JEE Advanced Physics Chemistry Math Syllabus
JEE Advanced Physics Chemistry Math Syllabus
06-12-20_SR.CO-SUPER CHAINA_Jee-Adv_PTA-14_SYLLABUS
PHYSICS: Fluid Statics and Surface tension: Pressure in a fluid; Pascal’s law;
Buoyancy; Surface energy and surface tension, capillary rise
CHEMISTRY: SURFACE CHEMISTRY LIQUID SOLUTIONS
Surface chemistry: Elementary concepts of adsorption (excluding
adsorption isotherms); Colloids: types, methods of preparation and
general properties; surfactants and micelles (only definitions and
examples).
EXCLUDING: emulsions and types, catalysis: homogenous and
heterogeneous, activity and selectivity of solid catalysts; enzyme
catalysis.
Liquid Solutions: Raoult’s law; Molecular weight determination from
lowering of vapour pressure, elevation of boiling point and depression of
freezing point
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Time: 3:00Hour’s IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N : 1 – 6) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 7 – 14) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 15-18) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
CHEMISTRY:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N :19 – 24) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N : 25 –32) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec – III(Q.N : 33-36) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
MATHEMATICS:
+Ve - Ve
Section Question Type No.of Qs Total marks
Marks Marks
Questions with Multiple Correct Choice
Sec – I(Q.N:37 – 42) +4 -2 6 24
(partial marking scheme) (+1,0)
Questions with Numerical Value Type
Sec – II(Q.N :43–50) +3 0 8 24
(e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30)
Questions with Comprehension Type
Sec –III(Q.N : 51-54) +3 -1 4 12
(2 Comprehensions – 2 +2 = 4Q)
Total 18 60
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PHYSICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are)
correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
1. A thin-walled hemispherical shell of mass ‘m’ and radius ‘R’ is pressed against a smooth
vertical wall, and through a small aperture at its top, is filled with a liquid (say, water) of
mass ‘M’ (see figure). If ‘F’ is (nearly) the minimal magnitude of the force that has to be
applied to the shell if liquid is not to escape from it and ‘ ’ (nearly) is the angular
position (P) at which ‘F’ is to be applied then choose correct options (Given M 3m )
A) F 4 mg B) F 2 mg C) 450 D) 370
2. A vertical glass capillary tube, open at both ends, contains some water. Which of the
following shapes may not be taken by the water in the tube?
A) B) C) D)
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3. A rectangular vessel of dimension l b h and mass ‘M’ contains a liquid density ‘ ’.
The vessel has an orifice at its bottom at a distance ‘c’ from the rear wall as shown in the
figure
A) The maximum volume of the water that can be stored when the vessel is accelerated
hcb
is
2
B) The maximum volume of the water that can be stored when the vessel is accelerated
hlb
is
2
hcb hg
C) Force ‘F’ that must be applied when maximum water stored is M
2 c
hcb lg
D) Force ‘F’ that must be applied when maximum water stored is M
2 c
A circular cylinder of radius ‘R’ and height ‘H’ is filled with water to a height H . It
2
4.
3
starts rotating about its axis with constantly increasing angular speed. Choose the correct
alternatives.
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5. A solid iron cube of volume 103 m3 is fastened to one end of a cord, the other end of
which is attached to a light plastic bucket containing water. The cord, which has
negligible mass, passes over a pulley, and the iron cube is suspended in the water, as
shown in the figure. It is found that the system is in equilibrium. (Given density of iron
is 7.8 times density of water.)
m H
D) For small oscillations time period of oscillation will be 2
T
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SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
7. A uniform cylinder made of a material of density ‘ 250 kg / m3 ’ is held at rest in a pool
so that its upper circular surface is in level with the water surface. Length of the cylinder
is l 20 cm and radius r 3.0 cm . When released, the cylinder jumps out of water moving
vertically. Find velocity (in m/s) with which the cylinder leaves the water surface.
Density of water is 0 1000 kg / m3 and acceleration due to gravity is g 10 m / s 2 . Neglect
all dissipative effects.
8. A closed tube of length ‘ l ’ completely filled with water has a small air bubble trapped in
it. When the tube is held at an angle ‘ 300 ’ with the vertical and rotated at a constant
angular velocity ‘ ’ about the vertical axis through its lower end, the bubble settles at
some intermediate position in the tube. The distance of the bubble from the lower end of
xg
the tube is . (Acceleration due to gravity is ‘g’) Find ‘x’?
