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Process parameters
27.1. Temperature: The temperature controls the microbial activity and, this, rate of the
composting process. The degradation rate usually increases strongly with temperature up
to about 70-80 oC as shown in Fig. 27.1. Above this temperature most microorganisms
will either be killed or form spores, which is a resting stage. This prevents further
increases in degradation rte and temperature of the compost. It is often important to
maintain a high temperature as long as possible to ensure rapid degradation and effective
use of the compost facility. High temperatures are also needed in many cases to achieve
proper hygienization of the compost material. Hygienization is often required if the
compost is to be used as a soil amendment on soils used on agricultural production.
Hygienization reduces the concentration of pathogenic organisms and weed seeds in the
compost. Adjusting the oxygen concentration (by mixing or blowing air through the
compost) and the water content (by irrigation) in the compost controls the microbial
activity and, thus, the temperature. If the oxygen concentration or water content is too
low the rate of degradation decreases and the temperature will fall even if there is plenty
of degradable organic material available. Watering the compost if too dry or increasing
the oxygen concentration if too low by turning or aeration will usually cause the
microbial activity and the temperature to go back up. In cold climate regions it can be
necessary to provide some type of insulation to maintain proper temperature. This may be
done by covering the composting material by a layer of finished compost, or by
processing the material in an enclosed space such as a building or directly in a reactor.
Fig 27.1. Relationship between temperature and oxygen consumption rate in
compost
27.2. Water content: The water content controls both the microbial activity and the
oxygen transportation in the compost material. At low water contents oxygen will be
transported faster and easier because a greater amount of the pores are filled with air. This
makes it easier to ensure a high oxygen concentration in the compost. Low water
contents, however, are inhibitory to microorganisms whose activity will cease at
gravimetric water contents below 8-12 %. The optimal water content also depends on the
structure of material being composted. Materials that are structurally strong can have
higher permissible gravimetric water contents (70-80% for wood chips, straw, hay, etc.)
because the structure of the materials ensure that there will be a sufficient amount of air-
filled pores. For less structured materials such as wastewater treatment sludge higher
water contents will result in low air filled porosity, poor air penetration and difficulty in
handling the materials, as they will become liquefied. Generally the optimal gravimetric
water content for most mixtures of organic wastes containing food residues is between 35
and 60% although practice have shown that water contents of 75% for sludge-straw-
garden waste compost air-filled porosity can be improved by adding a bulking agent such
as straw, wood chips or paper, or by increasing the airflow through the compost to
facilitate the evaporation of water. In wet climate it may be necessary to provide a roof
over the compost facility to prevent high water contents from developing, watering the
compost can cure low water contents. The water content can be adjusted by mixing the
waste with a material of different water content. Assuming that the waste has a water
content of a (g/g), the mixing material has a water content of b (g/g) and we want a
mixture of water content of c (g/g) we can calculate the amount of mixing material
required per kg of waste as:
kg of mixing material a–c
Mmix,water x =
kg of waste c–d
where Mmix,water is the amount of mixing material required per kg of waste to adjust the
water content. Note that c must be between a and b otherwise it is not possible to adjust
the water content.
27.3. pH: It is usually not necessary to control the pH of the compost if the composting
process is well operated such as to maintain adequate levels in temperature and oxygen
concentrations. In certain special types of organic material that is very easily degradable
anaerobic conditions can develop in the early stages of the process resulting in
overproduction of organic acids and a drop in pH. In such cases addition of lime amy be
necessary to maintain proper levels in pH. Such problems may be avoided altogether by
adding a bulking agent such as for example straw or wood chips that is more difficult to
degrade and will provide a higher air-filled porosity in the compost. At high values of pH
(>9), however, nitrogen losses may become significant due to the formation of ammonia
(NH3) that will evaporate. The degradation rate depends strongly upon the pH, low pH
levels are inhibitory to most aerobic microorganisms. Degradation experiments
conducted at 50 – 60 oC indicate that the degradation rate increases linearly with pH in
the interval 6 -9 (see Fig. 27.2.) Jerris and Regan 1973).
