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Maceral Concept
Coal is not homogeneous under the optical microscope and it can be seen to consist of a number of constituents. These are termed macerals (Stopes, 1935) and are distinguished on the basis of morphology, optical properties and some other properties such as polishing hardness Maceral recognition is dependent primarily upon the morphology and secondarily on the optical properties. Distinction of macerals under the microscope is made by considering the morphology, internal texture and polishing relief (polishing relief is assessed against adjacent components) and the optical properties, especially the reflectance. An analogy is commonly made for macerals with the relationship of minerals to rocks of inorganic origin. The analogy is not complete because whereas minerals have a distinct composition (or range), coal macerals range widely in their composition and physical properties even in coals of one level of rank and the properties of macerals vary systematically with rank It should also be noted that minerals are crystalline whereas macerals exhibit form anisotropy over most of the rank range and develop crystalline structures only at high rank or where heating to coke has occurred Studies on maceral concentrates show that each maceral has a range of composition at any given rank and that all of the macerals show systematic changes in properties with rank Many of the shapes and structures observed within macerals can be related to specific plant organs and plant genera and species
Maceral Concept
Thus, macerals are the coalified remains of various plant tissues or plant-derived substances existing at the time of peat formation However: variable and often severe alteration during the peatification and coalification processes It is not always possible to recognize the plant material from which many macerals were originally derived (ICCP, 1971). Clear distinction between the maceral groups can be made in most cases. However, transitions between maceral groups do occur The formation of macerals from plant remains during the early stages of peat accumulation depends on the type of plant community, climatic and ecological controls, and conditions of the depositional environment (Stach et al., 1982) These maceral groups are subdivided into a variety of macerals, submacerals, and maceral varieties on the basis of their reflectance, degree of destruction/preservation of original material, presence of cellular structure, gelification, and morphological features The relative proportions of the maceral groups determine coal type The vitrinite reflectance of a coal can be taken as a measure of its rank.
Introduction
These components which are called macerals are the basic and relatively homogenous organo-petrographic entities of coal, which by their chemical composition and physical characteristics determine properties and utilization of coal The classification is based either on similar origin (leptinite group) and/or on the difference in preservation (e.g. vitrinite and inertinite groups) Chemical and physical properties of the macerals such as elemental composition, moisture content, hardness, density and petrographic characteristics differ widely and are subjected to change in the course of diagenesis and coalification process Besides the parental material and the decomposition before & during the peat stage the degree of coalification is decisive factor for the microscopic appearance of macerals
Standard Analysis
Samples should be polished with some, but not excessive relief, and examined in oil of 1.518 refractive index, using a low glare optical system with objectives in the range of nominal magnification of 25 to 50x According to Stopes-Heerlen nomenclature system of macerals are based on the optical properties of organic constituents viewed under incident light Morphology and reflectance under incident light are the main properties in distinguishing macerals and maceral groups Incident light analysis was adopted in this system because only this method provide quantitative maceral analysis. The idea was adopted by ICCP in 1971 with some modification Each maceral group encompasses a set of macerals
Maceral associations at microscopic scale are also called as microlithotype Maceral-mineral associations at microlithotype scale are called as carbominerates
Introduction
Vitrinite group rich in oxygen, Leptinite rich in hydrogen Inertinite rich in carbon Liptinite contains almost twice much volatile matter as that of vitrinite inertinite contains half as much volatile matter as that of vitrinite With increasing rank, aromaticity increases in all of the maceral groups and this results in a convergence of many properties at higher rank At low rank, in reflected white light, liptinite appears dark, vitrinite appears as a mesostasis of medium grey appearance and the inertinite has a higher reflectance than the other maceral groups
Maceral Concept
NOTE: ICCP does not have a table in this form where vitrinite and huminite classifications are been combined. By using the maceral categories, the discrimination within the huminite group is retained without implying that vitrinite and huminite are different maceral groups. This form of terminology is more acceptable to oil exploration companies compared with the largely arbitrary division into vitrinite and huminite.
