process Integration Vet sustainatie dec Q prt! of Notural resources © 7 2 ee en _protection= —— Afecharge, env gee oe of products ecole qice cetenteasion at SOUISS , Iintenfeasion of the Waste ae ony Wentification of probiers bot see the foot cause of proble™ and cesotve ‘ther. auction AS Sustatnantitty: ertve of process Industriess IRS Oy conserving Resources mass bolarce con be cf tajviauo! a opseies, bur eneiqy balance is of the whore systers e REHAY congenation Fou Materia) at He fullest , No osses. mass concenvosion UtiT2akFon of cach Milnientsing coaste . vayincnea sing Produckiuity ext You suppifed: emeriqry to obtain qcestein product , afte this TA must be Producssve Energy eftictene Obt- by Product Energy suppiied to the reatante BEnhondng protittabt Te outeome Mist be More than the Ynvectmene - Lay Presrentin Folletos potiution cactro! tS now-a-days a enojor obfective OF any Tnasstry SUSTAINABILITY 2 Brundtiond report 19B7, ACED (Loortd comisston eNviroomnental and development ) 21987 * * ea % = ys. Meeting the necds of Present wsttpout Sem promising she ability of futere generiotiens to meet their puDN Needs. ee ete Ah. cetetockitty ocemre when Soe meainteso or tinprove the 3 eeu potandfitons fer human “heath and environ- BURGER ra ictisrncot cxcecasoyp iad ean nolodian! corabiti Ses Anos suppocts Tt3 pilars of custertnabtUty — prorit social eqotcy Society n 2 \ , ‘ y X 2 we protesion /Envi Ron. Economy) Economical Jrovow, =Ment J— —- — = —- Sedery equity a — Environmenta) batence Yoo waste | discharges SS protection — Profit, AkOaYs Qo for eronomicad qoaie. IM a soct aeraneer economical y x : ali! Sid gros Mates and Indicators: Moses — quantiterive Colestosans Incifeatse <5 narrative desentp tion | Yen] very useful to onaliise 4he so. (scheme of evatuation) One dimerSonas mnoaithx— Ether one of the dimension CsJem) &<0) two dTmrensiened matrix socioceonomeal , Ene economic Apree Aimencionas matrix —s au the three I= economicad matrix Veh ENVironMentes Mater. Tortef ty BOD 2oD operating cost 7 coptial Tnueetment pax boc, pento Return oo Investment ET tr O, Gwe=4 [We Bre ogensuesing, game Product hous much! tgs of Cox is being ero ttee | eben acuanied} team ol e10i1- zs Measure of relative C02 effects oF emiscion of seyeyay GHG ‘ a Gay 2uscane prti?de Gq tere CODaby BOE Poa i ) ynereasing heenan ctutifzation wage demand of eneigy. pepietion of na: + 3) Per Ratural eresources - decrease In tocetl Fuss a) Hee ciate changes La twe- dimensional matrics Index edss of rose _ mass oF matertats, 7 products mace of procduicts poser tatensity Tnaex= massof fresh waren used — mass of proclucts macs of produers: Energ Ses Ren: caengy ee Index uses tn process piesaenezs — cpass ct products Environmemtatty and eeonomicarry impacting wRos}) = change 30 environmen Increments) rexurn on Sosket most (th Ten poek change in Net enegy vsage y Resource COmse’y 2) Reajcie / Revse 3) ranroeaa secon aA proses ty en OD yes zenprovernent B) city Incease Dyeasire) prod i Be cortro! , ASSUTONCE and eEnhoncement a)Process SOSY Beeeere pares ote Soi oadThemes te achieve the Sustainability objective :. Vy Reduction Ih maid Metered cost dD RedvctiOr fq captial investment B Redwetion ip enesiqy vec a \nerease In process Hextbl (tty S: Emphasts on Ppresess safety €- INcheaged attention to quotity > Bettie environmented ann /, rere Hove te Systemaricarty Jmerrossicatiy approach s-p p — Process \nteqrotfon: PI %S5 a holistic opproash to Process, ese retrofitting and operatic, Ahad emphasizes the vntty of the procede. on In sisting process we arte doteg some mouttieation to Toe Getty Bt product (moditicatfon of ear ae Os tn quread 4 existing Sestqn 1) TASE Tdentificaric, 2} Tarqebing Socs 8) Gemenokion oF Alter, “4 tives 2 4) Serection of Attexnas i ™ 4 mn 5) Anoty sis of selectey K Altexnatives Two ev lors Process Cree) J Synthesis ene Sean ta aes te Task identification ; whet fs the bottlenesk of the pr, 56 thet slows down the ovensit Proceas eee gue Proaset Ter ty this ‘is the 4asic. Acivites: 2- Target: Ser the target Ext SHO waste Meabongs, 2 Atten targeting Process synthesis comes into y VP olp ProteSS parametens ee .