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Q1. Choose the correct answer:
1. Which of the following is an example of a heterocyclic compound with one hetero atom?
a) Pyran b) Pyridazine c) Pyrimidine d) Pyrazine e) None of the above
a- Benzo[a]thiophene b-Isoquinoline c- Morpholine d-Benzothiazole e- Quinoline
2-Regarding nomenclature of heterocyclic compounds, the IUPAC name of the following structure is:
a-1H-Pyrrole b-2H-Pyrrole c-3H-Pyrrole d-4H-Pyrrole e-None of the above
3. Which statement below is incorrect?
a) all Five-membered heterocycles aromatic compound. b) Pyrrole is aromatic
c) Thiophene is aromatic d) Furan is aromatic e- None of the above
4. ammonia and 1,4-diketone are used for the synthesis …
a) Pyridine b) Furan c) Pyrrole d) Thiophene e- None of the above
5. Main precursor of Paal-Knoor Synthesis
a) Hexane 2,5,7-trione b) 1,4-dicarboxyl compounds c) 1,5-dicarbonyl compounds d) 1,4-dicarbonyl
compounds e- None of the above
6. Pyrrole has a relatively high boiling point as compared to furan and thiophene, this is due to the …………..
a) presence of intramolecular hydrogen bonding in furan and thiophene.
b) presence of intramolecular hydrogen bonding in pyrrole.
c) presence of intermolecular hydrogen bonding in furan and thiophene.
d) presence of intermolecular hydrogen bonding in pyrrole.
e) None of the above
7- Which of the following intermediates are the most stable?
a-I and II b-I, II and III c-I, III and IV d-II and V e- III and V
8- Regarding the electrophilic substitution, which heterocycle undergoes polymerization when exposed to protic
acids?
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a- Furan b-Pyrrole c-Quinoline d-Thiophene e-None of the above
10. Pyrrole is less basic than pyridine because:
a) Pyrrole is ''anti-aromatic'' b) Pyrrole is smaller than pyridine
c) Pyrrole behaves as a cyclic diene d) Pyrrole has its electron pair as part of an "aromatic sextet" e- All of the
above
11. Select the correct IUPAC name of the following structure
a) 4-Bromo-2-methyl-pyrimidine b) 4-Bromo-2-methyl-4,5-dihydro-pyrimidine
c) 6-Bromo-2-methyl-5,6-dihydro-pyrimidine d) 4-Bromo-2-methyl-4,5-dihydro-pyridine e- All of the above
12- Nomenclature of fused heterocyclic compounds. The correct name of the compound is:
a- Benzo[a]oxazole b-Benzo[b]oxazole c-Benzo[c]oxazole d-Benzo[d]oxazole e- Benzo[e]oxazole
13- Electrophilic substitution reaction of five-member ring with one hetero atom. Where does electrophilic
substitution mainly occur in thiophene?
a- at the C2 atom b- at the C2 atom and C3 atom c- at the C3 atom d- at the O atom e- All of the above
a) Furan b) Indole c) Quinoline d) Piperidine e) None of the above
14. which of the following compounds has name (pyrimidine)
15. Systemic name of the following compound is………
a) 5-methyl-1,4-oxathin b) 3-methyl-1,4-oxathin
c) 6-methyl-1,4-oxathin d) 2-methyl-1,4-oxathin e) None of the above
16. Which two categories can heterocyclic compounds be classified into based on their structural and electronic
arrangement?
a) Aliphatic and Aromatic b) Cyclic and Acyclic c) Saturated and Unsaturated d) None of these e)All of the
above
17- Regarding heterocyclic systems, the chemical formula for Pyridine is:
a-C5H6N b- C5OHs c-C5H5NH2 d-C5H5N e-Both a and c
18-Regarding heterocyclic systems, which element is present as heteroatom in pyrrole?
a- Sulphur b-Sulphur and nitrogen c-Oxygen d- Nitrogen e- All of the above
19-Regarding heterocyclic systems, the saturated furan is called:
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a- Pyrrolidine b- Pyrrole c- Tetrahydrofuran d-Piperidine e-Both a and c
