. (4)
1 × 10−10 mA × vA
The four lobes of d x 2 − y2 orbital are lying along x =
λB mA × 2 × vA × 4
and y axes, while the two lobes of d z2 orbital are
λB =8Å
lying along z-axis, and contain a ring of negative
charge surrounding the nucleus in xy plane, 2s 54. (9)
orbitals has one spherical node, where electron W
×2 =0.074
density is zero. 244
p-orbital have direction character W = 9.028 g
Orbital ⟶ pz, px, py
Nodal plane ⟶ xy, yz, zx 55. (9)
r n = r 1 × n2
47. (2)
4.523 + 2.3 + 6.24 = 13.063. As 2.3 has least 56. (80)
number of decimal places i. e., one, therefore sum 2SO2 + O2 → 2SO3
should be reported to one decimal place only. 2 mol 1 mol 2 mol
If 10 mol SO2 is taken, O2 required is 5 mol,
After rounding off, reported sum=13.1 which has
forming 10 mol SO3
three significant figures.
But SO3 actual formed = 8 mol
Thus, percentage yield of SO3wrt SO2
48. (1)
8
A-Q; B-R; C-P; D-S = × 100 =
80%
10
[6]
 57. (4) 60. (18)
n2 – n1 = 6 – 2 = 4 In the given metal nitride, nitrogen present is 28%
that means, the nitride contains 28 g nitrogen and
58. (100)
72 g metal.
100 × 10−3
=
ppm ×=
106 100 72
1000 Moles of metal =
x
59. (6) 28
Moles of nitrogen = =2
We have 14
hc c  72
E = − hv0 =h  − v0  ⇒ Molar ratio, M : N = :2 = 4:2
λ λ  x
 3 × 108 ms −1  72
= (6.6 × 10−34 J s)  − 1.13 × 1017 s −1  =4
−9
 1.5 × 10 m
x

∴ x = 18
(6.6 × 10−34 J s)(0.87 × 1017 s −1 ) =
= 5.74 × 10−17 J

SECTION-III (MATHEMATICS)
61. (2) x 2 − 2 x − 16 < 0
We have,
⇒ 1 − 17 < x < 1 + 17
b cos 2θ + a sin 2θ
 1 − tan 2 θ  2a tan θ
= b + 65. (4)
 1 + tan θ  1 + tan θ
2 2
(Y × A ) =
{(1,1) , (1, 2 ) , ( 2,1) , ( 2, 2 ) ,

= b
(1 − a 2
/ b2 )
+
2a ( a / b )
=
b ( b 2 − a 2 ) + 2a 2 b
= b                 ( 3,1) , ( 3, 2 ) , ( 4,1) , ( 4, 2 ) , ( 5,1) , ( 5, 2 )}
(1 + a 2
/ b2 ) 1 + ( a 2 / b2 ) a 2 + b2
{(1, 3) , (1, 4 ) , (1, 5 ) , ( 2, 3) ,
And (Y × B ) =
  ( 2, 4 ) , ( 2, 5 ) , ( 3, 3) , ( 3, 4 ) , ( 3, 5 ) , ( 4, 3) ,
62. (4)
Since, power set is a set of all possible subsets of a ( 4, 4 ) , ( 4, 5) , ( 5, 3) , ( 5, 4 ) , ( 5, 5 )}
set. ∴ (Y × A ) ∩ (Y × B ) = φ
{φ,{ x} ,{ y} ,{ x, y}}
∴   P ( A ) =
66. (2)
63. (3) x 2 ( x 2 − 3 x + 2)
We have, ≥0
x 2 − x − 30
⇒ x ∈ (−∞, −5) ∪ [1, 2] ∪ (6, ∞) ∪ {0}
1
tan θ tan (120° − θ ) tan (120° + θ ) =
3
1
⇒ tan θ tan ( 60° + θ ) tan ( 60° − θ ) = 67. (2)
3 log2(18 – 14) = 2
 tan θ tan ( 60° − θ ) tan ( 60° +=θ ) tan 3 θ
68. (3)
1
⇒ tan 3 θ =
3
 A= {( a,b ) : a 2
+ 3b 2= 28, a, b ∈ Z }
π = {(5, 1), (–5, –-1), (5, –1), (–5, 1), (1, 3),
⇒ tan 3 θ = tan (–1, –3), (–1, 3),
6
π nπ π (1, –3), (4, 2), (–4, –2), (4, –2), (–4, 2)}
⇒ 3  θ= nπ + ,n∈Z ⇒ θ= + ,n∈Z and =B {( a, b ) : a > b, a,  
b∈ Z }
6 3 18
( −1, −5 ) , (1, −5 ) , ( −1, −3) , 
 
∴A ∩ B = 
64. (4) 
 (1, −3) , ( 4, 2 ) , ( 4, −2 ) 
x>0
Also ∴ Number of elements in A ∩ B is 6.
[7]
69. (1) 75. (1)
x +1 We have,
For x ≥ −3 , >0
x+2 = x sin130° + cos130°
⇒ x ∈ [−3, −2) ∪ (−1, ∞) = sin (180° − 50° ) + cos ( 90° + 40° )
For x < –3 ⇒
= x sin 50° − sin 40° > 0     [ sin 50° > sin 40°]
⇒ x ∈ (–5, –3)

