PUNJAB COLLEGE OF SCIENCE LAHORE

SUBJECT: CHEMISTRY
MCAT Past Paper of Chemistry :

1) it is experimentally found a) lower the b) increase the c) lower d) decrease the temperature of other reactants

that

catalyst activation activation the

is

used

to energy energy pH

2) carbon exists as allotropes, which are different crystalline molecular forms of the same substance. Graphite and diamond are allotropes of carbon. Diamond is non-conductor while graphite is conductor because a) graphite has a layered structure b) in graphite all valence electrons are tetrahedrally bounded c) in graphite one of the valence electron is free to move d) graphite is soft and greasy 3) when the elements of group 2A are exposed to air , they quickly become coated with layer of oxide. What is the purpose of this oxide layer a) the oxide layer exposes the metal to atmospheric attack b) the oxide layer increases the reactivity of metal c) the oxide layer protects the metal from further attack d) the oxide layer gives the metal a shiny look 4) hydrogenation a) b) c) d) copper of finally finally unsaturated vanadium the stable are ligand more correct than ordinary stable than form conversion of SO2 to oils is divided divided done by using nickel iron pentaoxide statement complexes chelates chelate SO3 is oxide oxide dioxide

5) tick a) chelates are more b) ordinary complexes c) monodentate d) chelates have no ring structure 6) in contact process a) b) c) d) vanadium pentaoxide the

catalyst used for magnesium Aluminium silicon

7) the unpolluted rain water is a) b) oxides c) d) hydrocarbons present in air 8) the compound with a) b) c) d) none of these an atom

slightly acidic Sulphur carbon which has

due to reaction of

of rain water with dioxide nitrogen dioxide is called nucleophile electrophile protophile

an unshared

pair of electron

9) 1-chloropropane and 2-chloropropane are isomers of each other. The type of isomerism between them is a) Cis-trans isomerism b) chain isomerism c) positional isomerism d) functional group isomerism 10) benzene a) b) c) d) ethanoic acid in presence of ACl3 gives acetyl acetic ethyl group by NO2 acetophenone when reacts with chloride acid benzene

11) the substitution a) b) c) d) reduction of benzene

of

group

in

benzene

called nitration ammonolusis sulphonation

is

12) when purely alcoholic solution of sodium/potassium hydroxide and halogenalkane are refluxed an alkene is formed : CH3-CH2-Br (in presence of alcoholic KOH )--> CH2=CH2 what is the mechanism of the reaction a) elimination b) dehydration c) debromination d) nucleophilic substitution 13) organic a) b)solvent c) d) plastic compound carbon tetra chloride is used as lubricant oxidant

14) an alcohol is converted into an aldehyde with same number of carbon atoms in the presence of K2CrO4/H2SO4 . the alcohol is a) CH2C(CH)2OH b)CH3CH2CH2OH c)(CH3)3COH d)(CH3)2CHOH 2

15)in the mass spectrometer ; a)masses b)percentages c)relative abundances d)mass numbers of isotopes 16)how many chlorine a)2 x b)35.5 x c)2x10^23 d)2x6.02x10^22 atoms atoms

detector of of

or

collector of

measures

the : isotopes isotopes isotopes Cl : atoms atoms atoms

are

in 2 6.022x10^23 6.022x10^23

moles

of

17)boiling point of water is higher than petrol , because intermolecular forces in water are : a)weaker than petrol b)stronger than petrol c)same as in petrol d)negligible 18)DNA molecule is double stranded , in which two chains of DNA are twisted around each other by: a)hydrogen bonds b)Van der Waal's forces c)covalent bonds d)dative bonds 19)the elements for a)gain b) gain C)lose d) lose electron readily which the value of electrons electrons ionization less energy is low can: readily difficulty readily : tube tube tube

with

electron

20)the nature of cathode rays in discharge tube a)depends upon the nature of the gas used in discharge b) depends upon the nature of the cathode used in discharge c)is independent of the nature of the gas used in discharge d) depends upon the nature of anode in the discharge tube

21)the ability of the atom in the covalent bond to attract the bonding electrons is called: a)ionization energy b)ionic bond energy c)electronegativity d)electron affinity 22)the paramagnetic character of substances A)bond pairs b)lone pairs c)unpaired electrons in the d)paired electrons in the valence shell of atoms 23)lattice energy a)combustion b)dissociation of an ionic is due to of of atom is the or the presence of : electrons electrons molecule of:

crystal

enthalpy

c)dissolution d)formation 24)mole fraction of any component is the ratio of moles of all components in a: a)compounds b)solution c)molecule d)solid 25)molarity is defined as the number of moles of solute of any substance dissolved: a)per dm^3 of water b)in one g of water c)per m^3 of water d)in 100 ml of water 26)in electrolytic cell a salt a)pass the b)prevent the c)mix solutions of d)allow movement of ions b/w two cells bridge flow two is used electric in of half order to : current ions cells