\ enOO the t/pland O/e “for anhieving this porarnetesis, for which we can age for triad and he error method “te ashteve abe neatest to the cestred product syrihPesie Abe Product by oprinntzing the process F= (ae aiven unknosn (1) (areas optimtze by trict Ac error Ubest it) Process “Analysts: In this the input and Patamettic condi Mons Are ENB, POW Yoo anaiize the prodwers obtained occ. +37 given conditional inpute! 3. MOCESS SYNTHESIS {> Process anauets Me ofr given ( ee Ce) parameters qe The ate Of Process Sypthesis fs to optimize togicol structure of chemicad process Speriticarty the squence of steps (reartion, distilakion, xtrankiao ,ekc) the chotee of chemfea) involved Viece aoa agents) and 4he source and destination of recycling streams c exe 4h. RHets avo ha process anaysis problem woe en fe plocess IPLts “Sth process ctruckore and Perarmsisrs csitle Se seex to y aexerspine the process ovspets Production of ocnylo nitetle catatys t Cec = SHS -t55.02 aoe C34gnN + 8H20 Elector Condensate NHS 5 On bo trom. waste ware Entratn mentwicaete do blotreatment —» bottle perk A) Renycle wastewater to aistitlatton column, it ts « POS. Solotion 5. B) Resycle to reece Scuubbest watery, Waste worter oer purification co “ Used to sormbber €) Rerycle to subsutute botled! feed water b) Renysle to Serubbet and BAH / bot tes: Waste wate dafstribotion -te aliffesient SITEAMS tO redsice the WC Ste ©) Segreqosion of Wasteumtey and feaycte OF 90 Segregated Streams ASUS SROnCe HOR INGGnPOTat on Separeantan, colomnn Ton, Separation p Ses SI airecien ep Mem optimal solotion Adsorption esomn to purify af gases, Incorporation ef Yeeuur Bump instead of Rotiox and sre hich solution ts the best Solutiong = Ge for Mott ond Indicators on, sic. Impark of each choice /ease oN Econdm: ) Sovitonment, Sock SSNS sot the Renchmosuc to “{t Fo More eseate the +a gee OVERBU MASS TARGETING |— Benehmasking Penfor mance through overall Mass, Targeting. — difeient process fequires diffeuent imitations ang Aanget setting dcpenaing om alt. factors MI Mintenizg aon of nos masarials, Maximization of yield of dest Indesimed tate process Bers eking: Mb tefers to the Went eation of that can be deteimined ahead of 90 without Gncesig indepth anatycty Detoited design concept te fon without conducking NEO Processes indepth Ghowistg ts for existing processes §ping forthe: moasticass sStoich‘iometryy based targets eS) ee SE Feed), ofp ‘Jer Physten) —_ Reatlor. Phyiegl ProsuSh Pobment © treatmenta Branton ae Separation a 9 reeasrore Ef Wecovenge Paw Sestonel , Select Sy Port Ti Re cle | By products - wagétes => eA* BB ——» cosy dn aekual teenaito b more te Re afferts the Yield. then Arent terns (b+%) ts cequtred alepeient and 4heoretical {fled ott) be Trestetfcal ufeld actuad vied care Prociick lessee SAthost podunk tasces > mass Hargett, d formed Reap OES. is of Bestred product obtained Aetuod desired procatch MASS of feactante ese eee Supplied AS compasied to the Aheoretics! stoichiomerrfc requirement SEM OR conte yal Ackucl, < Theoretical qteid coral SePP\ied ic Actus yield = antics ai arts of destred produrt amt. of ceactants supplied : ye yield = Actual ued Theoreticod yield gins of steichiometetc targets a) Theoretical stoichTomektic targets with full PCoduict recover b) Actual Stoichfomerrfc tergets usithoot product losses, co) a Thesretftcad ‘Glotchromentc| 0 rete. feedstock —= |cotesiatton | ———> |S! Jesevery of Stoichtomefrte assuming Target til Tar grad L__feayse J a Pettis peace recovery Ackics gtoich