2
9. A plastic sphere of radius ‘r’ floats almost fully submerged in a liquid as shown in the
figure. Density of the liquid is ‘ ’, acceleration of free fall is ‘g’. The force exerted by
the liquid on the lower half of the sphere excluding contribution of the atmospheric
pressure is n r 3 g . Find ‘n’?
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10. In a zero gravity region, a drop of a liquid of surface tension ‘ ’ assumes a cylindrical
shape of diameter ‘D’ between two parallel glass plates that are a distance ‘d’ apart. If
curved surface of the drop is at right angles to the plates as shown in the figure. Force
D
exerted by the drop on a plate is . Find ‘n’?
n
11. A soap bubble of radius ‘r’ is made in vacuum by blowing a diatomic gas in it. Surface
tension of the soap solution is ‘ ’ and density ‘ ’. The molar specific heat of the gas in
the bubble in terms of molar gas constant ‘R’ is nR . Find ‘n’?
12. When a glass plate is inserted vertically in water, water rises along the plate making its
surface close to the plate curved as shown in figure. The height h (in mm) to which
water rises along the plate is. Given (surface tension of water is 0.075 N / m , density of
water is 1000 kg / m3 and g = acceleration due to gravity 10 m / s 2 ,sin 0.2 ).
13. On heating water, bubbles being formed at the bottom of the vessel detach and rise. Take
the bubbles to be spheres of radius R and making a circular contact of radius r with the
bottom of the vessel. If r << R and the surface tension of water is T, value of r just
R2 2 g
before bubbles detach is (density of water is ) . Find ‘n’.
n T
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14. When a film of soap solution is created inside a loop formed by rectangular wire frame
and an inextensible light thread AB of length l, the thread assumes shape of a semicircle
and remains equilibrium. By pulling the midpoint of thread with a force F, the thread
can be given shape of two semicircles as shown in Figure. The surface tension of the
F
soap solution is given as . Here ‘n’ is an integer. Find ‘n’.
nl
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4 options
(A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 15 to 16:
When liquid medicine of density ‘ ’ is to be put in the eye, it is done with the help of a
dropper. As the bulb on the top of the dropper is pressed, a drop forms at the opening of
the dropper. We wish to estimate the size of the drop. We first assume that the drop
formed at the opening is spherical because that requires a minimum increase in its
surface energy. To determine the size, we calculate the net vertical force due to the
surface tension ‘T’ when the radius of the drop is ‘R’. When the force becomes smaller
than the weight of the drop. The drop gets detached from the dropper.
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15. If the radius of the opening of the dropper is ‘r’, the vertical force due to the surface
tension on the drop of radius ‘R’ (assuming r R ) is
A) 2 rT B) 2 RT C) 2 r 2T / R D) 2 R 2T / r
16. If r 5 104 m , 103 kgm3 , g 10ms 12 , T 0.11 Nm 1 , the radius of the drop when it
detaches from the dropper is approximately
17. Now level of the liquid starts decreasing slowly. When the level of liquid is at a height
‘ h1 ’ above the cylinder the blocks starts moving up. At what value of ‘ h1 ’ will the block
rise?
A) 4h / 9 B) 5h / 9 C) 5h / 3 D) Remains same
18. The block in the above question is maintained at the position by external means and the
level of liquid is lowered. The height ‘ h2 ’ when this external force reduces to zero is
4h 5h 2h
A) B) C) Remains same D)
9 9 3
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CHEMISTRY MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are)
correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
19. For a solution formed by mixing liquids L and M, the vapour pressure of L plotted
against the mole fraction of M in solution is shown in the following figure. Here xL and
xM represent mole fractions of L and M, respectively, in the solution. The correct
A) Attractive intermolecular interactions between L-L in pure liquid L and M-M in pure
liquid M are stronger than those between L-M when mixed in solution.
B) The point Z represent vapour pressure of pure liquid M and Raoult’s law is obeyed
when xL 0
C) The point Z represent vapour pressure of pure liquid L and Raoult’s law is obeyed
when xL 1
D) The point Z represent vapour pressure of pure liquid M and Raoult’s law is obeyed
from xL 0 to xL 1
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20. 0.015 moles of KCN is dissolved in 100 g of pure H 2O . To this solution 0.005 moles of
solid CuCN is added, which is completely dissolved. Pick out correct statement(s)
K b for H 2O 0.52 k .kg mol 1
21. The vapour pressure of two pure liquids A and B which forms an ideal solution are 300
torr and 800 torr respectively at temperature T. A liquid solution of A and B for which
mole fraction of A is 0.6 is contained in a cylinder closed by a piston on which pressure
can be varied. The solution is slowly vaporized at temperature T by decreasing the
applied pressure, staring with a pressure of about 1 atm
A) The pressure at which the first bubble of vapour is formed is 500 torr
B) The composition of the vapour in this first bubble is xA 0.36
C) The composition of the last liquid droplet is xA 0.8
D) The pressure when last droplet of liquid remains is 400 torr
22. For a dilute solution having molality ‘m’ for a given non-volatile, non-electrolyte solute
T
in a solvent of mol. wt. M, b.pt. Tb and heat of vaporization per mole H ; b is
m m0
equal to
A) Molal elevation constant of solvent
RTb2 M
B) ; where M in kg; vap H and R in SI Units.
