1.

Which compound is formed when phenol is heated with CCl₄ and

NaOH? (a) Salicylic acid (b) Benzoic acid (c) Phenolphthalein (d)
Salicylaldehyde.
2.Ascorbic acid is - (a) Vitamin (b) Protein (c) Enzyme (d)
Carbohydrate.
3.Which of the following bases is not present in DNA? (a) Thymine
(b) Uracil (c) Guanine (d) Cytosine.

4.Which is a non-reducing sugar? (a) Glucose (b) Sucrose (c) Ribose

(d) Maltose.
5.Complete hydrolysis of cellulose yields - (a) D-Fructose (b) D-
Ribose (c) D-Glucose (d) L-Glucose.
6.Which of the following is an epoxide? a)ethyl oxide b) ethylene glycol
c) ethylene oxide d) ether peroxide
7.Which of the following is rayon?a) cellulose acetate b) cellulose
nitrate c) methyl cellulose d) cellulose fibres
8.Which of the following is a polyester? a) Neoprene b) nylon 66 c)
polystyrene (d) Dacron
9.Which of the following is not consisting of amide linkage a)nylon
b)orlon c) silk d) protein
10.Which of the following is a thermosetting polymer - (a) PVC (b)
Polyethylene (c) Polystyrene (d) urea formal dehyde resin.
11.Which of the following is a polyamide - (a) Bakelite (b) Nylon 6,6
(c) Terylene (d) Rayon.
12.The industrially used name for polyacrylonitrile is - (a) Orlon
(b) PVC (c) Dacron (d) Bakelite.
13.Which of the following polymers contains an ester linkage - (a)
Nylon (b) Bakelite (c) Terylene (d) PVC
14.Which of the following solutions has the highest boiling
point? - (a) 1M NaOH (b) 1M NaCl (c) 1M NH₄NO₃ (d) 1M Na₂SO₄.
15.If the mole fraction of ethanol in an aqueous solution is X,
then the molality of that solution will be - (a) 6.32 mol.kg⁻¹ (b) 4.83
mol.kg⁻¹ (c) 3.82 mol.kg⁻¹ (d) 2.89 mol.kg⁻¹.
16.Identify the correct statement: (a) Relative lowering of vapor
pressure is not dependent on temperature (b) Osmotic pressure is
dependent on the nature of the solute (c) Elevation of boiling point is
 not dependent on the nature of the solvent (d) Depression of freezing
point is proportional to the molar concentration of the solute.
17.The correct order of boiling points of the given aqueous
solutions is - (a) 1m KNO₃ < 1m NaCl < 1m Sucrose> 1m CH₃COOH
(b) 1 m KNO₃ < 1m NaCl > 1m CH₃COOH > 1N Sucrose (c) All are
equal.
(d) 1m KNO₃=, 1m NaCl >1m CH₃OOH > 1m Sucrose.
18.Tyndall effect is exhibited by (a) Glucose solution (b) Starch
solution (c) Urea solution (d) NaCl solution.
19.An example of pumice stone is (a) Sol (b) Gel (c) Solid sol (d)
Foam.
20.The unit of ebullioscopic constant is (a) k.kg mol⁻¹ (b)
mol. kg. k⁻¹ (c) kg.mol⁻¹ k⁻¹ (Molality) (d) k. mol. kg⁻¹ or k (Molality)⁻¹.
21.The depression in freezing point of 0.01M MgCl₂ solution
compared to 0.01M glucose solution is (a) same (b) approximately
double (c) approximately triple (d) approximately six times.
22.For which of the following liquid pairs is ΔH_mix ≠ 0? (a)
Benzene/Toluene (b) CH₃COCH₃/CHCl₃ (c) CH₃COCH₃/CS₂ (d)
Ethanol/H₂O.
23.Which of the given compounds has the highest basic
strength? (a) NH₃ (b) PH₃ (c) AsH₃ (d) BiH₃.
24.Which of the following oxyacid contains P-P bond? (a) H₄P₂O₅
(b) H₄P₂O₆ (c) H₃PO₄ (d) None of these.
25.Which of the following is the correct order of boiling points of
hydrides?
(a) H₂O > H₂Te > H₂Se > H₂S (b) H₂S > H₂Se > H₂Te > H₂O (c) H₂O > H₂Te >
H₂Se > H₂S (d) H₂S > H₂O > H₂Te > H₂Se

26.The hybridization state of Group-16 elements in tetrahalides

is (a) Sp³ (b) Sp³d (c) Sp³d² (d) dSp².
27.Which halogen element has the most negative electron gain
enthalpy? (a) F (b) Cl (c) Br (d) I.
28.In ICl₂⁻ ion, the hybridization state of Iodine is (a) Sp²d (b)
Sp³d² (c) Sp³ (d) Sp².
29.The structure of XeO₃ is (a) Linear (b) Square planar (c)
Pyramidal (d) T-shaped.
 30.XeF₆ on hydrolysis in aqueous solution forms (a) XeO₃ (b) XeO₂
(c) XeOF₄ (d) XeOF₂.
31.Which of the following compounds has the highest reactivity
inSN2 reaction? (a) CH₃Cl (b) CH₃CH₂Cl (c) CH₃CHClCH₃ (d)
(CH₃)₃CCl.
32.Give the structural formula of the organic product formed in
the following reaction:
C₆H₅COOAg --Br₂, CCl₄ s reflux→E + CO₂ + AgBr The E is (a) C₆H₅Cl (b)
C₆H₅Br c)C₆H₅COBr d) C₆H6

