CALCIUM CHLORIDE : MALLINCKRODT INC.
,SCIENCE PRODUCTS DIVISION Page 1 of 7
First Aid Measures Fire Fighting Measures Manufacturer/Responsible Party
Personal Protection Physical-Chemical Properites Accidental Release Measures
Handling/Storage Chemical Ingredients HAZCOM Label
Product Identification
Product ID: CALCIUM CHLORIDE
MSDS Date: 01/01/1987 Tech Review: 06/12/1986
FSC: 6810 NIIN: 00-082-2644 LIIN: MSDS Number: 016702
Submitter: D DG
Status Cd: C
MFN: 01
Article: N
Kit Part: N
Manufacturer-Responsible Party
Company Name: MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION
Address:
Box:
City: N/P State: NK ZIP: 00000 Country: NK
Info Phone Num:
Emergency Phone Num: (314)982-5000
Resp. Party Other MSDS Num.:
Preparer's Name: N/P
Chemtrec Ind/Phone:
Proprietary Ind: N
Review Ind: Y
Published: Y
CAGE: 62910
Special Project Cd: N
Contractor Identification
Company Name: MALLINCKRODT SPECIALTY CHEMICALS CO
Address: 222 RED SCHOOL LANE
Box:
City: PHILLIPSBURG State: NJ ZIP: 08865 Country: US
Phone: 908-859-2151
Contract Num:
CAGE: 62910
Item Description Information
Item Name: CALCIUM CHLORIDE,ANHYDROUS,TECHNICAL
[Link] 8/14/2004
CALCIUM CHLORIDE : MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION Page 2 of 7
Item Manager: GSA
Specification Num: NK
Type/Grade/Class: NK
Unit of Issue: BG Quantitative Expression: 00000000080LB
UI Container Qty: 80 LB BAG
Type of Container: NK
CHEMICAL INGREDIENTS
Ingred Name: CALCIUM CYANIDE MIXTURE
CAS: Cd: X
RTECS #: EW0710000 Cd: M
= Wt: Cd:
= Vol: Cd:
> Wt: Cd:
>Vol: Cd:
< Wt: Cd:
<Vol: Cd:
% Low Wt: Cd:
% High Wt: Cd:
% Low Vol: Cd:
% High Vol: Cd:
% Text: >99
Environmental Wt:
Other REC Limits: N/P
OSHA PEL: 5 MG/M3 (CN) Cd: M
OSHA STEL: Cd:
ACGIH TLV: S, 5 MG/M3 (CN) Cd: M
ACGIH STEL: N/P Cd:
EPA Rpt Qty:
DOT Rpt Qty:
Ozone Depleting Chemical:
Hazards Identification
LD50 LC50 Mixture : N/P
Route of Entry Inds -
Inhalation: N/P
Skin: N/P
Ingestion: N/P
Carcinogenicity Inds -
NTP: N/P
IARC: N/P
OSHA: N/P
Health Hazards Acute and Chronic
N/P
Explanation of Carcinogenicity
N/P
Signs and Symptions of Overexposure
INH:DUST MAY IRRIT UPPR RESP TRACT;ING:MAY IRRIT MUC MEMB;SKIN:[Link]
BURN;EYES:BURNS/IRRIT.
Medical Cond Aggravated by Exposure
N/P
[Link] 8/14/2004
CALCIUM CHLORIDE : MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION Page 3 of 7
First Aid Measures
First Aid
INHAL:RMV TO FRESH [Link] MD FOR BREATHG DIFFICULTY;INGEST:IMMED INDUCE VOMIT
BY GIVING 2 GL OF WATER/[Link] BY MOUTH IF [Link] MD
IMMED;SKIN:WASH W/SOAP & [Link] MD IF IRRIT OCCURS;EYES:FLUSH W/H*2O FOR 15
[Link] MED AT TN IMMED.
