Environmental engineering
Section (1)
1- Concentration of air pollutant
1 PPM = 1,000 microgram per meter cubed (mg/m 3)
At sea level (T=288K)& p=1 atm
2- concentration of air pollutant at higher altitudes
Where:
Ch= Concentration, in mass per unit volume at altitude h and specified temperature T.
h = altitude (height), in km
C= Air pollutant concentration, in mass per unit volume at sea level Atmospheric
pressure and specified temperature T.
3- partial pressure at any altitude Ph
Ph = partial pressure of any air pollutant at any altitude h
P = partial pressure of any air pollutant at sea level
4- Calculating Air index AQI values
(𝑷𝑴𝒐𝒃𝒔 $𝑷𝑴𝐦𝐢𝐧 )(𝑨𝑸𝑰𝒎𝒂𝒙 $𝑨𝑸𝑰𝒎𝒊𝒏 )
AQI = (𝑷𝑴𝒎𝒂𝒙 $ 𝑷𝑴𝒎𝒊𝒏 )
+ AQImin
PMobs = observed 24- h average concentration in mg/m3
PMmax = maximum concentration of AQI color category that contains PM obs
PM min = minimum concentration of AQI color category that contains PM obs
AQI max = maximum AQI value for color category that corresponds to PM obs
AQI min = minimum AQI value for color category that corresponds to PM obs
[R= 8.20X10−5 atm. m3/gmol.K]
Sheet – 1
1-Express the following gas concentration in part per million (ppm):
a- CO2 concretion = 9000 mg/m3 [ 9ppm]
b- NO2 con. = 6.4 g/l [
c- CO con. = 550 mg/l
d- SO2 con. =140 g/m3
2- Carbon dioxide concentration is 1200 ppm at sea level (1atm and 288k. Express this
concentration in mg/m3? Is that concentration good or bad to the respiratory system?
3- The concentration of carbon monoxide CO in air is 50 g/m3 at 1 atm and t=15 Co
a- Express this concentration in ppm.
b- What the partial pressure of CO in air at sea level
c- What the concentration of CO in air at height = 4000m
d- What pressure of air in this altitude
4-the concentration of nitrogen dioxide is 0.05ppm at altitude equal to 1.8 km. what
the initial concentration of NO2 at sea level?
5-The following table illustrate the AQI (air quality index) for the corresponding
PM2.5breaking point? Calculate the AQI value at the corresponding concentration:
a- 50 mg/m3
b- 100 mg/m3
c- 150mg/m3 which one of them is unhealthy?
AQI value PM2.5 concentration
50 16.5
100 42
150 70.5
200 110
250 140
300 170
SOLUTION
1-1 PPM = 1,000 microgram per meter cubed (mg/m 3)
a- For CO2 .=9000mg/m3 ----------- CO2 .IN PPM = 9000/1000= 9ppm
b- For NO2 = 6.5g/l ------------------NO2 in ppm = 6.4 *1000= 6400 ppm
c- For CO = 550 mg/l ------------------ CO in ppm = 550 ppm
d- For SO2 = 140 g/m3----------------SO2 in ppm = 140 ppm
2- for CO2 = 1200ppm = 1200*1000 mg/m3
3- FOR CO = 50 g/m3= 50 ppm --------------------------a
Using PV = nRT
Pco= nRT/V : n/V= 50/(12+16)= 1.78 gmol /m3
T= 15+273 = 288 k , R = 8.2*10^-5 atm m3 /gmol k
Pco= 1.78 * 8.2*10^-5 *288= 0.043 atm --------------------b
At height = 4000m= 4km
Using eq,
Ch = 1.78( ( 288-6.5 *4 )/288) ^ 5.2558 = 1.08 gmol/m3--------------C
FOR P OF AIR
Ph = 1 (( 288-6.5*4) /288)) ^ 5.2558 = 0.61 atm -------------------------d
4-for NO2 = 0.05ppm AT altitude equal to 1.8 km
0.05 = C (( 288 – 6.5 *1.8 )/288 ))^ 5.2558
C OF NO2 = 0.0621 ppm
5- For AQI
A- FOR PM con. = 50 -------------USING TABLE AND the eq .
AQI = 114
b- for PM = 100 mg/m3
AQI= 187
C-for PM =150 mg/m3
AQI= 266.6