27.4. C/N ratio: The ratio of carbon (C) to nitrogen (N) of the material to be composted
is important with respect to the nutritional needs of the microbial biomass. If the C/N
ratio is too high, the lack of nitrogen will limit the microbial activity and thereby the
degradation and transformation of the carbon. On the other hand if the ratio is too low,
nitrogen will be in excess and may easily be lost in the form of ammonia (NH 3) to the
atmosphere or washed out as nitrate or ammonium ions (NO 3, NH4). The C/N ratio in
living bacterial biomass is approximately 5 and in fungi approximately 7. The optimal
C/N ratio in the compost is however, much higher because a significant amount of the
carbon will be mineralized to CO2 and another large amount is not biologically accessible
because it is bound in difficult-to-degrade organic compounds. The optimal C/N ration in
compost is on the order of 20 -30 (Diaz et al. 1993, Christensen et al. 1998). The C/N
ratio can easily be adjusted to a proper level by mixing materials with different C/N
ratios. A list of C/N ratios for different organic materials is listed in Table 27.1. The
procedure for calculating the amount of mixing material required for adjustment of the
C/N ratio is as follows. If the waste has a carbon content of a (kg of C/kg of wet waste)
and a nitrogen content of b (kg of N/kg of wet waste) and the mixing material has carbon
content c (kg of C/kg of wet waste) and nitrogen content d (kg of N/kg of wet waste), we
can calculate the amount of mixing material required to reach a C/N ratio of e (kgC/kgN):
kg of mixing material a – eb
Mmix,C/N x =
kg of wet waste ed – c
where Mmix, C/N is the amount of mixing material required to adjust the C/N ratio. Again
the final C/N ratio of the mixture must be between the C/N ratios of the mixing material
and the waste otherwise it is not possible to get proper adjustment. Note that the amount
of mixing material that is chosen to add to the waste must satisfy both the C/N ratio and
the water content requirements. This is normally done by calculating the two values of
Mmix, water corresponding to the endpoints of the water content interval (35% and 60%)and
similarly calculating the values of Mmix, C/N corresponding to the two endpoints of C/N
ratio interval (20 and 30). We now have two intervals for the mass of mixing material to
be added per kg of waste. The chosen value must be within both of these intervals in
order to satisfy both the constraints on water content and the C/N ratio. Normally we
wish to use as little mixing material as possible due to economic reasons and we should
therefore choose the smallest value of Mmix that satisfy both intervals. Using too much
mixing material means that more energy is required for composting, as we will have to
compost larger quantities. The mixing material must normally also be bought for instance
from local farmers.
Table 27.1 C/N ratios for different organic materials used in composting. Sources:
Christensen (1998) and Diaz et al. (1996)
Material C/N ratio (g/g)
Cow manure 18
Digested sewage sludge 4 – 28
Food waste 12 – 20
Garden waste 20 – 60
Grass clippings 12 – 20
Horse manure 25
Leaves 20 – 60
Night soil 6 – 10
Vegetable wastes (non-legume) 11 -12
Paper 170 – 800
Pig urine 5–7
Potato tops 25
Poultry manure 15
Raw sewage sludge 10 - 15
Sawdust 200 – 500
Sheep manure 128 – 150
Straw, wheat 120 – 150
Straw, oat 48 – 50
Urine 0.8
Wood chips 400 - 500
Lecture No: 28
28.1. Oxygen concentration:
One of the most important process parameters is the oxygen concentration.
Oxygen concentration is the limiting factor for biological degradation especially in the
early stages of the composting process. If the oxygen concentration is too low, the
process will proceed at a much slower rate resulting in lower temperatures in the
compost. Also low oxygen concentrations are usually the cause of foul odors originating
from organic acids that are produced as a result of anaerobic conditions. Proper oxygen
concentrations can be maintained by turning the compost more frequently or in case
forced aeration is used, by increasing the flow of air through the compost. Frequent
turning or high aeration rates can, however, lead to increased evaporation of water and
decreased compost temperatures. Usually proper turning or aeration levels have to be
determined by trial and error.