Accidental Release Measures
Spill Release Procedures
CLEAN-UP PERSONS MAY REQUIRE PROTECTIVE CLOTHING & RESP PROTECTION FROM
[Link] SPILLED MATL BY SWEEPING,PICKING OR SCOOPING & TRANSFER TO A
CLOSED,WATER-PROOF NON-METAL CONTAINER SUITABLE FOR SHIPPING (MOIST/WET CACLL*2
MAY CRODE STEEL ).
Neutralizing Agent
N/P
Disposal Considerations
Waste Disposal Methods
COLLECTED WASTE MAY BE SHIPPED I/A/W DOT REGS TO A RCRA-APPROVED WASTE DISPOSAL
[Link] COMPLIANCE WITH LOCAL,STATE,& FEDERAL REGULATIONS.
Handling and Storage
Handling and Storage Precautions
KEEP IN TIGHTLY CLOSED CONTNRS IN COOL,DRY,VENTLTD [Link] AGAINST PHY
[Link] CACL*2/CONC SOLN MAY CORRODE [Link] NOT STORE IN METAL CONT.
Other Precautions
AVOID CONTACT W/EYES,SKIN & CLOTHING. WASH THOROUGHLYAFTER HANDLING. DO NOT
EXPOSE TO ATMOSPHERE BECAUSE CALCIUM CHLORIDE WILLABSORB WATER & FORM A
SOLUTION.
Fire Fighting Measures
Flash Point Method: N/P
Flash Point: Flash Point Text: NONE
Autoignition Temp: Autoignition Temp Text: N/A
Lower Limits: N/R
Upper Limits: N/R
Extinguishing Media
EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures
WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL CONTR.
Unusual Fire/Explosion Hazard
NOT CONSIDERED TO BE AN EXPLOSION HAZARD.
Personal Protection
[Link] 8/14/2004
CALCIUM CHLORIDE : MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION Page 4 of 7
Respiratory Protection
SUPPLIED AIR RESPIR/SCBA; ESCAPE: GAS MASK
Ventilation
LOCAL EXHAUST TO MAINTN BELOW TLV.
Protective Gloves
IMPERVIOUS
Eye Protection
GOGGLES/FACE SHIELD
Other Protective Equipment
FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE WASH STATION
Work Hygienic Practices
N/P
Supplemental Safety and Health
MSDS FM MFR DATED: 05 SEP 85, CONFORMS TO OSHA HAZ COMM STD; BOILING POINT: OVER
1600C(2912F); MELTING POINT: 772C(1422F)
Physical/Chemical Properties
HCC: N1
NRC/State Lic Num:
Net Prop Wt for Ammo:
Boiling Pt: B.P. Text: >1600C
Melt/Freeze Pt: M.P/F.P Text: N/A
Decomp Temp: Decomp Text: N/A
Vapor Pres: N/R Vapor Density: N/R
Volatile Org Content %:
Spec Gravity: 2.15
VOC Pounds/Gallon:
pH: N/P
VOC Grams/Liter:
Viscosity: N/P
Evaporation Rate & Reference: N/R
Solubility in Water: COMPLETE
Appearance and Odor: WHITE OR GRAY-WHITE GRANULES. ODORLESS.
Percent Volatiles by Volume: N/R
Corrosion Rate: N/P
Stability and Reactivity Data
Stability Indicator/Materials to Avoid: YES METALS,AL,YELLOW BRASS,BROMINETRIFLUORIDE,MIX
OF LIME/BORATE
Stability Condition to Avoid: WET/MOIST CONDITIONS.(CACL*2 ABSORBS H*2O & MAKES ACID
SOLN)
Hazardous Decomposition Products: CHLORINE/HCL GAS FUMES,&OXIDES OF CALCIUM WHEN
HEATED.