Type of Maceral-Vitrinite
Vitrinite macerals are derived from the cell wall material (woody tissue) of plants, which are chemically composed of the polymers, cellulose and lignin and tannins The vitrinite group is the most abundant group of macerals but not all, coals The maceral of this group are characterised by their grey to white colour & reflectance between that of liptinite & inertinite groups in the same coal seam, autofluorescence properties Most liptinite macerals of low to medium rank show much stronger autofluorescence than vitrinite However the reflectance is highly variable which is directly dependant on the rank of coal Maceral collinite is homogeneous in appearance When collinite occurs as particulate form (<10 micron in size) it is characterize as vitrodetrinite Telinite shows good preservation of cell structures where cell lumens are either filled with collinite, resinite or clay minerals Telinite is divided into two submaceral: telinite-1 and telinite-2 Telinite-1 shows well defined cell structures (cell lumen may be round or oval) Telinite-2 cell structure is highly compressed and cell lumen can be reduced to slit like feature Telocollinite is characterised by its homogeneous appearance. It is most dominating constituents of the bituminous coals and occur as layers & bands or various thickness and length It forms the groundmass for most of the macerals of inertinite and almost all the macerals of liptinite group
Type of Maceral-Vitrinite
When macerals of liptinite group occur in appreciable concentration in the telocollinite groundmass then the reflectance of the telocollinite becomes lower & colour become darker than the liptinite free telocollinite in the same coal Such telocollinite bands with darker appearance are called desmocollinite The gelocollinte is characterised as the structure less coalified mass of genuine humic gel which generally acquires the shape of the cavity in which it occur as filling material It is rare in bituminous coal and has the similar colour and reflectance as telocollinite of same coal Corpocollinite occur as oval or rounded homogeneous bodies either in isolation or as cell filling with colour and reflectance close to the telocollinite in the same coal Vitrinite 1994-classification: The maceral group is defined by level of reflectance, maceral subgroup by degree of destruction of the original plant matter and the maceral by morphology and or degree of gelification Telovitrinite: Where plant tissue becomes humified but retains a more or less intact cell structure, it is normally preserved as telovitrinite. Both woody and leaf tissues can be preserved as telovitrinite. Cell preservation ranges from the primary cell wall only to preservation of secondary cell walls The most outstanding feature of telovitrinite is that it always has a slightly higher reflectance than the matrix vitrinite in the same coal. It also tends to occur in large particles that are usually free of other macerals and pyrite. Telovitrinite particles commonly show brecciated corners, serrated edges, wedge-shaped fractures, and slitted structures. telovitrinite does not usually fluoresce with ultra-violet excitation.
Type of Maceral-Vitrinite
Macerals within the telovitrinite subgroup: The main variations within telovitrinite relate to the degree of gelification. Gelification can occur as a result of processes within the peat stage and is a normal response to physicochemical coalification. Telovitrinite is divided into: Textinite - Well preserved and intact cell walls and cell lumens that are largely open, burial 300 to 600 m maximum cover. Texto-ulminite - Intermediate in texture between textinite and ulminite, cell lumens are partly open but infillings of cells with gelified material and collapsed cell walls are much more common than for textinite. Useful term but no longer in use, persists down to about 1500 m of cover. Ulminite : - Telovitrinite having a structure that is substantially massive but the layers may show small voids that are typically related to original cell structures. Collotelinite - Layers and lenses that typically lack cellular structure when viewed in oil immersion but are derived from stems, roots bark and leaves that retain cell structures. Sedimentary cover has been greater than about 1500 m. Telinite of the ICCP 1971 classification is reproduced here with the same optical properties but the sub-maceral telocollinite of the older system has been renamed here as collotelinite
Coal Maceral-Vitrinite
Detrovitrinite: Degraded vitrinite precursors become mixed with other maceral pre-cursors to form a mesostasis of detrovitrinite with inclusions of the other macerals. Macerals within the detrovitrinite subgroup Attrinite - fragmental cell wall and cell contents with poor preservation and discrete boundaries between most of the constituent grains. Attrinite is the characteristic mode of occurrence for detrovitrinite in soft brown coals and its presence indicates burial depths of less than about 500 m. Densinite- intermediate in texture between attrinite and vitrodetrinite and collodetrinite, densinite has a granular texture but most of the grains are cemented to the adjacent grains and few voids are present. Densinite forms when the grains within attrinite become cemented by colloidal humic material but the sutures are still visible in most cases. Vitrodetrinite consists of small particles of vitrinite but the boundaries between particles become obscured with increasing rank. Collodetrinite - detrovitrinite having a structure that is substantially massive. It forms when the grains in densinite become so fused (gelified) that the boundaries can no longer be distinguished. This maceral is called collodetrinite which was designated ad desmocollinite in the earlier system The maceral collodetrinite usually contains inclusions of liptinite macerals. So this makes collodetrinite than the collotelinite in the same coal. The fluorescence of collodetrinite is always higher than that of the collotelinite in the same coal The colloidal (humic) infilling of vitrinite is collectively includes in the subgroup gelovitrinite The gelinite and corpogelinite were presented as submacerals gelocollinite and corpocollinite respectively in the earlier classification.