vap H
RTb2 M
C) ; where M in kg; vap S and R in SI Units.
vap S
RTb2 M
D) ; where M in g; vap H and R in SI Units.
1000 vap H
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23. Which of the following statements is/are correct?
3
A) SO42 ion possesses greater flocculation value than Fe CN 6 ions, for ferric
hydroxide solution.
CH 3 CH 2 14 C O Na
B)
CH 3 CH 2 10 C O Na
A) True solution do not show Tyndall effect due to very small size of the solute
particles.
B) The diameter of the particles of the dispersed phase must not be much smaller than
D) The refractive index of the dispersed phase and dispersion medium must differ
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SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
25. Pure and dry air is passed through 1M MgCl2 , then weight of the solution decreased by
xg. Now the air coming from the MgCl2 solution is passed through 2.6 M urea solution.
Then no change in the weight of urea solution. Find out the percentage of dissociation of
MgCl2 .
26. For the mixture of ethyl alcohol and water at room temperature, among the following
how many are correct?
(a) Gsys is positive (b) S sys is negative (c) S sur is negative
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30. The flocculation value of HCl for arsenic sulphide sol. is 30 m mol L1 . If H 2 SO4 is used
for the flocculation of 250 ml arsenic sulphide, the amount (in milli grams) of H 2 SO4
required for the above purpose is (molecular mass of H 2 SO4 98 g / mol )
31. Calculate the number of sols which are negatively charged.
32. If unit mass of solid, taken as cube of volume 8 cm3 , is powdered into identical 1012
cubes, then the specific surface area of the solid increased by 10 x times. Then ‘x’ value is
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4 options
(A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 33 to 34:
Properties such as boiling point, freezing point and vapour pressure of a pure solvent
change when solute molecule are added to get homogenous solution. These are called
colligative properties. Applications of colligative properties are very useful in day-to-
day life. One of its examples is the use of ethylene glycol and water mixture as anti-
freezing liquid in the radiator of automobiles. A solution M is prepared by mixing
ethanol and water. The mole fraction of ethanol in the mixture is 0.9. Give:
Freezing point depression constant of water K water
f 1.86 K kg mol 1
Freezing point depression constant of ethanol K ethanol
f 2.0 K kg mol 1
Boiling point elevation constant of water Kbwater 0.52 K kg mol 1
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Standard boiling point of water 373 K
Standard boiling point of ethanol 351.5 K
Vapour pressure of pure water 32.8 mm Hg
Vapour pressure of pure ethanol 40 mm Hg
Molecular weight of water 18 g mol 1
Molecular weight of ethanol 46 g mol 1
In answering the following questions, consider the solution to be ideal dilute solutions
and solutes to be non-volatile and non-dissociative
33. The vapour pressure of the solution ‘M’ is
34. Water is added to the solution ‘M’ such that the mole fraction of water in the solution
becomes 0.9. The boiling point of this solution is
10 mole of liquid ‘A’ and 10 mole of liquid ‘B’ is mixed in a cylindrical vessel
containing a piston arrangement. Initially a pressure of 2 atm is maintained on the
solution. Now, the piston is raised slowly and isothermally. Assuming A and B to be
completely miscible and forming an ideal solution.
PA0 0.6 atm & PB0 0.9 atm
35. The pressure below which the evaporation of liquid solution will start is:
36. If ¼ of the total amount of liquid solution taken initially is converted to vapour, then
moles of A in the vapour will be: (Given: 2425 49.25 )
A) 2.125 B) 3.875 C) 4 D) 1
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MATHEMATICS MAX.MARKS: 60
SECTION- I
(Maximum Marks : 24)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is (are)
correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.