28.2. Structure material:
Structure material is usually needed when composting very wet and easily
degradable material such as food waste or sewage sludge in order to maintain a proper
level of air-filled porosity and to prevent liquefaction of the compost piles. Structure
materials often used in composting are straw clippings, wood chips or paper all of which
have high C/N ratios (Table 27.1) and are relatively difficult to degrade. The structure
materials are mixed with the wet organic material and go through the entire composting
process. After the compost is finished the structure material not degraded can be
recovered by sieving. If the structure material is rigid (such as wood chips) its optimal
particle size is 1 – 8 cm. Larger particles do not interfere with the composting process
other than making the handling more difficult. Normally it is not necessary to reduce the
size of wet easily degradable materials. The amount of structure material necessary
depends on the type of organic waste to be composted, the shape of the compost piles etc.
for source separated organic waste from private households the optimal range is 10 –
40% structure material by weight.
28.3. Inoculum:
Inoculum is material containing the microorganisms necessary for initiating the
composting process. Normally an inoculum is not necessary since most types of organic
waste already contain the organisms required for composting. Exemptions are special
materials that are difficult to degrade such as sawdust and bark etc. that will not easily
begin composting on its own. In such cases horse manure, finished compost, or a rich
loamy soil can serve as inoculum as these materials all contain the necessary
microorganisms. Recycling of finished compost, however, require additional space in the
composting facility and can therefore be problematic in some cases.
Lecture No: 29
29.1. Composting technology
The technology used in composting facilities range from very simple windrow
and mattress-composting facilities to highly advanced composting in closed reactors with
automated control of process parameters. Many facilities use a combination of reactor
composting followed by composting in windrows. In many industrialized countries the
development in composting has been toward an increased level in technology partly due
to demands of low odor emission, which is easier to achieve in closed systems with
advanced process control (Christensen, 1998). It is, however, important to bear in mind
that facilities based on advanced technology are not always the best choice. Often the use
of excessive complex systems leads to gross inefficiency (Diaz et al. 1996). It is also
important to select a technology that is adaptable to the economical, technological, and
manpower conditions of the region in which it is to be used. This is especially important
in developing countries where economy and technology are very different. In such
regions a highly sophisticated system may become unworkable due to the lack of skilled
labor and replacement parts. Chances are that a very simple labor-intensive low-
technology system will better serve the purpose. There are several proven types of
technologies available for composting ranging from very simple manual systems to
highly advanced systems. The following sections describe some of the most used
systems.
Composting facilities typically consist of three stages; primary treatment,
composting, and final treatment. The primary treatment usually involves some sort of
separation and screening to remove unwanted materials and ensure a proper particle size.
Primary treatment can also include mixing with structure materials or adjustment of the
C/N ratio pH, or water content. The composting can take place in one process for instance
in a reactor or in open windrows. The process may also be a combination of primary
composting in a reactor for a short period (1 – 3 days ) followed by composting in
windrows for several months. The purpose of the final treatment is to make the compost
ready for marketing or storage. This typically involves screening to 10-15 mm particle
size, hygeinization and in certain cases mixing of different types of compost to adjust the
nutrient (N, P, K) contents of the finished product. Figure 29.1 shows a schematic of the
major components of typical high tech. composting facility.
Fig 29.1. Major components of a typical high technology level composting
facility
29.2. Low technology composting
Low technology composting systems are usually based upon windrow or mattress
composting. These systems require a minimum of technology and skill to operate and are
widely used in many composting facilities throughout the world. The disadvantage of
these low technology systems is that it is difficult to accurately control the process
parameters, temperature, oxygen concentration or water content. The lack of control can
often lead to lower efficiency of the composting process.
