VELAMMAL NEW-GEN EDU NETWORK
MODEL – 2 EXAMINATION
DAY -1 _14.10.2024
WORKSHEET SOLUTIONS
MULTIPLE CHOICE QUESTIONS:
1. Mole fraction of glycerol in solution containing 36g of water and 46g of glycerine is
a. 0.46 b. 0.40 c. 0.20 d. 0.36
2. Which of the following condition is not satisfied by an ideal solution?
(a) ΔHmixing = 0 (b) ΔVmixing = 0
(c) Raoult’s Law is obeyed (d) Formation of an azeotropic mixture
3. Which has the lowest boiling point at 1 atm pressure?
(a) 0.1 M KCl(b) 0.1 M Urea(c) 0.1 M CaCl2(d) 0.1 M A1Cl3
4. People add sodium chloride to water while boiling eggs. This is to
(a) decrease the boiling point.(b) increase the boiling point.
(c) prevent the breaking of eggs.(d) make eggs tasty.
5. Which relationship is not correct?
6. When two perfect solutions with volume V each are combined, What is the volume of the solution as a result?
a) V b) 2V c) Greater than 2V d) Less than 2V
7. In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgSO 4 solution is
(a) the same (b) about twice (c) about three times (d) about six times
8. If a molecule AB undergoes dimerization in Benzene, its Van’t Hoff factor is found to be 0.60. The degree of
dissociation of AB is
(a) 20% (b) 60% (c) 80% (d) 50%
9. KH value for Ar(g), CO2 (g), HCHO (g) and CH4 (g) are 40.39, 1.67, 1.83×10–5 and 0.413 respectively.
Arrange these gases in the order of their increasing solubility.
(a) HCHO < CH4 < CO2 <Ar (b) HCHO < CO2 < CH4 <Ar
(c) Ar< CO2 < CH4 < HCHO (d) Ar< CH4 < CO2 < HCHO
10. Which of the following is dependent on temperature?
(a) Molality (b) Molarity (c) Mole Fraction (d) Mass percentage
11. Osmotic pressure of a solution is 0.0821 atm at a temperature of 300 K. The concentration in moles/lit will
be:
(a) 0.33 (b) 0.666 (c) 0.0033 (d) 3
12. How does the solubility of gasses vary with pressure?
(a) Increases with pressure (b) Decreases with pressure
(c) First increases and then decreases (d) No effect
13. If solute do not undergo neither association nor dissociation,itsVan’t Hoff factor (i) will be
(a)less than unity (b)greater than unity (c)unity (d)zero
14. Which of following is not a Colligative property?
(a)Relative lowering of vapour pressure b) Elevation in boiling point
(c)Osmotic pressure (d) Atmospheric pressure
15. Which among the following is least soluble in water?
(a) Phenol (b) Toluene (c) Ethylene glycol (d) Pentanol
II)ASSERTION REASON QUESTIONS: 5X1=5
1. Assertion : Molarity of a solution in liquid state changes with temperature.
Reason : The volume of a solution changes with change in temperature.
2. Assertion : If a liquid solute more volatile than the solvent is added to the solvent, the vapour
pressure of the solution may increase i.e., ps >po.
Reason : In the presence of a more volatile liquid solute, only the solute will form the vapours and
solvent will not.
3. Assertion : If one component of a solution obeys Raoult’s law over a certain range of composition,
the other component will not obey Henry’s law in that range.
Reason : Raoult’s law is a special case of Henry’s law.
4. Assertion : Azeotropic mixtures are formed only by non-ideal solutions and they may have boiling
points either greater than both the components or less than both the components.
Reason : The composition of the vapour phase is same as that of the liquid phase of an azeotropic
mixture.
5. Assertion : When NaCl is added to water a depression in freezing point is observed.
Reason : The lowering of vapour pressure of a solution causes depression in the freezing point.
III)SHORT ANSWERS: (EACH QUESTION CARRIES 2M) 5X2=10
6. Differentiate between molality and molarity of a solution. What is the effect of change in
temperature of a solution on its molality and molarity?
7. A 1.00 molal aqueous solution of trichloroacetic acid (CCl3COOH) is heated to its boiling point.
The solution has the boiling point of 100.18°C. Determine the van’t Hoff factor for trichloroacetic
acid. (Kb for water = 0.512 K kg mol-1)
8. Non-ideal solutions exhibit either positive or negative deviations from Raoult’s law. What are these
deviations and why are they caused? Explain with one example for each type.
9. 18 g of glucose, C6H12O6 (Molar mass – 180 g mol-1) is dissolved in 1 kg of water in a sauce pan. At
what temperature will this solution boil? (Kb for water = 0.52 K kg mol-1, boiling point of pure
water = 373.15 K)
10. Calculate the mass of compound (molar mass = 256 g mol-1) to be dissolved in 75 g of benzene to
lower its freezing point by 0.48 K (Kf = 5.12 K kg mol-1).
ANSWERS:
1 2 3 4 5 6 7 8 9 10
c d b b b b b c c b
11 12 13 14 15
c a c d b
AR TYPE
1. (a)2. (c)3. (b) 4. (b) 5. (a)
SHORT ANSWER (2M)
[Link] : It is the number of moles of solute dissolved in 1 litre of solution. It is temperature dependent.
M = ω×1000 [Link] ×V
Molality : It is the number of moles of solute dissolved in 1 kg of the solvent.
m = ω×1000M2×W
Molality is independent of temperature, whereas molarity is a function of temperature because volume
depends on temperature and mass does not.
7. Answer:
As ΔTb= iKbm
(100.18 – 100) °C = i × 0.512 K kg mol-1 × 1 m
∴ i = 0.3
0.18 K = i × 0.512 K kg mol-1 × 1 m
8. Answer:
Non-ideal solutions exhibit Negative deviation from Raoult’s law : For any composition of the non-
ideal solution, the partial vapour pressure of each component and total vapour pressure of the solution is
less than expected from Raoult’s law. Such solutions show negative deviation.
Example : Mixture of CHCl3 and acetone.
Non-ideal solutions show positive deviations from Raoult’s law on mixing of two volatile components of
the solution.
Example : Mixture of acetone and benzene solutions show positive deviation,
9. Answer:
We know that :
Elevation of boiling point ∆Tb
WBMB×100×Kbwt. of solvent
Given: WB = 18 g
MB = Formula of glucose is C6H12O6
= 6 × 12 + 12 + 6 × 16 = 180
Wt. of solvent = 1 kg or 1000 g,
Kb = 0.52 K kg mol-1
∴B.P of the solution = 373.15 + 0.052
Hence, ∆Tb = 18g180×1000×0.521000g = 0.52 K
= 373.202 K
10. Answer:
Given : ∆Tf = 0.48 K, W1 = 75g,
M2 = 256 g mol-1 W2 =?
Using formula, W2 = M2×W1×ΔTf1000×Kf
= 256×75×0.481000×5.12 = 1.8 g