amet cS Sith ULc) Actual SteTehTometrte “tearqers wre yee ~ feedstock» Stofechiomebte | ee, AaeSunttns, foe. |] corestaston with prodts lodce = askuel yf Net —_ Stoichfometric economic gergettog The frst target ts canted ESS 0S oe porentiot Cege) af the Proce. Sree, S. and fs defined ag Nerd. Cis he Annucd pLcion tate of product px Setting orice Neeasteant Prodker a ~ >i fe of 6 t far “MAG! feed rate of reactant rx Porchase, Pig Of feackan, Nered, Nreariant Se the no. of Products 2 reaseants EGP O38 The process may be considered for S more deteticd onciysis ; haben vauies of EGP ore more destrabie EGP £02 The process Ts NSt EEOMOMTEALLY yfabie USA by EGP catevlation ue cannot estimose thot the “product fs vfalie op ae SE WE Joke ENO! How much productos WH AS!es got accdUNe for any detefled anarijsis. (. cheek With Matrix tratieaton) SGP Fs ene OF the posiametes; to have idea ahout the viebi\tty OF the rocess. Nextte, for ine pecking sales and reantants Cnise ) Neroctvet MisR = 1 Annuel production’ cate of Product px Setting Price of Pat Product Nrgoct te: Annuss teed Tate of reactant rx potchase rt 1 - Tt price of factant & MISR > 1 2 The Process May be canstdered Tor more deta highex MSR Vv eX aNe More clestroble | Process is not saanomtcatly, viable led Anauycts OSE EES|Pureatal 8 Anes process in te he aestyned fer conversion of Iso MM vatye of segs As ethanol. The seqant fe taken to be fy orem of Ceehis Pa) ANd fa converted to ethanol Coy Heol) theouqh the FoVvousty g SVewall fesimeptatiag feackfon . \wcose Sea de 5 2 CaotsOH + 2609) cateviate the chaxtmoum theore ehancl Cal sto’ . chiometrfa sarqgek for Cari\a 0g —> 6x12 +12 + 6xIE 72412496 180 CatsOH — su+e+16 46 amoleg 46%2 = AD SO SS Wa an f a4 dipole see 44%2 8S — ESS aon So q for Isom eg /yr 0-54 xIsofe ers mmeg |r + a Rete ie em pece ta. chorgs O=* she: axtual Yfetd can be obtained is ONS Eq emanot /xq gweccee!s | Beterentne abrust stotentsmetrre Aerqes for exhano! o.46 4 150 = SF 7 \n Sepaxoting exhanel from xh mixture, it Ts expested to less 5 7/- oF ethanal ustth the woste Wate stream. Whah iS the aerual Stofchf omebyfa serqer for exHonal when Siem losses ane _ areounded For 2 — as‘ cecaS S| iat i . ee. F } eee ice os Som . 108 ‘ sMASS INTEGRATION TARGETING Tass Integration targeting Ys a systematic Secale yy ganelamental UNdesistanding SF the gqisbal fow of Mma Process Gnd employs thts Sod sustandung | in icecti dorgets and optimterng the Qensiatfon and ng ‘oF Ahroughout the Frecess: We address the overall Mass ‘targerf for Sie sues jor protesy designs wth suffictent detotis) using BME SS ry. of Mass Imeqrarton The Fotlowstng cases wit! be presented 2 le HMA MYND Caste Aischatge a= Misionem fresh osage Be Maximize Product yferd Targeting fer mintmum waste discharge The Hesh usage LF) Pefers to the acount of targeted Speafes +, Streams entet¥ag the process (the waste stre. May have ENS s nn ete, Protea a5 0 ech Feedstouc or A MASial Oty sd SS the Gt) corresponds to the leod of the tar The terminal eeenss esiqnoted gg waste Streams or potat speries fa streams pollution gq Sted SSP Ceg Genesrotfon (G) refers to the bet amount of which Ts Produced through chemica) peaction Depletion Cb) Mayteke Place through chemical Feactions b Te on alse be attributed to jeans iat = a TAive emisctons fat QFE Hot explicit accounted for, ee aot she Targeted spect SH loge The net qenesatton (Net-g) of © targeted Specfes tg defin. ed 98 the difForence blo enerostion and depletion 4 Net_q = G-D Overall rmass balance for the targeted species emt APien mass i BM AM) ASS Ite falta Tae CSE ee) as Totes : ‘ ' Before mags iment} cee whole point Totes cami) Ned generation Termina) Nek Get! cas= 5 fscharqe of the Monen WHE ovjective Te to reauice the ferroinal ats a) Margered species, the two +a1™MS on Pater tan clk Saas ) eqhvare tobe feduiced