33.In the presence of AlCl₃, chlorine and benzene react to form

chlorobenzene. Which of the following substances reacts with the
benzene ring? (a) Cl⁻ (b) Cl⁺ (c) AlCl₃ (d) [AlCl₄]⁻
34.CH₃-CH=CH₂ + HCl → A: In the given reaction, 'A' is - (a) Cl-
CH₂-CH=CH₂ (b) CH₃-CH₂-CH₂-Cl (c) CH₃-CH(Cl)-CH₃ (d) CH₃-CH₂-
CH(Cl)-CH₃
35.The correct IUPAC name of diethyl bromomethane is - (a) 1-
Bromo-2-ethylpropane (b) 1-Bromo-2-ethyl-2-methylethane (c) 3-
Bromopentane (d) 2-Methyl-1-bromobutane.
36.In the reaction of phenol with aqueous bromine at room
temperature, which of the following is formed? - (a) meta-
bromophenol (b) 2,6-dibromophenol (c) 2,4,6-tribromophenol (d) 3,5-
dibromophenol.
37.Which of the following compounds cannot be identified by the
iodoform test? - (a) CH₃CH₂OH (b) CH₃CH(OH)CH₃ (c) CH₃CH₂CH₂OH
(d) CH₃CHO
38.In the given multi-step reaction, the product formed will be -
CH₃-CH=CH₂--(i) HBr →A (ii) H₂O, NaOH →B(iii) PCC →C(iv)
CH₃MgBr/H₂O →D

(a) CH₃-CH₂-C-OCH3 (b) CH₃-C(OH)(CH₃)-CH₃ (c) CH₃-CH₂-CH₂-CH₂-OH (d)

CH₃-CH(OH)-CH₂-CH₃

39.Anisole reacts with HI to form - (a) C₆H₅I + C₆H₅OH (b) C₆H₅OH +

CH₃I (c) C₆H₅I + CH₃OH (d) C₆H₅OH + CH₃OH
40.Which alcohol reacts most rapidly with Lucas reagent? - (a)
CH₃-CH₂-CH₂-CH₂OH (b) CH₃-CH₂-CH(OH)-CH₃ (c) CH₃-CH(CH₃)-
CH₂OH (d) (CH₃)₃C-OH
41.Zwitterion is formed by - (a) Aniline (b) Acetanilide (c) Benzoic
acid d) sulphanilic acid
42.Which of the following reagents can distinguish between
glucose and fructose?
(a) Tollen's test (b) fehling test (c) seliwanoff test(d) molisch test
43.One molecule of glucose forms osazone with 'n' molecules of
phenylhydrazine. The value of 'n' is - (a) four (b) one (c) two (d)
three.

44. Which of the following bases is not found in DNA? (a) Thymine
(b) Quinoline (c)Adenine (d) Cytosine.

45.The correct structure of gly-ala dipeptide is –

46.Which of the following are biodegradable polymers? (a) PHBV

(b) Nylon-2,Nylon-6 (c) Nylon-6,6 (d) Both A and B.
47.Which of the following is a polyamide class polymer? (a)
Bakelite (b) Terylene(c) Teflon (d) Nylon.
48.Which of the following are addition polymers? - (a) Nylon (b)
Melamine-formaldehyde resin (c) Orlon (d) Polystyrene.
49.Which of the following are examples of synthetic rubber? - (a)
Polychloroprene, (b) Polyacrylonitrile (c) Buna-S (d) Cis-polyisoprene.
50.Which of the following is not affected by temperature?
(a) Molality (b) Molarity (c) Normality (d) Formality
51.18 grams of glucose are added to 178.2g of water. The vapor
pressure of this aqueous solution at 100°C will be-
(a) 748.6 mm Hg (b) 752.4 mm Hg (c) 760.6 mm Hg (d) 750.8 mm Hg
52. 6.2 grams of ethylene glycol are added to 200 grams of
water. The freezing point of this solution (k for water = 1.86
k.kg mol⁻¹) is-(a) 0.88°C (b) 0.78°C (c) 0.93°C (d) 0.99°C
53.20 grams of glucose are present in 1 liter of aqueous
solution. What is the osmotic pressure of this solution at 25°C?
(a) 3.298 atm (b) 1.212 atm (c) 4.20 atm (d) 2.718 atm
54.Which property of colloids does not depend on the number of
colloidal particles' charge?
(a) Coagulation (b) Electrophoresis (c) Electro-osmosis (d) Tyndall
effect.
55.The gold numbers of protective colloids A, B, C, D are 0.50,
0.01, 0.10, 0.005 respectively. The order of their protective
power is-
(a) D<A<C<B (b) C<B<D<A (c) A<C<B<D (d) B<D<A<C
56.(i) Statement: A mixture of acetone and aniline shows negative
deviation.(ii) Reason: The hydrogen bond between acetone-aniline
is stronger than between acetone-acetone and aniline-aniline.
(a) Both (i) and (ii) are correct and (ii) is the correct explanation of
(i) (b) Both (i) and (ii) are correct but (ii) is not the correct explanation
of (i) (c) (i) is correct but (ii) is wrong (d) (i) is wrong but (ii) is correct
57.Match the left column with the right column:
Column-I Column-II
(A) Dialysis (i) Cleansing action of soap (B) Peptization (ii)
coagulation
(C) Emulsification. (iii) Preparation of colloidal sol
(D) Delta formation (iv) Purification
The correct answer is: (a) (A)-(iv), (B)-(iii), (C)-(i), (D)-(ii) (b) (A)-(iv), (B)-
(iii), (C)-(ii), (D)-(i)
58.Which of the following statements is correct if the
concentration of each of the following solutions is 0.1 (M)?
(a) Osmotic pressure of NaCl and Na₂SO₄ solutions are equal (b)
Osmotic pressure of NaCl solution is greater than Na₂SO₄ (c) Osmotic
pressure of Na₂SO₄ solution is greater than NaCl (d) Osmotic pressure
of Na₂SO₄ solution is less than NaCl