70.
(2) 76. (3)
cot 54° tan 20°
+
tan 36° cot 70°
tan 36° tan 20°
= +
tan 36° tan 20°
=1+1 = 2

71. (2) 77. (2)

1 We have,
We have, sec θ = x + −5 ≤ 3sin θ − 4cos θ ≤ 5 for all θ
4x
Let sec θ + tan θ = λ …(i) ⇒ 2 ≤ 3sin θ − 4cos θ + 7 ≤ 12 for all θ
Then, 1 1 1
⇒ ≤ ≤ for all θ
sec 2 θ − tan 2 θ =1 12 3sin θ − 4cos θ + 7 2
⇒ ( sec θ − tan θ )( sec θ + tan θ ) =1
78. (3)
1
⇒ sec θ − tan θ = …(ii)
λ x 2 − 5 x + 6 > 0 ⇒ x ∈ (−∞, 2) ∪ (3, ∞)
Adding (i) and (ii), we get Case-I:
1 1 1 1 1
2sec θ ⇒ λ + ⇒ 2 x + = λ + ⇒ λ = 2 x, 2x > 1 ⇒ x >
λ 2x λ 2x 2
∴ x – 5x + 6 < 2x
2

72. (1)
⇒ x2 – 7x + 6 < 0
From Venn-Euler’s Diagram it is clear that
⇒ (x – 6) (x – 1) < 0
⇒ x ∈(1, 6)
⇒ x ∈(1, 2) ∪ (3, 6)
Case-II:
1
0 < 2x < 1 ⇒ 0 < x <
2
( A ∪ B)
'
∪ ( A′ ∩ B ) =
A' ∴ x – 5x + 6 > 2x
2

x2 – 7x + 6 > 0
(x – 6) (x – 1) > 0
73. (4)
( x − 5)( x − 4)( x − 3) < 0 ⇒ x < 1 or x > 6
⇒ x ∈ (−∞,3) ∪ (4,5)  1
⇒ x ∈  0, 
 2
74. (1)
sin A + sin B n + 1 79. (4)
=
sin A − sin B n − 1 2 x 1 −5
+ =
 A+ B  3 6 2
tan   n +1
 2 = 2 x −16
⇒ ⇒ =
 A − B  n −1 3 6
tan  
 2  ⇒ x = –4
[8]
80. (1) 85. (1)
1 1 cos1° + cos 2° + cos3° + ... + cos89° + cos90° +
(A) cos(3 × 20) × cos 60 = cos91° + cos92° + cos93° + ... + cos179° + cos180°
4 16
(B) If A+B =45°, (1 + tan A)(1 + tan B ) =
2 = cos1° + cos 2° + cos3° +
... + cos89° + 0 + cos (180° − 89° )
π π π π
(C) sin 2   + sin 2   + sin 2  − 
 18  9 2 9 + cos (180° − 88° ) + ... + cos (180° − 1° ) − 1
π π  = cos1° + cos 2° + cos3° + ...
+ sin 2  −  = 2 cos89° − cos89° − cos88° − ... − cos1° − 1
 2 18 
= −1
4sin(30° − 10°)
(D) =4
sin 20° 86. (16)
2 x log 4 3 + 3log 4 x =
27
81. (4)
2 ⋅ 3log 4 x + 3log 4 x =
27
 4  2log x 4log 2
log 6 54 + log 36   = −
 9  log 2 log x 3 ⋅ 3log 4 x =
27

 2  2(log x) 2 − 4(log 2) 2 3log 4 x =

9 ∴ log 4 x ==
2, x 16
⇒ log 6  54 ×  =
 3 (log x)(log 2)
87. (1)
⇒ [log x − 2(log 2)][log x + log 2] = 0
cos x + cos 2 x = ⇒
1   cos x= sin 2 x
1 Now, sin12 x + 3sin10 x + 3sin 8 x + sin 6 x
⇒ x = 4 and x =
2 =cos 6 x + 3cos5 x + 3cos 4 x + cos3 x
( cos x + cos x )
3
82. (60) = 2

Clearly, =1
Required percent = 20 + 50 − 10 = 60%
n ( A ∪ B=
) n ( A) + n ( B ) − n ( A ∩ B ) 88. (8)
A3 − 3 A =8−0 = 8
83. (4)
Required number of subsets is equal to the number 89. (5)
of subsets containing 2 and any number of elements {1, 3} × {2, 4} ⊆ A × B
from the remaining elements 1 and 4 ⇒ {(1, 2), (1, 4), (3, 2), (3, 4)} ⊆ {(1, 3), (1, 4),
So, required number of elements= 2= 2
4 (1, y), (2, 3), (2, 4), (2, y), (x, 3), (x, 4), (x, y)}
⇒ y = 2, x = 3
84. (8)
90. (4)
( x + 2)( x − 8)
<0
x ∈ ( −7, −3] ∪ ( 0, 4] (2 x + 5)
integral values of x are  −5 
⇒ x ∈  −∞,  ∪ (−2,8)
=−6, −5, −4, −3,1, 2,3, 4  2 
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