29.2.1. Turned windrow composting
The organic material that is to be composted is formed into piles that are roughly
triangular or trapezoidal in cross section. Trapezoidal windrows have the advantage that
the hot zone inside the pile is larger but their drawback is that they are more susceptible
to infiltration by water during rainy periods. Ideally the piles should be about 1.8 to 2 m
high. If manual turning is used they should be no higher than easily reached by the
average laborer. If mechanical turning is used, the machinery used for turning determines
the height and shape of the piles. Another factor determining the height is the moisture
content and compressibility of the organic material. Very wet or easily compacted
material should be laid out in small piles. The width of the piles at the base usually
depends on the method of construction. If manual construction is used the piles should be
about 2.5m wide, in case of mechanical turning they can be as wide as 3-4m. Each pile
should not contain more than approximately one week worth of fresh organic material to
make sure that the entire pile is finished at the same time. The piles are often 20-50m
long depending on the amount of input to the facility. The piles are normally turned 7-10
times over a period of about 15 weeks to ensure aeration and to expose all material to the
high temperatures in the center of the pile. Turning of the piles can be done either manual
or mechanical and should be done in such a manner that the material previously located
at the surface of the old pile should be at the center of the new pile to ensure proper
exposure to high temperature as illustrated in Fig. 29.2. Exposure to high temperatures is
important to reduce or inactivate unwanted or pathogenic organisms contained in the
incoming organic materials. The active composting period in the windrows is usually 1-4
months depending on the type of organic material that is being composted. After the
active composting period, the compost is stored in piles for 2-3 months without turning to
ensure proper stability, i.e., that the microbial activity in the compost material has
reached a level corresponding to natural soils. The course of the composting process is
typically controlled based on temperature and moisture content. If the temperature
decreases due to low moisture contents, the piles are watered. If temperature decreases
due to lack of oxygen, the piles are turned more frequently to increase oxygen
concentration and microbial turnover. Frequent turning in the beginning of the
composting process can also help decrease initially high water contents and reduce odor
problems caused by the development of anaerobic zones within the compost. Aeration of
the compost is accomplished by two mechanisms. Turning mixes fresh air into the
compost and thereby provides oxygen for a relatively short time after the turning. The
other and main mechanism is convection of air upward through the piles caused by the
heating of the air at the center of the piles as illustrated in Fig. 29.3. Because the air
transport through the piles is proportional to the air permeability of the compost and that
the air permeability usually is governed by the air-filled porosity it is important that the
compost is loose, well mixed, and as light as possible. Loosening and mixing of the
compost is achieved through turning of the piles and by maintaining an adequate and not
too high content of water in the compost. Wet compost will have to be turned more
frequently in the beginning of the composting process to reduce the water content to
optimum level. Under normal circumstances the compost will in general have a bulk
density of approximately 0.6 – 0.8 g/cm3 and a solids density of approximately 0.8-
1.2g/cm3 depending on the type of material being composted. After the active composting
period, the compost is stored in piles for 2-3 months without turning to ensure proper
stability, i.e., that the microbial activity in the compost material has reached a level
corresponding to natural soils.
Fig 29.3. Convective air transport in turned windrows caused by heating of air
Fig. 29.4. Components of a composting system using the static pile or forced
aeration technology
29.2.3. Mattress composting
Mattress composting is a very simple technology that is especially suitable for
yard and park waste, i.e., plant residues and tree branches etc. the mattress composting
process usually takes significantly longer than both turned and static windrow
composting due to the construction and operation of the mattress.
The mattress composting process typically follows three phases that are defined
based on application of technology rather than on the progress of the microbial processes
in the composting material.