27)if in AgCl solution , some salt of NaCl is added , AgCl will be precipitated due to : a)solubility b)electrolyte c)un saturation effect d)common ion effect 28)if Ka for an acid is higher , the stronger is the acid , relate the strength of acid with a)higher pKa , weaker the b)lower pKa , stronger the c)pKa has no relation with the strength of an d)both a and b pKa: acid acid acid

29)according to the collision theory of bimolecular reactions in gas phase , minimum amount of energy required for an effective collision is known as : a)heat of reaction b)rate of reaction c)has no effect on the reaction d)energy of activation 30) consider R-CHO + 2[Ag(NH3))2]OH ----this reaction represents a) b) c) d) tollen's test the > RCOONH4 which of Fehling benedict ninhydrin + following 2Ag + 2NH3 the following reaction: + H2O tests test test test

31) a polymer in which the number of amino acid residue is greater than 100 or the molecular mass is greater than 10,000 is called a) protein b) polypeptide 4

c) d) tripeptide

dipeptide

32) when hexanedioic acid is heated with hexamethylenediamine the compound formed is a) polypeptide b) ester c) addition polymer d) nylon 6,6 33) glucose a) pentoses b) c) d) butoses 34) the reaction a) b) c) d) saponification between fats and caustic soda and fructose are common example of hexoses heptoses is called hydrogenolysis fermentation carboxylation

35) macromolecules are defined as large molecules built up from small repeating units called a) monomers b) isomers c) metamers d) tautomers 36) PVC a) b) c) d) thermosetting polymer 37) Terylene, a) b) c) d) addition polymer a is addition condensation an example of polymer polymer biopolymer of biopolymer lipids polymer

polyester condensation

is

an

example

38) the suspected liver carcinogenic which also has a negative reproduction and developmental effects in human is a) iodoform b) bromoform c) chloroform d) tropoform 39) peroxyacetylene a) b) c) d) stomach is an irritant to human beings and it effects ears eyes nose

40) which a) b) c) d) diastase

enzyme

is

involved

in

fermentation

of

glucose? zymase invertase urease acids is water alcohol water surrounding same increases decreases

41) relative acidic strength of alcohol , phenol a) carboxylic acid > alcohol b) carboxylic acid > phenol c) phenol > carboxylic acid d) water > phenol > alcohol > carboxylic acid 42) in standard a) b) c) d) increases then decreases enthalpy

, > > >

water

and carboxylic phenol > water > alcohol > heat of

of atmomization remains

43) in all oxidation reactions, atoms of an element in a chemical species lose electrons and increases their a) oxidation state b) reduction states c) electrode d) negative charges 44) in Haber process for a) proteins b) ammonium c) d) minerals containing nitrates manufacturing occurring salts of ammonia , nitrogen in living obtained is taken from bodies industrially air

45) in comparison to oxygen gas a strong triple covalent bond is present between nitrogen atoms in a molecule and therefore nitrogen gas is: a) highly reactive gas b) completely inert like noble gases c) very less reactive gas d) moderately reactive gas 46) a) b) amino group c) d) peptide linkage 47) which a) b) c) d) alanine of the the NH-CO amide protein following has an amino R group is called group linkage group lysine proline valine

ECAT English Syllabus :

Error Detection Correct/Incorrect Direct/Indirect Active Passive Voice Punctuation Jumbled Sentences Synonyms Sentence Completion Reading Comprehension.

ECAT Chemistry Syllabus :

Basic Concepts Experimental Techniques in Chemistry Gases, Liquid and Solids Atomic Structure Chemical Bonding Thermo chemistry Chemical Equilibrium Solutions Electrochemistry Reaction Kinetics Periodic Classification of Elements and Periodicity s-Block Elements Group IIIA and Group VIA Elements The Halogens and the Noble Gases Transition Elements Fundamental Principles of Organic Chemistry Aliphatic Hydrocarbons Aromatic Hydrocarbons Alkyl Halides Alcohols Phenols and Ethers Aldehydes and Ketons Carboxylic Acids Macromolecules Common Chemical Industries Environmental Chemistry

ECAT Mathematics Syllabus :

Part One 7

Number System Sets Functions and Groups Matrices and Determinants Quadratic Equation Partial Fraction Sequence and Series Permutation Combination and Probability Mathematical Induction and Binomial Theorem Fundamental of Trigonometry Trigonometric Identities Trigonometric Functions and their Graphs Application of Trigonometry Inverse Trigonometric Functions Solutions of Trigonometric Equation.

Part Two

Functions and Limits Differentiation Integration Introduction to Analytic Geometry Linear Inequalities and Linear Programming Conic Section Vectors.

ECAT Physics Syllabus :

MeasurementVectors and Equilibrium Motion and Force Work, Circular Motion Fluid Dynamics Oscillations Waves Physical Optics Heat and Thermodynamics Electrostatics Current Electricity Electromagnetism Electromagnetism Induction Alternating Current Physics of Solids

Electronics Dawn of Modern Physics Atomic Spectra Nuclear Physics.