GulfSea Cylcare DCA 5040H

Page: 1 Revision nr: 1 13/03/09 Supersedes: 14/08/08

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1. Identification of the product and the company

Trade name Use Company identification : GulfSea Cylcare DCA 5040H : Cylinder Oil for 2-Cycle marine diesel engines : Gulf Oil Marine Ltd. 25F, 3 Lockhart Road, Wan Chai, Hong Tel : (852) 3693 0568 Fax : (852) 3748 9960 www.gulf-marine.com Emergency phone nr Company : Tel : (852) 3693 0568 : As above

2. Information on ingredients
This product is considered to be hazardous and contains hazardous components. : Mixture of Mineral base stocks & performance additives Composition (preparation)
Substance name Zinc alkyl dithiophosphate Branched alkylphenol and Calcium branched alkylphenol Ethanediol

:
:

Value(s) 0.5 - 1 % 0.5 - 1 %

CAS nr 68649-42-3 74499-35-7

EINECS nr 272-028-3 -----

EC index ---------

CERTIFICATE Xi; R41 N; R51-53 Xn; R62 Xi; R38 N; R50-53 Xn; R22

0.1 - 0.2 %

107-21-1

203-473-3

603-027-00-1

3. Hazards identification
Main hazards Adverse human health effects Environmental hazards : Classified as a dangerous preparation according to Directive 1999/45/EC : None under normal conditions. : Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment.

4. First aid measures

Inhalation Skin contact Eye contact Ingestion Note to physician : Assure fresh air breathing. Obtain medical attention if breathing difficulty persists. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Seek medical attention if irritation develops. : Rinse immediately with plenty of water. Seek medical attention if irritation develops. : DO NOT INDUCE VOMITING. Seek medical attention immediately. : If there is any suspicion of aspiration into the lungs either directly or as a result of vomiting, obtain medical advice.

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5. Fire - fighting measures

Suitable extinguishers Extinguishers not to be used Surrounding fires Special exposure hazards Protection against fire : : : : : Water fog. Carbon dioxide. Dry chemical. Foam. Sand. Do not use a heavy water stream. Use water spray or fog for cooling exposed containers. None under normal conditions. Do not enter fire area without proper protective equipment, including respiratory protection.

6. Accidental release measures

Personal precautions Environmental precautions After spillage and/or leakage : Keep public away from danger area. Wear recommended personal protective equipment. Equip cleanup crew with proper protection. : Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. : Clean up any spills as soon as possible, using an absorbent material to collect it. Collect spills and put it into appropriated container. Use suitable disposal containers. Recover the cleaning water for disposal. Spill area may be slippery. : May require excavation of contaminated soil.

on soil

7. Handling and storage

General Precautions in handling and storage Storage Handling : No naked lights. No smoking. Keep away from sources of ignition. : Handle in accordance with good industrial hygiene and safety procedures. : Keep container closed when not in use. Keep only in the original container in a cool, well ventilated place. Keep at temperature not exceeding 45 C. : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work.

8. Exposure controls / personal protection

Personal protection Respiratory protection Hand protection Skin protection Eye protection Industrial hygiene

Occupational Exposure Limits

: No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation. : Use neoprene or rubber gloves. : No special clothing/skin protection equipment is recommended under normal conditions of use. : Safety glasses. : Provide local exhaust or general room ventilation to minimize dust and/or vapour concentrations. When using, do not eat, drink or smoke. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. : according to TWA (TLV) ACGIH : 3 mg/m for oil mist.

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9. Physical and chemical properties

Physical state Colour Odour Pour point [ C] Viscosity at 100C [mm/s] Specific gravity : : : : : : Oily liquid. Amber. Mild. -18 18.3 0.913

10. Stability and reactivity

Physico-chemical stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous reactions Hazardous Polymerization : : : : : : Stable. Open flame. Sparks. Overheating. Oxidizing agents. Strong acids, bases. Carbon dioxide. Carbon monoxide. Hydrogen sulfide. None under normal conditions. Will not occur.

11. Toxicological information

Acute toxicity Inhalation Dermal Ingestion Carcinogenicity Mutagenicity : Not expected to be toxic. : Practically non toxic at normal conditions of usage. May cause respiratory irritation following prolonged or repeated inhalation of excessive oil mist and vapours. : Not expected to be a primary skin irritant. Prolonged or repeated exposure may lead to dermatitis. : Practically non toxic if swallowed in small doses. Larger quantities may cause nausea & diarrhoea. : No data available. : Not expected to be a mutagenic hazard

12. Ecological information

Ecological effects information Bioaccumulative potential Mobility soil : Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment. : Not determined. : Ground water contamination may be caused through spillages

13. Disposal considerations

Disposal : Dispose in a safe manner in accordance with local/national regulations.

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14. Transport information

General information UN No. ADR/RID IMO-IMDG code ICAO/IATA : : : : : Not regulated. Not regulated Not regulated. Not regulated. Not regulated.

15. Regulatory information

Symbol(s) R Phrase(s) S Phrase(s) : None. : R52/53 : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : S29/35 : Do not empty into drains ; dispose of this material and its container in a safe way. S29/56 : Do not empty into drains, dispose of this material and its container to hazardous or special waste collection point. S59 : Refer to manufacturer/supplier for information on recovery/recycling. S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.

16. Other information

R-phrases listed in chapter 2 : R22 : Harmful if swallowed. R38 : Irritating to skin. R41 : Risk of serious damage to eyes. R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 : Possible risk of impaired fertility. : For specific or detailed technical data for this product, please contact your local sales representative.

Product information Note

The contents and format of this MSDS are in accordance with Regulation (EC) Np 1907/2006 of the European Parliament and of the Council. DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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