1) Pre-treatment of material, construction of mattress and pre-composting
2) Composting of material
3) Screening and marketing of finished compost
During phase I the organic material is placed on the mattress in thin layers about 20 to 40
cm thick. Each layer is treated with a crushing device typically mounted on a tractor (pre-
treatment). This is done in order break the surface of the materials to free cell fluids and
accelerate the microbial degradation processes. The purpose of the pre-treatment is not to
cut the material to small pieces rather material such as tree branches are to retain their
structure and only their surface is to be broken. It is important not to destroy the structure
of the material, as the structure of the mattress is necessary to ensure adequate air
transport within the mattress. The air transport can be improved by constructing the lower
layers of the mattress of coarser materials as illustrated in Fig 29.5.
Fig 29.5. Construction of a mattress with the coarser material in the bottom layers
using a tractor with mounted crushing device
The construction of the mattress progresses by continuously applying layer after layer of
organic material until the mattress is approximately 2 to 6 m high. The height of the
mattress can be varied depending on the space available but a height of 2 to 6 m has been
used widely. The higher the mattress the more difficult control and monitoring of the
composting process becomes. During the construction of the mattress the temperature
will rise proportional to the thickness of the mattress due to initiation of the microbial
degradation in the already finished layers. The temperature in the mattress can be
controlled to ensure that a broad range of microorganisms is active in the mattress. The
optimum temperature during phase I is approximately 50 oC. The temperature is the only
parameter that in practice can be used for control of process. If the temperature is too low
the mattress can be irrigated to increase the microbial activity. The aeration of the
mattress is controlled by advection similar to that of turned windrow composting. Phase
1, i.e., the mattress construction and pre-composting at 50oC can take from 3 months up
to approximately one year.
At the beginning of phase 2 the mattress is usually rebuilt using a tractor or
bulldozer to ensure homogeneity of the materials. The mattress may actually be “turned”
several times during the composting phase. During this phase the temperature can rise to
approximately 70oC. Again the process can be controlled by monitoring the temperature
and applying water if the temperature decreases. If the mattress is moist enough but the
transport of air through the mattress is inadequate the upper layers of the mattress can be
loosened using the tractor, or alternatively the whole mattress cn be reconstructed. The
phase 2 composting takes from 8 to 12 months typically. When the composting phase is
nearing its end, the microbial activity and temperature will start to decrease and the
temperature will reach about 40oC.At this point the composted material is typically
screened (phase 3) and perhaps mixed with other types of compost to adjust nitrogen and
phosphorous content and then stored for later marketing. The screening material (large
branches etc.) is normally used in the construction of new mattress.
Because it is difficult to actively control temperature and microbial degradation
rate in the mattress this type of composting technology is best suited for composting of
materials that are not contaminated with pathogens, i.e., hazardous viruses or bacteria that
usually needs high temperatures to be inactivated or destroyed.
29.3. Site preparation for open systems
Often some sort of site preparation is required before composting can be initiated.
In many cases a hard surface (concrete or asphalt)is established to facilitate easy
movement of machinery and compost piles, if the facility is not operated under a roof
larger quantities to leachate are likely to be generated due to precipitation. This is
especially a problem in regions with high levels of rainfall. In such cases a membrane and
drainage system to collect the leachate and prevent contamination of the groundwater can
be necessary. The collected leachate is usually either recycled for irrigation of the
compost piles or discharged to a wastewater treatment facility. The actual requirements
with respect to site preparation depend on the composting technology used and on the
legal requirements with respect to generation of odor, leachate and other environmental
impacts.
Lecture No: 30
30.1. Composting in closed reactors.
A wide range of composting systems employing closed reactors in which the
composting process takes place has been proposed. In general reactor systems can be
divided into two main categories, (a) systems where the reactor itself is stationary and the
compost is mixed using devices mounted inside the reactor, and (b) moving reactors
where the movement of the reactor provides the mechanical action necessary for mixing
and turning the compost. Reactor systems often employ forced aeration where the air
typically is supplied at the outlet end of the reactor and moves in the opposite direction of
the compost flow inside the reactor.
Classical examples of stationary systems are tunnel reactors and tower reactors.