37. Three circles C3 , C2 , C1 of radius 3, 6, 9 respectively touch as shown in figure. A chord
AB to the circle C1 touch circles C2 and C3 at P and Q respectively, then
B
P
Q
A
C) k 2h 5
4
D) Area of quadrilateral O1 APB is Sq.units. If angle between PA and PB is 1200
3
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39. Let f x, y 0 be the equation of a circle such that f 0, y 0 has equal real roots and
f x, 0 0 has two distinct real roots. Let g x, y 0 be the locus of points ‘P’ from
where tangents to circle f x, y 0 make angle between them and
3
g x, y x 2 y 2 5 x 4 y C , C R . Which of the following is/are correct?
25
B) The area of triangle QAB is , with the above description
4
C) The area of region bounded by the circle f x, y 0 with x-axis in first quadrant is
25 24
3 tan 1
8 7
D) The area of region bounded by the circle f x, y 0 with x-axis in first quadrant is
25 24
3 2 tan 1
8 7
B) The slope of tangent to the curve g x, y 0 at the point where the line y 1 intersects
it in first quadrant is 1/3
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41. A tangent PT is drawn to the circle x 2 y 2 4 at the point P 3,1 . A straight line L,
B) Possible equation of L is x 3 y 1
C) Possible equation of L is x 3 y 1 0
D) Possible equation of L is x 3 y 1
A) Circles of radii 36 and 9 touch externally. The radius of the circle which touches the
two circles externally and also their common tangent is 4.
y
B) The largest value of such that the pair x, y satisfies the equation
x
x 3 y 3 6 is 2 2
2 2
SECTION - II
(Maximum Marks : 24)
This section contains EIGHT (08) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the second
decimal place; e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) designated to enter the answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +3 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.
43. Two circles of radius 8 are placed inside a semi circle of radius 25. The two circles are
each tangent to the diameter and to the semi circle. If the distance between the centres of
6
the two circles is ‘ ’, then is equal to
5
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44. In the figure AB is tangent at A to circle with centre ‘O’. Point ‘D’ is interior to circle
and DB intersects the circle at ‘C’. If BC DC 3, OD 2 and AB 6 , then find square of
the radius of the circle.
45. Triangles ABC are described on a given base BC and of a given vertical angle ‘ ’. The
locus of orthocenter of ABC is part of circle such that BC subtend angle K1 at its
circumference where as locus of incentre of ABC is part of circle such that BC subtends
K K
angle K 2 at its circumference. Calculate 1 2
2
46. There are two circles in a parallelogram one of them of radius 3, is inscribed in the
parallelogram, and the other touches two sides of the parallelogram and the first circle.
The distance between the points of tangents which lie on the same side of the
parallelogram is equal to 3. Let d1 , d 2 denote the lengths of the diagonals of
parallelogram, then the product d1 d 2 is equal to
47. Tangents drawn from P 1,8 to the circle x 2 y 2 6 x 4 y 11 0 touches the circle at the
points A and B, respectively. The radius of the circle which passes through the points of
a
circumcircle of the PAB orthogonally is equal to , where ‘a’ is prime, ‘b’ is an even
b
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48. Let S x, y : x 2 y 2 6 x 8 y 21 0
Let a min
x y 2 1 x y ; x, y S
1 2
2
3 y x 3
b min ; x, y S
x3
Calculate 3a 4b 7
3 a 4 b 28
49. Let A be the centre of circle x 2 y 2 2 x 4 y 20 0 suppose the tangents at the points
B 1, 7 and D 4, 2 on the circle meet at ‘C’. The area of the quadrilateral ABCD is N.
50. A ray of light incident at the point 2, 1 gets reflected from the tangent at 0, 1 to the
circle x 2 y 2 1 . The reflected ray touches the circle. The equation of the line along
ba
which the incident ray moves, is by 11 ax then
4
SECTION – III
(COMPREHENSIN TYPE)
This section contains 2Paragraphs. Based on each paragraph, there are 2 questions. Each question has 4 options
(A), (B), (C) and (D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Paragraph for Question Nos. 51 to 52:
Consider three circles:
S1 : x 2 y 2 2 x 3 0
S2 : x 2 y 2 1 0
S3 : x 2 y 2 2 y 3 0
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51. The radius of the circle which bisect the circumferences of the circles
S1 0; S 2 0; S3 0 is
A) 2 B) 2 2 C) 3 D) 10
52. If the circle S 0 is orthogonal to S1 0; S2 0 and S3 0 and has its centre at a, b and
of the circle for which the point ‘P’ is mid point, then
53. The point of intersection of the tangent at the ends points of the chord ‘L’
A) , B) , C) , D) ,
32 48 32 48 32 48 32 48
13 13 13 13 13 13 13 13
54. Number of non-negative integral value(s) of ‘ ’ for which the point Q and origin lie on
same side of line ‘L’ is
A) 3 B) 12 C) 13 D) Infinite
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