Hazardous Polymerization Indicator: NO
Conditions to Avoid Polymerization: NOT KNOWN
Toxicological Information
Toxicological Information: N/P
[Link] 8/14/2004
CALCIUM CHLORIDE : MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION Page 5 of 7
Ecological Information
Ecological: N/P
MSDS Transport Information
Transport Information: N/P
Regulatory Information
SARA Title III Information: N/P
Federal Regulatory Information: N/P
State Regulatory Information: N/P
Other Information
Other Information: N/P
HMIS Transportation Information
Responsible Party CAGE: 62910
Trans ID Num: 46818
Product ID: CALCIUM CHLORIDE
MSDS Prepared Date: 01/01/1987
Review Date: 06/12/1986
MFN: 1
Submitter: D DG
Status Cd: C
Article w/o MSDS : N
Tech Entry NOS Shipping Nm:
Radioactivity:
Form:
Net Explosive Weight:
Coast Guard Ammo Cd:
Magnetism: N/P
Net Unit Weight: 80 POUNDS
AF MMAC Cd:
DOD Exemption Num:
Limited Qty Ind:
Multiple Kit Num: 0
Kit Ind: N
Kit Part Ind: N
Review Ind: Y
Unit of Issue: BG
Container Qty: 80 LB BAG
Type of Container: NK
Additional Data:
Detail DOT Information
[Link] 8/14/2004
CALCIUM CHLORIDE : MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION Page 6 of 7
DOT PSN Cd: ZZZ
Symbols: N/R
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
DOT PSN Modifier:
Hazard Class: N/R
UN ID Num: N/R
DOT Packaging Group: N/R
Label: N/R
Special Provision: N/R
Packaging Exception: N/R
Non Bulk Pack: N/R
Bulk Pack: N/R
Max Qty Pass: N/R
Max Qty Cargo: N/R
Vessel Stow Req: N/R
Water/Ship/Other Req: N/R
Detail IMO Information
IMO PSN Cd: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
IMO PSN Modifier:
IMDG Page Num: N/R
UN Num: N/R
UN Hazard Class: N/R
IMO Packaging Group: N/R
Subsidiary Risk Label: N/R
EMS Num: N/R
Med First Aid Guide Num: N/R
Detail IATA Information
IATA PSN Cd: ZZZ
IATA UN ID Num: N/R
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
IATA PSN Modifier:
IATA UN Class: N/R
Subsidiary Risk Class: N/R
IATA Label: N/R
UN Packing Group: N/R
Packing Note Passenger: N/R
Max Qty Pass: N/R
Packaging Note Cargo: N/R
Max Qty Cargo: N/R
Exceptions: N/R
Detail AFI Information
AFI PSN Cd: ZZZ
AFI Symbols:
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
[Link] 8/14/2004
CALCIUM CHLORIDE : MALLINCKRODT INC.,SCIENCE PRODUCTS DIVISION Page 7 of 7
AFI PSN Modifier:
AFI Hazard Class: N/R
AFI UN ID Num: N/R
AFI Packing Group: N/R
AFI Label: N/R
Special Provisions: N/A
Back Pack Reference: N/A
HAZCOM Label
Product ID: CALCIUM CHLORIDE
CAGE: 62910
Assigned Ind: N
Company Name: MALLINCKRODT SPECIALTY CHEMICALS CO
Street: 222 RED SCHOOL LANE
PO Box:
City: PHILLIPSBURG State: NJ ZIP: 08865 Country: US
Health Emergency Phone: (314)982-5000
Label Required Ind: Y
Date of Label Review: 12/16/1998
Status Cd: C
Mfg Label Num:
Label Date: 12/16/1998
Year Procured: N/K
Origination Cd: G
Chronic Hazard Ind: N/P
Eye Protection Ind: N/P
Skin Protection Ind: N/P
Signal Word: N/P
Respiratory Protection Ind: N/P
Health Hazard:
Contact Hazard:
Fire Hazard:
Reactivity Hazard:
Hazard And Precautions INH:DUST MAY IRRIT UPPR RESP TRACT;ING:MAY IRRIT MUC
MEMB;SKIN:[Link] BURN;EYES:BURNS/IRRIT.
[Link] 8/14/2004