Examples of these types of reactors are illustrated schematically in Fig. 30.1 and 30.2
respectively. An example of a moving reactor system is the drum reactor. The principle in
this system is illustrated in Fig. 29.1. One of the advantages of reactor composting is that
it is easier to control the process parameters (water content, aeration, and temperature)
thereby ensuring maximum performance of the composting process. Also it is generally
possible to maintain higher temperatures in closed reactors. The composting process will
generally proceed faster in a reactor than in an open windrow system and it is possible to
ensure better hygienization of the compost (inactivation of pathogens). In Denmark
hygienization of compost produced in a reactor is not required to undergo further
hygienization if it is documented that the temperature inside the reactor has been above
70oC for at least one hour, which for most reactor systems is easy to achieve. The
composting time required in reactor systems is typically on the order of weeks where
months usually are required for simple open systems. It is also much easier to control and
minimize environmental problems such as odor or spreading of pathogens in the near
space. On the other hand are reactor systems in general much more expensive to
construct, maintain and operate as compared to the simple mattress or windrow systems.
Reactors are often used in combined systems where the pre-composting (initial phase)
takes place in a reactor (typically a rotating drum) over a period of a few days. The
organic material is then deposited in open windrows where the remainder of the
composting process takes place. The purpose of the reactor in this type of system is to
initiate the composting process and to ensure that the organic materials are properly
mixed before they are put into windrows. Also most of the odor problems are associated
with the initial phase and they are easily taken care of by cleaning the exit air from the
reactor in bio filter.
Where ▲P = atmospheres, MO2 = molecular weight of O2, PO2 = oxygen partial pressure
in the atmosphere, Vflask and Vcompost = volumes of flask and compost sample in liters, R=
universal gas constant (litre atm./mole degrees K), T= absolute temperature (K), and
Wcompost = dry mass of the compost organic matter (g).
Lecture No: 32
32.1. Self –heating capacity:
The basis for the self-heating test is that biological activity associated with
decomposition of any decomposable organic material present in the compost will produce
heat and thus increase the compost temperature. A handful of adequately moist compost
is placed in a 1.5 liter. Dewar bottle (thermo flask) and a thermometer is placed in the
compost. The temperature is measured at intervals over a period of 10 days and the
maximum temperature is taken as measure of the stability of the compost.
Soluble organic carbon to soluble organic nitrogen ratio: The basis for this
parameter is that mature compost will contain less water-soluble organic carbon relative
to water-soluble organic nitrogen compared to raw and fresh compost. The compost is
shaken with water at a liquid-solid ratio of 20 (20 g H2O per g dry matter) for 2 hours and
the supernatant is analyzed for water-soluble organic carbon (non-volatile organic
carbon) and water-soluble organic nitrogen (total nitrogen minus ammonia nitrogen and
nitrate nitrogen). If the ratio of organic carbon to organic nitrogen is greater than 7 the
compost is raw.
It is important that the compost used for testing is adequately moist, as compost
that is too dry may appear stable because the biological activity on which the above tests
are based will be minimal at low water contents. Values of the test parameters (oxygen
demand, self heating and organic C to organic N ratio) and the corresponding level of
compost stability for each of the above tests are listed in Table 32.1.
Table 32.1. Methods for evaluating the level of compost stability (Christensen 1998)
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Degree of stability Raw Fresh Stable Very stable
O2 demand (mg/Gvs) >40 20 – 40 10 – 19 <10
Self demand >60 40 – 60 30 – 39 20 – 29
Org. C/org. N >7 <7 <7 n/a
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Lecture No: 33
Composting examples
The following sections presents two different types of composting plants. In Vejle
biodegradable municipal wastes and garden wastes are composted separately using static
pile aeration and open turned windrows respectively. In Odense sewage sludge is
composted in open turned windrows with straw as structure material.
Fig 34.1. Degradation of NPE, LAS, PAH and DEHP at a windrow compost
facility in Odense, Denm