Coal Maceral-Vitrinite
Material referred to gelovitrinite is presumed to have passed through a structureless colloidal stage during the biochemical coalification It is seldom possible to demonstrate this for any given entity without special treatments such as etching the surface of the sample with a powerful oxidized agent In most coals, gelovitrinite is a minor component of the total vitrinite Macerals within the gelovitrinite subgroup Corpohuminite structureless bodies filling cell lumens. In some usages this term includes phlobaphinite. Corpogelinite structureless bodies derived from humic cell filling, may occur isolated from the source tissues or in situ. Gelinite- a maceral of secondary origin and can occur as cell filling or more rarely as discrete veins. Dark vitrinite is characterised by its significantly low reflectance and strong fluorescence as compared a to the normal vitrinite in the same coal May be due to the coating of bituminous substances over the vitrinite surface which are produced by the associated lipid constituents Pseudovitrinite is regarded as transitional phase between vitrinite and semifusinite. This is also called as semivitrinite. Shows reflectance value 0.2-0.3% higher than that of the associated normal vitrinite It may be structure less or may posses faint cell structures This type of vitrinite is very common in Tertiary and Lower Gondwana coals of India
Coal Maceral-Vitrinite
The uniform gray material is Vitrinite showing a well developed cell structure. This material is derived from coalified woody tissue. Carboniferous age (~320 MY) The uniform gray material is Vitrinite showing a well developed cell structure. The vertical slitted structures are a common feature in this type of vitrinite.
Uniform gray material showing a well developed cell structure in the right half of the frame is Telovitrinite. The gray material in the upper left is Detrovitrinite which acts as a matrix for dark stringers of Sporinite and bright particles of Inertinite.
The particle at the right is Telovitrinite showing no cell structure. The particle on the left is a good example of Detrovitrinite. The detrovitrinite acts a matrix holding dark particles of Liptinite macerals and bright particles of Inertinite macerals.
Coal Maceral-Vitrinite
The entire particle at the right is Telovitrinite , well preserved cell structure. All of the other particles are of Detrovitrinite. The detrovitrinite acts a matrix holding dark particles of liptinite macerals and bright particles of inertinite. The two gray round particles are Vitrodetrinite. The are the result of vitrinite particles being disbursed in sedimentary rocks.
The sample has been excited with ultra-violet light and the Resinite filling the cells The cells in this case are filled with much darker Resinite. fluoresces with a yellow . The Vitrinite does not appear to fluoresce
Structureless ovoid is excited withResinite. Thelight and the resinite common with The sample has been a typical of ultra-violet dark orange color is fluoresces althoughcolor. The vitrinite surrounding theto light gray innot appear to fluoresce. a yellow resinite also can range from black resinite does reflected white light.
Resinite particles to fluoresce in green, yellow and orange colors. The Resinite occurs in the coal as vein fillings and is therefore of secondary origin
The dark folded structure is Megaspore. It has a reflectance darker than vitrinite and displays bilateral. The much smaller dark bodies are Microspores
The sample has been excited with ultra-violet light and the Sporinite fluoresces with a yellow color.
The sample has been excited with ultra-violet light and the Microspores The small dark structures are typical megaspores. They are set in vitrinite fluoresce with a bright yellow color. matrix with brighter particles of inertinite.
The dark stringers running across the field are typical occurrences of Cutinite. Their linear aspect is a distinguishing feature.
In this case the sample has been excited with ultra-violet light. Note how the Cutinite fluoresces and how much easier it is to distinguish.
The bright reflectance and open cell structure characterize fusinite. It is the structure of pyrolyzed woody tissue.
The bright reflectance and open cell structure characterize fusinite. Note the delicate plant derived cell structures that are well preserved.
The two bright round bodies are Macrinite. They are characterized by the high reflectance of fusinite and a lack of cell structure. Similar materials with a reflectance equal to semifusinite are called semimacrinite.
The bright fine-grained material is Micrinite. Identified by its brightness and small grain size. The shape of the micrinite occurrence are similar to occurrences of cutinite suggesting a replacement process.
Bright fine-grained material is Micrinite. The shape of the micrinite is similar to occurrences of sporinite suggesting a replacement process.
Coal petrographers, using the ICCP System 1994 classification of coal organic components (ICCP, 1998, 2001; Skorov and others, 2005), usually identify the following macerals
Telovitrinite
Telohuminite
Telinite Collotelinite
o
Textinite
Ulminite
Detrovitrinite
Detrohuminite
Collodetrinite Vitrodetrinite
o
Attrinite/Densinite
Gelohuminite
Gelovitrinite
Corpohuminite Gelinite
Corpogelinite Gelinite
Liptinite
o o o o o o
Inertinite
o
Fusinite
o
o o o
Semifusinite
Inertodetrinite Funginite Macrinite Secretinite Micrinite
Liptodetrinite
o o
Inertodetrinite
Inertodetrinite
Fusinite
Fusinite
Fusinite
Fusinite
Sporinite
Semifusinite
Micrinite
Micrinite
Vitrinite
Cutinite
Vitrinite
Vitrinite
When viewed closely, most pieces of coal are composed of alternating bands of bright and dull material. 1. Pith, 2. Protoxylem, 3. Xylem I, 4. Phloem I, 5. Sclerenchyma (bast fibre), 6. Cortex, 7. Epidermis